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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 蔡曜陽(Yao-Yang Tsai) | |
| dc.contributor.author | Pei-Lun Song | en |
| dc.contributor.author | 宋沛倫 | zh_TW |
| dc.date.accessioned | 2021-06-15T02:35:11Z | - |
| dc.date.issued | 2009 | |
| dc.date.submitted | 2009-08-13 | |
| dc.identifier.citation | [1] Cotton, J., “Decorative Finishes on Titanium”, The Annual Conference of The Institute of Metal Finishing, Vol. 45, 1967, pp 4-6.
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[36] 周開平, 陳郁文, “二氧化鈦光觸媒應用”, 科學發展, Vol. 395, 2005, pp 66-69. [37] Kalpakjian, S., Schmid, S., “Manufacturing Engineering And Technology 5th Edition”, Prentice Hall Inc., 2006. [38] Kuznetsov, V.N. et al., “Visible Light Absorption by Various Titanium Dioxide Specimens”, Journal of Physical Chemistry B, Vol. 110(50), 2006, pp. 25203-25209. [39] 洪國維, “水溶性介電液於鈦合金放電發色”, 國立台灣大學機械工程學系碩士論文, 2006. [40] Fernandes, A.C., et al., “Influence of The O/C Ratio in The Behaviour of TiCxOy Thin Films”, Surface and Coatings Technology, Vol. 201, 2007, pp. 5587-5591. [41] Hascalik, A., et al., “Electrical Discharge Machining of Titanium Alloy (Ti-6Al-4V) ”, Applied Surface Science, Vol. 253(22), 2007, pp. 9007-9016. [42] Kuznetsov, V.N., et al., “Photoinduced Coloration and Photobleaching of Titanium Dioxide in TiO2/Polymer Compositions upon UV- and Visible-light Excitation of Color Centers' Absorption Bands: Direct Experimental Evidence Negating Band-gap Narrowing in Anion-/Cation-Doped TiO(2)s”, Journal of Physical Chemistry C, Vol. 111(42), 2007, pp. 15277-15288. [43] Lütjering, G., Williams, J.C., “Titanium – 2nd Edition”, Springer Verlag, 2007. [44] Yao, H.K., et al., “Optical and Electrical Properties of TiOx Thin Films Deposited by Electron Beam Evaporation”, Vacuum, 2007, Vol. 81(9), pp. 1023-1028. [45] Assim, E.M., “Optical Constants of Titanium Monoxide TiO Thin Films”, Journal of Alloys and Compounds, Vol. 465(1-2), 2008, pp. 1-7. [46] Chi, G.X., et al., “The Fabrication of A Micro-spiral Structure using EDM Deposition in The Air”, Journal of Micromechanics and Microengineering, Vol. 18(3), 2008, pp. 27-35. [47] Crowell, B., “Optics”, Free E-book on Website http://www.lightandmatter.com/, 2008. [48] Diamanti, M.V., et al., “Interference Colors of Thin Oxide Layers on Titanium”, Color Research and Application, Vol. 33(3), 2008, pp. 221-228. [49] Diamanti, M.V., et al., “Thickness of Anodic Titanium Oxides as A Function of Crystallographic Orientation of The Substrate”, Metallurgical and Materials Transactions A-Physical Metallurgy and Materials Science, Vol. 39A(9), 2008, pp. 2143-2147. [50] Peatross, J., Ware, M., “Physics of Light and Optics”,Brigham Young University, 2008. [51] 日本鈦協會, 周連生譯,“鈦材料及其應用”, 冶金工業出版社, 2008. [52] 台灣自來水公司, “平均水質”, http://www.water.gov.tw/, 2009. [53] 台灣自來水公司, “自來水製造流程”, http://www.water.gov.tw/, 2009. | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/43985 | - |
| dc.description.abstract | 鈦及其合金因具有良好的機械與化學性質而廣泛應用於汽車、航太與生醫等工業，近年來開始應用於民生工業上。鈦金屬的氧化物，除了有耐磨與化學性質穩定的特性，當其為薄膜時更是有著多種色彩，有可觀的商業應用價值。
本研究改良一般商業用放電加工機，使用銅電極加工純鈦工件，介電液為自來水，探討放電加工主要參數對氧化鈦放電反應膜之影響，探討參數包含加工時間、開路電壓、放電電流、放電脈衝時間、放電休止時間、放電發數、放電間隙，以此研究基礎開發不傷害材料表面，僅產生彩色氧化鈦的製程。 研究結果顯示，隨著設定的開路電壓升高，形成的氧化鈦反應膜厚度依序增厚；氧化鈦反應層之顏色會隨電壓從10到240V依序呈現土黃色（10V）、紫色（20V）、靛色（30V）、黃色（70V）、桃紅色（100V）、藍色（130V）、黃綠色（180V）、粉紅色（240V），其餘開路電壓則為前後兩色的過度色彩；放電脈衝時間與放電休止時間的增加均會造成氧化鈦反應層的色彩不均勻；放電電流對氧化鈦反應層色彩沒有影響，但放電電流大於2A後會造成材料產生移除性加工，留下凹坑；放電間隙會影響氧化鈦反應層擴散範圍的大小。 本實驗所形成的氧化鈦反應膜結構，經由XRD與EDS分析為一氧化二鈦，推論本製程為綜合熱化學氧化反應與電化學氧化反應。反應膜厚度在200nm內，折射率隨著光的波長增加而降低，並且隨著反應膜厚度增厚，折射率變化曲線整體向上提昇；而膜厚超過200nm之後，折射率隨著光波長增加的變化趨勢較為平緩；所有氧化鈦反應膜的吸收率則保持穩定。 本研究成功開發氧化鈦放電反應膜製程，相較於陽極處理，產生色彩相似，但本製程簡單、加工速度快、生產效率高、成本低、介電液環保、危險性低。 | zh_TW |
| dc.description.abstract | Titanium and its alloys have been used widely in automotive, aerospace, and biomedical industries for a long time due to its excellent mechanical and chemical properties. They were used in civil industry just in recent years. The oxide of titanium not only has good wear resistance and chemical stabilization, but also displays various colors when it is in thin film form. These attractive and various colors of titanium oxide thin film make itself have considerable commercial benefit.
