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http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/44281| Title: | 超枝化三苯胺高分子的合成與性質研究 Synthesis and Characterization of Hyperbranched-Triphenylamine polymers |
| Authors: | Yi-Ting Wu 吳易庭 |
| Advisor: | 梁文傑(Man-kit Leung) |
| Keyword: | 亞甲基三苯胺,親電取代反應,異丙基三苯胺,超枝化三苯胺., hyperbranched,triphenylamine,methylene-triphenylamine,isopropyl triphenylamine., |
| Publication Year : | 2009 |
| Degree: | 碩士 |
| Abstract: | 我們利用亞甲基三苯胺活性中間體之親電取代反應進行超枝化三苯胺高分子之合成。在本論文中，我們將研究產生亞甲基三苯胺活性中間體之不同合成方法，以及對其聚合反應的影響。此外，我們也改變亞甲基三苯胺活性體上的取代基，對聚合反應之影響進行探討，並且利用相同原理合成異丙基三苯胺聚合物，並針對合成之聚合物之光學性質及熱性質進行探討。 In this paper, we synthesize hyperbranched-triphenylamine polymer by electrophilic substitution reaction of methylene-triphenylamine cation. We use different method to synthesize methylene-triphenylamine cation, and discuss the influence on polymerization.We also synthesize isopropyl triphenylamine polymer by isopropyl triphenylamine cation. The photophysical and thermo properties of these polymers have been explored. |
| URI: | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/44281 |
| Fulltext Rights: | 有償授權 |
| Appears in Collections: | 化學系 |
Files in This Item:
| File | Size | Format | |
|---|---|---|---|
| ntu-98-1.pdf Restricted Access | 5.28 MB | Adobe PDF |
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