請用此 Handle URI 來引用此文件:
http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/77641
完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 廖文彬 | |
dc.contributor.author | Bo-Cheng Huang | en |
dc.contributor.author | 黃柏誠 | zh_TW |
dc.date.accessioned | 2021-07-10T22:13:11Z | - |
dc.date.available | 2021-07-10T22:13:11Z | - |
dc.date.copyright | 2018-07-05 | |
dc.date.issued | 2018 | |
dc.date.submitted | 2018-07-03 | |
dc.identifier.citation | 1. Sotomura, T., et al., Denki Kagaku, 1993. 61: pp. 1366–1372.
2. 陳壽安, 化工, 1992. 38: p. 98. 3. Tsamouras, D., et al., Appl. Surface Sci., 1993. 65-66: pp. 388-393. 4. Gustafsson, G., et al., The “plastic” led: A flexible light-emitting device using a polyaniline transparent electrode. Synthetic Metals, 1993. 57(1): pp. 4123-4127. 5. 黃桂武, 軟性印製透明導電高分子材料技術發展. 光連雙月刊, 2012. 6. Natta, G., G. Mazzanti, and R. Corradini, Rend. Accad. Nazl. Lincei., 1958. 28: p. 2. 7. Shirakawa, H. and S. Ikeda, Infrared Spectra of Poly(Acetylene). Polymer Journal, 1971. 2(2): p. 231. 8. Chiang, C.K., et al., Electrical-Conductivity in Doped Polyacetylene. Physical Review Letters, 1977. 39(17): pp. 1098-1101. 9. Chiang, J.-C. and A.G. MacDiarmid, ‘Polyaniline’: Protonic acid doping of the emeraldine form to the metallic regime. Synthetic Metals, 1986. 13(1): pp. 193-205. 10. 臺大化學系普化教學組, 導電塑膠聚苯胺. 2015. 11. Averill, B.A. and P. Eldredge, Principles of General Chemistry. 2004. 12. 工業技術研究院材料與化工研究所知識推廣室, 共軛性導電高分子材料技術簡介. 工業材料雜誌, 2010. 288期. 13. Askeland, D.R., et al., The Science and Engineering of Materials. 1996. 14. Beverina, L., G.A. Pagani, and M. Sassi, Multichromophoric electrochromic polymers: colour tuning of conjugated polymers through the side chain functionalization approach. Chemical Communications, 2014. 50(41): pp. 5413-5430. 15. Jelle, B.P., et al., Synth. Met., 1993. 54: p. 315. 16. Ohtani, A., et al., Synth. Met., 1993. 55-57: p. 3696. 17. Mirmohseni, A. and A. Oladegaragoze, Anti-corrosive properties of polyaniline coating on iron. Synthetic Metals, 2000. 114(2): pp. 105-108. 18. Olad, A. and H. Rasouli, Enhanced corrosion protective coating based on conducting polyaniline/zinc nanocomposite. Journal of Applied Polymer Science, 2009. 115(4): pp. 2221-2227. 19. Wei, Y., et al., Polyaniline as corrosion protection coatings on cold rolled steel. Polymer, 1995. 36(23): pp. 4535-4537. 20. Yang, L.-Y. and W.-B. Liau, Environmental responses of polyaniline inverse opals: Application to gas sensing. Vol. 160. 2010. 609-614. 21. Yang, L.-Y. and W.-B. Liau, Environmental responses of nanostructured polyaniline films based on polystyrene–polyaniline core–shell particles. Vol. 115. 2009. 28-32. 22. Bernard, M.C. and V.T. Bich, Synth. Met., 1999. 101: p. 811. 