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  1. NTU Theses and Dissertations Repository
  2. 工學院
  3. 材料科學與工程學系
請用此 Handle URI 來引用此文件: http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/31697
完整後設資料紀錄
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dc.contributor.advisor陳敏璋(Miin-Jang Chen)
dc.contributor.authorYing-Tsang Shihen
dc.contributor.author施穎蒼zh_TW
dc.date.accessioned2021-06-13T03:17:50Z-
dc.date.available2016-07-27
dc.date.copyright2006-07-31
dc.date.issued2006
dc.date.submitted2006-07-30
dc.identifier.citationChap.1
[1] 2005 International Technology Roadmap for Semiconductors.(http://www.itrs.net/)
[2] M.A. Sanchez-Garcia, F.B. Naranjo, J.L. Pau., “Ultraviolat electroluminescence in GaN/AlGaN single-hetetojunction light-emitting diodes grown on Si(111)”,
J.Appl. Phys.,vol.87, 1569 (2000)
[3] Donald A. Neamen, “Semiconductor Physics ﹠Devices”, Magraw-Hill, secondEdition (1997)
[4] D. Zhang, R. M. Kolbas, P.D. Milewski, D.J. Lichtenwalner, A.I. Kingon, and J.M. Zavada “Light emission from thermally oxidized silicon nanoparticles”,
Appl. Phys. Lett., vol.65, 2684 (1994)
[5] David B. Geohegan, Alex A. Puretzky, Gerd Duscher, and Stephen J. Pennycook, “Photoluminescence from gas-suspended nanoparticles synthesized by laser ablation”, Appl. Phys. Lett., vol.73, 438 (1998)
[6] L. Heikkila, T. Kuusela, and H. P. Hedman, “Laser type of spectra narrowing in electroluminescent superlattice prepared by low pressure chemical vapor deposition”, Superlattices and Microstructures, vol.26, 157 (1999)
[7] L. T. Canham, “Electroluminescence in the visible range during anodic oxidation of porous silicon films”, Appl. Phys. Lett., vol.57, 1046 (1990)
[8] S. Lazarouk, P. Jaguiro, “Stable electroluminescence from reverse biased n-typeporous silicon–aluminum Schottky junction device”, Appl. Phys. Lett., vol.68, 2108 (1996)
[9] M. Matsuoka and S. Tohno, “Electroluminescence of erbium-doped silicon films as grown by ion beam epitaxy ”, Appl. Phys. Lett. vol.71, 96 (1997)
[10] Miin-Jang Chen, Eih-Zhe Liang, Shu-Wei Chang and Ching-Fuh Lin, “Model for band-edge electroluminescence from metal-oxide-semiconductor silicon tunneling diodes”, J. Appl. Phys., vol.90, 789 (2001)

[11] Wai Lek. Ng, M. A. Lourenco, R.M. Gwillian, S. Ledain, G. Shao and K.P. Homewood, “An efficient room-temperature silicon-based light emitting diodes”, Nature, vol.410, 192 (2001)
[12] Martin A. Green, Jianhua Zhao, Aihua Wang, Peter J. Reece, “Efficient siliconlight-emitting diodes”, Nature, vol.412, 805 (2001)
chap.2
[1] L. Niinisto, J. Paivasaari, J. Niinisto, M. Putkonen and M. Nieminen,” Advanced electronic and optoelectronic materials by Atomic Layer Deposition: An overview with special emphasis on recent progress in processing of high-k dielectrics andother oxide materials”, Phys. Stat. Sol.(a), vol.201, 1443 (2004)
