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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 徐澔德 | zh_TW |
| dc.contributor.advisor | J Bruce H Shyu | en |
| dc.contributor.author | 高秉辰 | zh_TW |
| dc.contributor.author | Wallace Kao | en |
| dc.date.accessioned | 2025-02-26T16:15:52Z | - |
| dc.date.available | 2025-02-27 | - |
| dc.date.copyright | 2025-02-26 | - |
| dc.date.issued | 2025 | - |
| dc.date.submitted | 2025-02-10 | - |
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Partitioning riverine sulfate sources using oxygen and sulfur isotopes: Implications for carbon budgets of large rivers. Earth and Planetary Science Letters, 567(2), 116957 Siever, R. (1968), Sedimentological consequences of a steady-state ocean-atmosphere. Sedimentology, 11, 5-29. Taylor, B. E., Wheeler, M. C., & Nordstrom, D. K. (1984). Stable Isotope Geochemistry of Acid-Mine Drainage - Experimental Oxidation of Pyrite. Geochimica Et Cosmochimica Acta, 48(12), 2669-2678. Torres, M., West, A. & Li, G. (2014) Sulphide oxidation and carbonate dissolution as a source of CO2 over geological timescales. Nature, 507(7492), 346–349. Walker, J. C. G., Hays, P. B., & Kasting, J. F. (1981). A Negative Feedback Mechanism for the Long-Term Stabilization of Earths Surface-Temperature. Journal of Geophysical Research, 86(C10), 9776-9782. Wang, P. L., Tu, T. H., Lin, L. H. et al. (2024) Microbial communities modulate chemical weathering and carbon dioxide cycling in an active orogen in Taiwan. 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Sulfide-bearing Quartz Veins in the Szeleng Sandstone, Chinmienshan, Northeastern Taiwan: A Preliminary Study on Fluid Inclusions and Stable Isotopes (In Chinses with English abstract). Journal of the Geological Society of China, 40(4), 723-742. Encyclopaedia Britannica. https://www.britannica.com/science/water-cycle First River Management Branch, Water Resources Agency, Ministry of Economic Affairs, https://www.wra01.gov.tw/Default.aspx . Geological Survey and Mining Management Agency (formally Central Geological Survey, CGS), Ministry of Economic Affairs, Taiwan. https://twgeoref.gsmma.gov.tw/GipOpenWeb/wSite/lp?ctNode=339&mp=106 Water Education Foundation. https://www.watereducation.org/ Water Resources Department, Yilan County. https://wres.e-land.gov.tw/cp.aspx?n=79FB5DB9DC2E17BE | - |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/97059 | - |
| dc.description.abstract | 河流系統是沉積物由造山帶輸送至海洋的主要管道，因此河水的化學組成對於自然界的物質循環具有重要的意義。近年有研究指出臺灣地區受到高侵蝕與風化速率影響，河流中具有相當高的硫酸根濃度，可能與變質岩岩層中硫化鐵礦物的溶解有關。然而河流流經不同之岩層是否的確會出現不同的化學組成，過去並沒有系統性的研究。因此本研究嘗試採集流經不同岩層的河水樣本，藉由分析河水中的陰陽離子組成，探討河水的化學組成與其可能的地質控制。
本研究以蘭陽溪的上游數個主要支流作為研究區域，河水採樣點根據支流所流經的地層差異挑選。其中西北側源自雪山山脈的支流主要流經四稜砂岩、乾溝層與西村層，岩性以砂岩、硬頁岩、變質砂岩為主。東南側中央山脈發源的支流流過以硬頁岩、板岩、千枚岩為主的廬山層，其中武荖坑溪更流經變質程度較高的大南澳片岩。另一方面，雨水及溫泉水的注入亦影響河水的離子變化，因此我們亦採集分析雨水與溫泉水，以推算來自岩層之離子貢獻。 本研究共採集11條支流的河水樣本，並收集蘭陽平原雨水與芃芃溫泉、天狗溪噴泉的溫泉水進行分析。於2022年至2023年間進行六次採樣，水樣經過處理後利用離子層析儀 (IC) 與感應耦合電漿質譜儀 (ICP-MS) 分別獲得陰離子與陽離子濃度數據。根據前人建立的端成分模型，蘭陽溪流域河水的陽離子成分均來自矽酸鹽岩與碳酸鹽岩的化學風化及混合，證明此處沒有蒸發鹽礦的影響。硫酸根濃度較高的樣本幾乎都臨近或流經溫泉露頭，暗示硫酸根受到溫泉的影響可能較大。唯在保養溪，除潛在未發現的溫泉影響外，現地的觀察顯示其高濃度之硫酸根亦可能來自四稜砂岩中硫化鐵礦物的風化。武荖坑溪之陽離子組成與其他溪流相差甚遠，可能與其流經之大南澳片岩中的大理岩有關。基於得到的結果，在蘭陽溪流域，只有當河床底岩差異夠明顯且流域不受溫泉影響時，受到底岩岩性影響之河水離子組成差異才會比較明顯。 | zh_TW |
| dc.description.abstract | River systems play a crucial role in various natural cycles, thus the chemical compositions of river water are important to understanding the circulations of matter in nature. Some previous studies reported high sulfate concentrations in rivers in southern Taiwan, and suggest the weathering of sulfide minerals as the cause. Despite this, no systematic research has been conducted to examine any links between rivers and the rock formations they run through. This study analyzes samples from rivers of basins with varying lithology, and aims to discuss the possible geological controls of the chemical compositions with major ions analysis.