23. Sherman, B.C., W.B. Euler, and R.R. Force, J. Chem. Educ., 1994. 71: p. A94. 24. 匡汀, 廖力夫, and 劉傳湘, 聚苯胺溶解性研究. 應用化工, 2006. 35(6): pp. 445-447. 25. Letheby, H., XXIX.-On the production of a blue substance by the electrolysis of sulphate of aniline. Journal of the Chemical Society, 1862. 15(0): pp. 161-163. 26. Adams, P.N., P.J. Laughlin, and A.P. Monkman, Synthesis of high molecular weight polyaniline at low temperatures. Synthetic Metals, 1996. 76(1): pp. 157-160. 27. Goto, H., et al., J. Chem. Educ., 2008. 85: p. 1067. 28. Huang, J.X., et al., J. Am. Chem. Soc., 2003. 125: p. 314. 29. Huang, J.X. and R.B. Kaner, Chem. Commun., 2006: p. 367. 30. Chiou, N.R. and A.J. Epstein, Adv. Mater., 2005. 73: p. 1679. 31. Mohilner, D.M., R.N. Adams, and W.J. Argersinger, Investigation of the Kinetics and Mechanism of the Anodic Oxidation of Aniline in Aqueous Sulfuric Acid Solution at a Platinum Electrode. Journal of the American Chemical Society, 1962. 84(19): pp. 3618-3622. 32. Sapurina, I. and J. Stejskal, The mechanism of the oxidative polymerization of aniline and the formation of supramolecular polyaniline structures. Polymer International, 2008. 57(12): pp. 1295-1325. 33. Zhou, Y.-k., et al., Preparation and Electrochemistry of SWNT/PANI Composite Films for Electrochemical Capacitors. Journal of The Electrochemical Society, 2004. 151(7): pp. A1052-A1057. 34. Armes, S.P. and J.F. Miller, Optimum reaction conditions for the polymerization of aniline in aqueous solution by ammonium persulphate. Synthetic Metals, 1988. 22(4): pp. 385-393. 35. Blinova, N.V., et al., Polyaniline and polypyrrole: A comparative study of the preparation. European Polymer Journal, 2007. 43(6): pp. 2331-2341. 36. Stejskal, J., I. Sapurina, and M. Trchová, Progress in Polymer Science., 2010. 35: p. 1420. 37. Nicolas-Debarnot, D. and F. Poncin-Epaillard, Polyaniline as a new sensitive layer for gas sensors. Anal. Chim. Acta, 2003. 475: pp. 1-15. 38. Han, M.G., et al., Preparation and characterization of polyaniline nanoparticles synthesized from DBSA micellar solution. Synthetic Metals, 2002. 126(1): pp. 53-60. 39. Fitch, R.M. and R.C. Watson, J. Colloid Interface Sci., 1979. 68: p. 14. 40. Odian, G., Emulsion Polymerization, in Principles of Polymerization. 2004. pp. 350-371. 41. Harkins, W.D., J. Am. Chem. Soc., 1947. 69: p. 1428. 42. Hansen, F.K. and J. Ugelstad, J. Polym. Sci., Polym. Chem. , 1978. 16: p. 1953. 43. Fitch, R.M., M.B. Prenosil, and K.J. Sprick, J. Polym. Sci., 1969. C, 27: p. 95. 44. Ugelstad, J., F.K. Hansen, and S. Lange, Makromol. Chem., 1974. 175: p. 507. 45. Matsumoto, T. and A. Ochi, Kobunshi Kagaku, 1965. 22: p. 481. 46. 林怡君, 導電性聚苯乙烯/聚苯胺核殼乳膠之合成與研究. 國立臺灣大學化學工程學研究所碩士論文, 2001. 