[2] M. D. Groner, F. H. Fabreguette, J. W. Elam and S. M. George, ”Low-Temperature Atomic Layer Deposition”, Chem. Mater, vol.16, 639 (2004)
[3] Dennis M. Hausmann, Philippe de Rouffignac, Amethyst Smith, Roy Gordon,Douwe Monsma, “Highly conformal atomic layer deposition of tantalum oxideusing alkylamide precursors”, Thin Solid Film, vol.443, 1 (2003)
[4] Mikko Ritala and Markku Leskela “Atomic Layer Deposition” in “Handbook of Thin Film Materials”, vol.1, edited by H.S.Nalwa,chap.2
[5] J. D. Ferguson, E. R. Smith, A. W. Weimer,b and S. M. George, “ALD of SiO2 at Room Temperature Using TEOS and H2O with NH3 as the Catalyst” Journal ofThe Electrochemical Society, vol.151, 528, (2004)
[6] Dennis Hausmann, Jill Becker, Shenglong Wang, Roy G.Gordon” Rapid VaporDeposition of Highly Conformal Silica Nanolaminates”, Science, vol.298, 402(2002)
[7] Philippe de Rouffignac, Zhengwen Li, and Roy G. Gordon” Sealing Porous Low-k Dielectrics with Silica” Electrochemical and Solid-State Letters, vol.7, 306 (2004)
chap.3
[1] Ching-Fuh Lin, C. W. Liu, Miin-Jang Chen, M. H. Lee and I. C. Lin,
“Electroluminescence at Si band gap energy based on metal-oxide-silicon
structure” J. Appl. Phys., vol.87, 8793 (2000)
[2] C. W. Liu, M. J.Chen, I. C. Lin, M. H. Lee, C.F.Lin, “Temperature dependence of the electron-hole-plasma electroluminescence from metal-oxide-silicon tunneling diode”, Appl. Phys. Lett., vol.77, 1111 (2000)
[3]M.J.Chen ,Ching-Fuh Lin, M. H. Lee, S. T. Chang and C. W. Liu, “Carrier lifetime measurement on electroluminescnect metal-oxide-silicon tunneling diode”, Appl. Phys. Lett.,vol.79,2264 (2001)
[4] Miin-Jang Chen, Eih-Zhe Liang, Shu-Wei Chang and Ching-Fuh Lin, “Model for band-edge electroluminescence from metal-oxide-semiconductor silicon tunneling diodes,” J. Appl. Phys., vol.90, 789 (2001)
[5] Ching-Fuh Lin, Miin-Jang Chen, Shu-Wei Chang, Peng-Fei Chung, Eih-Zhe Liang, Ting Wien Su and C. W. Liu, 'Electroluminescence at Si bandgap energy from mechanically pressed indium-tin-oxide/Si contact', Appl. Phys. Lett., vol.78, 1808 (2001)
[6] C. W Liu, C.-H. Lin, M. H. Lee, S. T. Chang; Y. H. Liu, M. J. Chen and C. F. Lin, 'Enhanced reliability of electroluminescece from metal-oxide-silicon tunneling diodes by deuterium incorporation', Appl. Phys. Lett., vol.78, 1397 (2001)
[7] Min-Hung Lee, K. F. Chen, C. C. Lai, C. W. Liu, W. W. Pai, M. J. Chen and C. F. Lin, “The roughness-enhanced light emission from metal-oxide-silicon light-emitting diodes using very high vacuum prebake”, Jpn. J. Appl. Phys. Part2 Lett, vol.41, 326 (2002)
