請用此 Handle URI 來引用此文件：
http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/49025完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 葉安義 | |
| dc.contributor.author | Wei-You Su | en |
| dc.contributor.author | 蘇韋友 | zh_TW |
| dc.date.accessioned | 2021-06-15T11:13:58Z | - |
| dc.date.available | 2021-09-14 | |
| dc.date.copyright | 2016-09-14 | |
| dc.date.issued | 2016 | |
| dc.date.submitted | 2016-08-21 | |
| dc.identifier.citation | 李河水; 王素梅; 陳玉玲; 陳麗婷; 彭素玲; 黃秋香; 邱盟媚; 鄔嫣珊; 賴孟利; 陳致遠; 羅伊珊; 鄭佩真; 林淨鈴; 溫采薇, 食品產業年鑑. 台北: 財團法人食品工業發展研究所 2015; pp 202-212.
蔡佳芬; 郭景豪; 黃立宇; 曾素香; 蘇淑珠; 闕麗卿, 高效液相層析串聯質譜法分析食品中之防腐劑. 食品藥物研究年報 2011, 97-106. 行政院衛生福利部食品藥物管理署。2013。公告食品化學檢驗方法之確效規範。行政院衛生福利部食品藥物管理署102年09月09日第二次修正。 Abraham, K.; Appel, K. E.; Berger-Preiss, E.; Apel, E.; Gerling, S.; Mielke, H.; Creutzenberg, O.; Lampen, A., Relative oral bioavailability of 3-MCPD from 3-MCPD fatty acid esters in rats. Arch Toxicol 2013, 87, 649-659. Barocelli, E.; Corradi, A.; Mutti, A.; Petronini, P., Comparison between 3‐MCPD and its palmitic esters in a 90‐day toxicological study. EFSA Supporting Publications 2011, 8. Becalski, A.; Feng, S.; Lau, B. P. Y.; Zhao, T., A pilot survey of 2- and 3-monochloropropanediol and glycidol fatty acid esters in foods on the Canadian market 2011–2013. Journal of Food Composition and Analysis 2015, 37, 58-66. Buckle, A., Rodenticides. In Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH Verlag GmbH & Co. KGaA: 2000; pp 576-577. Buhrke, T.; Weißhaar, R.; Lampen, A., Absorption and metabolism of the food contaminant 3-chloro-1,2-propanediol (3-MCPD) and its fatty acid esters by human intestinal Caco-2 cells. Arch Toxicol 2011, 85, 1201-1208. Cho, W.-S.; Han, B. S.; Lee, H.; Kim, C.; Nam, K. T.; Park, K.; Choi, M.; Kim, S. J.; Kim, S. H.; Jeong, J.; Jang, D. D., Subchronic toxicity study of 3-monochloropropane-1,2-diol administered by drinking water to B6C3F1 mice. Food and Chemical Toxicology 2008, 46, 1666-1673. Collier, P.; Cromie, D.; Davies, A., Mechanism of formation of chloropropanols present in protein hydrolysates. Journal of the American Oil Chemists Society 1991, 68, 785-790. Craft, B. D.; Nagy, K.; Sandoz, L.; Destaillats, F., Factors impacting the formation of Monochloropropanediol (MCPD) fatty acid diesters during palm (Elaeis guineensis) oil production. Food Addit. Contam. Part A-Chem. 2012, 29, 354-361. Crews, C.; Chiodini, A.; Granvogl, M.; Hamlet, C.; Hrncirik, K.; Kuhlmann, J.; Lampen, A.; Scholz, G.; Weisshaar, R.; Wenzl, T.; Jasti, P. R.; Seefelder, W., Analytical approaches for MCPD esters and glycidyl esters in food and biological samples: a review and future perspectives. Food Addit. Contam. Part A-Chem. 2013, 30, 11-45. Destaillats, F.; Craft, B. D.; Sandoz, L.; Nagy, K., Formation mechanisms of Monochloropropanediol (MCPD) fatty acid diesters in refined palm ( Elaeis guineensis ) oil and related fractions. Food Additives & Contaminants. Part A: Chemistry, Analysis, Control, Exposure & Risk Assessment 2012, 29, 29-37. Divinova, V.; Svejkovska, B.; Dolezal, M.; Velisek, J., Determination of free and bound 3-chloropropane-1,2-diol by gas chromatography with mass spectrometric detection using deuterated 3-chloropropane-1,2-diol as internal standard. Czech. J. Food Sci. 2004, 22, 182-189. EFSA CONTAM Panel (EFSA Panel on Contaminants in the Food Chain), 2016. Scientific opinion on the risks for human health related to the presence of 3- and 2-monochloropropanediol (MCPD), and their fatty acid esters, and glycidyl fatty acid esters in food. EFSA Journal 2016;14(5): 4426, 159 pp. Epstein, S. S.; Arnold, E.; Andrea, J.; Bass, W.; Bishop, Y., Detection of chemical mutagens by the dominant lethal assay in the mouse. Toxicology and Applied Pharmacology 1972, 23, 288-325. Ericsson, R. J.; Baker, V. F., Male antifertility compounds - biological properties of U-5897 and U-15,646. J. Reprod. Fertil. 1970, 21, 267-273. Ermacora, A.; Hrncirik, K., Evaluation of an improved indirect method for the analysis of 3-MCPD esters based on acid transesterification. J Am Oil Chem Soc 2012, 89, 211-217. Ermacora, A.; Hrncirik, K., Influence of oil composition on the formation of fatty acid esters of 2-chloropropane-1,3-diol (2-MCPD) and 3-chloropropane-1,2-diol (3-MCPD) under conditions simulating oil refining. Food Chemistry 2014a, 161, 383-389. Ermacora, A.; Hrncirik, K., Study on the thermal degradation of 3-MCPD esters in model systems simulating deodorization of vegetable oils. Food Chemistry 2014b, 150, 158-163. Frei, H.; Würgler, F. E., The vicinal chloroalcohols 1,3-dichloro-2-propanol (DC2P), 3-chloro-1,2-propanediol (3CPD) and 2-chloro-1,3-propanediol (2CPD) are not genotoxic in vivo in the wing spot test of Drosophila melanogaster. Mutation Research/Genetic Toxicology and Environmental Mutagenesis 1997, 394, 59-68. Gunstone, F. D., Extraction, Refining, and Modification Processes. In Oils and Fats in the Food Industry, Wiley-Blackwell: 2009; pp 26-36. Hamlet, C. G.; Sadd, P. A.; Gray, D. A., Chloropropanols and their esters in baked cereal products. Abstracts of Papers of the American Chemical Society 2004, 227, U38-U38. Hamlet, C. G.; Sadd, P. A., Chloropropanols and Chloroesters. In Process-Induced Food Toxicants, John Wiley & Sons, Inc.: 2008; pp 175-214. Hrncirik, K.; van Duijn, G., An initial study on the formation of 3-MCPD esters during oil refining. Eur. J. Lipid Sci. Technol. 2011, 113, 374-379. Hrncirik, K.; Zelinkova, Z.; Ermacora, A., Critical factors of indirect determination of 3-chloropropane-1,2-diol esters. Eur. J. Lipid Sci. Technol. 