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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 吳錫侃 | |
dc.contributor.author | Chien-Hui Chen | en |
dc.contributor.author | 陳芊卉 | zh_TW |
dc.date.accessioned | 2021-06-08T05:14:04Z | - |
dc.date.copyright | 2006-07-11 | |
dc.date.issued | 2006 | |
dc.date.submitted | 2006-07-07 | |
dc.identifier.citation | 參考文獻
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dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/24010 | - |
dc.description.abstract | 本研究以TiNi形狀記憶合金為基材使用六甲基二矽胺(Hexamethyldisilazane, HMDSN)單體以脈衝式電漿輔助化學沉積法 (PECVD) 沉積非晶質SiC:H薄膜於TiNi合金之上並利用UV 光誘導接枝聚合丙烯醯胺(Acrylamide, AAm)單體,改變薄膜表面官能基,做酵素固定使TiNi合金成為具抗凝血生化特性之生醫材料。薄膜沉積速率快,表面形貌均勻、孔洞少、粗糙度低均在2~4nm之間。並顯著地提升抗腐蝕性,使腐蝕電流密度下降約至少四個數量級。由FTIR所得之吸收光譜,可知Si-C 與C-H等鍵結受破壞,形成Si-H與C=O等鍵結,沉積出高度分支且交錯連結之薄膜。經歷UV 光誘導接枝聚合AAm後,由FTIR光譜可證明成功接枝,表面粗糙度下降至1-2nm,形成新的ㄧ層緻密有機薄膜。接枝後水接觸角由87°下降至36°,與玻璃之相對濕摩擦係數由0.25下降至0.2以下,有利生醫方面之應用。後續經歷固定肝素之處理後,可觀察到聚合鍵結之肝素分子形成之團聚物,且由XPS可偵測出S元素存在為肝素固定之證明。 | zh_TW |
dc.description.abstract | SiC:H organic-like thin films are deposited on TiNi shape memory alloy (SMA) by DC-pulsed plasma enhanced chemical vapor deposition (PECVD) of HMDSN and Ar gas mixtures at room temperature. The organic-like thin films containing peroxides or free radicals can be subsequently grafted with hydrophilic polymer acrylamide (AAm) by UV-induced grafting polymerization. Heparin is immobilized onto grafted-AAm thin films to take TiNi SMA into the anti-thrombin biomaterials. The deposition rate of the plasma-polymerized HMDSN (PPHMDSN) thin film is fast and the root mean square surface roughness is between 2~4 nm. The PPHMDSN thin films not only enhance the corrosion resistance but make the corrosion current density decay four orders. Based on the micro-FTIR spectra, the Si-C and C-H bonds of the original HMDSN monomer are destroyed and new Si-H and C=O bonds are formed. The success of grafting is proved by FTIR. After grafting polymerization of AAm, a new dense organic thin films layer is formed in which the water contact angle decreases from 87° to 36° and the friction coefficient becomes lower. These properties are beneficial to the biomedical applications. According to XPS, the element S can be detected to prove that heparin is covalently immobilized on TiNi SMA. | en |
dc.description.provenance | Made available in DSpace on 2021-06-08T05:14:04Z (GMT). No. of bitstreams: 1 ntu-95-R93527071-1.pdf: 7484706 bytes, checksum: 9649ee5d7355738624b55f983a2165ee (MD5) Previous issue date: 2006 | en |
dc.description.tableofcontents | 致謝 i
摘要 iii Abstract v 目錄 vii 第一章 前言 1 第二章 文獻回顧 3 2-1 形狀記憶合金簡介 3 2-1-1 形狀記憶效應(SME) 4 2-1-2 擬彈性(PE) 8 2-2 TiNi 基形狀記憶合金 10 2-2-1 TiNi 形狀記憶合金之各相與結晶構造 10 2-2-2 TiNi 形狀記憶合金之力學特性 12 2-2-3 TiNi形狀記憶合金之生物相容性 16 2-3 薄膜製程 19 2-3-1 電漿簡介 19 2-3-2 電漿基本反應 21 2-3-3 電漿表面改質 23 2-3-4 電漿輔助化學氣相沈積(PECVD) 25 2-3-5 直流輝光放電(D. C glow discharge) 27 2-3-6 脈衝式直流電漿輔助化學氣相沈積 (Pulsed-DC PECVD) 30 2-4 生物分子之固定 31 2-4-1 固定理論 31 2-4-2 共價鍵接合機制 33 2-4-3 生物單體-肝素(Heparin)簡介 36 第三章 實驗方法及步驟 53 3-1 薄膜試片之製作 53 3-1-1 TiNi基材之製備 53 3-1-2 鍍膜設備 54 3-1-3 非晶質SiC:H薄膜試片之製備 55 3-1-4 非晶質SiC:H薄膜試片接枝AAm 56 3-1-5 肝素固定 57 3-2 實驗分析 57 3-2-1 薄膜沉積速率之量測 57 3-2-2 水接觸角之量測 58 3-2-3 薄膜化學性質之量測 58 3-2-4 薄膜表面型態之量測 59 3-2-5 電化學分析 60 3-2-6 摩擦係數分析 60 第四章 實驗結果與討論 71 4-1 SiC:H薄膜性質 71 4-1-1 直流脈衝式電漿波形 71 4-1-2 沉積速率 73 4-1-3 FTIR之測試結果 75 4-1-4 抗腐蝕性 79 4-1-5 表面形貌之觀察 81 4-1-6 ESCA (XPS)之測試結果 84 4-2 生物相容性之改善 85 4-2-1 接枝率 86 4-2-2 FTIR之測試結果 87 4-2-3 水接觸角 88 4-2-4 摩擦測試 89 4-2-5 表面形貌 90 4-2-6 固定肝素 91 第五章 結論 119 參考文獻 123 | |
dc.language.iso | zh-TW | |
dc.title | TiNi形狀記憶合金以脈衝電漿沉積HMDSN薄膜之研究 | zh_TW |
dc.title | The Study on PPHMDSN Thin Film Deposited on TiNi SMA by DC-pulsed PECVD | en |
dc.type | Thesis | |
dc.date.schoolyear | 94-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 王文雄,楊木榮,林新智 | |
dc.subject.keyword | TiNi形狀記憶合金,六甲基二矽胺,脈衝式電漿輔助化學沉積法,丙烯醯胺(AAm),肝素, | zh_TW |
dc.subject.keyword | TiNi shape memory alloy,HMDSN,DC-Pulsed PECVD,AAm,Heparin, | en |
dc.relation.page | 129 | |
dc.rights.note | 未授權 | |
dc.date.accepted | 2006-07-11 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 材料科學與工程學研究所 | zh_TW |
顯示於系所單位: | 材料科學與工程學系 |
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