47. Zhang, J., et al., Preparation of monodisperse polystyrene spheres in aqueous alcohol system. Materials Letters, 2003. 57(28): pp. 4466-4470. 48. 陳二強, 單分散聚苯乙烯微粒/奈米碳管導電複合材料之製備與物性研究 國立中興大學材料工程學系研究所博士論文, 2009. 49. 張恒睿, 聚苯胺的導電度對銀金屬還原之影響及其成長機制. 國立臺灣大學材料科學與工程學研究所碩士論文, 2014. 50. Zhang, B., et al., Acid-directed synthesis of SERS-active hierarchical assemblies of silver nanostructures. Journal of Materials Chemistry, 2011. 21(8): pp. 2495-2501. 51. Ozyilmaz, A.T., et al., Electrochemical synthesis of polyaniline films on zinc-cobalt alloy deposited carbon steel surface in sodium oxalate. Progress in Organic Coatings, 2014. 77(4): pp. 872-879. 52. Keddie, J., Film formation of latex. Vol. 21. 1997. 101-170. 53. 孫鈺婷, 陽離子型聚苯乙烯-聚苯胺核殼型態奈米導電膜之製備. 國立臺灣大學材料科學與工程學研究所碩士論文, 2003. 54. 王正全 and 工研院材化所, 濕式透明導電膜技術簡介. 工業材料雜誌, 2006. 236. 55. Wei, G., et al., One-step synthesis of silver nanoparticles, nanorods, and nanowires on the surface of DNA network. J. Phys. Chem. B., 2005. 109(18): p. 8738-43. 56. Piquemal, J.-Y., et al., One-step construction of silver nanowires in hexagonal mesoporous silica using the polyol process. Materials Research Bulletin, 2003. 38(3): pp. 389-394. 57. Murphy, C.J. and N.R. Jana, Controlling the Aspect Ratio of Inorganic Nanorods and Nanowires. Advanced Materials, 2002. 14(1): pp. 80-82. 58. Yen, M.Y., et al., Synthesis of Cable‐Like Copper Nanowires. Advanced Materials, 2003. 15(3): pp. 235-237. 59. Sun, Y., et al., Uniform Silver Nanowires Synthesis by Reducing AgNO3 with Ethylene Glycol in the Presence of Seeds and Poly(Vinyl Pyrrolidone). Chemistry of Materials, 2002. 14(11): pp. 4736-4745. 60. Sun, Y., et al., Polyol Synthesis of Uniform Silver Nanowires: A Plausible Growth Mechanism and the Supporting Evidence. Nano Letters, 2003. 3(7): pp. 955-960. 61. Li, X., L. Wang, and G. Yan, Review: Recent research progress on preparation of silver nanowires by soft solution method and their applications. Crystal Research and Technology, 2011. 46(5): pp. 427-438. 62. 李哲瑋, 聚(3-己基噻吩)-銀金屬複合材料之製備與形成機制探討. 國立臺灣大學材料科學與工程學研究所碩士論文, 2013. 63. 邱淵, 不同溶劑對聚(3-己基噻吩)-銀金屬複合材料製備與形成機制探討之影響. 國立臺灣大學工學院高分子科學與工程學研究所碩士論文, 2015. 64. Bodner, G.M.P., Harry L., Chemistry: An Experimental Science, Second Edition. Journal of Chemical Education, 1995. 72(12): p. A246. 65. Stejskal, J., J. Prokeš, and I. Sapurina, The reduction of silver ions with polyaniline: The effect of the type of polyaniline and the mole ratio of the reagents. Materials Letters, 2009. 63(8): pp. 709-711. 66. Porter, D.A. and K.E. Easterling, Phase Transformations in Metals and Alloys, SECOND EDITION, 1981: pp. 185-197. 67. Ratke, L. and P.W. Voorhees, Growth and Coarsening. Ostwald Ripening in Material Processing, 2002: pp. 117-118. 68. V., Z.A. and S.A. A., island coarsening. Glossary. 