2011, 113, 361-367. Jędrkiewicz, R.; Kupska, M.; Głowacz, A.; Gromadzka, J.; Namieśnik, J., 3-MCPD: A Worldwide Problem of Food Chemistry. Critical Reviews in Food Science and Nutrition 2015, 00-00. Jeong, J.; Han, B.; Cho, W.-S.; Choi, M.; Ha, C.-S.; Lee, B.-S.; Kim, Y.-B.; Son, W.-C.; Kim, C.-Y., Carcinogenicity study of 3-monochloropropane-1, 2-diol (3-MCPD) administered by drinking water to B6C3F1 mice showed no carcinogenic potential. Arch Toxicol 2010, 84, 719-729. Jones, A.; Davies, P.; Edwards, K.; Jackson, H., Antifertility effects and metabolism of alpha and epi-chlorohydrins in the rat. Nature 1969, 224, 83. Jones, A. R., The Metabolism of 3-Chloro-, 3-Bromo- and 3-Iodopropan-1,2-diol in Rats and Mice. Xenobiotica 1975, 5, 155-165. Jones, A. R., The antifertility actions of α-chlorohydrin in the male. Life Sciences 1978, 23, 1625-1645. Jones, A. R.; Milton, D. H.; Murcott, C., The oxidative metabolism of α-chlorohydrin in the male rat and the formation of spermatocoeles. Xenobiotica 1978, 8, 573-582. Karasek, L.; Wenzl, T.; Ulberth, F., Proficiency test on the determination of 3-MCPD esters in edible oil. Luxembourg: Publications Office of the European Union; 2010: pp 1-62 Kim, K.; Song, C.; Park, Y.; Koh, S.; Kim, J.; Kim, S.; Kim, Y.; Kim, S. U.; Jung, H., 3-monochloropropane-1,2-diol does not cause neurotoxicity in vitro or neurobehavioral deficits in rats. NeuroToxicology 2004, 25, 377-385. Küsters, M.; Bimber, U.; Reeser, S.; Gallitzendörfer, R.; Gerhartz, M., Simultaneous Determination and differentiation of glycidyl esters and 3-monochloropropane-1,2-diol (MCPD) esters in different foodstuffs by GC-MS. Journal of Agricultural and Food Chemistry 2011, 59, 6263-6270. Lee, J. K.; Byun, J. A.; Park, S. H.; Kim, H. S.; Park, J. H.; Eom, J. H.; Oh, H. Y., Evaluation of the potential immunotoxicity of 3-monochloro-1,2-propanediol in Balb/c mice: I. Effect on antibody forming cell, mitogen-stimulated lymphocyte proliferation, splenic subset, and natural killer cell activity. Toxicology 2004, 204, 1-11. Lee, J. K.; Byun, J. A.; Park, S. H.; Choi, H. J.; Kim, H. S.; Oh, H. Y., Evaluation of the potential immunotoxicity of 3-monochloro-1,2-propanediol in Balb/c mice: II. Effect on thymic subset, delayed-type hypersensitivity, mixed-lymphocyte reaction, and peritoneal macrophage activity. Toxicology 2005, 211, 187-196. Liu, M.; Gao, B.-Y.; Qin, F.; Wu, P.-P.; Shi, H.-M.; Luo, W.; Ma, A.-N.; Jiang, Y.-R.; Xu, X.-B.; Yu, L.