The study area focuses on upstream tributaries along the Lanyang River in northeastern Taiwan. The basins of these tributaries spread across the Hsuehshan Range and the Central Range. These ranges differ in lithology, with the Central Range consisting of higher-grade and older metamorphic rocks. We sampled 11 rivers and 2 hot springs from 2022 to 2023. In addition, rainwater samples were collected to represent atmospheric input for calibration. We obtained anion and cation concentrations using Ion Chromatography (IC) and Induced Coupled Plasma Mass Spectrometer (ICP-MS) respectively. Based on the cation end-member model, riverine cations originate from a mixture of silicate and carbonate weathering, while evaporite weathering is absent in this region. Anion results show a potential correlation between high sulfate concentrations and hot springs. At Baoyang River, however, apart from the possible influence of an unknown hot spring, field observations suggest that its high sulfate concentrations may be contributed by the weathering of sulfides in the Szeleng Sandstone. The cation characteristics of WRK stand out from the other rivers, which is likely due to marbles in the Tananao Schist in its drainage basin. Based on the results, in the Lanyang River region, the influence of bedrock lithology on the chemical composition of river waters is only more obvious when the bedrock is distinctive enough, and there is no hot spring influence in the drainage basin. | en |
| dc.description.provenance | Submitted by admin ntu (admin@lib.ntu.edu.tw) on 2025-02-26T16:15:52Z No. of bitstreams: 0 | en |
| dc.description.provenance | Made available in DSpace on 2025-02-26T16:15:52Z (GMT). No. of bitstreams: 0 | en |
| dc.description.tableofcontents | 口試委員會審定書 i
致謝 ii 中文摘要 iii Abstract iv Chapter 1 Introduction 1 1.1 Motives 1 1.1.1 Chemical weathering of rocks and minerals 1 1.1.2 Sulfate and chemical weathering in Taiwanese riverine waters 5 1.2 Purpose 9 Chapter 2 Background 11 2.1 Sources of major ions 11 2.1.1 Surface runoff 11 2.1.2 Chemical weathering of silicates and carbonates 12 2.1.3 Sources of riverine sulfate 16 2.2 Study area 18 2.2.1 Geological Background 18 2.2.2 Sample sites 21 Chapter 3 Methods 25 3.1 Field work 26 3.1.1 Water collection 26 3.1.2 Rainwater 30 3.1.3 River water & hot spring 31 3.1.4 On site observations and measurements 31 3.2 Chemical analysis 33 3.2.1 Anion Analysis 33 3.2.2 Cation Analysis 35 3.2.3 Data analysis 37 Chapter 4 Results 39 4.1 Field observations 39 4.1.1 River and hot spring collection 39 4.1.2 On-site observations 41 4.1.3 On-site measurements 43 4.2 Ion results 49 4.2.1 Measured concentration results 49 4.2.2 Rainwater results 51 4.2.3 Atmospheric correction with chloride 54 4.2.4 Corrected riverine concentration results 58 4.2.5 Hot spring water 62 Chapter 5 Discussion 64 5.1 Water – rock relationships 64 5.1.1 Anthropogenic and atmospheric sources of sulfate 64 5.1.2 Cation end-member 67 5.1.3 Characteristics of sulfate concentration 71 5.1.4 Sulfate versus cation 73 5.2 Hot spring influences 79 5.3 Noticeable cases 85 5.3.1 BY 85 5.3.2 WRK 87 Chapter 6 Conclusions 88 References 90 Appendix 97 | - |
| dc.language.iso | en | - |
| dc.subject | 硫酸根 | zh_TW |
| dc.subject | 蘭陽溪 | zh_TW |
| dc.subject | 化學風化 | zh_TW |
| dc.subject | 硫化礦物 | zh_TW |
| dc.subject | 河水化學 | zh_TW |
| dc.subject | river chemistry | en |
| dc.subject | sulfate | en |
| dc.subject | sulfide | en |
| dc.subject | Lanyang River | en |
| dc.subject | chemical weathering | en |
| dc.title | 蘭陽溪流域河水的化學組成與其可能之地質控制 | zh_TW |
| dc.title | River chemistry of Lanyang River and its possible geological controls | en |
| dc.type | Thesis | - |
| dc.date.schoolyear | 113-1 | - |
| dc.description.degree | 碩士 | - |
| dc.contributor.coadvisor | 王興麟 | zh_TW |
| dc.contributor.coadvisor | Shing-Lin Wang | en |
| dc.contributor.oralexamcommittee | 王珮玲;朱美妃;林玉詩 | zh_TW |
| dc.contributor.oralexamcommittee | Pei-Ling Wang;Mei-Fei Chu;Yu-Shih Lin | en |
| dc.subject.keyword | 蘭陽溪,化學風化,河水化學,硫酸根,硫化礦物, | zh_TW |
| dc.subject.keyword | Lanyang River,chemical weathering,river chemistry,sulfate,sulfide, | en |
| dc.relation.page | 112 | - |
| dc.identifier.doi | 10.6342/NTU202500428 | - |
| dc.rights.note | 同意授權(全球公開) | - |
| dc.date.accepted | 2025-02-10 | - |
| dc.contributor.author-college | 理學院 | - |
| dc.contributor.author-dept | 地質科學系 | - |
| dc.date.embargo-lift | 2025-02-27 | - |
| 顯示於系所單位： | 地質科學系 | |
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