69. E., M.T., et al., Combining ESTEM and Kinetic Monte Carlo simulations to investigate sintering of Cu. ID-12-P-1569. 70. Rayleigh, L., Philosophical Magazine 1882. 14: p. 184. 71. Cooley, J.F., US Pattern., 1902, 692,631. 72. Cooley, J.F., US Pattern., 1903, 745,276. 73. Morton, W.J., US Pattern., 1902, 705,691. 74. Formhals, A., US Pattern., 1934, 1,975,504. 75. Taylor., G., Proceedings of the Royal Society A., 1964: p. 280, 1382, 383. 76. K., V. and D.J. P., Chem. Mater., 2003. 15: pp. 4317-4324. 77. Zhang, J., et al., Macromolecular Symposia, 2006. 242: p. 274. 78. Osamu, O., M. Shigenori, and Y. Katsumi, Gel Characteristics of Polyaniline and Its Anomalous Doping Effect. Japanese Journal of Applied Physics, 1990. 29(4A): p. L679. 79. Aussawasathien, D., J.H. Dong, and L. Dai, Electrospun polymer nanofiber sensors. Synthetic Metals, 2005. 154(1): pp. 37-40. 80. Norris, I.D., et al., Electrostatic fabrication of ultrafine conducting fibers: polyaniline/polyethylene oxide blends. Synthetic Metals, 2000. 114(2): pp. 109-114. 81. Li, M., et al., Electrospinning polyaniline-contained gelatin nanofibers for tissue engineering applications. Biomaterials, 2006. 27(13): pp. 2705-2715. 82. Picciani Paulo, H.S., et al., Development of conducting polyaniline/poly(lactic acid) nanofibers by electrospinning. Journal of Applied Polymer Science, 2009. 112(2): pp. 744-753. 83. Hidayat, A., et al., Effect of polyaniline polymerization methods on the preparation of electrospun polyaniline nanofiber. Vol. 1755. 2016. 150015. 84. Merlini, C., et al., Electrospinning of doped and undoped-polyaniline/poly(vinylidene fluoride) blends. Synthetic Metals, 2016. 213: pp. 34-41. 85. Zhang, Y. and G.C. Rutledge, Electrical Conductivity of Electrospun Polyaniline and Polyaniline-Blend Fibers and Mats. Macromolecules, 2012. 45(10): pp. 4238-4246. 86. 曹鐵平, et al., 靜電紡絲法製備聚丙烯腈/聚苯胺複合納米纖維及其表徵. 高分子學報, 2010(12): pp. 1464-1469. 87. Yu, J.H., S.V. Fridrikh, and G.C. Rutledge, Production of Submicrometer Diameter Fibers by Two‐Fluid Electrospinning. Advanced Materials, 2004. 16(17): pp. 1562-1566. 88. Yu, Q.-Z., et al., Morphology and conductivity of polyaniline sub-micron fibers prepared by electrospinning. Materials Science and Engineering: B, 2008. 150(1): pp. 70-76. 89. Aussawasathien, D., et al., Poly(o-anisidine)–polystyrene composite fibers via electrospinning process: Surface morphology and chemical vapor sensing. Vol. 151. 2011. 341-350. 90. Stoiljkovic, A., et al., Preparation of water-stable submicron fibers from aqueous latex dispersion of water-insoluble polymers by electrospinning. Polymer, 2007. 48(14): pp. 3974-3981. 91. Yuan, W., et al., Structural Coloration of Colloidal Fiber by Photonic Band Gap and Resonant Mie Scattering. ACS Applied Materials & Interfaces, 2015. 