-L., Acute oral toxicity of 3-MCPD mono- and di-palmitic esters in Swiss mice and their cytotoxicity in NRK-52E rat kidney cells. Food and Chemical Toxicology 2012, 50, 3785-3791. Lynch, B. S.; Bryant, D. W.; Hook, G. J.; Nestmann, E. R.; Munro, I. C., Carcinogenicity of monochloro-1,2-propanediol (α-chlorohydrin, 3-MCPD). International Journal of Toxicology 1998, 17, 47-76. MacMahon, S., Processing Contaminants in Edible Oils: MCPD and Glycidyl Esters. Elsevier Science: 2015. Mogol, B. A.; Pye, C.; Anderson, W.; Crews, C.; Gökmen, V., Formation of Monochloropropane-1,2-diol and Its Esters in Biscuits during Baking. Journal of Agricultural and Food Chemistry 2014, 62, 7297-7301. Painter, R. B.; Howard, R., The HeLa DNA-synthesis inhibition test as a rapid screen for mutagenic carcinogens. Mutation Research/Fundamental and Molecular Mechanisms of Mutagenesis 1982, 92, 427-437. Piasecki, A.; Ruge, A.; Marquardt, H., Malignant transformation of mouse M2-fibroblasts by glycerol chlorohydrines contained in protein hydrolysate and commercial food. Arzneimittel-Forschung/Drug Research 1990, 40-2, 1054-1055. Rahn, A. K. K.; Yaylayan, V. A., What do we know about the molecular mechanism of 3‐MCPD ester formation? Eur. J. Lipid Sci. Technol. 2011, 113, 323-329. Rossi, A. M.; Migliore, L.; Lascialfari, D.; Sbrana, I.; Loprieno, N.; Tortoreto, M.; Bidoli, F.; Pantarotto, C., Genotoxicity, metabolism and blood kinetics of epichlorohydrin in mice. Mutation Research 1983, 118, 213-226. Sampaio, K. A.; Arisseto, A. P.; Ayala, J. V.; Stevens, C.; Ceriani, R.; Verhé, R.; Meirelles, A. J. A., Influence of the process conditions on the formation of 3-MCPD esters in palm oil. Toxicology Letters 2013, 221, Supplement, S122. Seefelder, W.; Seefelder, N.; Varga, A.; Studer, G.; Williamson, F. P.; Scanlan, R. H., Esters of 3-chloro-1,2-propanediol (3-MCPD) in vegetable oils: Significance in the formation of 3-MCPD. Food Additives & Contaminants. Part A. Chemistry, Analysis, Control, Exposure & Risk Assessment 2008, 25, 391-400. Silhankova, L.; Smid, F.; Cerna, M.; Davidek, J.; Velisek, J., Mutagenicity of glycerol chorohydrines and of their esters with higher fatty-acids present in protein hydrolysates. Mutation Research 1982, 103, 77-81. Skoog, D. A.; Holler, F. J.; Crouch, S. R., Principles of Instrumental Analysis. Thomson Brooks/Cole: 2007; pp 20-21. Smidrkal, J.; Ilko, V.; Filip, V.; Dolezal, M.; Zelinkova, Z.; Kyselka, J.; Hradkova, I.; Velisek, J., Formation of Acylglycerol Chloro Derivatives in Vegetable Oils and Mitigation Strategy. Czech. J. Food Sci. 2011, 29, 448-456. Sonnet, P. E., A short highly regio-and stereoselective synthesis of triacylglycerols. Chemistry and Physics of Lipids 1991, 58, 35-39. Stolzenberg, S. J.; Hine, C. H., Mutagenicity of 2-carbon and 3-carbon halogenated compounds in the Salmonella-mammalian-microsome test. Environmental Mutagenesis 1980, 2, 59-66. Sun, J.; Bai, S.; Bai, W.; Zou, F.; Zhang, L.; Su, Z.; Zhang, Q.; Ou, S.; Huang, Y., Toxic mechanisms of 3-monochloropropane-1,2-diol on progesterone production in R2C rat leydig cells. Journal of Agricultural and Food Chemistry 2013, 61, 