請用此 Handle URI 來引用此文件:
http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/77071
完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 陳俊維(Chun-Wei Chen) | |
dc.contributor.author | Kuan-Jung Chen | en |
dc.contributor.author | 陳冠融 | zh_TW |
dc.date.accessioned | 2021-07-10T21:45:30Z | - |
dc.date.available | 2021-07-10T21:45:30Z | - |
dc.date.copyright | 2020-07-17 | |
dc.date.issued | 2020 | |
dc.date.submitted | 2020-07-02 | |
dc.identifier.citation | Grätzel, Michael. 'Photoelectrochemical cells.' Materials For Sustainable Energy: A Collection of Peer-Reviewed Research and Review Articles from Nature Publishing Group. 2011. 26-32.
National Renewable Energy Laboratory. Best Research-Cell Efficiency Chart. (https://www.nrel.gov/pv/cell-efficiency.html) Hoang, Minh Tam, et al. 'Integrated photoelectrolysis of water implemented on organic metal halide perovskite photoelectrode.' ACS Applied Materials Interfaces 8.19 (2016): 11904-11909. Nam, SeongSik, Cuc Thi Kim Mai, and Ilwhan Oh. 'Ultrastable photoelectrodes for solar water splitting based on organic metal halide perovskite fabricated by lift-off process.' ACS applied materials interfaces 10.17 (2018): 14659-14664. Poli, Isabella, et al. 'Graphite-protected CsPbBr 3 perovskite photoanodes functionalised with water oxidation catalyst for oxygen evolution in water.' Nature communications 10.1 (2019): 1-10. Kim, Dohun, et al. 'Photoelectrochemical Water Splitting Reaction System Based on Metal-Organic Halide Perovskites.' Materials 13.1 (2020): 210. Da, Peimei, et al. 'High-performance perovskite photoanode enabled by Ni passivation and catalysis.' Nano Letters 15.5 (2015): 3452-3457. Tao, Ran, et al. 'Achieving Organic Metal Halide Perovskite into a Conventional Photoelectrode: Outstanding Stability in Aqueous Solution and High-Efficient Photoelectrochemical Water Splitting.' ACS Applied Energy Materials 2.3 (2019): 1969-1976. Luo, Jingshan, et al. 'Water photolysis at 12.3% efficiency via perovskite photovoltaics and Earth-abundant catalysts.' Science 345.6204 (2014): 1593-1596. Brimblecombe, Robin, et al. 'Molecular water-oxidation catalysts for photoelectrochemical cells.' Dalton Transactions 43 (2009): 9374-9384. Cheng, Ziyong, and Jun Lin. 'Layered organic–inorganic hybrid perovskites: structure, optical properties, film preparation, patterning and templating engineering.' CrystEngComm 12.10 (2010): 2646-2662. Cohen, Ronald E. 'Origin of ferroelectricity in perovskite oxides.' Nature 358.6382 (1992): 136-138. Zheng, Ting, et al. 'Recent development in lead-free perovskite piezoelectric bulk materials.' Progress in materials science 98 (2018): 552-624. Maeno, Y., et al. 'Superconductivity in a layered perovskite without copper.' Nature 372.6506 (1994): 532-534. Chen, Qi, et al. 'Under the spotlight: The organic–inorganic hybrid halide perovskite for optoelectronic applications.' Nano Today 10.3 (2015): 355-396. Rondinelli, James M., Steven J. May, and John W. Freeland. 'Control of octahedral connectivity in perovskite oxide heterostructures: An emerging route to multifunctional materials discovery.' MRS bulletin 37.3 (2012): 261-270. Fan, Zhen, Kuan Sun, and John Wang. 'Perovskites for photovoltaics: a combined review of organic–inorganic halide perovskites and ferroelectric oxide perovskites.' Journal of Materials Chemistry A 3.37 (2015): 18809-18828. Ossila Ltd. (https://www.ossila.com/pages/perovskite-solar-cells-methods-increase-stability) Zhang, Fei, et al. 