請用此 Handle URI 來引用此文件：
http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/62413完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 吳錫侃 | |
| dc.contributor.author | Chun-Yu Lai | en |
| dc.contributor.author | 賴俊宇 | zh_TW |
| dc.date.accessioned | 2021-06-16T16:02:15Z | - |
| dc.date.available | 2018-07-11 | |
| dc.date.copyright | 2013-07-11 | |
| dc.date.issued | 2013 | |
| dc.date.submitted | 2013-07-08 | |
| dc.identifier.citation | [1] K. Otsuka, T. Sawamura and K. Shimizu, Phys. Status Solidi A, 5 (1971) 457.
[2] G.D. Sandrock, A.J. Perkins and R.F. Hehemann, Metall. Trans., 2 (1971) 2769. [3] T.H. Nam, T. Saburi, Y. Kawamura and K.i. Shimizu, Mater. Trans, JIM, 31 (1990) 262. [4] T.H. Nam, T. Saburi, Y. Nakata and K.i. Shimizu, Mater. Trans, JIM, 31 (1990) 1050. [5] T.H. Nam, T. Saburi and K. Shimizu, Mater. Trans., JIM, 31 (1990) r5. [6] T.H. Nam, T. Saburi and K.i. Shimizu, Mater. Trans., JIM(Japan), 32 (1991) 814. [7] J.H. Lee, T.H. Nam, H.J. Ahn and Y.W. Kim, Mat. Sci. Eng. a-Struct., 438 (2006) 691. [8] T.H. Nam, J.H. Lee, K.W. Kim, H.J. Ahn and Y.W. Kim, J. Mater. Sci., 40 (2005) 4925. [9] T.H. Nam, J.H. Lee, J.M. Nam, K.W. Kim, G.B. Cho and Y.W. Kim, Mat. Sci. Eng. a-Struct., 483-84 (2008) 460. [10] 林新智, 國立台灣大學材料科學與工程學研究所博士論文, (1992) 18. [11] H. Kessler and W. Pitsch, Acta Metall. Mater., 15 (1967) 401. [12] 林凱南, 國立台灣大學材料科學與工程學研究所碩士論文, (2005). [13] 李芝媛, 吳錫侃, 科儀新知第十六卷, 6 (1995) 6. [14] A. Nagasawa, K. Enami, Y. Ishino, Y. Abe and S. Nenno, Scripta Metall., 8 (1974) 1055. [15] T. Saburi, S. Nenno and Scripta Metall., 8 (1974) 1363. [16] T.A. Schroeder and C.M. Wayman, Scripta Metall., 11 (1977) 225. [17] K. Enami, A. Nagasawa and S. Nenno, Scripta Metall., 9 (1975) 941. [18] L. Delaey and J. Thienel, in:Shape Memory Effects in Alloys, (J. Perkins, ed. ), Plenum Press, New York, 1975, p.341. [19] T. Saburi and S. Nenno, in:Proc. Int. Conf. On Solid to Soild Phase Transformations, ASM, Metals Park, Ohio, 1982, p.1455. [20] M. Nishida and T. Honma, Scripta Metall., 18 (1984) 1299. [21] M. Nishida and T. Honma, Scripta Metall., 18 (1984) 1293. [22] M. Nishida, C.M. Wayman and T. Honma, Scripta Metall., 18 (1984) 1389. [23] K. Otsuka and C.M. Wayman, Shape memory materials, Cambridge University Press, 1999. [24] K. Otsuka and K. Shimizu, Met Forum, 4 (1981) 142. [25] K. Otsuka and C.M. Wayman, in: Reviews on the Deformation Behavior of Materials, (P. Feltham ed. ), Isarael, 1977, p. 81. [26] K. Otsuka, in: Proc. Int. Conf. On Solid to Solid Phase Transformations, TMS-AIME Pittsburgh, Pa. (USA), 1981, p.1267. [27] K. Otsuka and K. Shimizu, International Metals Reviews, 31 (1986) 93. [28] K. Otsuka and X.B. Ren, Intermetallics, 7 (1999) 511. [29] C.M. Jackson, H.J. Wanger and R.J. Wasilewski, Nasa-SP 5110, 1972. [30] O. Matsumoto, S. Miyazaki, K. Otsuka and H. Tamura, Acta Metall. Mater., 35 (1987) 2137. [31] K.M. Knowles and D.A. Smith, Acta Metall. Mater., 