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http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/99277完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 劉振良 | zh_TW |
| dc.contributor.advisor | Cheng-Liang Liu | en |
| dc.contributor.author | 鄭羽媗 | zh_TW |
| dc.contributor.author | Yu-Syuan Jheng | en |
| dc.date.accessioned | 2025-08-21T17:05:39Z | - |
| dc.date.available | 2025-08-26 | - |
| dc.date.copyright | 2025-08-21 | - |
| dc.date.issued | 2025 | - |
| dc.date.submitted | 2025-07-31 | - |
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Mater. 2017, 3 (4), 1700013. DOI: https://doi.org/10.1002/aelm.201700013. (123) Yang, X.; Tian, Y.; Wu, B.; Jia, W.; Hou, C.; Zhang, Q.; Li, Y.; Wang, H. High-Performance Ionic Thermoelectric Supercapacitor for Integrated Energy Conversion-Storage. Energy Environ. Mater. 2022, 5 (3), 954-961. DOI: https://doi.org/10.1002/eem2.12220. | - |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/99277 | - |
| dc.description.abstract | 隨著化石燃料逐漸枯竭及全球暖化問題日益嚴峻，如何在資源取得與環境保護之間取得平衡，已成為迫切且重要的課題。我們觀察到，在能源轉換過程中，例如燃料燃燒與工業生產，會產生大量廢熱。若能有效回收並轉換這些廢熱為可用能源，不僅有助於能源的再利用，更將成為推動永續發展的重要里程碑。熱電材料因能直接將熱能轉換為電能而備受關注。然而，傳統電子熱電材料普遍存在毒性及脆性問題，對環境造成潛在傷害，且限制其應用場域。相較之下，離子熱電材料展現出優異的熱電性能與柔韌性，但部分現有材料在環境友善性方面仍具挑戰性。基於此，本論文聚焦於綠色高分子凝膠於熱充電電容之研究，期望開發出兼具環境友善與能源效率的離子熱電材料，為綠色能源技術貢獻一份心力。
本研究共分為兩個部分。第一部分以α 硫辛酸 (LA)、丙烯酸 (AA) 及羥丙基纖維素 (HPC) 為組成，通過化學合成方法製備出凝膠基材，其中 LA 所含的雙硫鍵及凝膠網路中豐富的氫鍵共同促成動態交聯結構的形成，賦予材料良好的可回收性。不僅如此，研究中以 1 丁基 3 甲基咪唑氯鹽 (BMIM:Cl) 作為離子供體，並引入氯化鈣 (CaCl2) 以建立離子選擇性傳輸通道，進而優化熱電性能。實驗結果顯示，LACIG 3% (含3% CaCl2) 的離子熱電係數 (thermopower) 可達 −30.4 mV K−1，當該凝膠搭配鎳-鉑電極組裝成熱電元件後，在僅5 K的溫差下即可產生142.8 mV的輸出電壓，LACIG 3%也展現出優異的再加工性，能以澆鑄法製備成各種形狀並貼合複雜表面。此研究結果凸顯了該系統在熱電性能、再加工性及環境永續性之間的出色平衡。 第二部分以PVA作為高分子基材，在不額外添加化學交聯劑和添加劑的條件下，保有其環境友好特性，並以深共熔溶劑 (DES) 作為離子供體。研究比較了以甘油為氫鍵供體 (HBD)、氯化膽鹼 (ChCl)、溴化膽鹼 (ChBr) 及碘化膽鹼 (ChI) 為氫鍵受體 (HBA) 的三種配方。結果發現，Cl–, Br–, I–的chaotropic effect將影響高分子鏈的結構，導致結晶度的下降，降幅趨勢為 I– > Br– > Cl–，與chaotropic effect的強弱一致。熱電性能中，含有 ChCl 的凝膠 (ETG-Cl) 因溶液黏度過高，限制離子傳輸；而含有 ChI 的凝膠 (ETG-I) 雖因I–降低結晶度而使離子傳輸更為容易，然而受限於空間障礙及I–與高分子間相互作用力過低，導致離子傳輸缺乏選擇性，影響熱電表現。相比之下，含有 ChBr 的凝膠 (ETG-Br) 在黏度、結晶性及離子傳輸之間取得最佳平衡，表現出最高的離子導電率 (ionic conductivity) 為63.33 mS cm–1，離子熱電係數 (thermopower) 為5.70 mV K–1及無因次離子熱電優值 (zTi) 達 0.14。研究結果顯示，ChBr極有潛力成為目前研究中常用 ChCl 的更佳候選者，並為深共熔溶劑在離子熱電材料領域的設計和應用提供新方向。 這些研究結果共同突顯了設計環境友好、高性能離子熱電材料的可行性，說明透過動態交聯網絡及離子傳輸通道的構建，並納入離子液體與深共熔溶劑系統的加入，能有效促進離子傳輸並提升元件性能。此研究不僅拓展了離子熱電材料的設計思路，也為後續開發兼具可再加工性、環境相容性及優異離子傳輸特性的熱電元件奠定了重要基礎，對推動新一代綠色能源技術的應用與發展具有關鍵意義。 | zh_TW |
| dc.description.abstract | With fossil fuel depletion and global warming becoming urgent concerns, recovering industrial waste heat offers a sustainable energy pathway. While thermoelectric materials convert heat into electricity, traditional thermoelectric materials often face toxicity and brittleness issues. Ionic thermoelectric materials provide better flexibility and performance but may lack environmental compatibility. This study explores green polymer gels for thermally chargeable capacitors, aiming to develop eco-friendly, efficient materials for sustainable energy applications.
