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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 陳建彰 | zh_TW |
| dc.contributor.advisor | Jian-Zhang Chen | en |
| dc.contributor.author | 陳奇松 | zh_TW |
| dc.contributor.author | Ci-Song Chen | en |
| dc.date.accessioned | 2025-07-11T16:09:50Z | - |
| dc.date.available | 2025-07-12 | - |
| dc.date.copyright | 2025-07-11 | - |
| dc.date.issued | 2025 | - |
| dc.date.submitted | 2025-07-01 | - |
| dc.identifier.citation | 1. Chen, C.-S., et al., Flexible Asymmetric Supercapacitors with Reduced Graphene Oxide and Lithium Manganese Oxide Electrodes Processed by Atmospheric-Pressure Plasma Jet. Ceramics International, 2025.
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/97682 | - |
| dc.description.abstract | 本研究提出一種應用於柔性非對稱超級電容（Asymmetric Supercapacitor, ASC）之製程方法，利用常壓噴射電漿（Atmospheric-Pressure Plasma Jet, APPJ）對還原氧化石墨烯（rGO）與鋰錳氧化物（LMO）電極進行表面改質，以調控其微觀結構並提升電化學性能。電極材料分別由rGO-LiCl-Mn(NO3)2⋅4H2O複合漿料及純rGO漿料製備，透過網版印刷轉印至碳布基材後進行APPJ處理，最後與聚乙烯醇–硫酸鋰（PVA–Li₂SO₄）凝膠電解質組裝為三明治結構的柔性非對稱超級電容。
材料分析結果顯示，APPJ處理顯著改變電極表面微觀結構與化學組成。SEM影像觀察到表面形成多孔性奈米結構，提升了比表面積與電解質滲透性；接觸角量測結果顯示，電漿處理後的電極具備良好親水性，有助於提升與電解質的接觸效率。XRD與XPS分析則確認電極表面生成LiMnO₂與LiMn₂O₄等具高理論電容的晶相，且表面含氧官能基與高價態錳比例上升，增強了法拉第反應活性與電荷儲存能力。 電化學測試結果顯示，經APPJ處理300秒之裝置（ASC-300s）在1.6 V操作電壓下，可達最大面積比電容40.47 mF/cm²與能量密度9.40 μWh/cm²。該裝置亦展現優異的循環穩定性，於4000次充放電後仍維持96%電容，並在彎曲曲率1 cm⁻¹下保有89%電容，展現出良好的機械穩定性。Ragone plot進一步顯示其具備優異的能量與功率密度平衡特性。 綜上所述，本研究成功運用APPJ技術進行柔性電極之表面改質，有效提升其界面特性與儲能表現，並成功製備具高性能、長壽命與良好可撓性的非對稱超級電容。此成果不僅拓展了常壓電漿於儲能材料領域的應用，也為穿戴式電子與便攜式能源系統提供具發展潛力的儲能解決方案。 | zh_TW |
| dc.description.abstract | This study presents a flexible asymmetric supercapacitor (ASC) fabricated through atmospheric-pressure plasma jet (APPJ) treatment to enhance the electrochemical performance of reduced graphene oxide (rGO) and lithium manganese oxide (LMO) electrodes. The electrode films were prepared by screen-printing a rGO–LiCl–Mn(NO₃)₂·4H₂O composite and pure rGO slurry onto carbon cloth substrates, followed by APPJ surface modification. The resulting electrodes were assembled into a sandwich-structured device using a PVA–Li₂SO₄ gel electrolyte.
Material characterization confirmed that APPJ treatment effectively tailored the electrode surface. SEM revealed porous nanostructures, contact angle measurements showed improved wettability, and XRD/XPS analyses identified the formation of LiMnO₂ and LiMn₂O₄ phases, along with increased oxygen functional groups and high-valence Mn—both of which contribute to enhanced faradaic activity and charge storage capability. The optimized device (ASC-300s) achieved an areal capacitance of 40.47 mF/cm² and energy density of 9.40 μWh/cm² at 1.6 V, with 96% retention over 4000 cycles and 89% retention under 1 cm bending radius. Ragone plot analysis further confirmed its balanced energy and power density. Overall, APPJ provides a simple yet effective approach to enhance the interfacial and electrochemical properties of flexible electrodes, enabling the development of high-performance, durable, and mechanically resilient ASCs for wearable and portable energy storage applications. | en |