7(25): pp. 14064-14071. 92. Clogston, J.D. and A.K. Patri, Zeta Potential Measurement, in Characterization of Nanoparticles Intended for Drug Delivery, S.E. McNeil, Editor. 2011, Humana Press: Totowa, NJ. pp. 63-70. 93. 王宛婷, 聚苯胺奈米纖維與銀金屬複合材料之製備. 國立臺灣大學材料科學與工程學研究所碩士論文, 2012. 94. Jiang, W., et al., Facile aqueous synthesis of [small beta]-AgI nanoplates as efficient visible-light-responsive photocatalyst. Dalton Transactions, 2014. 43(1): pp. 300-305. 95. Pauling, L., General Chemistry, 1970. 96. Djokic, S.S., Journal of The Electrochemical Society, 204. 151: p. 359. 97. Elechiguerra, J.L., J. Reyes-Gasga, and M.J. Yacaman, The role of twinning in shape evolution of anisotropic noble metal nanostructures. Journal of Materials Chemistry, 2006. 16(40): pp. 3906-3919. 98. 鮑忠興、劉思謙, 近代穿透式電子顯微鏡實務. 2012: 滄海書局. 93-98. 99. SATYENDRA, Twinning Induced Plasticity Steels. ISPAT DIGEST, 2014. 100. Cherns, D., Direct resolution of surface atomic steps by transmission electron microscopy. The Philosophical Magazine: A Journal of Theoretical Experimental and Applied Physics, 1974. 30(3): pp. 549-556. 101. Iijima, S., Observation of atomic steps of (111) surface of a silicon crystal using bright field electron microscopy. Ultramicroscopy, 1981. 6(1): pp. 41-52. 102. Kirkland, A.I., et al., Structural studies of trigonal lamellar particles of gold and silver. Proceedings of the Royal Society of London. Series A: Mathematical and Physical Sciences, 1993. 440(1910): p. 589. 103. Chen, X. and J.M. Gibson, Measurement of roughness at buried Si/SiO 2 interfaces by transmission electron diffraction. Physical Review B, 1996. 54(4): p. 2846. 104. Lofton, C. and W. Sigmund, Mechanisms Controlling Crystal Habits of Gold and Silver Colloids. Advanced Functional Materials, 2005. 15(7): pp. 1197-1208. 105. Goessens, C., D. Schryvers, and J.V. Landuyt, Transmission electron microscopy studies of (111) twinned silver halide microcrystals. Microscopy Research and Technique, 1998. 42(2): pp. 85-99. 106. Jiang, X.C., et al., Role of Temperature in the Growth of Silver Nanoparticles Through a Synergetic Reduction Approach. Nanoscale Research Letters, 2011. 6(1): pp. 32-32. 107. Yang, Z., et al., Controllable Biosynthesis and Properties of Gold Nanoplates Using Yeast Extract. Nano-Micro Letters, 2016. 9(1): p. 5. 108. Metals.com, S.L. 109. Silvert, P.-Y., R. Herrera-Urbina, and K. Tekaia-Elhsissen, Preparation of colloidal silver dispersions by the polyol process. Journal of Materials Chemistry, 1997. 7(2): pp. 293-299. 110. Anderson, A.B. and H.A. Asiri, Reversible potentials for steps in methanol and formic acid oxidation to CO2; adsorption energies of intermediates on the ideal electrocatalyst for methanol oxidation and CO2 reduction. Physical Chemistry Chemical Physics, 2014. 