This study consists of two parts. In the first part, a matrix was synthesized from α-lipoic acid (LA), acrylic acid (AA), and hydroxypropyl cellulose (HPC). The disulfide bonds in LA, together with extensive hydrogen bonding, formed a dynamic crosslinked network, imparting good recyclability. 1-butyl-3-methylimidazolium chloride (BMIM:Cl) was used as the ionic donor, and calcium chloride (CaCl2) was added to create ion-selective channels, thereby enhancing thermoelectric performance. The LACIG 3% gel (with 3% CaCl2) exhibited a thermopower of −30.4 mV K−1 and generated 142.8 mV under a 5 K temperature gradient when paired with Ni-Pt electrodes. It also showed excellent reprocessability, enabling casting into various shapes and conformal contact with complex surfaces. The second part uses poly(vinyl alcohol) (PVA) as the polymer matrix without added chemical crosslinkers, preserving environmental friendliness. Deep eutectic solvents (DES) with glycerol as hydrogen bond donor and choline salts (ChCl, ChBr, ChI) as hydrogen bond acceptors were compared. The chaotropic effects of Cl−, Br−, and I− reduced polymer crystallinity in the order I− > Br− > Cl−. The eutectogel containing ChCl (ETG-Cl) showed limited ion transport due to high viscosity, while the eutectogel containing ChI (ETG-I) had improved mobility but poor thermoelectric performance from weak polymer-ion interactions and low selectivity. The eutectogel containing ChBr (ETG-Br) achieved the best balance, with the highest ionic conductivity (63.33 mS cm−1), thermopower (5.70 mV K−1), and ionic figure of merit (zTi = 0.14). These results demonstrate the feasibility of designing eco-friendly, high-performance ionic thermoelectric materials. The use of dynamic networks, ion transport channels, ionic liquids, and deep eutectic solvents enhances ion mobility and overall performance. This work provides a foundation for sustainable, reprocessable thermoelectric systems in green energy applications. | en |
| dc.description.provenance | Submitted by admin ntu (admin@lib.ntu.edu.tw) on 2025-08-21T17:05:39Z No. of bitstreams: 0 | en |
| dc.description.provenance | Made available in DSpace on 2025-08-21T17:05:39Z (GMT). No. of bitstreams: 0 | en |
| dc.description.tableofcontents | 致謝………………………………………………………………………………….. i
ABSTRACT…………………………………………………………………………..ii 摘要…………………………………………………………………………………..iv Table of Contents……………………………………………………………………..vi Figure Captions………………………………………………………………………..x Table Captions……………………………………………………………………….xix 1. Chapter 1. Introduction 1 1.1. Background 1 1.2. Ionic Thermoeletric Mechanisms 7 1.2.1. Fundamental Effect 7 1.2.2. Thermogalvanic Effect 8 1.2.3. Thermodiffusion Effect 9 1.3. Green Ionic Thermoeletric Materials 13 1.3.1. Matrixes 14 1.3.1.1. Natural Origin 16 1.3.1.2. Chemical Synthesis 19 1.3.2. Solvent 22 1.3.2.1. Water 22 1.3.2.2. Organic Solvent 22 1.3.3. Ion