'Advances in two-dimensional organic–inorganic hybrid perovskites.' Energy Environmental Science 13.4 (2020): 1154-1186. Xu, Xiaoxiang, et al. 'A red metallic oxide photocatalyst.' Nature materials 11.7 (2012): 595-598. Mitzi, David B. 'Synthesis, structure, and properties of organic‐inorganic perovskites and related materials.' Progress in inorganic chemistry (1999): 1-121. Noh, Jun Hong, et al. 'Chemical management for colorful, efficient, and stable inorganic–organic hybrid nanostructured solar cells.' Nano letters 13.4 (2013): 1764-1769. Saliba, Michael, et al. 'Perovskite solar cells: from the atomic level to film quality and device performance.' Angewandte Chemie International Edition 57.10 (2018): 2554-2569. Wu, Yinghui, et al. 'The Impact of Hybrid Compositional Film/Structure on Organic–Inorganic Perovskite Solar Cells.' Nanomaterials 8.6 (2018): 356. Weber, Dieter. 'CH3NH3PbX3, ein Pb (II)-system mit kubischer perowskitstruktur/CH3NH3PbX3, a Pb (II)-system with cubic perovskite structure.' Zeitschrift für Naturforschung B 33.12 (1978): 1443-1445. Thomson, S. Observing Phase Transitions in a Halide Perovskite Using Temperature Dependent Photoluminescence Spectroscopy. Edinburgh Instruments Ltd. Thind, Arashdeep Singh, et al. 'First-principles prediction of a stable hexagonal phase of CH3NH3PbI3.' Chemistry of Materials 29.14 (2017): 6003-6011. Whitfield, P. S., et al. 'Structures, phase transitions and tricritical behavior of the hybrid perovskite methyl ammonium lead iodide.' Scientific reports 6.1 (2016): 1-16. Yin, Wan-Jian, Tingting Shi, and Yanfa Yan. 'Superior photovoltaic properties of lead halide perovskites: insights from first-principles theory.' The Journal of Physical Chemistry C 119.10 (2015): 5253-5264. Xing, Guichuan, et al. 'Long-range balanced electron-and hole-transport lengths in organic-inorganic CH3NH3PbI3.' Science 342.6156 (2013): 344-347. Ponseca Jr, Carlito S., et al. 'Organometal halide perovskite solar cell materials rationalized: ultrafast charge generation, high and microsecond-long balanced mobilities, and slow recombination.' Journal of the American Chemical Society 136.14 (2014): 5189-5192. Kojima, Akihiro, et al. 'Organometal halide perovskites as visible-light sensitizers for photovoltaic cells.' Journal of the American Chemical Society 131.17 (2009): 6050-6051. Im, Jeong-Hyeok, et al. '6.5% efficient perovskite quantum-dot-sensitized solar cell.' Nanoscale 3.10 (2011): 4088-4093. Lee, Michael M., et al. 'Efficient hybrid solar cells based on meso-superstructured organometal halide perovskites.' Science 338.6107 (2012): 643-647. Zhou, Huanping, et al. 'Interface engineering of highly efficient perovskite solar cells.' Science 345.6196 (2014): 542-546. Yang, Woon Seok, et al. 'High-performance photovoltaic perovskite layers fabricated through intramolecular exchange.' Science 348.6240 (2015): 1234-1237. Saliba, Michael, et al. 'Cesium-containing triple cation perovskite solar cells: improved stability, reproducibility and high efficiency.' Energy environmental science 9.6 (2016): 1989-1997. Sun, Shuangyong, et al. 'The origin of high efficiency in low-temperature solution-processable bilayer organometal halide hybrid solar cells.' Energy Environmental Science 7.1 (2014): 399-407. Zhao, Yixin, and Kai Zhu. 'Organic–inorganic hybrid lead halide perovskites for optoelectronic and electronic applications.' Chemical Society Reviews 45.3 (2016): 655-689. Burschka, Julian, et al. 'Sequential deposition as a route to high-performance perovskite-sensitized solar cells.' Nature 499.7458 (2013): 316-319. Liu, Mingzhen, Michael B. Johnston, and Henry J. Snaith. 