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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 林新智 | |
dc.contributor.author | Jian-Hong Chen | en |
dc.contributor.author | 陳建宏 | zh_TW |
dc.date.accessioned | 2021-06-16T13:05:39Z | - |
dc.date.available | 2013-08-20 | |
dc.date.copyright | 2013-08-20 | |
dc.date.issued | 2013 | |
dc.date.submitted | 2013-08-02 | |
dc.identifier.citation | 1. A. Sato, E. Chishima, K. Soma, and T. Mori, Shape Memory Effect in Gamma Reversible Epsilon Transformation in Fe-30mn-1si Alloy Single-Crystals. Acta Metallurgica, 1982. 30(6): p. 1177-1183.
2. K. Yamauchi, I. Ohkata, K. Tsuchiya, and S. Miyazaki, Shape Memory and Superelastic Alloys :Ttechnologies and Applications. 2011, Philadelphia, PA: Woodhead Publishing. 3. 楊政修, 博士論文-鐵錳矽基形狀記憶合金熱機處理與合金元素添加之效應, 材料科學與工程研究所2009, 逢甲大學. 4. L.C. Chang and T.A. Read, Plastic Deformation and Diffusionless Phase Changes in Metals - the Gold-Cadmium Beta-Phase. Transactions of the American Institute of Mining and Metallurgical Engineers, 1951. 191(1): p. 47-52. 5. L.M. Schetky, Shape-memory alloys. Scientific American, 1979. 241(Nov.): p. 74-82. 6. M. Murakami, H. Otsuka, H.G. Suzuki, and S. Matsuda. Complete Shape Memory Effect in Polycrystalline Fe-Mn-Si Alloys. in Proceedings of the International Conference on Martensitic Transformations. ICOMAT-86. 1986. 7. H.C. Lin, S.K. Wu, and M.T. Yeh, Damping Characteristics of TiNi Shape Memory Alloys. Metallurgical Transactions A, 1993. 24: p. 2189-2194. 8. T. Tadaki, K. Otsuka, and K. Shimizu, Shape memory alloys, in Annual Review of Materials Science1988. p. 25. 9. H. Warlimont and L. Delaey, Thermoelasticity pseudoelasticity and the memory effects associated with martensitic transformations. Journal of Materials Science, 1974. 9: p. 1545. 10. H. Kessler and W. Pitsch, On the nature of the martensite to austenite reverse transformation. Acta Metallurgica, 1967. 15: p. 401. 11. J. Ortin and A. Planes, Thermodynamic Analysis of Thermal Measurements in Thermoelastic Martensitic Transformations. Acta Metallurgica, 1988. 36(8): p. 1873-1889. 12. H.C.Tong and C.M. Wayman, Characteristic temperature and other properties of thermoelastic martensites. Acta Metallurgica, 1974. 22: p. 887. 13. R.J. Salzbrenner and M. Cohen, On the thermodynamics of thermoelastic martensitic transformations. Acta Metallurgica, 1979(27): p. 739. 14. G.B. Olson and M. Cohen, Thermoelastic behavior in martensitic transformation. Scripta Metallurgica, 1975. 9: p. 1247. 15. T. Saburi, S. Nenno, and C.M. Wayman, Shape Memory Mechanisms in Alloys, in ICOMAT-79. 1979. p. 619. 16. M. Nishida and T. Honma, All-Round Shape Memory Effect in Ni-Rich Tini Alloys Generated by Constrained Aging. Scripta Metallurgica, 1984. 18(11): p. 1293-1298. 17. Y. Matsuzaki, T. Kamita, and T. Yamamoto, Vibration characteristics of shape memory alloys in In: Proceedings of SPIE’s 1998 Symposium on Smart Structures and Materials1998. p. 562-569. 18. Y.K. Au and C.M. Wayman, Thermoelastic Behavior of Martensitic Transformation in Beta-' Nial Alloys. Scripta Metallurgica, 1972. 6(12): p. 1209-1214. 19. R. Oshima, S. Sugimoto, M. Sugiyama, T.Hamada, and F.E. Fujiya, Shape Memory Effect in an Ordered Fe3Pt Alloy Associated with the FCC-FCT Thermoelastic Martensite Transformation. Materials Transactions JIM, 1985. 26: p. 523. 20. C.M. Wayman, On memory effects related to martensitic transformations and observations in β-brass and Fe3Pt. Scripta Metallurgica, 1971. 9(5): p. 489-492. 