| dc.description.provenance | Submitted by admin ntu (admin@lib.ntu.edu.tw) on 2025-07-11T16:09:50Z No. of bitstreams: 0 | en |
| dc.description.provenance | Made available in DSpace on 2025-07-11T16:09:50Z (GMT). No. of bitstreams: 0 | en |
| dc.description.tableofcontents | 致謝 i
摘要 iii Abstract iv 目次 v 圖次 viii 表次 xiv 1 第一章 緒論 1 1.1 前言 1 1.2 研究動機 2 1.3 論文大綱 3 2 第二章 文獻回顧與理論介紹 4 2.1 常壓電漿 4 2.1.1 電漿理論概述 4 2.1.2 常壓電漿的種類與應用 11 2.2 超級電容 16 2.2.1 超級電容與儲能裝置簡介 16 2.2.2 超級電容之種類與儲能機制 18 2.2.3 超級電容之電極材料 27 2.2.4 超級電容之電解質 34 2.3 鋰錳氧化物與還原氧化石墨烯 38 2.3.1 鋰錳氧化物 38 2.3.2 還原氧化石墨烯 40 3 第三章 實驗步驟與各項設備 41 3.1 實驗材料與實驗設備 41 3.1.1 實驗藥品與材料 41 3.1.2 實驗設備 43 3.2 製程設備 45 3.2.1 旋轉式真空濃縮機 45 3.2.2 氣壓式網版印刷機 46 3.2.3 常壓噴射電漿系統 47 3.3 實驗步驟 48 3.3.1 配製還原氧化石墨烯-鋰錳氧化物電極之網印漿料 48 3.3.2 配製還原氧化石墨烯電極之網印漿料 48 3.3.3 製作還原氧化石墨烯-鋰錳氧化物電極與還原氧化石墨烯電極 49 3.3.4 製作硫酸鋰凝膠電解質 50 3.3.5 組裝柔性非對稱超級電容 51 3.4 分析設備 53 3.4.1 場發射鎗掃描式電子顯微鏡 53 3.4.2 接觸角量測儀 55 3.4.3 X射線繞射分析儀 56 3.4.4 X射線光電子能譜儀 57 3.4.5 電化學工作站 59 4 第四章 結果與討論 66 4.1 氮氣常壓噴射電漿之實驗參數設定 66 4.2 還原氧化石墨烯-鋰錳氧化物非對稱超級電容電極之表面形態分析 67 4.3 還原氧化石墨烯-鋰錳氧化物非對稱超級電容電極之親水性測試 70 4.4 還原氧化石墨烯-鋰錳氧化物非對稱超級電容電極之晶體結構分析 72 4.5 還原氧化石墨烯-鋰錳氧化物非對稱超級電容電極之表面化學型態表徵 74 4.6 還原氧化石墨烯-鋰錳氧化物非對稱超級電容之電化學分析 83 4.6.1 電極之循環伏安法分析與恆電流充放電分析 83 4.6.2 還原氧化石墨烯-鋰錳氧化物非對稱超級電容之循環伏安法與恆電流充放電分析 88 4.6.3 還原氧化石墨烯-鋰錳氧化物非對稱超級電容之Trasatti分析 92 4.6.4 還原氧化石墨烯-鋰錳氧化物非對稱超級電容之Ragone plot 94 4.6.5 還原氧化石墨烯-鋰錳氧化物非對稱超級電容之電化學阻抗譜分析 96 4.6.6 還原氧化石墨烯-鋰錳氧化物非對稱超級電容之穩定性測試 98 4.7 還原氧化石墨烯-鋰錳氧化物非對稱與對稱型超級電容之性能比較 100 4.8 還原氧化石墨烯-鋰錳氧化物非對稱超級電容與其他金屬氧化物材料非對稱超級電容之性能比較 102 5 第五章 結論 103 6 第六章 附錄:利用常壓噴射電漿處理電化學沉積鋅錳氧化物電極於超級電容之應用 104 6.1 摘要 104 6.2 實驗步驟 104 6.3 結果與討論 106 6.3.1 鋅錳氧化物超級電容之循環伏安法分析 106 6.3.2 鋅錳氧化物超級電容之恆電流充放電分析 108 6.3.3 鋅錳氧化物超級電容之循環穩定性測試 110 6.4 結論 111 7 參考文獻 112 8 個人期刊發表 125 | - |
| dc.language.iso | zh_TW | - |
| dc.subject | 鋰錳氧化物 | zh_TW |
| dc.subject | 還原氧化石墨烯 | zh_TW |
| dc.subject | 常壓噴射電漿 | zh_TW |
| dc.subject | 非對稱超級電容 | zh_TW |
| dc.subject | Lithium manganese oxide (LMO) | en |
| dc.subject | Asymmetric supercapacitor (ASC) | en |
| dc.subject | Atmospheric-pressure plasma jet (APPJ) | en |
| dc.subject | reduced graphene oxide (rGO) | en |
| dc.title | 常壓噴射電漿處理還原氧化石墨烯與鋰錳氧化物電極於柔性非對稱超級電容器中的應用 | zh_TW |
| dc.title | Application of rGO and Lithium Manganese Oxide Electrodes Processed by Atmospheric-Pressure Plasma Jet in Flexible Asymmetric Supercapacitors | en |
| dc.type | Thesis | - |
| dc.date.schoolyear | 113-2 | - |
| dc.description.degree | 碩士 | - |
| dc.contributor.oralexamcommittee | 陳奕君;羅世強 | zh_TW |
| dc.contributor.oralexamcommittee | I-Chun Cheng;Shyh-Chyang Luo | en |
| dc.subject.keyword | 非對稱超級電容,常壓噴射電漿,還原氧化石墨烯,鋰錳氧化物, | zh_TW |
| dc.subject.keyword | Asymmetric supercapacitor (ASC),Atmospheric-pressure plasma jet (APPJ),reduced graphene oxide (rGO),Lithium manganese oxide (LMO), | en |
| dc.relation.page | 125 | - |
| dc.identifier.doi | 10.6342/NTU202501409 | - |
| dc.rights.note | 同意授權(全球公開) | - |
| dc.date.accepted | 2025-07-02 | - |
| dc.contributor.author-college | 工學院 | - |
| dc.contributor.author-dept | 應用力學研究所 | - |
| dc.date.embargo-lift | 2025-07-12 | - |
| 顯示於系所單位： | 應用力學研究所 | |
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