16(22): pp. 10587-10599. 111. Ulich, H., Ionic mobilities in non-aqueous solvents. Transactions of the Faraday Society, 1927. 23: pp. 388-393. 112. Boskou, D. and I. Elmadfa, Frying of Food: Oxidation, Nutrient and Non-Nutrient Antioxidants, Biologically Active Compounds and High Temperatures. CRC Press, 1999: p. 60. 113. Kassaee, M.Z., et al., In situ formation of silver nanoparticles in PMMA via reduction of silver ions by butylated hydroxytoluene. Structural Chemistry, 2011. 22(1): pp. 11-15. 114. (Sweden), S.C.A.K., 1'st of Marts 2010. 115. Trefalt, G. and M. Borkovec, Overview of DLVO theory. 2014. 116. 陳一葦, 靜電紡絲製備聚(3-己基噻吩)/聚環氧乙烷混摻纖維-銀金屬複合材料製備與形成機制探討之影響. 國立臺灣大學材料科學與工程學研究所碩士論文, 2017. 117. Tang, C., et al., In Situ Cross-Linking of Electrospun Poly(vinyl alcohol) Nanofibers. Macromolecules, 2010. 43(2): pp. 630-637. | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/77641 | - |
dc.description.abstract | 本研究以核殼型態聚苯乙烯/聚苯胺乳膠粒子製備薄膜與靜電紡絲,利用聚苯胺的氧化還原性質與導電特性可從硝酸銀水溶液中還原出一維方向延長之奈米銀帶。本論文旨在探討此系統中奈米銀結構的成長機制。
以乳化聚合方式合成的聚苯乙烯顆粒表面包覆上聚苯胺殼層後可形成懸浮在水相中的導電粒子,不須透過有機溶劑的參與即可沉積形成導電薄膜或進行水相靜電紡絲。導電薄膜依酸的摻雜、聚苯胺殼層的包覆程度及乳膠顆粒的堆疊狀況而有不同尺度規模的導電能力。中間鹽式態的聚苯胺可作為還原劑,能從硝酸銀水溶液中將銀離子還原成銀金屬,而在初期成核容易、且電子能夠傳遞補充的情況下,銀金屬能以透過奧斯瓦爾德熟化的方式成長成一維方向延長之銀帶。同條銀帶上的面心立方堆疊方向均相同,且以最密堆疊面{111}面族為成長嗜好面、銀帶沿最密堆疊方向族<110>方向族延長。本研究進一步透過不同的操縱變因,如摻雜酸、硝酸銀共溶劑比例、成核劑有無等,以驗證此成長模型與調控奈米銀金屬形貌。 | zh_TW |
dc.description.abstract | In this study, polystyrene(PS)/polyaniline(PANI) core/shell latex particles were formed into conducting films and electrospun fibers. The redox and conductive properties of polyaniline enabled it to gain one-dimensional elongating silver bands from silver nitrate aqueous solution by reduction. This thesis aimed to investigate the growth mechanisms of the nano-silver structures in the cases.
The polystyrene latexes were first synthesized as the cores, then polyaniline was polymerized onto the latex particles to form core/shell structures. The core/shell latex particles were suspended in water, which made it possible to fabricate cast films and electrospun fibers without organic solvents. The conductance depends on the acid doping level, the degree of coverage, and the assembly of particles, which differs from small to large scales. With the emeraldine salt form polyaniline as the reducing agent, the silver ions in silver nitrate aqueous solution could be reduced to silver (solid). Under the conditions that nucleation and transfer of electrons were facilitated at the beginning of the reactions, the nano-silver could stretch out by ripening with other nuclei. Every site on the same silver band is in the same zone axis and with the same diffraction