以CTV為基礎之分子容器合成研究

Abstract

有別於實驗室之前發展的籠狀分子，我們合成出新的以CTV (Cyclotirveratrylene，環三聚藜烴)為基礎的分子容器1。我們將分子1與一系列的客體分子進行鍵結的測試，希望找出合適的客體分子，以便將之封鎖於分子籠子中。由於CTV在溶液中與客體分子結合的傾向甚為微弱，截至目前，我們在客體分子的尋覓上尚未有所突破。

Herein, we’ve synthesized new molecular hosts 1 in order to develop new molecular systems differing from our previous molecular hosts. The cyclotriveratrylene-based molecular container is more complex and more challenge than ones before. First, we tended to use molecular hosts 1 to achieve encapsulation of proper guests by chemical reactions to lock in it. Up to now, we’ve not found any proper guests fitting in the molecular host 1 because the binding ability is weaker in the solution phase than in the solid phase.