21. T. Sohmura, R.Oshima, and F.E. Fujita, Thermoelastic FCC-FCT martensitic transformation in Fe-Pd alloy. Scripta Metallurgica, 1980. 14(8): p. 855-856. 22. U. Allenstein, Y. Ma, A. Arabi-Hashemi, M. Zink, and S.G. Mayr, Fe-Pd based ferromagnetic shape memory actuators for medical applications: Biocompatibility, effect of surface roughness and protein coatings. Acta Biomaterialia, 2013. 9(3): p. 5845-5853. 23. S. Kajiwara, Nearly Perfect Shape Memory Effect in Fe-Ni-C Alloys. Materials Transactions JIM, 1985. 26(8): p. 595-596. 24. T. Maki, K. Kobayashi, M. Minato, and I. Tamura, Thermoelastic martensite in an ausaged Fe-Ni-Ti-Co alloy. Scripta Metallurgica, 1984. 18(10): p. 1105-1109. 25. D.Z. Liu, N. Bergeon, T. Kikuchi, S. Kajiwara, and N. Shinya, Observation on plastic accommodation of shape strain in martensitic transformation in Fe-Ni-C shape memory alloys, in Shape Memory Materials, T. Saburi, Editor. 2000, Trans Tech Publications Ltd: Zurich-Uetikon. p. 405-408. 26. A. Sato, E. Chishima, Y. Yamaji, and T. Mori, Orientation and Composition Dependencies of Shape Memory Effect in Fe-Mn-Si Alloys. Acta Metallurgica, 1984. 32(4): p. 539-547. 27. A. Sato, Y. Yamaji, and T. Mori, Physical-Properties Controlling Shape Memory Effect in Fe-Mn-Si Alloys. Acta Metallurgica, 1986. 34(2): p. 287-294. 28. T. Maki, E.K. Otsuka, and C.M. Wayman, Shape memory materials. 1998, New York: Cambridge University Press. 29. K. Enami, A. Nagasawa, and S. Nenno, Reversible shape memory effect in Fe-base alloys. Scripta Metallurgica, 1975. 9(9): p. 941-948. 30. A.P. Midownik, The effect of irradiation on the phase stability of the sigma phase (in the W-Re and Fe-Cr-Mo systems). Calphad, 1977. 1: p. 281. 31. Y. Tomota, W. Nakagawara, K. Tsuzaki, and T. Maki, Reversion of Stress-Induced Epsilon-Martensite and 2-Way Shape Memory In Fe-24mn And Fe-24mn-6si Alloys. Scripta Metallurgica Et Materialia, 1992. 26(10): p. 1571-1574. 32. H. Li, D. Dunne, and N. Kennon, Factors influencing shape memory effect and phase transformation behaviour of Fe–Mn–Si based shape memory alloys. Materials Science and Engineering: A, 1999. 273–275(0): p. 517-523. 33. H.C. Lin, C.S. Lin, K.M. Lin, and Y.C. Chuang, An investigation of grain-boundary phase in Fe–30Mn–6Si–5Cr shape memory alloy. Journal of Alloys and Compounds, 2001. 319: p. 283. 34. A. Redjaimia, A. Proult, P. Donnadieu, and J.P. Morniroli, Morphology, crystallography and defects of the intermetallic χ-phase precipitated in a duplex (δ + γ) stainless steel. Journal of Materials Science, 2004. 39(7): p. 2371-2386. 35. C.H. Yang, H.C. Lin, K.M. Lin, and H.K. Tsai, Effect of thermo-mechanical treatment on a Fe-30Mn-6Si shape memory alloy. Materials Science and Engineering: A, 2008. 497: p. 445. 36. Y.J. Oh and J.H. Hong, Nitrogen effect on precipitation and sensitization in cold-worked Type 316L(N) stainless steels. Journal of Nuclear Materials, 2000. 278(2–3): p. 242-250. 37. B. Weiss and R. Stickler, Phase instabilities during high temperature exposure of 316 austenitic stainless steel. Metallurgical Transactions, 1972. 3(4): p. 851-866. 38. N. Stanford, D.P. Dunne, and B.J. Monaghan, Austenite stability in Fe-Mn-Si-based shape memory alloys. Journal of Alloys and Compounds, 2007. 430(1-2): p. 107-115. 39. Y.H. Wen, L.R. Xiong, N. Li, and W. Zhang, Remarkable improvement of shape memory effect in an Fe-Mn-Si-Cr-Ni-C alloy through controlling precipitation direction of Cr23C6. Materials Science and Engineering a-Structural Materials Properties Microstructure and Processing, 2008. 474(1-2): p. 60-63. 