In this study, a commercial EDM machine was reformed to use. The electrode were copper, the workpiece were pure titanium, and dielectric fluid were just tap water. This study investigated the influence of EDM parameters on making titanium oxide reacted thin film by EDM process, including processing time, open voltage, pulse duration, pulse interval, peak current, gap. Finally, colorful titanium oxide thin film manufacturing process without damage on workpiece surface was developed by using the database of this study. The result shows that the reacted film became thicker while higher open voltage. The colors of titanium oxide reacted films were changed by the following open voltage, from 0 to 240 volts: yellow（10V）、purple（20V）、indigo（30V）、golden yellow（70V）、peach（100V）、blue（130V）、yellow green（180V）、pink（240V）. The other open voltage produced transitive color which was between the colors produced by the neighbor open voltage. The increasing of pulse duration and pulse interval caused the non-uniform color distribution. The peak current did not influence the color of reacted film. But while peak current was higher then 2A, the craters appeared on the worked surface. The gap influenced the expending area of reacted film. And the results of XRD and EDS analysis show that the structure of reacted film is . This process was inferred that it includes electrochemistric reaction and thermochemistric reaction. Using ellipsometer, we got the variation of index of refraction and absorption in visible light range with different film thickness. Compared with anodizing process, the colorful titanium oxide reacted film with EDM process we developed is simpler, faster, cheaper, having advantages in environment protection and lower hazard. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-15T02:35:11Z (GMT). No. of bitstreams: 1 ntu-98-R96522721-1.pdf: 11207716 bytes, checksum: 88ecf3b1e2464340cdce7b6878bea129 (MD5) Previous issue date: 2009 | en |
| dc.description.tableofcontents | 口試委員會審定書---I
誌謝---II 中文摘要---III 英文摘要---IV 目錄---V 圖目錄---VII 表目錄---XI 第一章 緒論---1 1.1研究背景---1 1.2文獻回顧---4 1.2.1氧化鈦薄膜製作相關文獻---4 1.2.2使用水基放電加工液的放電加工與放電加工鈦合金的相關文獻---9 1.3研究動機與目的---12 1.4論文大綱---14 第二章 相關技術理論---15 2.1放電加工製程---15 2.1.1放電加工發展---15 2.1.2放電加工原理---17 2.1.3放電加工參數與加工特性---20 2.1.4放電加工介電液---25 2.2光與色彩---26 2.2.1基礎光學---26 2.2.2幾何光學與波動光學---27 2.2.3基礎色彩學---31 2.2.4物體的色彩---32 2.3鈦金屬---38 2.3.1鈦金屬簡介---38 2.3.2鈦金屬及鈦合金分類---40 2.3.3鈦金屬應用---44 2.4二氧化鈦---45 2.4.1二氧化鈦簡介---45 2.4.2二氧化鈦應用---47 2.4.3二氧化鈦薄膜色彩形成原理---48 2.4.4鈦金屬陽極氧化反應處理製程介紹---49 第三章 實驗內容---51 3.1實驗目的---51 3.2實驗規劃---52 3.3實驗材料---53 3.4實驗參數---56 3.5實驗設備---57 3.6量測儀器---61 第四章 實驗結果與討論---68 4.1本製程的放電波形與加工時間關係---68 4.2開路電壓對氧化鈦反應層的影響---76 4.3不同氧化鈦反應層厚度的色彩觀察---77 4.4加工時間對氧化鈦反應層的影響---84 4.5放電能量對氧化鈦反應層的影響---86 4.6放電間隙對氧化鈦反應層的影響---92 4.7本製程的加工機制推論與參數設定建議---97 4.8氧化鈦反應層的組成結構---100 4.9氧化鈦反應層的光學性質---103 第五章 結論---110 5.1結論---110 5.2本製程與陽極處理製程之比較---111 5.3未來展望---112 參考文獻---113 作者簡歷---118 | |
| dc.language.iso | zh-TW | |
| dc.title | 放電加工製作彩色氧化鈦薄膜之製程開發與光學色彩研究 | zh_TW |
| dc.title | The Study of The Optics Characteristics of Colorful Titanium Oxide Thin Layer Manufactured by EDM Process | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 97-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 邱源成(Yuang-Cherng Chiou),李驊登(Hwa-Teng Lee) | |
| dc.subject.keyword | 氧化鈦反應膜,開路電壓,色彩,一氧化二鈦, | zh_TW |
| dc.subject.keyword | Titanium oxide reacted film,Open voltage,Color,Bititanium oxide, | en |
| dc.relation.page | 118 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2009-08-13 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 機械工程學研究所 | zh_TW |
| 顯示於系所單位： | 機械工程學系 | |
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