'Efficient planar heterojunction perovskite solar cells by vapour deposition.' Nature 501.7467 (2013): 395-398. You, Jingbi, et al. 'Low-temperature solution-processed perovskite solar cells with high efficiency and flexibility.' ACS nano 8.2 (2014): 1674-1680. Yang, Guang, et al. 'Recent progress in electron transport layers for efficient perovskite solar cells.' Journal of Materials Chemistry A 4.11 (2016): 3970-3990. Chen, Yichuan, et al. 'SnO2-based electron transporting layer materials for perovskite solar cells: A review of recent progress.' Journal of Energy Chemistry 35 (2019): 144-167. Wang, Qi, et al. 'Large fill-factor bilayer iodine perovskite solar cells fabricated by a low-temperature solution-process.' Energy Environmental Science 7.7 (2014): 2359-2365. You, Jingbi, et al. 'Improved air stability of perovskite solar cells via solution-processed metal oxide transport layers.' Nature nanotechnology 11.1 (2016): 75-81. Upama, Mushfika Baishakhi, et al. 'Role of fullerene electron transport layer on the morphology and optoelectronic properties of perovskite solar cells.' Organic Electronics 50 (2017): 279-289. Jeon, Nam Joong, et al. 'Solvent engineering for high-performance inorganic–organic hybrid perovskite solar cells.' Nature materials 13.9 (2014): 897-903. Guo, Yunlong, et al. 'Enhancement in the efficiency of an organic–inorganic hybrid solar cell with a doped P3HT hole-transporting layer on a void-free perovskite active layer.' Journal of Materials Chemistry A 2.34 (2014): 13827-13830. Elumalai, Naveen Kumar, et al. 'Perovskite solar cells: progress and advancements.' Energies 9.11 (2016): 861. Chen, Jie, et al. 'Metal Halide Perovskites for Solar‐to‐Chemical Fuel Conversion.' Advanced Energy Materials 10.13 (2020): 1902433. Tahir, Muhammad, et al. 'Electrocatalytic oxygen evolution reaction for energy conversion and storage: a comprehensive review.' Nano Energy 37 (2017): 136-157. Seh, Zhi Wei, et al. 'Combining theory and experiment in electrocatalysis: Insights into materials design.' Science 355.6321 (2017). Lee, Sol A., et al. 'Si-Based Water Oxidation Photoanodes Conjugated with Earth-Abundant Transition Metal-Based Catalysts.' ACS Materials Letters 2.1 (2019): 107-126. Bukhtiyarova, M. V. 'A review on effect of synthesis conditions on the formation of layered double hydroxides.' Journal of Solid State Chemistry 269 (2019): 494-506. Guo, Beidou, et al. 'Facile integration between Si and catalyst for high-performance photoanodes by a multifunctional bridging layer.' Nano Letters 18.2 (2018): 1516-1521. Kojima, Akihiro, et al. 'Organometal halide perovskites as visible-light sensitizers for photovoltaic cells.' Journal of the American Chemical Society 131.17 (2009): 6050-6051. Im, Jeong-Hyeok, et al. '6.5% efficient perovskite quantum-dot-sensitized solar cell.' Nanoscale 3.10 (2011): 4088-4093. Kim, Hui-Seon, et al. 'Lead iodide perovskite sensitized all-solid-state submicron thin film mesoscopic solar cell with efficiency exceeding 9%.' Scientific reports 2.1 (2012): 1-7. Liu, Mingzhen, Michael B. Johnston, and Henry J. Snaith. 'Efficient planar heterojunction perovskite solar cells by vapour deposition.' Nature 501.7467 (2013): 395-398. Jeon, Nam Joong, et al. 'Solvent engineering for high-performance inorganic–organic hybrid perovskite solar cells.' Nature materials 13.9 (2014): 897-903. Jiang, Qi, et al. 'Planar‐structure perovskite solar cells with efficiency beyond 21%.' Advanced materials 29.46 (2017): 1703852. Yang, Woon Seok, et al. 