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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 吳錫侃 | |
dc.contributor.author | Bo-Yi Li | en |
dc.contributor.author | 李柏毅 | zh_TW |
dc.date.accessioned | 2021-07-11T14:38:35Z | - |
dc.date.available | 2027-07-19 | |
dc.date.copyright | 2017-08-29 | |
dc.date.issued | 2017 | |
dc.date.submitted | 2017-07-19 | |
dc.identifier.citation | References
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dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/77970 | - |
dc.description.abstract | 本研究探討富鎳Ti48.9Ni51.1及Ti48.8Ni51.2形狀記憶合金 (SMAs) 在固溶處理後及時效於250~600 ºC之相變態行為。當試片時效於250 ºC和300 ºC時,Ti48.9Ni51.1及Ti48.8Ni51.2 SMAs 發生一階B2↔R相變態;當試片時效於350 ºC和400 ºC時,兩SMAs 皆發生二階B2↔R↔B19’相變態;當試片時效於450 ºC時,兩SMAs 發生三階相變態。當試片時效於500 ºC時,由於Ti3Ni4析出物的大小及分布不均勻之關係,Ti48.9Ni51.1 SMA可觀察到四階相變態而Ti48.8Ni51.2 SMA可觀察到為三階相變態。當試片時效於550 ºC時,兩SMAs 皆在早期時效階段發生三階相變態,而於長時效時間發生二階B2↔R↔B19’相變態。當試片時效於600 ºC時,兩SMAs 皆在早期時效階段發生B2↔B19’1變態,中期時效階段發生B2↔B19’1與B2↔B19’2相變態,而於長時效時間只發生B2↔B19’2相變態,其中B2↔B19’1與Ti3Ni4析出物有關,而B2↔B19’2則與Ti2Ni3析出物相關。本研究透過時效450~600 ºC 後Ti48.9Ni51.1 SMA 之SEM圖來觀察顯微結構及析出物Ti3Ni4及Ti2Ni3之分布,同時也探討經過固溶處理後之Ti50-xNi50+x (x=1.0~1.3 at.%) SMAs之微硬度、熱物理性質及制振能特性等,發現固溶處理後之Ti49Ni51、Ti48.9Ni51.1、Ti48.8Ni51.2 SMAs皆發生B2↔B19’相變態,然而Ti48.7Ni51.3 SMA轉變為應變玻璃型態,且Ti48.7Ni51.3 SMA與Ti48.8Ni51.2 SMA之間的微硬度、熱物理性質等均有顯著的差異。 | zh_TW |
dc.description.abstract | In this study, Ni-rich Ti48.9Ni51.1 and Ti48.8Ni51.2 shape memory alloys (SMAs) are systematically studied to investigate their transformation behaviors exhibited in as solution-treated specimens and then they are aged at 250 ºC to 600 ºC for different aging times by DSC tests. Both SMAs exhibit a B2↔R transformation when aged at 250 ºC and 300 ºC, and a B2↔R↔B19’ transformation occurs when the specimens aged at 350 ºC and 400 ºC. A three-stage transformation occurs in both SMAs aged at 450 ºC due to the compositional inhomogeneity. When the specimens aged at 500 ºC, the transformation sequence of Ti48.9Ni51.1 SMA is a quadruple-stage transformation, whereas Ti48.8Ni51.2 SMA behaves a three-stage transformation due to the inhomogeneous size and distribution of Ti3Ni4 precipitates at grain interior. When the specimens aged at 550 ºC, a three-stage transformation occurs in both SMAs for the early aging time, and a B2↔R↔B19’ transformation occurs for the longer aging time. Both SMAs’ specimens aged at 600 ºC exhibit B2↔B19’1 for the early aging time, behave B2↔B19’1 and B2↔B19’2 for the middle aging time, and show B2↔B19’2 for the longer aging time. SEM images of Ti48.9Ni51.1 specimens aged at 450~600 ºC are observed. At the same time, Vickers microharness, thermal physical properties and damping characteristics of as solution-treated Ti50-xNi50+x (x=1.0~1.3 at.%) SMAs are also studied. Experimental results indicate a B2↔B19’ martensitic transformation exhibits in as solution-treated Ti49Ni51, Ti48.9Ni51.1 and Ti48.8Ni51.2 SMAs; however, Ti48.7Ni51.3 SMA behaves a strain glass transition. | en |
