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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 邱勝賢 | |
| dc.contributor.author | Ming-Jhe Li | en |
| dc.contributor.author | 李明哲 | zh_TW |
| dc.date.accessioned | 2021-06-14T17:19:31Z | - |
| dc.date.available | 2010-08-05 | |
| dc.date.copyright | 2008-08-05 | |
| dc.date.issued | 2008 | |
| dc.date.submitted | 2008-07-24 | |
| dc.identifier.citation | 1. (a) Nicolaou, K. C.; Vourloumis, D.; Winssinger, N.; Baran, P. S. Angew. Chem. Int. Ed. 2000, 39, 44–122.
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/41139 | - |
| dc.description.abstract | 有別於實驗室之前發展的籠狀分子，我們合成出新的以CTV (Cyclotirveratrylene，環三聚藜烴)為基礎的分子容器1。我們將分子1與一系列的客體分子進行鍵結的測試，希望找出合適的客體分子，以便將之封鎖於分子籠子中。由於CTV在溶液中與客體分子結合的傾向甚為微弱，截至目前，我們在客體分子的尋覓上尚未有所突破。 | zh_TW |
| dc.description.abstract | Herein, we’ve synthesized new molecular hosts 1 in order to develop new molecular systems differing from our previous molecular hosts. The cyclotriveratrylene-based molecular container is more complex and more challenge than ones before. First, we tended to use molecular hosts 1 to achieve encapsulation of proper guests by chemical reactions to lock in it. Up to now, we’ve not found any proper guests fitting in the molecular host 1 because the binding ability is weaker in the solution phase than in the solid phase. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-14T17:19:31Z (GMT). No. of bitstreams: 1 ntu-97-R95223075-1.pdf: 2227946 bytes, checksum: ea18b8dbe6df2b0ac9f1a428da7eaf3d (MD5) Previous issue date: 2008 | en |
| dc.description.tableofcontents | 謝誌…………………………………………………………………I
中文摘要……………………………………………………………II 英文摘要…………………………………………………………III 目次………………………………………………………………IV 圖表…………………………………………………………………VI 流程…………………………………………………………………IX 表格…………………………………………………………………X 壹、導論………………………………………………………………1 1.1 前言………………………………………………………………1 1.2 超分子化學的發展與冠醚的起源………………………………3 1.3 超分子系統………………………………………………………6 1.3.1 主客化學 (Host-guest chemistry) ………………………6 1.3.2 準車輪烷 ( Psudorotaxane ) ……………………………7 1.3.2a DB24C8和DBA+的系統 ………………………………………9 1.3.2b DB24C8和BPE的系統 ………………………………………9 1.3.2c 三維立體結構的冠醚分子 …………………………………10 1.4 環三聚藜烴相關文獻與應用……………………………………11 1.5 環三聚藜烴衍生物的合成方法及應用…………………………15 1.5.1 環三聚藜烴衍生物合成………………………………………15 1.5.2 環三聚藜烴衍生物的應用……………………………………16 1.5.3 總結……………………………………………………………19 1.6 分子監獄 ( Carcerand ) 簡介 ………………………………20 1.6.1 Carcerand 相關文獻報導……………………………………20 貳、結果與討論………………………………………………………22 2.1 研究動機…………………………………………………………22 2.2 目標分子的合成…………………………………………………24 2.3 鍵結測試…………………………………………………………28 參、結論………………………………………………………………35 肆、實驗部份 …………………………………………………………36 伍、參考文獻 …………………………………………………………46 陸、附錄 1H-NMR與 13C-NMR 核磁共振光譜 ………………………50 | |
| dc.language.iso | zh-TW | |
| dc.title | 以CTV為基礎之分子容器合成研究 | zh_TW |
| dc.title | Synthesis of Molecular Container Based on CTV | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 96-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 徐秀福,賴建成 | |
| dc.subject.keyword | 冠醚,環三聚藜烴,分子監獄, | zh_TW |
| dc.subject.keyword | crown ether,CTV,carcerand, | en |
| dc.relation.page | 50 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2008-07-27 | |
| dc.contributor.author-college | 理學院 | zh_TW |
| dc.contributor.author-dept | 化學研究所 | zh_TW |
| 顯示於系所單位： | 化學系 | |
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