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http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/67859
Title: | 以醯胺鍵合成內鎖[c3]與[c4]雛菊鏈之研究 Interlocking [c3]- and [c4]Daisy Chain by Amidation |
Authors: | Chun Hung 洪群 |
Advisor: | 邱勝賢(Sheng-Hsien Chiu) |
Keyword: | 醯胺鍵,內鎖,雛菊鏈, Interlocking,Daisy Chain,Amidation, |
Publication Year : | 2017 |
Degree: | 碩士 |
Abstract: | 利用單體分子本身結構的剛性與配位金屬的方向性,我們可以在溶液中進行 [c3]與[c4]雛菊鏈的選擇性自組裝。有別於以往利用苯胺與異氰酸酯的內鎖反應,本研究希望以苯胺與醯胺化反應來合成內鎖的高階雛菊鏈,以利未來合成出複雜度更高的結構。 In this research, molecular daisy chains were synthesized using structure rigidity, coordination geometries and bond rotational barriers to selectively form [c3] or [c4]daisy chains. Differ from the previous work, these daisy chains were synthesized through amide formation by introducing an aldehyde- or amine-group on the stopper. This approach opens a new perspective for the synthesis of even more complicated structures. |
URI: | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/67859 |
DOI: | 10.6342/NTU201701789 |
Fulltext Rights: | 有償授權 |
Appears in Collections: | 化學系 |
Files in This Item:
File | Size | Format | |
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ntu-106-1.pdf Restricted Access | 7.22 MB | Adobe PDF |
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