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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 劉振良 | zh_TW |
| dc.contributor.advisor | Cheng-Liang Liu | en |
| dc.contributor.author | 吳維妮 | zh_TW |
| dc.contributor.author | Wei-Ni Wu | en |
| dc.date.accessioned | 2025-09-10T16:15:00Z | - |
| dc.date.available | 2025-09-11 | - |
| dc.date.copyright | 2025-09-10 | - |
| dc.date.issued | 2025 | - |
| dc.date.submitted | 2025-07-24 | - |
| dc.identifier.citation | 1. Bell, L. E., Cooling, Heating, Generating Power, and Recovering Waste Heat with Thermoelectric Systems. Science 2008, 321 (5895), 1457-1461.
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Mater. 2020, 32 (30), 2002060. | - |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/99425 | - |
| dc.description.abstract | 熱電材料可直接將熱能轉換為電能，為收集低階廢熱提供了一項相當具有前途的解決途徑。在各種熱電材料系統中，有機共軛高分子因其固有的柔軟性和低熱傳導係數受到越來越多的關注。然而，目前尚對其分子結構與各項性質(如材料的介面性質、熱電性能、與機械性能)之間的關係瞭解不足，導致這類材料的應用仍受到限制。本論文透過三個研究項目，探討分子設計策略對於熱電性能及薄膜拉伸性的影響，期望提供對於分子層面的瞭解。
第一項研究利用由共軛的聚(3-己基噻吩) (P3HT)與絕緣的聚(丙烯酸正丁酯) (PnBA)組成的金屬超分子嵌段高分子，著重探討嵌段結構如何影響高分子奈米級形貌、摻雜效率以及摻雜高分子薄膜的拉伸性。 第二項研究為拓展對於三(五氟苯基)硼烷(BCF)布忍斯特酸摻雜效果的應用與瞭解，利用聚[3,4-二(2-乙基己基)噻吩乙烯] (P3,4EHTV)、聚[3-(2-乙基己基)噻吩乙烯] (P3EHTV)和聚[3-(乙基己基)噻吩] (P3EHT)三種共軛高分子，以探討高分子共軛主鏈和側鏈工程對於摻雜行為和電荷傳輸的影響。 第三項研究開發了一系列以P3,4EHTV為基礎的二嵌段高分子，其中結合了不同極性的絕緣鏈段(聚環氧乙烷(PEO)、聚苯乙烯(PS)和聚五氟苯乙烯(PFS))，以控制高分子的聚集結構並改善單壁奈米碳管(SWCNT)在高分子溶液中的分散。本研究利用溶液態散射和光譜分析，探討高分子聚集結構對於材料介面的相互作用及奈米碳管分散性，以及進一步探討介面作用力對於複合物薄膜的拉伸性。 這些研究共同為下一代軟性熱電材料應用提供了結構與性能相互關係的觀點，以及提供了開發高性能和可拉伸的有機熱電材料的材料設計準則及方向。 | zh_TW |
| dc.description.abstract | Thermoelectric materials, which enable direct conversion of heat into electricity, offer a promising route for harvesting low-grade thermal energy. Among various thermoelectric systems, organic conjugated polymers (CPs) have attracted increasing attention due to their intrinsic mechanical flexibility and low thermal conductivity. However, their widespread application remains limited by insufficient molecular-level understanding of the structure–property relationships that govern thermoelectric performance, mechanical stretchability, and interfacial behavior across diverse material systems. This thesis addresses these challenges through three thematically connected studies that explore molecular design strategies to improve the performance and understanding of polymer-based thermoelectric systems.
The first study investigates metallo-supramolecular block copolymers composed of poly(3-hexylthiophene) (P3HT) and poly(n-butyl acrylate) (PnBA), focusing on how block architecture modulates nanoscale morphology, doping efficiency, and mechanical deformability of the doped polymer thin films. The second study examines Brønsted acid doping effect using tris(pentafluorophenyl)borane (BCF) in poly[3,4-di(2-ethylhexyl)thienylene vinylene] (P3,4EHTV), and compares its behavior to poly[3-(2-ethylhexyl)thienylene vinylene] (P3EHTV) and poly[3-(ethylhexyl)thiophene] (P3EHT). This project amins to reveal how molecular engineering in polymer backbone and side chain influence doping behavior and charge transport property. The third study develops a series of P3,4EHTV-based diblock copolymers incorporating insulating blocks of varying hydrophobicity (poly(ethylene oxide) (PEO), polystyrene (PS), and poly(pentafluorostyrene) (PFS)) to control polymer aggregation and enhance single-walled carbon nanotube (SWCNT) dispersion. Using solution-state scattering and spectroscopic analysis, this work establishes how aggregation structure impacts interfacial interactions, SWCNT dispersion, and strain tolerance in composite thin films. Together, these studies offer structure–property perspectives and guiding principles for the rational design of high-performance, stretchable organic thermoelectric materials for next-generation soft energy harvesting applications. | en |
| dc.description.provenance | Submitted by admin ntu (admin@lib.ntu.edu.tw) on 2025-09-10T16:15:00Z No. of bitstreams: 0 | en |
| dc.description.provenance | Made available in DSpace on 2025-09-10T16:15:00Z (GMT). No. of bitstreams: 0 | en |
| dc.description.tableofcontents | 口試委員會審定書 i
