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http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/63454完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 林新智 | |
| dc.contributor.author | Chen-Chih Lin | en |
| dc.contributor.author | 林楨智 | zh_TW |
| dc.date.accessioned | 2021-06-16T16:42:49Z | - |
| dc.date.available | 2017-08-29 | |
| dc.date.copyright | 2012-08-29 | |
| dc.date.issued | 2012 | |
| dc.date.submitted | 2012-08-23 | |
| dc.identifier.citation | 1.S.Miyazaki, K.Otsuka, and Y.Suzuki; Scripta Metall., 15(1981)287.
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Li and C. X., “Improvement of shape memory effect in Fe-Mn-Si alloy by Cr and Ni addition”, Shi. Scripta Metallurgica et Materialia, 32, (1995), p.1905 63.R.A. Shakoor and F.A. Khalid, “Thermoechanical behavior of Fe-Mn-Si-Cr-Ni shape memory alloys modified with samarium”, Materials Science and Engineering A, 499, (2009) , p.411 | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/63454 | - |
| dc.description.abstract | Fe-Mn-Si-Cr基形狀記憶合金具有加工性良好、價格低廉等特性，在套筒元件的接合與應用具有其優勢。本實驗於具有良好形狀記憶能力之Fe-Mn-Si-Cr基合金中，嘗試添加微量錸(Re)元素，經過不同熱處理後，進行形狀記憶效應與微結構之檢測分析，並針對形狀記憶效應最高的成分，作熱機訓練與形狀記憶訓練，以達到形狀記憶最佳化之研究。
實驗結果顯示：在Fe-30Mn-6Si-5Cr合金、Fe-30Mn-6Si-5Cr-0.05Re合金、Fe-30Mn-6Si-5Cr-0.1Re合金、Fe-30Mn-6Si-5Cr-0.3Re合金中，經600℃以上的退火處理兩小時，會在晶界與母相中產生BCC結構的析出相，此析出相為成分與母相類似之 相。以添加0.1wt.%的Re，經700℃兩小時的退火處理後，其硬度測試及形狀回復率皆表現最好。 藉Fe-30Mn-6Si-5Cr-0.1Re合金並利用冷輥壓做冷加工處理，預應變量分別為0%、5%、10%、15%、20%。其中以5%應變量之合金在700℃兩小時的退火處理後，形狀回復率最好。以此合金進行形狀記憶訓練，形狀回復率隨著循環次數而遞增，經2次形狀記憶訓練後即接近100%之形狀回復，可得知合併熱機處理與形狀記憶訓練，可以有效達到形狀記憶最佳化之效果。 | zh_TW |
| dc.description.abstract | Fe-Mn-Si-Cr-based shape memory alloys have good workability, low price and advantages in the bonding of the sleeve element. With good shape memory Fe-Mn-Si-Cr-based alloys in this study, we try to add it with trace rhenium (Re) element. After different aging treatment, we go through the bending test and analysis of micro-structure, then we choose the one of the better shape memory effect to do heat treatment and shape memory training.
In Fe-30Mn-6Si-5Cr、Fe-30Mn-6Si-5Cr-0.05Re、Fe-30Mn-6Si-5Cr-0.1Re and Fe-30Mn-6Si-5Cr-0.3Re alloys, there will be BCC structure of the precipitated phase in the grain boundaries and the parent phase through aging above 600℃ for 2 hours. It is called phase which is similar to the parent phase. Afer aging at 700℃ for 2 hours, the alloys have the better hardness and shape memory recovery. Apply cold-working on Fe-30Mn-6Si-5Cr-0.1Re alloy to make pre-strain 5%, 10%, 15% and 20%. The shape memory recovery will be better through the one of pre-strain 5% through aging at 700℃ for 2 hours. Use this one to do shape memory training experiment. The recovery rate will increase with training times. After 2 times, the recovery rate will almost be 100%. It is concluded that we can get the best shape memory alloy efficiently by using both heat treatment and shape memory training. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-16T16:42:49Z (GMT). No. of bitstreams: 1 ntu-101-R99527058-1.pdf: 3712266 bytes, checksum: bc7b8d201da3a83af5dc70d8d5130643 (MD5) Previous issue date: 2012 | en |
| dc.description.tableofcontents | 摘要 I
Abstract II 總目錄 III 表目錄 VI 圖目錄 VII 第一章 前言 1 第二章 理論基礎與文獻回顧 3 2.1 形狀記憶合金概述 3 2.1.1熱彈性與非熱彈性麻田散體相變態 3 2.1.2形狀記憶效應 6 2.2 鐵基形狀記憶合金之發展與原理 9 2.3 提升鐵基記憶合金的形狀回復率之方法 16 2.3.1熱機處理 16 2.3.2形狀記憶訓練 17 2.3.3添加合金元素 17 2.3.4析出效應 19 2.4 電化學反應 24 2.5 合金之相的組成與腐蝕之間的關係 25 2.6 腐蝕膜之生成 25 第三章 實驗方法與設備 28 3.1 合金熔煉與試片製備 28 3.2 冷熱軋延 30 3.3 EPMA分析 31 3.4 X-ray繞射分析 31 3.5 硬度測試 32 3.6 DSC量測分析 32 3.7 形狀回復率量測 32 3.8 掃描式電子顯微鏡(SEM)觀察顯微組織 33 3.9 穿透式電子顯微鏡(TEM)觀察顯微組織 34 3.11 電化學測試 35 第四章 結果與討論 36 4.1 Fe-Mn-Si-Cr基記憶合金基本性質 36 4.2 微硬度分析 41 4.3 電化學腐蝕試驗 44 4.4 形狀記憶效應量測 47 4.5 X-ray繞射分析 50 4.6 微結構分析 57 4.7 析出相分析 62 4.8 熱機處理 69 4.9 形狀記憶訓練 71 第五章 結論 74 參考文獻 76 | |
| dc.language.iso | zh-TW | |
| dc.subject | Fe-Mn-Si-Cr基形狀記憶合金 | zh_TW |
| dc.subject | 形狀記憶訓練 | zh_TW |
| dc.subject | 熱機處理 | zh_TW |
| dc.subject | 錸元素 | zh_TW |
| dc.subject | Fe-Mn-Si-Cr-based shape memory alloy | en |
| dc.subject | Re | en |
| dc.subject | heat treatment | en |
| dc.subject | shape memory training | en |
| dc.title | Fe-Mn-Si-Cr-Re形狀記憶合金性能最佳化之研究 | zh_TW |
| dc.title | A Study on Property Optimization of Fe-Mn-Si-Cr-Re
Shape Memory Alloys | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 100-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 吳錫侃,林昆明,謝世峰 | |
| dc.subject.keyword | Fe-Mn-Si-Cr基形狀記憶合金,錸元素,熱機處理,形狀記憶訓練, | zh_TW |
| dc.subject.keyword | Fe-Mn-Si-Cr-based shape memory alloy,Re,heat treatment,shape memory training, | en |
| dc.relation.page | 80 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2012-08-23 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 材料科學與工程學研究所 | zh_TW |
| 顯示於系所單位： | 材料科學與工程學系 | |
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