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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 陳俊維 | |
dc.contributor.author | Shao-Sian Li | en |
dc.contributor.author | 李紹先 | zh_TW |
dc.date.accessioned | 2021-06-13T00:20:52Z | - |
dc.date.available | 2012-08-22 | |
dc.date.copyright | 2011-08-22 | |
dc.date.issued | 2011 | |
dc.date.submitted | 2011-08-04 | |
dc.identifier.citation | CH1
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dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/28752 | - |
dc.description.abstract | 本研究主要利用暫態分析技術對高分子太陽能電池中光載子的動態行為進行探討。近年來,高分子太陽能電池的光電轉換效率已有大幅度的進展,主要來自於其施體與受體混摻的奈米形貌優化,顯示控制施體與受體的混摻形貌對於光載子的動態行為有著重大的影響。
在本研究中首先針對高分子與無機二氧化鈦奈米粒子混摻太陽能電池進行分析,應用不同濃度的二氧化鈦奈米粒子的潻加量,在50wt%時可得到最好的元件效率,同時也對應到最平衡的電子與電洞遷移率及最佳的載子生命週期。接著藉由控制二氧化鈦奈米粒子的尺寸及形狀,並使用掃描式電子穿透顯微鏡做3-D結構的影像重建,可以得知棒狀的奈米粒子能夠提供電子更有效率的傳導路經,且較容易形成較施體與受體材料分別的連續相,使得載子有更長的生命週期,因此在電荷的傳導及收集上,棒狀奈米粒子比球狀更有效率,能夠減少更多不必要的損失。本研究也利用化學方式來修飾二氧化鈦奈米粒子表面,除了增進與有機高分子的相容性,並有效地增進了電荷轉移能力及減少了電子電洞在異質接面上的再結合損失,其光電轉換效率可被提升到2.2%。 利用石墨稀氧化物來取代傳統電洞傳導層的應用也在本研究中有詳盡的描述。中性的石墨稀氧化物可利用溶液製備方式將其塗布於氧化錫銦電極上,做為一電洞傳導層並抑制電子往陽極的傳輸,可有效地減少電子與電洞的再結合速率,使得元件光電轉換效率可與以傳統導電高分子做為電洞傳導層的元件相匹敵。 | zh_TW |
dc.description.abstract | In this thesis, photocarrier dynamics in bulk heterojunction polymer solar cell was comprehensively investigated with various transient techniques. Power conversion efficiency of polymer solar cells have been remarkably improved by the optimization of donor/acceptor blending nanomorphologies, which are vital for efficient photocurrent generation. It also significantly affects the phtotocarrier dynamics such as exciton dissociation, carrier mobility and transport recombination. This thesis not only aims to correlate carrier dynamics and solar cell performance by morphology control but also providing a promising methodology for the future study of improvement in power conversion efficiency.
In chapter 3, TiO2 concentration dependent carrier dynamics was investigated in P3HT/TiO2 nanorods hybrid BHJ PVs. The best power conversion efficiency was found at 50wt% of TiO2 nanorods where the amount of TiO2 are enough to create a bi-continuous transport phase and resulted in balanced electron and hole mobility and also a longest carrier lifetime. Further in chapter 4, we investigated the interplay of 3-D morphologies by STEM-HAADF and the photocarrier dynamics of P3HT/TiO2 NPs and NRs hybrids BHJ PVs. The anisotropic TiO2 nanorods can not only reduce the probability of the inter-particle hopping transport of electrons by providing better connectivity with respect to the TiO2 nanoparticles, but also tend to form a large-scale donor-acceptor phase-separated morphology. The presence of dimensionality of TiO2 nanocrystals ensures the formation of favorable morphology for polymer/inorganic hybrid solar cells and results in more effective mobile carrier generation and more efficient and balanced transport of carriers. Furthermore, in chapter 5, we present that through interface modification with effective molecules, the photovoltaic performance of P3HT/TiO2 NRs can be largely improved by enhancing charge separation and suppressing interface recombination rate in the polymer/inorganic hybrids. Similar process of surface modification can was also successfully demonstrated in P3HT/nanostructured ZnO hybrid solar cells. The utilization of graphene oxide (GO) thin films as the hole transport and electron blocking layer in organic photovoltaics (OPVs) is demonstrated in chapter 6. The incorporation of GO as a hole transport layer leads to the decrease in recombination and leakage currents. Solar cell performance is comparable to devices fabricated with PEDOT:PSS as the hole transport layer. Indicating that GO could be a simple solution-processable alternative to PEDOT:PSS as the effective hole transport and electron blocking layer in OPV and light-emitting diode devices. | en |
dc.description.provenance | Made available in DSpace on 2021-06-13T00:20:52Z (GMT). No. of bitstreams: 1 ntu-100-D95527020-1.pdf: 6651750 bytes, checksum: b4a146d75b33d5fddf1910966d4bb5ef (MD5) Previous issue date: 2011 | en |
dc.description.tableofcontents | ACKNOWLEDGEMENT I