[8] Miin-Jang Chen, C. F. Lin; W. T. Liu; S. T. Chang and C. W. Liu, “Visible and band-edge electroluminescence from ITO/SiO2/Si metal-oxide-semiconductor structures,” J. Appl. Phys.,vol.89, 323,(2000)
[9] Jacques I. Pankove, “Optical Processes in Semiconductors”, Prentice-Hall, Inc. (1971)
[10] E.R. Andrew, G.E. Brown, J. I. Budnick, D,K. Campbell, E.G.D. Cohen, J.Eichler, D. Ter Haar,E.W. Mcdaniel,D.L. Mills,B. Muhlschlegel,R. Petronizio,D.N. Schramm, A. Schwimmer, R. Slansky,”The optical properties of luminescence centers in silicon”, Physics reports, vol.176, 83(1989)
[11] Dieter K. Schroder, “Semiconductor Material and Device Characterization ”,
Wiley-interscience, second edition,(1998)
chap.4
[1] Zhang, X.; Garfunkel, E.; Chabal, Y. J.; Christman, S. B.; Chaban,“Stability ofHF-etched Si(100) surface in oxygen ambuent”, Appl. Phys. Lett., vol.79, 4051 (2001)
[2] Min Xu;Cong-Hui Xu;Shi-Jin Ding;Hong-Liang Lu; David Wei Zhang andLi-Kang Wang, “Spectroscopic and electrical properties of atomic layer deposition Al2O3 gate dielectric on surface pretreated Si substrate” Journal of Appl. Phys., vol.99, 074109 (2006)
[3] Martin M. Frank and Yves J. Chabal, “Enhanced initial growth of atomic-layer-
deposition metal oxides on hydrogen-terminated silicon” Appl. Phys. Lett., vol.83, 740 (2003)
[4] R. T. Brewer, M.-T. Ho,K. Z. Zhang, L. V. Goncharova, D.G.Starodub,T.Gustafsson,and Y.J.Chaba,“Ammonia Pretreatment for high-K dielectric growth onsilicon“, Appl. Phys. Lett., vol.85, 3830 (2004)
[5] M. D. Groner, F. H. Fabreguette, J. W. Elam and S. M. George, ”Low-Temperature Atomic Layer Deposition”, Chem. Mater, vol.16, 639 (2004)
[6] Jong Cheol Lee, and S.-J. Oh, ” Nondestructive depth profile of the chemical state of ultrathinAl2O3/Si interface”, vol.84, 3561(2004)
[7] Gosset, L.G.,Damlencourt, J.-F.,Renault, O.,Rouchon, D.,olliger, Ph.,Ermolieff,A.,Trimaille, I.,J.-J. Ganem ,F. Martin a,M.-N. S_em_eria,” Interface and materialcharacterization of thin Al2O3 layers deposited by ALD using TMA/H2O” Journal ofNon-Crystalline Solids, vol.303, 17 (2002)
chap.5
[1] Puurunen Riikka L, Vandervorst Wilfried, Besling Wim F. A., Richard Olivier, Bender Hugo, Conard Thierry, Chao Zhao, Delabie Annelies, Caymax Matty, DeGendt Stefan, Heyns Marc, Viitanen Minna M., de Ridder Marco, BrongersmaHidde H., Tamminga Yde, Thuy Dao, de Win Toon, Verheijen Marcel, Kaiser Monja;, Tuominen Marko.,“Island growth in the atomic layer deposition of zirconium oxideand aluminum oxide on hydrogen-terminated silicon:growth modeling and transmissionelectron microscopy”, J. Appl. Phys., vol.96, 4878 (2004)
[2] Martin M. Frank and Yves J. Chabal, “ Nucleation and interface formation mechanisms in atomic layer deposition of gate oxides”Appl. Phys. Lett.,
vol.82 ,4758 (2003)