Acknowledgements iii 摘要 v Abstract vii Table of Contents ix Lists of Figures xii Lists of Tables xviii Chapter 1 Introduction 1 1.1 Introduction of Thermoelectricity 1 1.2 Doping of Conjugated Polymers 7 1.2.1 Doping Mechanisms 7 1.2.2 Common p-type Dopants 9 1.2.3 Doping Methods 11 1.2.4 Polymer Design Strategies for Doping 13 1.3 Incorporation of Carbon Nanotubes in Conjugated Polymers 20 1.3.1 Polymer Design Strategies for CP/CNT Composites 22 1.3.2 Role of Polymer Aggregation in CNT Dispersion 24 1.4 Development of Stretchable Thermoelectrics 27 1.4.1 Molecular Design Strategies for Stretchable Doped Polymers 27 1.4.2 Strategies for Stretchable CNT-Based Composites 30 1.5 Research Objectives 32 Chapter 2 General Methods 35 2.1 Materials 35 2.1.1 Conjugated Polymers 35 2.1.2 Other Chemicals and Materials 38 2.2 Fabrication Procedures 39 2.2.1 Project 1: Stretchable Block Copolymer Thin Films 39 2.2.2 Project 2: BCF-Doped Polythiophene Derivatives 40 2.2.3 Project 3: CP/SWCNT Composite Thin Films 41 2.2.4 Fabrication of Stretchable Thermoelectric Films 42 2.3 Characterization Methods 43 2.3.1 Thermoelectric Property Measurements 43 2.3.2 Spectroscopic Characterizations 44 2.3.3 Morphological Characterization 45 2.3.4 Scattering Analyses 46 Chapter 3 Developing Stretchable Multiblock Copolymers Based on Conjugated Poly(3-hexylthiophene) and Insulating Poly(n-butyl acrylate) 47 3.1 Research Background 47 3.2 Results and Discussion 50 3.2.1 Characterizations of Pristine Polymers 50 3.2.2 Thermoelectric Properties of Doped Polymer Thin Films 58 3.2.3 Spectroscopic Studies on Doping Behaviors 60 3.2.4 Morphology and Microstructure of Doped Polymer Thin Films. 68 3.2.5 Stretchability Evaluation of Doped Polymer Films. 75 3.2.6 Thermoelectric Properties under Mechanical Strain 80 3.3 Conclusion 85 Chapter 4 Investigating Brønsted Acid Doping in Poly(thienylene vinylene) 87 4.1 Research Background 87 4.2 Results and Discussion 89 4.2.1 Characterizations of Undoped Polymers 89 4.2.2 Spectroscopic Studies on Doping Behavior 92 4.2.3 Morphology and Microstructure of Doped Polymer Films 100 4.2.4 Thermoelectric Properties of Doped Polymer Films 105 4.2.5 Comparison with Low-Molecular-Weight Analogue P3EHTV 112 4.3 Conclusion 115 Chapter 5 Controlling Aggregation of Poly(thienylene vinylene)-Based Diblock Copolymers for Improved Single-Walled Carbon Nanotube Dispersion 117 5.1 Research Background 117 5.2 Results and Discussion 120 5.2.1 Morphology and Microstructure of CP/SWCNT Composite Thin Films 120 5.2.2 Characterization of Solution-State Polymer Aggregation 125 5.2.3 Characterization of SWCNT Suspension Stability 129 5.2.4 Proposed Mechanisms of SWCNT Debundling 131 5.2.5 Spectroscopic Studies on CP/SWCNT Composites 133 5.2.6 Thermoelectric Properties of Composite Thin Films 139 5.2.7 Polarity Switching in the P1/SWCNT 141 5.2.8 Effect of PS Block Length on CP/SWCNT Composites 144 5.2.9 Stretchability Assessment of Composite Thin Films 150 5.3 Conclusion 154 Chapter 6 Conclusion and Future Outlook 157 6.1 Overall Conclusion 157 6.2 Future Outlook 160 References 165 Biography 177 Publications and Presentations 178 | - |
| dc.language.iso | en | - |
| dc.subject | 有機熱電材料 | zh_TW |
| dc.subject | 共軛高分子 | zh_TW |
| dc.subject | 分子摻雜 | zh_TW |
| dc.subject | 奈米碳管複合物 | zh_TW |
| dc.subject | 結構-性能相互關係 | zh_TW |
| dc.subject | 可拉伸電子元件 | zh_TW |
| dc.subject | molecular doping | en |
| dc.subject | organic thermoelectric materials | en |
| dc.subject | stretchable electronics | en |
| dc.subject | structure–property relationships | en |
| dc.subject | carbon nanotube composites | en |
| dc.subject | conjugated polymers | en |
| dc.title | 共軛高分子熱電材料的結構設計與機制探討 | zh_TW |
| dc.title | Structural Design and Mechanistic Insights for Conjugated Polymer-Based Thermoelectrics | en |
| dc.type | Thesis | - |
| dc.date.schoolyear | 113-2 | - |
| dc.description.degree | 博士 | - |
| dc.contributor.oralexamcommittee | 詹益慈;童世煌;陳銘洲;鄭彥如 | zh_TW |
| dc.contributor.oralexamcommittee | Yi-Tsu Chan;Shih-Huang Tung;Ming-Chou Chen;Yen-Ju Cheng | en |
| dc.subject.keyword | 有機熱電材料,共軛高分子,分子摻雜,奈米碳管複合物,結構-性能相互關係,可拉伸電子元件, | zh_TW |
| dc.subject.keyword | organic thermoelectric materials,conjugated polymers,molecular doping,carbon nanotube composites,structure–property relationships,stretchable electronics, | en |
| dc.relation.page | 180 | - |
| dc.identifier.doi | 10.6342/NTU202502187 | - |
| dc.rights.note | 同意授權(限校園內公開) | - |
| dc.date.accepted | 2025-07-28 | - |
| dc.contributor.author-college | 工學院 | - |
| dc.contributor.author-dept | 材料科學與工程學系 | - |
| dc.date.embargo-lift | 2030-07-23 | - |
| 顯示於系所單位： | 材料科學與工程學系 | |
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