摘要 III ABSTRACT IV CONTENTS VI LIST OF FIGURES X LIST OF TABLES XV CHAPTER 1 Introduction 1 1-1 Motivation 1 1-2 Polymer solar cells 2 1-2.1 Semiconducting polymer 2 1-2.2 Bulk heterojunction structure 6 1-3 Classification of polymer solar cells 8 1-3.1 Polymer-fullerene solar cells 9 1-3.2 Polymer-inorganic nanocrystal solar cells 13 1-3.3 Nanocarbon based polymer solar cells 18 1-4 Outline of this thesis 21 1-5 Reference 24 CHAPTER 2 Transient Techniques in the Study of Polymer Solar Cells 27 2-1 Carrier dynamics in photocurrent generation process 27 2-1.1 Light absorption and excition generation 28 2-1.2 Exciton diffusion 30 2-1.3 Exciton dissociation 30 2-1.4 Charge transport and collection 31 2-1.5 Loss mechanisms in conversion process 32 2-2 Exciton dissociation: Time resolved photoluminescence 34 2-2 Exciton recombination across heterojunctions: Transient photovoltage 38 2-3 Carrier transport mobility: Time of flight and CELIV 40 2-3.1 Time of flight 40 2-3.2 CELIV 45 2-4 Carrier transport recombination rate: Photo-CELIV 50 2-5 Reference 55 CHAPTER 3 Effects of TiO2 Concentration on Carrier Dynamics and Solar Cell Performance in P3HT/TiO2 Nanorods BHJs 57 Abstract 57 3-1 Introduction 59 3-2 Material characterization 63 3-2.1 Characterization of P3HT 63 3-2.2 Characterization of TiO2 nanorods 64 3-2.3 Preparation of P3HT/TiO2 nanorods hybrid materials 67 3-3 Correlation between concentration dependent morphology and photocarrier dynamics 68 3-3.1 Solar cell performance with various concentrations 68 3-3.2 Concentration dependent bi-carrier and single carrier mobility 70 3-3.3 Concentration dependent carrier transport recombination rate 79 3-4 Conclusion 85 3-5 Reference 86 CHAPTER 4 Interplay of Three-Dimensional Morphologies and Photocarrier Dynamics of Polymer/TiO2 Bulk Heterojunction Solar Cells 87 Abstract 87 4-1 Introduction 89 4-2 Preparation of TiO2 nanocrystals 91 4-3 Device fabrication and power conversion efficiency characterization 93 4-4 3D nanomorphology study by STEM-HAADF electron tomography 95 4-4.1 Sample preparation and experimental of STEM-HAADF 95 4-4.2 Exploration of nanomorphology in P3HT/TiO2 NPs and NRs 95 4-5 Study of morphology related carrier dynamic behaviors in P3HT/TiO2 NPs and NRs hybrid BHJ solar cells 101 4-5.1 Interface dominated exciton dissociation and recombination 101 4-5.2 Carrier recombination and mobility with respect to the inter-connectivity of P3HT/TiO2 nanocrystal nanomorphology 104 4-6 Conclusion 111 CHAPTER 5 Carrier Dynamics in Interface Modified Polymer/Metal Oxide Hybrid Solar Cells 114 Abstract 114 5-1 Introduction 115 5-2 P3HT/TiO2 BHJ solar cells 116 5-2.1 TiO2 surface modification 116 5-2.2 Device fabrication and performance characterization 117 5-2.3 Effects of interfacial modifier on exciton dissociation and recombination 119 5-3 Nanostructured ZnO/P3HT hybrid solar cells 123 5-3.1 Device structure and fabrication 123 5-3.2 Surface modification of ZnO 125 5-3.3 Surface ligand effects on device performance and interface recombination 126 5-4 Conclusion 130 5-5 Reference 131 CHAPTER 6 Solution-Processable Graphene Oxide as an Efficient Hole Transport Layer in Polymer Solar Cells 133 Abstract 133 6-1 Introduction 134 6-2 Material characterization 136 6-2.1 Nature of GO 136 6-2.2 Synthesis of GO 137 6-2.3 Characterizations of GO 138 6-2.4 Energy band alignment of GO in P3HT/PCBM solar cell 141 6-3 P3HT/PCBM polymer solar cells using graphene oxide as hole transport layers 143 6-3.1 Device fabrication 143 6-3.2 Enhancement of power conversion efficiency and recombination rate 144 6-3.3 Thickness and conductivity effects of GO on device performance and recombination 147 6-4 Conclusions 152 6-5 Reference 153 CONCLUSIONS 157 LIST OF PUBLICATIONS 159 | |
dc.language.iso | en | |
dc.title | 高分子混摻異質接面太陽能電池光載子動態行為分析 | zh_TW |
dc.title | Photocarrier Dynamics in Polymer Bulk Heterojunction Solar Cells | en |
dc.type | Thesis | |
dc.date.schoolyear | 99-2 | |
dc.description.degree | 博士 | |
dc.contributor.oralexamcommittee | 朱明文,吳季珍,陳學禮,杜昭宏 | |
dc.subject.keyword | 有機太陽能電池,載子動態行為,載子傳輸,載子再結合,載子生命週期,石墨烯氧化物, | zh_TW |
dc.subject.keyword | polymer solar cell,carrier dynamics,carrier transport,carrier recombination,carrier lifetime,graphene oxide, | en |
dc.relation.page | 160 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2011-08-05 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 材料科學與工程學研究所 | zh_TW |
顯示於系所單位: | 材料科學與工程學系 |
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