29 (1981) 101. [32] T. Onda, Y. Bando, T. Ohba and K. Otsuka, Mater. Trans. JIM, 33 (1992) 354. [33] M. Nishida, N. Ohgi, I. I, A. Chiba and K. Yamauchi, Acta Metall., 43 (1995) 1219. [34] Dautovic.Dp and G.R. Purdy, Can Metall Quart, 4 (1965) 129. [35] D. Bradley, J Acoust Soc Am, 37 (1965) 700. [36] C.M. Wayman and K. Shimizu, I. Cornelis, Scripta Metall., 6 (1972) 115. [37] H.C. Ling and R. Kaplow, Metall. Trans. A, 11 (1980) 77. [38] F.E. Wang, B.F. Desavage, W.J. Buehler and W.R. Hosler, J. Appl. Phys., 39 (1968) 2166. [39] O. Mercier and K.N. Melton, Y. Depreville, Acta Metall. Mater., 27 (1979) 1467. [40] E. Goo and R. Sinclair, Acta Metall. Mater., 33 (1985) 1717. [41] K.H. Eckelmeyer, Scripta Metall., 10 (1976) 667. [42] J.E. Hanlon, S.R. Butler, and Wasilews.Rj, T Metall. Soc. Aime., 239 (1967) 1323. [43] C.M. Hwang, M. Meichle, M.B. Salamon and C.M. Wayman, Philos. Mag. A, 47 (1983) 31. [44] M. Nishida, C.M. Wayman and A. Chiba, Metallography, 21 (1988) 275. [45] G. Airoldi, G. Bellini and C. Difrancesco, J. Phys. F. Met. Phys., 14 (1984) 1983. [46] S. Miyazaki, Y. Igo and K. Otsuka, Acta Metall. Mater., 34 (1986) 2045. [47] T. Saburi, T. Tatsumi and S. Nenno, J. Phys. Paris, 43 (1982) 261. [48] T. Tadaki, Y. Nakata, and K. Shimizu, T. Jpn. I. Met., 28 (1987) 883. [49] S.K. Wu and H.C. Lin, Scripta Metall. Mater., 25 (1991) 1529. [50] L. Bataillard, J.E. Bidaux and R. Gotthard, Philos. Mag. A, 78 (1998) 327. [51] L. Bataillard and R. Gotthardt, J. Phys. Iv, 5 (1995) 647. [52] J.K. Allafi, X. Ren and G. Eggeler, Acta Mater., 50 (2002) 793. [53] M.C. Carroll, C. Somsen and G. Eggeler, Scripta Mater., 50 (2004) 187. [54] A. Dlouhy, J. Khalil-Allafi and G. Eggeler, Philos. Mag., 83 (2003) 339. [55] J. Khalil-Allafi, A. Dlouhy and G. Eggeler, Acta Mater., 50 (2002) 4255. [56] S.H. Chang, S.K. Wu and G.H. Chang, Scripta Mater., 52 (2005) 1341. [57] R.H. Bricknell and K.N. Melton, Metall. Trans. A, 11 (1980) 1541. [58] R.H. Bricknell, K.N. Melton and O. Mercier, Metall. Trans. A, 10 (1979) 693. [59] K.N. Melton and O. Mercier, Metall. Trans. A, 9 (1978) 1487. [60] O. Mercier and K.N. Melton, Metall. Trans. A, 10 (1979) 387. [61] T. Saburi, T. Komatsu, S. Nenno and Y. Watanabe, J Less-Common Met, 118 (1986) 217. [62] Y. Shugo and T. Honma, Bull. Res. Inst. Miner. Dressing Metall., 43 (1987) 117. [63] T. Tadaki and C.M. Wayman, Metallography, 15 (1982) 233. [64] T. Tadaki and C.M. Wayman, Metallography, 15 (1982) 247. [65] W. Moberly, J. Proft, T. Duerig and R. Sinclair, Mater. Sci. Forum, Trans. Tech. Publ., 1991, pp. 605. [66] Y. Watanabe, T. Saburi, Y. Nakagawa and S. Nenno, J. Japan. Ins. Metals, 54 (1990) 861. [67] Y. Liu, Mater. Sci. Eng. A., 354 (2003) 286. [68] J. Flinn, Rapid solidification technology for reduced consumption of strategic materials, Noyes Publications, 1985. [69] A. Inoue and K. Hashimoto, Amorphous and nanocrystalline materials: preparation, properties, and applications, Springer Verlag, 2001. [70] A. Gillen and B. Cantor, Acta Metall. Mater., 33 (1985) 1813. [71] Y.