'Iodide management in formamidinium-lead-halide–based perovskite layers for efficient solar cells.' Science 356.6345 (2017): 1376-1379. Jeon, Nam Joong, et al. 'A fluorene-terminated hole-transporting material for highly efficient and stable perovskite solar cells.' Nature Energy 3.8 (2018): 682-689. Jiang, Qi, Xingwang Zhang, and Jingbi You. 'SnO2: a wonderful electron transport layer for perovskite solar cells.' Small 14.31 (2018): 1801154. Xiong, Liangbin, et al. 'Review on the application of SnO2 in perovskite solar cells.' Advanced Functional Materials 28.35 (2018): 1802757. Park, Minwoo, et al. 'Low-temperature solution-processed Li-doped SnO2 as an effective electron transporting layer for high-performance flexible and wearable perovskite solar cells.' Nano Energy 26 (2016): 208-215. Xiong, Liangbin, et al. 'Performance enhancement of high temperature SnO 2-based planar perovskite solar cells: electrical characterization and understanding of the mechanism.' Journal of Materials Chemistry A 4.21 (2016): 8374-8383. Yang, Guang, et al. 'Reducing hysteresis and enhancing performance of perovskite solar cells using low‐temperature processed Y‐doped SnO2 nanosheets as electron selective layers.' Small 13.2 (2017): 1601769. Bai, Yang, et al. 'Low temperature solution-processed Sb: SnO 2 nanocrystals for efficient planar perovskite solar cells.' (2016). Ren, Xiaodong, et al. 'Solution-processed Nb: SnO2 electron transport layer for efficient planar perovskite solar cells.' ACS applied materials interfaces 9.3 (2017): 2421-2429. Roose, Bart, et al. 'A Ga-doped SnO 2 mesoporous contact for UV stable highly efficient perovskite solar cells.' Journal of Materials Chemistry A 6.4 (2018): 1850-1857. Lee, Yonghui, et al. 'Enhanced charge collection with passivation of the tin oxide layer in planar perovskite solar cells.' Journal of Materials Chemistry A 5.25 (2017): 12729-12734. Wu, Cuncun, et al. 'TiO2/SnOxCly double layer for highly efficient planar perovskite solar cells.' Organic Electronics 50 (2017): 485-490. Tavakoli, Mohammad Mahdi, et al. 'Mesoscopic oxide double layer as electron specific contact for highly efficient and UV stable perovskite photovoltaics.' Nano letters 18.4 (2018): 2428-2434. Hou, Yu, et al. 'A Band‐Edge Potential Gradient Heterostructure to Enhance Electron Extraction Efficiency of the Electron Transport Layer in High‐Performance Perovskite Solar Cells.' Advanced Functional Materials 27.27 (2017): 1700878. Zuo, Lijian, et al. 'Tailoring the interfacial chemical interaction for high-efficiency perovskite solar cells.' Nano letters 17.1 (2017): 269-275. Wu, Wu‐Qiang, et al. 'Thin films of tin oxide nanosheets used as the electron transporting layer for improved performance and ambient stability of perovskite photovoltaics.' Solar Rrl 1.11 (2017): 1700117. Wang, Ying‐Chiao, et al. 'Efficient and Hysteresis‐Free Perovskite Solar Cells Based on a Solution Processable Polar Fullerene Electron Transport Layer.' Advanced Energy Materials 7.21 (2017): 1701144. Liu, Kuan, et al. 'Fullerene derivative anchored SnO 2 for high-performance perovskite solar cells.' Energy Environmental Science 11.12 (2018): 3463-3471. Zhang, Fei, and Kai Zhu. 'Additive engineering for efficient and stable perovskite solar cells.' Advanced Energy Materials 10.13 (2020): 1902579. Liu, Shuang, et al. 'A review on additives for halide perovskite solar cells.' Advanced Energy Materials 10.13 (2020): 1902492. Lee, Jin-Wook, Hui-Seon Kim, and Nam-Gyu Park. 