pattern in the same orientation. The most preferred growth planes are {111} and the preferred growth directions are <110>, which are exactly the closed-packed planes and closed-packed directions of the face-centered cubic (FCC) structure. Also, experiments with independent variables such as kinds of doping acids, ratios of cosolvents for silver nitrate, the addition of the nucleating agent, were carried out to examine the growth mechanism and regulate the morphology of nano-silver structures. | en |
dc.description.provenance | Made available in DSpace on 2021-07-10T22:13:11Z (GMT). No. of bitstreams: 1 ntu-107-R04527020-1.pdf: 10103632 bytes, checksum: dc6a0f634e8b7043739206bf778f799e (MD5) Previous issue date: 2018 | en |
dc.description.tableofcontents | 摘要 i
Abstract ii 目錄 iv 圖目錄 vii 表目錄 xii 第一章 緒論 1 第二章 文獻回顧 2 2-1 導電高分子 2 2-1-1發展歷史 2 2-1-2導電原理 3 2-1-3應用 6 2-2 聚苯胺 6 2-2-1特性 6 2-2-2合成方法 8 2-2-3合成機制 8 2-2-4摻雜 12 2-3 乳膠粒子 13 2-3-1乳化聚合反應 13 2-3-2醇/水共溶劑相中的乳化聚合反應 16 2-3-3乳膠粒子乾燥成膜機制 17 2-4 聚苯乙烯/聚苯胺核殼乳膠 18 2-5銀金屬之還原 19 2-5-1 低維度銀金屬結構 19 2-5-2 銀金屬之成長 24 2-6靜電紡絲 29 2-6-1靜電紡絲的發展 29 2-6-2原理 29 2-6-3聚苯胺靜電紡絲製備方法 31 2-6-4乳膠靜電紡絲 34 第三章 實驗 36 3-1 實驗藥品 36 3-2 實驗儀器 39 3-3 實驗方法 42 3-3-1 合成聚苯乙烯/聚苯胺之核殼乳膠粒子 42 3-3-2 聚苯乙烯/聚苯胺之核殼乳膠粒子膜之製備 44 3-3-3 聚苯乙烯/聚苯胺之核殼乳膠粒子膜與硝酸銀溶液的還原反應 44 3-3-4 聚苯乙烯/聚苯胺之核殼乳膠粒子膜與添加BHT之硝酸銀溶液的還原反應 44 3-3-5 聚苯乙烯/聚苯胺之核殼乳膠粒子之靜電紡絲 45 3-4性質分析及測試 46 3-4-1 聚苯乙烯/聚苯胺之核殼乳膠粒子粉末之性質 46 3-4-2 聚苯乙烯/聚苯胺之核殼乳膠膜與還原銀金屬之性質 47 3-4-3 聚苯乙烯/聚苯胺之核殼乳膠靜電紡絲纖維之性質 48 第四章 結果與討論 49 4-1 乳膠粒子之合成與鑑定 49 4-1-1 聚苯乙烯乳膠粒子 49 4-1-2 聚苯乙烯/聚苯胺核殼乳膠粒子 51 4-2 聚苯乙烯/聚苯胺核殼乳膠粒子還原低維度銀金屬 53 4-2-1 聚苯乙烯/聚苯胺核殼乳膠粒子在水溶液中還原銀金屬 53 4-2-2 觀察核殼粒子在水溶液中還原銀金屬過程 62 4-2-3 掃描式電子顯微鏡觀察 64 4-2-4 穿透式電子顯微鏡鑑定 67 4-3 導電聚苯乙烯/聚苯胺核殼顆粒還原銀金屬形貌機制之建構 77 4-3-1 成核與成長 77 4-3-2 生長方向 81 4-4 聚苯乙烯/聚苯胺核殼乳膠粒子還原銀形貌之調控 85 4-4-1 醇 85 4-4-2 BHT 89 4-5聚苯乙烯/聚苯胺核殼乳膠靜電紡絲 95 第五章 結論 101 參考文獻 102 | |
dc.language.iso | zh-TW | |
dc.title | 聚苯乙烯/聚苯胺核殼顆粒還原銀金屬之形貌與成長機制探討 | zh_TW |
dc.title | The Morphology and Growth Mechanism of Silver Fabricated by the Reduction Reaction of Polystyrene/Polyaniline Core/shell Particles | en |
dc.type | Thesis | |
dc.date.schoolyear | 106-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 林招松,曾勝茂,顏鴻威 | |
dc.subject.keyword | 聚苯胺,聚苯乙烯,硝酸銀,核殼乳膠顆粒,靜電紡絲,奈米銀帶,成長機制, | zh_TW |
dc.subject.keyword | polyaniline,polystyrene,silver nitrate,core/shell latex particle,electrospinning,nano-silver belt,growth mechanism, | en |
dc.relation.page | 109 | |
dc.identifier.doi | 10.6342/NTU201801219 | |
dc.rights.note | 未授權 | |
dc.date.accepted | 2018-07-03 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 材料科學與工程學研究所 | zh_TW |
顯示於系所單位: | 材料科學與工程學系 |
文件中的檔案:
檔案 | 大小 | 格式 | |
---|---|---|---|
ntu-107-R04527020-1.pdf 目前未授權公開取用 | 9.87 MB | Adobe PDF |
系統中的文件,除了特別指名其著作權條款之外,均受到著作權保護,並且保留所有的權利。