-W. Kim and T.-H. Nam, Scripta Mater., 51 (2004) 653. [72] G.C.S. Anselmo, W.B.d. Castro and C.J.d. Araujo, Mater. Sci. Appl., 2 (2011) 1256. [73] R. Nagarajan and K. Chattopadhyay, Acta metall. et materialia, 42 (1994) 947. [74] H.Y. Xing, H.Y. Kim and S. Miyazaki, Mater. Sci. Forum, Trans. Tech. Publ., 2007, pp. 1481. [75] P. Donner and S. Eucken, Mater. Sci. Forum, Trans. Tech. Publ., 1991, pp. 723. [76] Y. Tong and Y. Liu, J. Alloy Compd., 449 (2008) 152. [77] G. Cheng, Z. Xie and Y. Liu, J. Alloy Compd., 415 (2006) 182. [78] J.R. Williams, H. Gong, N. Hoff, O.I. Olubodun and P.J. Carroll, Organ. Lett., 6 (2004) 269. [79] M. Sato, A. Ishida and S. Miyazaki, Thin Solid Films, 315 (1998) 305. [80] A. Khantachawana, H. Mizubayashi and S. Miyazaki, Mater. Trans., 45 (2004) 214. [81] Y. Furuya, M. Matsumoto, H. Kimura, K. Aoki and T. Masumoto, Mater. Trans., JIM, 31 (1990) 504. [82] Y. Furuya, M. Matsumoto, H. Kimura and T. Masumoto, Mater. Sci. Eng. A., 147 (1991) L7. [83] V. Saravanan, A. Khantachawana and S. Miyazaki, Mater. Trans., 45 (2004) 208. [84] Z. Xie, J. Van Humbeeck, Y. Liu and L. Delaey, Scripta Mater., 37 (1997) 363. [85] H. Rosner, P. Schlossmacher, A. Shelyakov and A. Glezer, Acta Mater., 49 (2001) 1541. [86] H. Rosner, P. Schlomacher, A. Shelyakov and A. Glezer, Scripta Mater., 43 (2000) 871. [87] P. Schlossmacher, N. Boucharat, H. Rosner and A. Shelyakov, J. Phys. IV, 2003, pp. 731. [88] Y.W. Kim and T.H. Nam, Scripta Mater., 51 (2004) 653. [89] D. Tabor, The hardness of metals, Oxford University Press on Demand, 1951. [90] B. Bhushan, Handbook of micro/nano tribology, CRC press, 2010. [91] D. Tabor, Philos. Mag. A., 74 (1996) 1207. [92] W.C. Oliver and G.M. Pharr, J. Mater. Res., 7 (1992) 1564. [93] W.D. Nix, Metall. Trans. A., 20 (1989) 2217. [94] I.N. Sneddon, Inter. J. Eng. Sci., 3 (1965) 47. [95] J. Harding and I. Sneddon, Mathematical Proceedings of the Cambridge Philosophical Society, Cambridge Univ Press, 1945, pp. 16. [96] J. Loubet, J. Georges, O. Marchesini and G. Meille, J. Lubric. Tech., 106 (1984) 43. [97] R. King and T. O'sullivan, Inter. J. Solids Struct., 23 (1987) 581. [98] P. Wierenga and A. Franken, Philips Tech. Rev. 42, 1985, pp. 85. [99] 張瑞慶, 奈米壓痕技術與應用,力學學會會訊, 114 (2006). [100] W.D. Nix and H. Gao, J. Mech. Phys. Solids, 46 (1998) 411. [101] X.-G. Ma and K. Komvopoulos, Appl. Phys. Lett., 83 (2003) 3773. [102] K. Komvopoulos and X.-G. Ma, Appl. Phys. Lett., 87 (2005) 26 [103] X.-G. Ma and K. Komvopoulos, Appl. Phys. Lett., 84 (2004) 4274. [104] X.