'Lewis acid–base adduct approach for high efficiency perovskite solar cells.' Accounts of chemical research 49.2 (2016): 311-319. Ahn, Namyoung, et al. 'Highly reproducible perovskite solar cells with average efficiency of 18.3% and best efficiency of 19.7% fabricated via Lewis base adduct of lead (II) iodide.' Journal of the American Chemical Society 137.27 (2015): 8696-8699. Lee, Jin-Wook, et al. 'Tuning molecular interactions for highly reproducible and efficient formamidinium perovskite solar cells via adduct approach.' Journal of the American Chemical Society 140.20 (2018): 6317-6324. Lee, Jin-Wook, et al. 'A bifunctional lewis base additive for microscopic homogeneity in perovskite solar cells.' Chem 3.2 (2017): 290-302. Hsieh, Cheng-Ming, et al. 'Low-temperature, simple and efficient preparation of perovskite solar cells using Lewis bases urea and thiourea as additives: stimulating large grain growth and providing a PCE up to 18.8%.' RSC advances 8.35 (2018): 19610-19615. Fei, Chengbin, et al. 'Highly efficient and stable perovskite solar cells based on monolithically grained CH3NH3PbI3 film.' Advanced Energy Materials 7.9 (2017): 1602017. Wharf, Ivor, et al. 'Synthesis and vibrational spectra of some lead (II) halide adducts with O-, S-, and N-donor atom ligands.' Canadian Journal of Chemistry 54.21 (1976): 3430-3438. Yang, Haidong, et al. 'In situ growth of ultrathin Ni–Fe LDH nanosheets for high performance oxygen evolution reaction.' Inorganic Chemistry Frontiers 4.7 (2017): 1173-1181. Chen, Rong, et al. 'Achieving stable and efficient water oxidation by incorporating NiFe layered double hydroxide nanoparticles into aligned carbon nanotubes.' Nanoscale Horizons 1.2 (2016): 156-160. Guo, Beidou, et al. 'Facile integration between Si and catalyst for high-performance photoanodes by a multifunctional bridging layer.' Nano Letters 18.2 (2018): 1516-1521. LaserFocusWorld. (https://www.laserfocusworld.com/lasers-sources/article/16566681/photovoltaics-measuring-the-sun) (http://ned.ipac.caltech.edu/level5/Sept03/Li/Li4.html) Wang, Ying‐Chiao, et al. 'Electron‐Transport‐Layer‐Assisted Crystallization of Perovskite Films for High‐Efficiency Planar Heterojunction Solar Cells.' Advanced Functional Materials 28.9 (2018): 1706317. | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/77071 | - |
dc.description.abstract | 有機-無機混合鈣鈦礦因其卓越的光電性質包含在可見光譜範圍內具有良好吸收率、相對較弱的激子束縛能以及微米等級的載子擴散距離,且透過結構離子的更換即可擁有不同大小之能階變化等,使其在許多不同領域上都有很好的發展。
鈣鈦礦太陽電池在短短十年間快速發展將光電轉換效率提升至20%以上,除了鈣鈦礦優異的光電性質外,加上其溶液製程、低成本、易加工性,因而成為太陽能電池領域的明日之星。為了繼續提升元件載子傳輸效能,如何藉由其他傳輸層材料的輔助,提高汲取載子之能力是如今重要的研究內容之一。鈣鈦礦混合路易士鹼添加劑已被證實可以有效提升轉換率,因此本實驗選用尿素作為添加劑,通過加入不同比例的尿素,觀察其表面形貌,最後成功降低鈣鈦礦吸光層中的缺陷,並提升元件效率。接著,引入介面改質材料使鈣鈦礦吸光層產生之激子能夠更快速的分離為載子,並經由傳輸層傳輸分離,減少載子再結合的機率。本實驗使用碳60-吡咯烷三羧酸(CPTA)披覆於氧化錫表面,通過CPTA的氫氧官能基和氧化錫中含有氧空缺缺陷之錫原子進行鍵結,以達到更佳的載子傳輸能力,進一步提升太陽能元件之光電轉換效率。 太陽能的間歇性要求開發系統來存儲多餘的能量,發展利用光電化學(PEC)水分解為氫氣和氧氣的形式儲存,其可再生性、可持續性以及環境友善等特性,被視為另一種解決能源危機最有希望的方法之一。以往金屬氧化物由於其長期穩定性而被廣泛的作為PEC水分解光陽極進行研究,但是較大能隙的金屬氧化物不能充分吸收可見光區域的波長,因此造成較低的光電流。而由於鈣鈦礦具有能隙工程和吸收各種波長的潛力,能夠取代金屬氧化物應用在光電化學分解水方面。本實驗初步架構將鈣鈦礦太陽能電池浸泡在水溶液中通過陽光將水直接分解為氧氣和氫氣之光電化學系統,並利用保護層對鈣鈦礦太陽能電池進行保護,提升在溶液中的穩定性,接著嘗試利用電化學沉積的方式成長鎳-鐵層狀雙氫氧化合物作為催化劑,觀察不同電位成長之鎳-鐵層狀雙氫氧化合物表面形貌,透過線性掃描安伏法進行量測,有效降低起始氧化電位,並提升光電流。 | zh_TW |
dc.description.abstract | Organic-inorganic hybrid perovskites have been well developed in many different fields due to their exceptional optoelectronic properties such as remarkably high absorption over the visible spectrum, low exciton binding energy, long charge carrier diffusion lengths in the μm range, and a tuneable bandgap by interchanging various structure ions.