9955-9960. Svejkovska, B.; Novotny, O.; Divinova, V.; Reblova, Z.; Dolezal, M.; Velisek, J., Esters of 3-chloropropane-1,2-diol in foodstuffs. Czech. J. Food Sci. 2004, 22, 190-196. Van Den Wijngaard, A. J.; Janssen, D. B.; Witholt, B., Degradation of epichlorohydrin and halohydrins by bacterial cultures isolated from freshwater sediment. Microbiology 1989, 135, 2199-2208. Velíšek, J.; Doležal, M.; Crews, C.; Dvoøák, T., Optical isomers of chloropropanediols: mechanisms of their formation and decomposition in protein hydrolysates. Czech J. Food Sci 2002, 20, 161-170. Velisek, J.; Davidek, J.; Kubelka, V.; Janicek, G.; Svobodova, Z.; Simicova, Z., New chlorine-containing organic compounds in protein hydrolysates. Journal of Agricultural and Food Chemistry 1980, 28, 1142-1144. Weisshaar, R., Determination of total 3-chloropropane-1,2-diol (3-MCPD) in edible oils by cleavage of MCPD esters with sodium methoxide. Eur. J. Lipid Sci. Technol. 2008, 110, 183-186. Weisshaar, R.; Perz, R., Fatty acid esters of glycidol in refined fats and oils. Eur. J. Lipid Sci. Technol. 2010, 112, 158-165. Weisshaar, R., Fatty acid esters of 3-MCPD: Overview of occurrence and exposure estimates. Eur. J. Lipid Sci. Technol. 2011, 113, 304-308. Yale, H. L.; Pribyl, E. J.; Braker, W.; Bergeim, F. H.; Lott, W. A., Muscle-relaxing compounds similar to 3-(o-Toloxy)-1,2-propanediol.1 I. Aromatic ethers of polyhydroxy alcohols and related compounds2,3. Journal of the American Chemical Society 1950, 72, 3710-3716. Yu, L.; Wang, S.; Sun, B. G., Food Safety Chemistry: Toxicant Occurrence, Analysis and Mitigation. CRC Press: 2014; pp 89-132 Zelinková, Z.; Svejkovská, B.; Velíšek, J.; Doležal, M., Fatty acid esters of 3-chloropropane-1,2-diol in edible oils. Food Additives & Contaminants 2006, 23, 1290-1298. Zelinková, Z.; Novotný, O.; Schůrek, J.; Velíšek, J.; Hajšlová, J.; Doležal, M., Occurrence of 3-MCPD fatty acid esters in human breast milk. Food Additives & Contaminants: Part A 2008, 25, 669-676. Zhang, X.; Gao, B.; Qin, F.; Shi, H.; Jiang, Y.; Xu, X.; Yu, L., Free radical mediated formation of 3-monochloropropanediol (3-MCPD) fatty acid diesters. Journal of Agricultural and Food Chemistry 2013, 61, 2548-2555. Zhou, H.; Jin, Q.; Wang, X.; Xu, X., Direct measurement of 3-chloropropane-1,2-diol fatty acid esters in oils and fats by HPLC method. Food Control 2014a, 36, 111-118. Zhou, H.; Jin, Q.; Wang, X.; Xu, X., Effects of temperature and water content on the formation of 3-chloropropane-1,2-diol fatty acid esters in palm oil under conditions simulating deep fat frying. Eur Food Res Technol 2014b, 238, 495-501. Zulkurnain, M.; Lai, O. M.; Latip, R. A.; Nehdi, I. A.; Ling, T. C.; Tan, C. P., The effects of physical refining on the formation of 3-monochloropropane-1,2-diol esters in relation to palm oil minor components. Food Chemistry 2012, 135, 799-805. Zulkurnain, M.; Lai, O. M.; Tan, S. C.; Latip, R. A.; Tan, C. P., Optimization of Palm Oil Physical Refining Process for Reduction of 3-Monochloropropane-1,2-diol (3-MCPD) Ester Formation. Journal of Agricultural and Food Chemistry 2013, 61, 3341-3349. | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/49025 | - |