donor 23 1.3.3.1. Ionic liquid 23 1.3.3.2. Deep Eutectic Solvent (DES) 25 1.4. Ionic Thermoeletric Capacitors 28 1.4.1. Mechanisms of Ionic Thermoeletric Capacitors 28 1.4.2. Application of Ionic Thermoeletric Capacitors 29 1.5. Motivation 32 2. Chapter 2 Experimental Section 36 2.1. Materials 36 2.2. Synthesis of Green Materials 36 2.2.1. The LACIG Ionogels 36 2.2.2. The Eutectogels 37 2.3. Characterization 38 2.4. Thermoeletric Measurement 39 3. Chapter 3 Green Ionogels for Dual Thermoelectric and Energy Storage Functions 40 3.1. Research Background 40 3.2. Results and Discussion 44 3.2.1. Design and synthesis of the LACIG ionogels 44 3.2.2. Mechanical Performance Analysis 50 3.2.3. Small-angle X-ray Scattering Analysis 52 3.2.4. Thermoelectric Performance Analysis 56 3.2.5. Ionic Thermoelectric Mechanism 62 3.2.6. Ionic Thermoelectric Capacitor 67 3.2.7. Recyclability 69 3.2.8. Processability and thermoelectric application 74 3.3. Summary 77 4. Chapter 4 Investigating the Influence of Halogen Variations in Choline-Based Deep Eutectic Solvents on Thermoelectric Properties 79 4.1. Research Background 79 4.2. Results and Discussion 83 4.2.1. Design and Synthesis of Eutectogels 83 4.2.2. Mechanical Performance Analysis 88 4.2.3. Spectroscopic and Structural Characterization 91 4.2.4. Small-angle X-ray Scattering Analysis 98 4.2.5. Thermoelectric Performance Analysis 104 4.2.6. Ionic Thermoelectric Capacitor 115 4.2.7. Wearable Device Application 117 4.3. Summary 119 5. Conclusion 121 6. Reference 122 | - |
| dc.language.iso | en | - |
| dc.subject | 有機離子熱電材料 | zh_TW |
| dc.subject | 離子液體 | zh_TW |
| dc.subject | 深共熔溶劑 | zh_TW |
| dc.subject | 廢熱回收 | zh_TW |
| dc.subject | 離子傳輸 | zh_TW |
| dc.subject | 環境永續 | zh_TW |
| dc.subject | deep eutectic solvents | en |
| dc.subject | Organic ionic thermoelectric materials | en |
| dc.subject | environmental sustainability | en |
| dc.subject | ion transport | en |
| dc.subject | waste heat recovery | en |
| dc.subject | ionic liquids | en |
| dc.title | 綠色高分子凝膠於熱充電電容之研究 | zh_TW |
| dc.title | Investigation of Green Polymer Gels for Thermally Chargeable Capacitors | en |
| dc.type | Thesis | - |
| dc.date.schoolyear | 113-2 | - |
| dc.description.degree | 碩士 | - |
| dc.contributor.oralexamcommittee | 鄭有舜;郭紹偉;劉英麟 | zh_TW |
| dc.contributor.oralexamcommittee | U-Ser Jeng;Shiao-Wei Kuo;Ying-Ling Liu | en |
| dc.subject.keyword | 有機離子熱電材料,離子液體,深共熔溶劑,廢熱回收,離子傳輸,環境永續, | zh_TW |
| dc.subject.keyword | Organic ionic thermoelectric materials,ionic liquids,deep eutectic solvents,waste heat recovery,ion transport,environmental sustainability, | en |
| dc.relation.page | 144 | - |
| dc.identifier.doi | 10.6342/NTU202503218 | - |
| dc.rights.note | 未授權 | - |
| dc.date.accepted | 2025-08-05 | - |
| dc.contributor.author-college | 工學院 | - |
| dc.contributor.author-dept | 材料科學與工程學系 | - |
| dc.date.embargo-lift | N/A | - |
| 顯示於系所單位： | 材料科學與工程學系 | |
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