Perovskite solar cells (PSCs) have drawn enormous attention in recent years owing to their high power conversion efficiency over 20%. In addition to the excellent photoelectronic properties of perovskite, solution process, low cost, and low temperature synthesis, which make it a rising star in the field of solar cells. In order to promote carrier transmission efficiency of devices, how to elevate the ability of quenching carriers via aiding with other transport layers’ is one of the important issues nowadays. Perovskite added Louis base has been proven to facilitate power conversion efficiency of perovskite solar cells; therefore, urea is adopted as an additive. Through observation of the surface morphology with different proportion of urea in perovskite, finally the defects in the light absorption layer were successfully reduced, further enhances the efficiencies of devices. After that, our research is introducing the surface modification material to effectively separate excitons into carriers, then quench by electron transport layer (ETL), reducing the probability of carrier recombination. Here, C60 pyrrolidine tris-acid (CPTA) is passivated on the surface of tin oxide (SnO2), the hydroxyl terminal groups on CPTA are coordinated with oxygen-vacancy-related defects of Sn in SnO2, and chemical bonding with interface modification brings better transfer ability, further improves the performance of perovskite solar cells. The intermittent nature of solar energy requires the development of systems to store excess energy, thus advance of photoelectrochemical (PEC) water splitting into hydrogen and oxygen, which is renewable, sustainable, and environment-friendly, has been regarded as one of the most promising candidates for solving the energy crisis. In the past, metal oxides have been extensively researched as PEC water splitting photoanodes due to their long-term stability, but a metal oxide with a large band gap possesses a low photocurrent, as it is unable to sufficiently absorb the wavelengths of the visible light region. However, perovskite as a substitute for metal oxide, due to its potential for bandgap engineering and absorbing various wavelengths, which can apply to photoelectrochemical water splitting. Here, our research preliminary set up a photoelectrochemical system which immerse a perovskite solar cell in aqueous solution to decompose water into oxygen and hydrogen through sunlight. Moreover, utilize protect layer to prevent the solution from invading into the perovskite solar cell, to increase the stability in the solution. Use electrochemical deposition to grow Nickel-Iron layered double hydroxides (Ni-Fe LDH) as a catalyst afterwards. By means of linear sweep voltammetry measurement and the observation of surface morphology of Ni-Fe LDH grown at different potentials, found that the Ni-Fe LDH can effectively reduce the onset potential and increase the photocurrent. | en |
dc.description.provenance | Made available in DSpace on 2021-07-10T21:45:30Z (GMT). No. of bitstreams: 1 U0001-0207202012513600.pdf: 12369415 bytes, checksum: 1d874ea0e7cb12a97f969a03371c3110 (MD5) Previous issue date: 2020 | en |
dc.description.tableofcontents | CONTENTS