| dc.description.abstract | 世界衛生組織癌症研究署(International Agency for Research on Cancer, IARC) 於2013年將3-單氯丙二醇(3-Monochloropropane-1,2-diol , 3-MCPD)歸類為「Group 2B」-對人類懷疑為致癌物，德國聯邦風險評估所(Bundesinstitut für Risikobewertung, BfR)，在2008年假設在人體3-MCPD-E水解程度為100%，且基於3-MCPD現有毒性報告，進行風險評估，歐洲食品安全局(European Food Safety Authority, EFSA)，也認同此假設，因此，在現有文獻下，3-MCPD-E毒性評估與3-MCPD相同。本研究以GC/MS 分析食用油中3-MCPD-E含量，及IC分析食用油中無機氯含量，並進行方法確效，無論再現性、重複性及準確性均良好。本研究共調查市售29件食用油，以及各種精煉階段棕櫚油31件。發現植物油中，3-MCPD-E含量依高低排列分別為棕櫚油(4.72 μg/g)>葵花油(1.31 μg/g)>大豆油(0.44 μg/g) >芥花油(0.22 μg/g)>紅花籽油(0.19 μg/g)>玉米胚芽油(0.18 μg/g) >苦茶油(0.11 μg/g)，動物油及其類似產品的部分，加鹽奶油(11.15~7.35 μg/g)>瑪琪琳(5.52 μg/g)>無鹽奶油(< 0.02 μg/g)>豬油(< 0.01 μg/g)，由於奶油不需高溫精煉，因此3-MCPD-E可能有低溫生成路徑。PCA分析發現植物油中總氯含量與3-MCPD-E呈現高度正相關，無機氯與3-MCPD-E為低度負相關。動物油及其類似產品無機氯則與3-MCPD-E呈現高度正相關。觀察精煉階段棕櫚油中3-MCPD-E與氯消長，發現壓榨後棕櫚油原油中總氯為5.8 μg/g，其中無機氯為4.2 μg/g，但3-MCPD-E則為未檢出。當經過初次精煉後，原油中的總氯下降，且無機氯下降至定量極限以下(<0.25 μg/g)，而3-MCPD-E上升至2.88 μg/g，顯示無機氯確實與3-MCPD-E含量有關，另外發現，凡經二次精煉的棕櫚油，皆發現3-MCPD-E含量有顯著性的下降。 | zh_TW |
| dc.description.abstract | 3-monochloropropane-1,2-diol (3-MCPD) has been classified as Group 2B, ‘‘possibly carcinogenic to humans’’ by the International Agency on Research on Cancer in 2013. In this study, analyzed the content of 3-MCPD-E of edible oils was determined by using GC / MS, and inorganic chloride content of edible oils was analyzed by using IC. Based on the content of 3-MCPD-E, palm oil (4.72 μg/g)> sunflower oil (1.31 μg/g)> soybean oil (0.44 μg/g)> canola oil (0.22 μg/g)> safflower oil (0.19 μg/g)> corn germ oil (0.18 μg/g)> camellia (0.11 μg/g). Nevertheless, among animal oil products, 3-MCPD-E contents of salted butter (11.15 ~ 7.35 μg/g) and margarine (5.52 μg/g) they were much greater than unsalted butter (<0.02 μg/g) and lard (<0.01 μg/g). Chlorine was found positively correlated with the 3-MCPD-E by using PCA analysis. Nevertheless, 3-MCPD-E in animal oil products (butter, margarine and lard) was positively correlated with inorganic chloride. There were 5.8 μg/g of chlorine amd 4.2 μg/g of inorganic chlorine in crude palm oil, but no 3-MCPD-E. Refining resulted in disappearance of inorganic chloride and occurrence of 3-MCPD-E (2.88 μg/g). The content of 3-MCPD-E was further lowered after second refining process. The data has shown that chloride is an important factor affectively the formation of 3-MCPD-E. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-15T11:13:58Z (GMT). No. of bitstreams: 1 ntu-105-R02641050-1.pdf: 2883647 bytes, checksum: 888dd862d5eff2b67697ad33abf401f1 (MD5) Previous issue date: 2016 | en |