40. K. Yamaguchi, Y. Morioka, and Y. Tomota, Anisotropy in the shape memory effect in thermomechanically treated Fe-Mn-Si alloys. Scripta Materialia, 1996. 35(10): p. 1147-1152. 41. J.H. Yang and C.M. Wayman, Development of Fe-based shape memory alloys associated with face-centered cubic-hexagonal close-packed martensitic transformations: Part III. microstructures. Metallurgical Transactions A, 1992. 23(5): p. 1445-1454. 42. V.G. Gavriljuk, V.V. Bliznuk, B.D. Shanina, and S.P. Kolesnik, Effect of silicon on atomic distribution and shape memory in Fe–Mn base alloys. Materials Science and Engineering: A, 2005. 406(1–2): p. 1-10. 43. S.N. Balo, A Comparative Study on Crystal Structure and Magnetic Properties of Fe-Mn-Si and Fe-Mn-Si-Cr Alloys. Journal of Superconductivity and Novel Magnetism, 2013. 26(4): p. 1085-1088. 44. O. Matsumura, S. Furusako, T. Sumi, T. Furukawa, and H. Otsuka, Improvement of shape memory effect due to low-finishing-temperature hot-rolling in an Fe–28Mn–6Si–5Cr alloy. Materials Science and Engineering: A, 1999. 272(2): p. 459-462. 45. Characteristics and applications of Fe-Mn-Si-based shape memory alloys. [cited 2013 June]; AWAJI MATERIA CO., LTD. Available from: http://www.awaji-m.jp/english/r_and_d/pdf/memory_alloy.pdf. 46. 安田弘行, 丸山武紀, S. Harjo, and 伊藤崇芳. 新規超弾性材料及び超弾性機構, 第3回MLFシンポジウム. 2012. いばらき量子ビームセンター. 47. 蒲生隆政, 修士論文-鉄系形状記憶合金の形状回復特性, 工学研究科機械工学専攻修士課程2010, 法政大学大学院. 48. T. Maruyama, T. Kurita, S. Kozaki, K. Andou, S. Farjami, and H. Kubo, Innovation in producing crane rail fishplate using Fe–Mn–Si–Cr based shape memory alloy. Materials Science and Technology, 2008. 24(8): p. 908-912. 49. Wikipedia, Manual rivet installation with ball peen hammer, Rivet.svg, Editor 2007, Wikipedia. 50. FTM技資. 形状記憶合金の応用例. 1997 [cited 2013 June]; 古河テクノマテリアル. Available from: http://www.furukawa-ftm.com/nt/lib/furu-nt2.htm. 51. X.H. Min, T. Sawaguchi, K. Ogawa, T. Maruyama, F.X. Yin, and K. Tsuzaki, Shape memory effect in Fe–Mn–Ni–Si–C alloys with low Mn contents. Materials Science and Engineering: A, 2011. 528(15): p. 5251-5258. 52. J.H. Jun and C.S. Choi, Variation of stacking fault energy with austenite grain size and its effect on the MS temperature of γ→ε martensitic transformation in Fe-Mn alloy. Material Science and Engineering. A, 1998. 257: p. 353-356. 53. B.H. Jiang, X.A. Qi, S.X. Yang, W.M. Zhou, and T.Y. Hsu, Effect of stacking fault probability on γ–ε martensitic transformation and shape memory effect in Fe–Mn–Si based alloys. Acta Materialia, 1998. 46(2): p. 501-510. 54. L. Engel and H. Klingele, An Atlas of Metal Damage: Surface Examination by Scanning Electron Microscope. 2001: Flender Service. 55. D.A. Porter, K.E. Easterling, and M.Y. Sherif, Phase Transformations in Metals and Alloys. 2009: Taylor & Francis Group. | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/61552 | - |
dc.description.abstract | Fe-Mn-Si-Cr形狀記憶合金具有良好的加工成形性、良好的形狀記憶效應、以及相對低廉的單位成本。除此之外,Fe-Mn-Si-Cr合金只具有單向記憶效應,一旦經過加熱回復形狀一次後,形狀就不會再隨溫度變化而改變。因此Fe-Mn-Si-Cr合金對於大尺度、只需要一次性變形的機構應用來說,是相當理想的材料。工業上應用的實例如連接管路用的套筒元件、連接軌道的魚尾板、以及鉚釘。本研究藉由添加0.1wt%以及1.0wt%的鉭元素於Fe-30Mn-6Si-5Cr合金中,搭配2小時500到800℃的時效處理,來改善其形狀記憶效應。其中添加1.0wt%鉭並經過2小時700℃時效處理後的合金,與未經添加與熱處理的合金相比,有最高的形狀回復率,其增加量達16%。經過時校處理後,在γ基地發現有TaC與χ相兩種不同的第二相顆粒,在不同的鉭添加與時效處理溫度下,這些析出物的大小與分佈也隨之不同。本研究發現,鉭添加對於改善形狀記憶效應的機制有以下數種:固溶強化與析出第二相強化 γ奧氏體母相、γ奧氏體母相的晶粒細化、析出物在γ晶粒內對於不同方向ε麻田散鐵成長的區隔效應、以及增加γ母相內的疊差機率。 | zh_TW |