-G. Ma and K. Komvopoulos, J. Mater. Res., 20 (2005) 1808. [105] A. Muir Wood, J. You and T. Clyne, Proc. SPIE., 2004, pp. 216. [106] A. Wood and T. Clyne, Acta Mater., 54 (2006) 5607. [107] A. Muir Wood, S. Sanjabi, Y. Fu, Z. Barber and T. Clyne, Surf. Coat. Tech., 202 (2008) 3115. [108] J. Pfetzing, A. Schaefer, C. Somsen and M.F.X. Wagner, Int. J. Mater. Res., 100 (2009) 936. [109] H. Zheng, J. Pfetzing, J. Frenzel and G. Eggeler, Int. J. Mater. Res., 100 (2009) 594. [110] H. Zheng, J. Rao, J. Pfetzing, J. Frenzel, C. Somsen and G. Eggeler, Scripta Mater., 58 (2008) 743. [111] J. Pfetzing, M.F.X. Wagner, T. Simon, A. Schaefer, C. Somsen and G. Eggeler, ESOMAT 2009-8th European Symposium on Martensitic Transformations, 2009, pp. 06027. [112] TA DMA 2980 Manual, (2002). [113] S. Chang, S. Wu and L. Wu, Intermetallics, 18 (2010) 965. [114] K.N. Lin, and S.K. Wu, J. Alloy. Compd., 424 (2006) 171. [115] R. Nagarajan and K. Chattopadhyay, Acta Metall. Et Materialia, 42 (1994) 947. [116] C.H. Chen, S.Y. Cheng and S.K. Wu, Intermetallics, 36 (2013) 109. [117] J. Eckert, L. Schultz and K. Urban, J. Non-Cryst. Solids, 127 (1991) 90. [118] K.H.J. Buschow, J. Phys. F. Met. Phys., 13 (1983) 563. [119] S.H. Chang, S.K. Wu and H. Kimura, Intermetallics, 15 (2007) 233. [120] J.Z. Chen and S.K. Wu, Thin Solid Films, 339 (1999) 194. [121] J.Z. Chen and S.K. Wu, J. Non-Cryst. Solids, 288 (2001) 159. [122] Y.D. Dong, G. Gregan and M.G. Scott, J. Non-Cryst. Solids, 43 (1981) 403. [123] H.E. Kissinger, Anal. Chem., 29 (1957) 1702. [124] P.Y. Hsu and J.M. Ting, Thin Solid Films, 420 (2002) 524. [125] H.S. Chen and B.K. Park, Acta Metall. Mater., 21 (1973) 395. [126] H.S. Chen, Acta Metall. Mater., 22 (1974) 897. [127] A.R. Miedema, Philips Tech. Rev., 36 (1976) 217. [128] A.W. Weeber and H. Bakker, Phys. B, 153 (1988) 93. | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/62413 | - |
| dc.description.abstract | 本研究利用快速凝固製程(RSP)製備2000rpm以及4000rpm Ti50Ni40Cu10合金箔帶(Ribbon)，並針對其麻田散體變態、顯微結構、析出硬化以及形狀記憶效應等進行探討。其中as-spun 2000rpm Ti50Ni40Cu10合金箔帶為完全結晶的，但as-spun 4000rpm Ti50Ni40Cu10合金箔帶為部分非晶質的，此因RSP製備時，其箔帶越薄，凝固時冷卻速度愈快導致過冷度太大所造成，其Wavenumber Qp、結晶起始溫度Tx以及結晶之活化能Ea皆較Ti-Ni二元合金箔帶及薄膜低，但較Ti50Ni25Cu25合金箔帶者高，可知箔帶中Cu含量越高，非晶質合金箔帶的熱穩定性也就越低。此兩種合金箔帶各別經過400℃以及 550℃時效後之相變態行為，皆與塊材(Bulk) Ti50Ni40Cu10形狀記憶合金之B2↔B19↔B19’二階相變態不同，而是產生兩個B2↔B19’相變態，透過DSC，XRD以及SEM分析結果顯示此種相變態是由於箔帶中晶粒大小的不同所造成的。奈米壓痕硬度試驗顯示，箔帶經過時效後有析出硬化之效果，其強化程度估計可高於0.3GPa(約30Hv)。此析出硬化提供Ti50Ni40Cu10形狀記憶合金箔帶之強化，並可有效提升其形狀記憶效應。奈米壓痕硬度試驗以及形狀記憶效應測試的結果顯示，影響可回復應變之主要因素為析出硬化之效果，較高的析出硬化效果可降低塑性變形量，使得可回復之變形量增加。本研究之箔帶試片，不論是2000rpm或4000rpm者，其可回復應變量均高於5%，顯示經過時效處理之Ti50Ni40Cu10形狀記憶合金箔帶具有相當良好之形狀記憶效應。 | zh_TW |
| dc.description.abstract | 2000/4000rpm Ti50Ni40Cu10 ribbons prepared by rapid solidification process were studied their transformation behavior, microstructure, precipitation hardening and shape memory effect (SME) properties. As-spun 2000rpm Ti50Ni40Cu10 ribbons are completely crystallized, but as-spun 4000rpm Ti50Ni40Cu10 ribbons are partially amorphous due to their thinner thickness leads to the higher degree of cooling rate. The crystallization behaviors of wavenumber Qp, the starting crystallization temperature Tx and the activation energy