| dc.description.tableofcontents | 謝誌 i
摘要 ii Abstract iii 目錄 I 圖目錄 V 表目錄 VII 壹、 前言 1 貳、 文獻回顧 2 一、 3-單氯丙二醇簡介 2 (一) 特性與用途 2 (二) 食品中3-單氯丙二醇及其酯類的發現 2 (三) 3-單氯丙二醇與其酯類之風險評估 3 1. 吸收與代謝 3 2. 組織病理學 5 3. 急性毒性 6 4. 免疫毒性 6 5. 神經毒性 6 6. 生殖毒性 6 7. 基因毒性 7 8. 致癌性 7 (四) 食品中3-單氯丙二醇酯生成機制 8 (五) 3-單氯丙二醇酯生成因子 9 1. 有機氯與無機氯 9 2. 甘油類 9 (六) 3-單氯丙二醇及其酯類檢測分析 9 1. 直接法 9 2. 間接法 9 二、 食用油概況 10 (一) 全球主要油籽 10 (二) 全球植物油主要生產及進出口概況 10 (三) 台灣油脂 11 (四) 油品精煉製程 11 1. 油脂提取 11 2. 脫膠 11 3. 脫酸 12 4. 脫色 12 5. 脫臭 12 參、 研究目的及試驗設計 13 一、 研究目的 13 二、 試驗設計 13 (一) GC/MS 分析方法之確效 13 (二) IC 分析方法之確效 16 (三) 3-單氯丙二醇酯與無機氯/總氯關聯性之試驗 19 肆、 材料與方法 21 一、 試驗材料 21 二、 試驗方法 21 (一) 3-單氯丙二醇酯含量之測定 21 1. 原理 21 (1). 游離態3-MCPD之測定 21 (2). 總3-MCPD之測定 21 2. 標準品 22 3. 試藥 22 4. 器具 23 5. 儀器裝置 23 6. 油品游離態3-MCPD測定方法 24 7. 油品中總3-MCPD測定方法 26 8. 油品中3-MCPD-E之計算 29 9. 方法確效 29 (二) 無機氯測定 33 1. 標準品 33 2. 試藥 33 3. 器具 33 4. 儀器裝置 33 5. 方法 34 6. 方法確效 37 (三) 總氯測定 40 1. 標準品 40 2. 試藥 40 3. 儀器裝置 40 4. 方法 41 (四) 統計分析 43 伍、 結果與討論 44 (一) 氣相層析質譜儀之確效評估 44 1. 方法改善 44 2. 校正曲線 48 3. 回收試驗 52 4. 重複性試驗 52 5. 再現性試驗 52 6. 方法偵測極限與定量極限 56 7. 鑑別試驗 58 (二) 離子層析儀之確效評估 61 1. 校正曲線 61 2. 回收試驗 61 3. 重複性試驗 65 4. 再現性試驗 65 5. 方法偵測極限與定量極限 68 6. 鑑別試驗 68 (三) 市售食用油中3-單氯丙二醇酯、無機氯及總氯之測定 72 1. 市售食用油中3-單氯丙二醇酯 72 (1). 市售植物油 72 (2). 市售動物性油品及其類似產品 72 2. 市售食用油中無機氯及總氯 76 (1). 市售植物油 76 (2). 市售動物性油品及其類似產品 76 (四) 市售食用油中3-單氯丙二醇酯、無機氯及總氯之主成分分析 77 (1). 市售植物油 77 (2). 市售動物性油品及其類似產品 77 (五) 不同精煉製程階段棕櫚油 82 (1). 3-單氯丙二醇酯與無機氯含量 82 (2). 不同精煉製程階段棕櫚油之3-單氯丙二醇酯生成與無機氯之關係 85 陸、 結論 87 柒、 參考文獻 88 捌、 附錄 94 | |
| dc.language.iso | zh-TW | |
| dc.subject | 3-單氯丙二醇酯 | zh_TW |
| dc.subject | 致癌物 | zh_TW |
| dc.subject | 棕櫚油 | zh_TW |
| dc.subject | 油脂精煉 | zh_TW |
| dc.subject | 無機氯 | zh_TW |
| dc.subject | refining process | en |
| dc.subject | palm oil | en |
| dc.subject | inorganic chloride | en |
| dc.subject | carcinogen | en |
| dc.subject | 3-MCPD ester | en |
| dc.title | 台灣食用油中3-單氯丙二醇酯與氯含量之關聯性 | zh_TW |
| dc.title | Correlation between 3-MCPD Ester and Chloride Contents of Edible Oils in Taiwan | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 104-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 陳時欣,鄭維智,戴淑文 | |
| dc.subject.keyword | 3-單氯丙二醇酯,致癌物,油脂精煉,無機氯,棕櫚油, | zh_TW |
| dc.subject.keyword | 3-MCPD ester,carcinogen,refining process,inorganic chloride,palm oil, | en |
| dc.relation.page | 139 | |
| dc.identifier.doi | 10.6342/NTU201602810 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2016-08-21 | |
| dc.contributor.author-college | 生物資源暨農學院 | zh_TW |
| dc.contributor.author-dept | 食品科技研究所 | zh_TW |
| 顯示於系所單位： | 食品科技研究所 | |
文件中的檔案：
| 檔案 | 大小 | 格式 | |
|---|---|---|---|
| ntu-105-1.pdf 未授權公開取用 | 2.82 MB | Adobe PDF |
系統中的文件，除了特別指名其著作權條款之外，均受到著作權保護，並且保留所有的權利。