dc.description.abstract | Fe-Mn-Si-Cr based shape memory alloys (SMAs) have desirable formability, moderate shape memory effect (SME) and low cost. This makes ferrous SMAs highly potential in large-scaled applications such as pipe coupling, rail fish plates, and other smart construction methods. Also, Fe-Mn-Si-Cr alloys only have one-way shape memory effect, which is ideal for applications that require only-one-time shape recovery as the fixed structure shape. In this study, the shape memory effect of Fe-30Mn-6Si-5Cr (in wt%) SMAs are improved by adding 0.1 wt% and 1.0 wt% Ta along with ageing treatment from 500 to 800℃ for 2 hours. 1.0 weight percent Ta addition followed by ageing at 700℃ for 2 hours increases recovery ratio up to 16 percent. Precipitate particles such as TaC and χ were found in the aged samples with different size and distribution in the γ matrix. Mechanisms of improving SME by Ta addition are proposed in the work: Solid solution and precipitation strengthening on the γ matrix, grain refining of γ parent phase, domain effect of precipitate particles, and increasing of stacking fault probability. | en |
dc.description.provenance | Made available in DSpace on 2021-06-16T13:05:39Z (GMT). No. of bitstreams: 1 ntu-102-R00527025-1.pdf: 15892992 bytes, checksum: 65d964cb17ff114f63b20be34559ac12 (MD5) Previous issue date: 2013 | en |
dc.description.tableofcontents | 誌謝 III
摘要 IV Abstract V Contents VI List of Figures VIII List of Tables XIII Chapter 1 Introduction 1 Chapter 2 Literature Review 3 2.1 Properties of Shape Memory Alloys 3 2.1.1 Thermoelastic and Non-thermoelastic Martensitic Transformation 4 2.1.2 Shape Memory Effect of Thermoelastic SMAs 9 2.1.3 Pseudoelastic Effect of Thermoelastic SMAs 16 2.2 Fe-based Shape Memory Alloys 22 2.2.1 The Development of Different SMA Systems 22 2.2.2 Types of Fe-based SMAs 23 2.2.3 The Mechanism and Development of Fe-Mn-Si SMAs 25 2.3 Modifications on Fe-based SMAs 35 2.3.1 The Effects of Heat Treatment and Precipitation 35 2.3.2 The Effects of Pre-strain/ Cold Working 36 2.3.3 The Effects of Adding Elements 37 2.3.4 Variation of Transformation temperatures 39 2.4 Application of Fe-based SMAs 46 2.4.1 The Advantage of Fe-based SMAs 46 2.4.2 Pipe Coupling 47 2.4.3 Fish Plate 50 2.4.4 Smart Rivet 52 2.4.5 High Damping Steel Structure 53 Chapter 3 Experimental Procedure 55 3.1 Alloy Preparation 55 3.2 Composition Analysis 56 3.3 XRD Phase Analysis 57 3.4 SME Recovery Ratio 58 3.5 Hardness Test 60 3.6 Differential Scanning Calorimetry 60 3.7 Fracture Surface Morphology 61 3.8 Scanning Electron Microscopy 61 3.9 Transmission Electron Microscopy 62 Chapter 4 Results and Discussion 63 4.1 Composition Analysis 63 4.2 XRD Phase Analysis 64 4.3 SME Recovery Ratio 67 4.4 Hardness Test 68 4.5 Differential Scanning Calorimetry 70 4.6 Fracture Surface Morphology 74 4.7 Transmission Electron Microscopy 91 Chapter 5 Conclusions 105 Reference Lists 108 Appendices 113 | |
dc.language.iso | en | |
dc.title | 鉭添加對於Fe-30Mn-6Si-5Cr形狀記憶合金之效應 | zh_TW |
dc.title | Effects of Tantalum Addition on Fe-30Mn-6Si-5Cr Shape Memory Alloys | en |
dc.type | Thesis | |
dc.date.schoolyear | 101-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 吳錫侃,林昆明,薛人愷 | |
dc.subject.keyword | Fe-Mn-Si-Cr形狀記憶合金,形狀記憶效應,麻田散鐵變態,鉭元素,固溶強化,析出,疊差, | zh_TW |
dc.subject.keyword | Fe-Mn-Si-Cr shape memory alloys,shape memory effect,martensitic transformation,tantalum,solid solution strengthening,precipitation,stacking fault, | en |
dc.relation.page | 120 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2013-08-02 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 材料科學與工程學研究所 | zh_TW |
顯示於系所單位: | 材料科學與工程學系 |
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