誌謝 I 中文摘要 III ABSTRACT IV CONTENTS VI LIST OF FIGURES IX LIST OF TABLES XIX Chapter 1 Introduction 1 1.1 The solution of energy crisis 1 1.1.1 Solar cells 1 1.1.2 Photoelectrochemical (PEC) water splitting 4 1.2 Perovskite solar cells 8 1.2.1 Structure and properties of perovskite 8 1.2.2 History of perovskite solar cells 14 1.2.3 Working principles of perovskite solar cells 16 1.2.4 Architectures of perovskite solar cells 19 1.2.5 Transport materials in perovskite solar cells 22 1.3 Perovskite-based photoelectrochemical water splitting 28 1.3.1 Mechanism of Perovskite PEC cells 28 1.3.2 Electrocatalysts for oxygen evolution reaction (OER) 32 1.3.3 Development of perovskite PEC water oxidation 36 1.4 Motivation 43 Chapter 2 Literature Review 45 2.1 Development of perovskite solar cells 45 2.2 Improvement of heterojunction by surface modification 54 2.2.1 The variety of surface modifiers 54 2.2.2 Fullerene derivative surface passivation 66 2.3 Additive Engineering for Perovskite light absorption layer 72 2.4 Perovskite-based water splitting photoelectrode 81 2.4.1 Organic metal halide perovskite photoanodes 81 2.4.2 Nickel (Ni)-Iron (Fe) layered double hydroxides (LDHs) 85 2.4.3 List of photoanodes in literatures 87 Chapter 3 Experimental section 89 3.1 Preparation of materials 89 3.2 Fabrication of perovskite solar cells 92 3.3 Fabrication of perovskite-based photoelectrochemical cell 94 3.4 Photovoltaic characteristic 96 3.4.1 Solar energy 96 3.4.2 Current versus voltage (I-V) characteristics of photovoltaic devices 99 3.4.3 Quantum efficiency of solar cells 102 3.5 Experiment and analysis instruments 104 3.5.1 Scanning electron microscope (SEM) 104 3.5.2 X-ray powder diffraction (XRD) 105 3.5.3 Photoluminescence and time-resolved photoluminescence 106 3.6 Photoelectrochemical Measurement 108 3.6.1 Three-electrode system 108 3.6.2 Linear sweep voltammetry (LSV) 109 3.6.3 Chronoamperometry/Chronopotentiometry 110 Chapter 4 Urea additive and surface modification 112 4.1 Morphology control by incorporating with urea 112 4.2 Surface modification of fullerene derivative 121 4.3 Summary 128 Chapter 5 Perovskite-based photoanode 129 5.1 Perovskite solar cell 129 5.2 Protection strategy of photoanode in water 132 5.3 Nickel-Iron layered double hydroxide for photoanode 137 5.4 Summary 143 Reference 144 | |
dc.language.iso | en | |
dc.title | 有機-無機混合鈣鈦礦從光伏系統至光電化學裂解水的應用與研究 | zh_TW |
dc.title | Organic-inorganic hybrid perovskites from photovoltaics to photoelectrochemical water splitting | en |
dc.type | Thesis | |
dc.date.schoolyear | 108-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 李紹先(Shao-Sian Li),王迪彥(Di-Yan Wang) | |
dc.subject.keyword | 鈣鈦礦太陽電池,尿素添加劑,CPTA,光電化學,水分解,產氧反應,鎳-鐵層狀雙氫氧化合物, | zh_TW |
dc.subject.keyword | Perovskite solar cell,Urea additive,CPTA,Photoelectrochemistry (PEC),Water splitting,Oxygen evolution reaction (OER),Nickel-Iron layered double hydroxides (Ni-Fe LDH), | en |
dc.relation.page | 152 | |
dc.identifier.doi | 10.6342/NTU202001266 | |
dc.rights.note | 未授權 | |
dc.date.accepted | 2020-07-03 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 材料科學與工程學研究所 | zh_TW |
顯示於系所單位: | 材料科學與工程學系 |
文件中的檔案:
檔案 | 大小 | 格式 | |
---|---|---|---|
U0001-0207202012513600.pdf 目前未授權公開取用 | 12.08 MB | Adobe PDF |
系統中的文件,除了特別指名其著作權條款之外,均受到著作權保護,並且保留所有的權利。