dc.description.provenance | Made available in DSpace on 2021-07-11T14:38:35Z (GMT). No. of bitstreams: 1 ntu-106-R04527013-1.pdf: 14031967 bytes, checksum: 4bcfc5d2f88f45241cae9b390fec7889 (MD5) Previous issue date: 2017 | en |
dc.description.tableofcontents | Contents
摘要 i Abstract iii Contents v Chapter 1 Introduction 1 Chapter 2 Literature Reviews 3 2.1 Introduction to Shape Memory Alloys (SMAs) 3 2.1.1 Thermoelastic Martensitic Transformation 3 2.1.2 Shape Memory Effect (SME) 6 2.1.3 Superelasticity/Pseudoelasticity (PE) 7 2.2 Microstructures of TiNi Alloys and R Phase Transformation 8 2.3 Aging Effect of Ni-rich TiNi Shape Memory Alloys 10 2.4 Two-stage and Multi-stage Transformations of Ni-rich TiNi Shape Memory Alloys 12 2.5 Damping Characteristics in TiNi Shape Memory Alloys 17 Chapter 3 Experimental Procedures 35 3.1 Specimen Preparation 35 3.2 Aging Treatment 36 3.3 Differential Scanning Calorimetry (DSC) Measurement 36 3.4 Dynamic Mechanical Analyzer (DMA) Measurement 37 3.5 Vickers Microhardness Test 38 3.6 Thermal Physical Properties Measurements 38 3.7 X-ray Diffractometer 39 3.8 Scanning Electron Microscope (SEM) Observation 39 Chapter 4 Results and Discussion 45 4.1 DSC Measurement 45 4.1.1 DSC Results of As Solution-treated Ti50-xNi50+x (x=1.0~1.3 at.%) Specimens 45 4.1.2 DSC Results of Ti48.9Ni51.1 and Ti48.8Ni51.2 Specimens Aged at 250 ºC 46 4.1.3 DSC Results of Ti48.9Ni51.1 and Ti48.8Ni51.2 Specimens Aged at 300 ºC 48 4.1.4 DSC Results of Ti48.9Ni51.1 and Ti48.8Ni51.2 Specimens Aged at 350 ºC 48 4.1.5 DSC Results of Ti48.9Ni51.1 and Ti48.8Ni51.2 Specimens Aged at 400 ºC 49 4.1.6 DSC Results of Ti48.9Ni51.1 and Ti48.8Ni51.2 Specimens Aged at 450 ºC 51 4.1.7 DSC Results of Ti48.9Ni51.1 and Ti48.8Ni51.2 Specimens Aged at 500 ºC 52 4.1.8 DSC Results of Ti48.9Ni51.1 and Ti48.8Ni51.2 Specimens Aged at 550 ºC 54 4.1.9 DSC Results of Ti48.9Ni51.1 and Ti48.8Ni51.2 Specimens Aged at 600 ºC 56 4.1.10 Discussions on Transformation Sequence of Ti48.9Ni51.1 and Ti48.8Ni51.2 Specimens 57 4.2 Results and Discussion of Vickers Microhardness Tests 59 4.3 Results and Discussion of Thermal Physical Properties Measurements 59 4.4 Results and Discussion of DMA Measurement 61 4.5 Results and Discussion of XRD 64 4.6 Results and Discussion of SEM Observation 65 Chapter 5 Conclusions 139 References 143 | |
dc.language.iso | en | |
dc.title | 富鎳Ti48.9Ni51.1及Ti48.8Ni51.2形狀記憶合金相變態
行為之研究 | zh_TW |
dc.title | Transformation Behavior of Ni-rich Ti48.9Ni51.1 and Ti48.8Ni51.2 Shape Memory Alloys | en |
dc.type | Thesis | |
dc.date.schoolyear | 105-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 林新智,張世航,周棟勝,陳志軒 | |
dc.subject.keyword | 富鎳鈦鎳形狀記憶合金,固溶處理,時效處理,多階麻田散體相變態,Ti3Ni4/Ti2Ni3析出物, | zh_TW |
dc.subject.keyword | Ni-rich TiNi SMAs,As solution-treated,Aging treatment,Multi-stage martensitic transformation,Ti3Ni4/Ti2Ni3 precipitates, | en |
dc.relation.page | 148 | |
dc.identifier.doi | 10.6342/NTU201701707 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2017-07-20 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 材料科學與工程學研究所 | zh_TW |
dc.date.embargo-lift | 2027-07-19 | - |
顯示於系所單位: | 材料科學與工程學系 |
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