[3] M. D. Groner; J. W. Elam; F. H. Fabreguette; S. M. George,”Electrical
Characterization of films grown by atomic layer deposition on silicon and various metal substrates ”, Thin Solid Films,vol.413,186 (2002)
[4] Gosset, L.G.,Damlencourt, J.-F.,Renault, O.,Rouchon, D.,olliger, Ph.,Ermolieff,A.,Trimaille, I.,J.-J. Ganem ,F. Martin a,M.-N. S_em_eria,” Interface and material characterization of thin Al2O3 layers deposited by ALD using TMA/H2O”, Journal of Non-Crystalline Solids, vol.303,17 (2002)
dc.identifier.urihttp://tdr.lib.ntu.edu.tw/jspui/handle/123456789/31697-
dc.description.abstract直接使用矽半導體製作出高效率之發光二極體,一直是重要地位的研究課題,本論文研究金屬-氧化層-矽半導體(MOS)發光二極體之發光特性。我們利用新穎的薄膜成長技術-原子層沉積技術(Atomic Layer Deposition,ALD)-來成長氧化鋁薄膜,由於ALD技術具有低材料成長溫度、厚度控制精準、薄膜缺陷密度低、無孔洞結構、介面品質良好等優點,因此所成長的高品質氧化層,可以提供優良的表面鈍化效果,藉此抑制元件中的非放光性複合
(nonradiative recombination)能階的密度,矽發光二極體的發光效率可以因此而提升。我們首先研究材料成長溫度對氧化鋁薄膜與矽半導體之介面的影響,得到最佳的氧化鋁成長溫度為100°C,接著使用三甲基鋁(trimethylaluminum)在不同的溫度下,對矽半導體表面做預處理,藉此得到更好的矽半導體與氧化鋁之介面品質。最後在最佳的氧化鋁成長溫度下,我們研究不同厚度的氧化鋁薄膜對發光效率的影響,得到最佳的氧化鋁薄膜厚度為5nm,藉由量測PL (Photoluminescence)頻譜隨溫度變化的情形,我們發現利用ALD成長之氧化鋁薄膜與矽半導體介面之間,具有bound exciton traps,此機制有效抑制非放光性能階的活化能(activation energy),藉此可以提高MOS發光二極體的外部量子效率。在室溫時利用ALD成長氧化鋁薄膜之MOS元件,其最佳之外部量子效率(external quantum efficiency)可以達到 ,遠超過使用相同基材成長相同厚度之熱氧化層之MOS發光二極體的發光效率。
zh_TW
dc.description.provenanceMade available in DSpace on 2021-06-13T03:17:50Z (GMT). No. of bitstreams: 1
ntu-95-R93527032-1.pdf: 1360759 bytes, checksum: 9602cb6baeca9da623cddf8aec3dd265 (MD5)
Previous issue date: 2006
en
dc.description.tableofcontents第一章 簡介
1-1簡介 1
1-2文獻回顧 5
1-3論文導覽 8
第二章 原子層沉積技術
2-1簡介 11
2-2原子層沉積技術之原理與特性 13
2-3原子層沉積技術之反應裝置 17
2-4氧化鋁薄膜之成長 19
2-5結論 24
參考文獻 25
第三章 使用ALD在不同溫度下成長氧化鋁薄膜作為
    MOS矽發光二極體之氧化層
3-1簡介 27
3-2元件結構與製作步驟 28
3-3元件的電性量測 31
3-4元件的光學特性量測 47
3-5結論 68
參考文獻 69
第四章 使用ALD在不同溫度下進行TMA預處理
對元件發光效率之影響
4-1簡介 71
4-2實驗設計 74
4-3元件光電特性量測 77
4-4結論 80
參考文獻 81
第五章 使用ALD成長不同厚度氧化鋁薄膜
  對元件發光效率之影響
5-1簡介 83
5-2元件製作步驟 84
5-3元件光電特性量測 85
5-4結論 90
參考文獻 91
第六章 結論
6-1論文回顧 93
6-2未來展望 95
dc.language.isozh-TW
dc.subject矽發光二極體zh_TW
dc.subject原子層沉積技術zh_TW
dc.subjectatomic layer depositionen
dc.subjectsilicon light emitting diodeen
dc.title利用原子層沉積技術成長氧化鋁-應用於矽發光二極體之研究zh_TW
dc.titleStudy of Silicon Light-Emitting Diodes with Al2O3 thin films grown by Atomic Layer Depositionen
dc.typeThesis
dc.date.schoolyear94-2
dc.description.degree碩士
dc.contributor.oralexamcommittee陳俊維(Chun-Wei Chen),陳學禮(Hsuen-Li Chen),蔡豐羽(Feng-Yu Tsai),鄭永楨
dc.subject.keyword原子層沉積技術,矽發光二極體,zh_TW
dc.subject.keywordatomic layer deposition,silicon light emitting diode,en
dc.relation.page95
dc.rights.note有償授權
dc.date.accepted2006-07-30
dc.contributor.author-college工學院zh_TW
dc.contributor.author-dept材料科學與工程學研究所zh_TW
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