of crystallization Ea of as-spun 4000rpm ribbons are investigated and all are lower than those of binary TiNi thin films/ribbons, but higher than those of Ti50Ni25Cu25 thin films/ribbons. This feature indicates that the thermal stability of amorphous Ti50Ni50-xCux alloys is worse with the higher Cu content. Two B2↔B19’ phase transformations, instead of two stage B2↔B19↔B19’ are observed in both aged ribbons, which are caused by the quite different grain sizes existed inherently in ribbons. Nanoindentation tests indicate that precipitation hardening occurs and the hardness increment is 0.3GPa, which can decrease the plastic deformation and increase the SME strain in aged ribbons. Experimental results show the SME strain can reach above 5% in aged ribbons, indicating rather good shape memory properties exhibited in aged ribbons. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-16T16:02:15Z (GMT). No. of bitstreams: 1 ntu-102-R00527042-1.pdf: 11048564 bytes, checksum: cd5b37c8d536c2629d02260dde35a4b9 (MD5) Previous issue date: 2013 | en |
| dc.description.tableofcontents | 摘要 i
Abstract iii 目錄 v 第一章 前言 1 第二章 文獻探討 3 2-1形狀記憶合金簡介 3 2-2 形狀記憶合金之特性 4 2-2-1 熱彈性麻田散體變態 4 2-2-2 形狀記憶效應 6 2-2-3 超彈性 7 2-3 TiNi形狀記憶合金 9 2-4 TiNiCu形狀記憶合金 11 2-5 快速凝固製程 13 2-6奈米壓痕技術 16 2-6-1技術起源及基本原理 16 2-6-2 奈米壓痕分析模型 17 2-6-3 實驗校正參數 18 2-6-4 影響實驗的因素 19 2-6-5 對形狀記憶合金的相關應用 20 第三章 實驗方法與設備 45 3-1 塊狀Ti50Ni40Cu10合金之配置及熔煉 45 3-2 RSP製備之Ti50Ni40Cu10合金箔帶 45 3-3 Ti50Ni40Cu10合金箔帶之時效處理 46 3-4 DSC熱分析儀實驗 46 3-5 OM與SEM觀察 47 3-6 TEM觀察 47 3-7 XRD晶體結構分析 47 3-8 奈米壓痕硬度試驗 48 3-9 形狀記憶效應實驗 48 第四章 Ti50Ni40Cu10 箔帶實驗結果與討論 57 4-1 2000rpm Ti50Ni40Cu10合金箔帶 57 4-1-1 As-spun及200℃~600℃時效一小時之實驗結果 57 4-1-2 400℃時效處理後之DSC及XRD結果 58 4-1-3 SEM顯微組織觀察結果 59 4-1-4 TEM顯微組織觀察結果 62 4-1-5 奈米壓痕硬度結果 62 4-1-6 形狀記憶效應結果 63 4-2 4000rpm Ti50Ni40Cu10合金箔帶 65 4-2-1 As-spun 4000rpm Ti50Ni40Cu10合金箔帶之實驗結果 65 4-2-2 Wavenumber之計算以及高溫DSC之試驗結果 66 4-2-3 不同溫度下時效1小時後之DSC結果 68 4-2-4 550℃時效後之DSC及XRD結果 69 4-2-5 550℃時效後之SEM顯微組織的觀察結果 70 4-2-6 奈米壓痕硬度之結果 71 4-2-7 形狀記憶效應結果 72 4-3 2000rpm與4000rpm Ti50Ni40Cu10合金箔帶之比較 74 第五章 結論 109 參考文獻 111 | |
| dc.language.iso | zh-TW | |
| dc.title | 鈦鎳銅形狀記憶合金箔帶麻田散體變態及其性能之研究 | zh_TW |
| dc.title | Characteristics of Martensitic Transformation and Shape Memory Properties of TiNiCu Ribbons | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 101-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 胡塵滌,張世航,周棟勝 | |
| dc.subject.keyword | 鈦鎳銅形狀記憶合金,快速凝固製程,箔帶,析出硬化,奈米壓痕,非晶質, | zh_TW |
| dc.subject.keyword | TiNiCu Shape Memory Alloys,Rapid Solidification Proccess,Ribbon,Precipitation Hardening,Nanoidentation,Amorphous, | en |
| dc.relation.page | 115 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2013-07-08 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 材料科學與工程學研究所 | zh_TW |
| 顯示於系所單位： | 材料科學與工程學系 | |
文件中的檔案：
| 檔案 | 大小 | 格式 | |
|---|---|---|---|
| ntu-102-1.pdf 目前未授權公開取用 | 10.79 MB | Adobe PDF |
系統中的文件，除了特別指名其著作權條款之外，均受到著作權保護，並且保留所有的權利。