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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 劉如熹 | zh_TW |
| dc.contributor.advisor | Ru-Shi Liu | en |
| dc.contributor.author | 黃尚洋 | zh_TW |
| dc.contributor.author | Shang-Yang Huang | en |
| dc.date.accessioned | 2024-07-01T16:13:37Z | - |
| dc.date.available | 2024-07-02 | - |
| dc.date.copyright | 2024-07-01 | - |
| dc.date.issued | 2024 | - |
| dc.date.submitted | 2024-06-25 | - |
| dc.identifier.citation | [1]Yaqoob, L.; Noor, T.; Iqbal, N. An Overview of Metal–Air Batteries, Current Progress, and Future Perspectives. J. Energy Storage 2022, 56, 106075–106114.
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/92812 | - |
| dc.description.abstract | 溫室氣體之排放控制為眾人所關注之熱門議題，為減少運輸業造成之廢氣汙染，電動車、無人機等使用電能之新型載具成為近年眾人積極研究開發之項目。當中具高能量密度與高理論開路電壓優勢之可充電鎂氧氣(Mg–O2)電池作為有望替代鋰離子電池以運用於電動載具之新穎技術。
本研究首先合成可運用於Mg–O2電池之聚合物固態電解質並進行分析。藉添加丁二腈(succinonitrile; SN)可達最佳3.9 × 10–5 S cm–1之室溫離子電導率，並藉各式分析儀器揭示SN於聚合物電解質特性之影響，以探討SN與離子電導率之關聯性。其次將合成之聚合物電解質延伸組裝為鈕扣型準固態Mg–O2電池，其可具25000 mAh g–1之最大放電電容量、50圈穩定充放電循環壽命及0.99 V電池過電位等優異之電性表現。若將其組裝為軟包型準固態Mg–O2電池，則可具4.1 mAh cm–2之最大放電電容量，並藉點亮紅光LED展示其應用性。隨後藉各式分析儀器進行陰極界面之成分鑑定，探討準固態Mg–O2電池之反應機制，可得知氧化鎂(MgO)與過氧化鎂(MgO2)皆為主要之放電產物。同時藉各式分析儀器鑑定陽極界面之穩定性，可得知陽極表面不僅無副產物生成，更減少裂縫等缺陷發生，證明聚合物電解質具陽極保護之效果。 本研究之新穎性為使用SN提升聚合物固態電解質之離子電導率，並藉此電解質延伸配製為準固態聚合物型電解質以組裝出可充電Mg–O2電池，使其可具50圈穩定充放電循環壽命表現，並將其組裝為軟包型電池，測試其於環境大氣下運作之電性表現，改善過往鈕扣型金屬空氣電池之缺點以提升其商業實用性。 | zh_TW |
| dc.description.abstract | The control of greenhouse gas emissions grabbed worldwide attention due to global warming. To reduce the exhaust pollution caused by transportation, electric vehicles and drones have been the focus in recent years. Rechargeable batteries with high energy density, such as magnesium–oxygen (Mg–O2) batteries are being explored as an alternative to lithium-ion batteries for electric vehicles.
This study synthesized a polymer electrolyte suitable for Mg–O2 batteries. By adding succinonitrile (SN), the ionic conductivity could be optimally enhanced to 3.9 × 10–5 S cm–1 under room temperature. The effect of SN on the properties of the polymer electrolyte was characterized. Subsequently, the polymer electrolyte was assembled into a coin-type quasi-solid-state Mg–O2 battery, exhibiting a maximum discharge capacity of 25000 mAh g–1, stable cycle life of 50 cycles, and an overpotential of 0.99 V. When assembled into a pouch-type Mg–O2 battery, its applicability was demonstrated by lighting up a red LED. Moreover, the cathode interface was characterized to explore the reaction mechanism, revealing that magnesium oxide (MgO) and magnesium peroxide (MgO2) are the main discharge products. Simultaneously, the stability of the anode interface was confirmed, which demonstrated the anode protection effect of the polymer electrolyte. The novelty of this study is the introduction of SN to enhance the ion conductivity of polymer electrolytes, which enables the quasi-solid-state Mg–O2 battery to have a stable cycle life of 50 cycles. Additionally, the pouch-type Mg–O2 batteries were assembled and tested in ambient atmospheric conditions, which provide the possibility for large-scale commercial production. | en |
| dc.description.provenance | Submitted by admin ntu (admin@lib.ntu.edu.tw) on 2024-07-01T16:13:37Z No. of bitstreams: 0 | en |
| dc.description.provenance | Made available in DSpace on 2024-07-01T16:13:37Z (GMT). No. of bitstreams: 0 | en |
| dc.description.tableofcontents | 口試委員會審定書 I
誌謝 II 摘要 III Abstract IV 目次 V 圖次 IX 表次 XIII 第一章 緒論 1 1.1金屬空氣電池之發展與介紹 1 1.1.1金屬氧氣電池 2 1.1.1.1鋰氧氣電池 3 1.1.1.2鈉氧氣電池 6 1.1.1.3鎂氧氣電池 10 1.1.2金屬二氧化碳電池 15 1.1.2.1鋰二氧化碳電池 16 1.1.2.2鈉二氧化碳電池 18 1.1.2.3鎂二氧化碳電池 20 1.2常用於鎂氧氣電池之電解質 21 1.2.1水系電解質 22 1.2.2有機溶劑電解質 23 1.2.3聚合物型固態電解質 25 1.3常用於鎂氧氣電池之陰極材料與觸媒 26 1.3.1碳材料 27 1.3.2貴金屬 28 1.3.3過渡金屬氧化物 30 1.3.4含氮金屬大環化合物 31 1.4常用於鎂電解質之添加劑 32 1.4.1緩蝕劑 32 1.4.2氧化還原介質 34 1.4.3塑化晶體 36 1.5 軟包電池 38 1.6研究動機與目的 40 第二章 實驗步驟與儀器分析原理 43 2.1 化學藥品 43 2.2 實驗步驟 45 2.2.1聚合物電解質之合成 45 2.2.2釕金屬修飾之奈米碳管之合成 46 2.2.3陰極漿料之混合與塗佈 47 2.2.4鈕扣型準固態鎂氧氣電池之組裝 48 2.2.5軟包型準固態鎂氧氣電池之組裝 49 2.3 分析儀器與其原理 50 2.3.1 X光繞射儀(X-ray diffractometer; XRD) 50 2.3.2拉曼光譜儀(Raman spectroscopy) 52 2.3.3傅立葉轉換紅外光譜(Fourier-transform infrared spectroscopy; FTIR) 54 2.3.4熱重量與差熱分析儀(thermogravimetric analysis and differential thermal analysis; TGA and DTA) 56 2.3.5掃描式電子顯微鏡(scanning electron microscope; SEM) 57 2.3.6穿透式電子顯微鏡(transmission electron microscopy; TEM) 58 2.3.7 X光光電子能譜儀(X-ray photoelectron spectroscopy; XPS) 59 2.3.8 X光吸收光譜(X-ray absorption spectroscopy; XAS) 61 2.3.9線性掃描伏安法與循環伏安法(linear sweep voltammetry and cyclic voltammetry; LSV and CV) 63 2.3.10電化學阻抗頻譜(electrical impedance spectroscopy; EIS) 65 2.3.11拉伸試驗機(tensile testing machine) 67 2.3.12充放電量測儀(cycling machine) 67 第三章 結果與討論 69 3.1聚合物固態電解質之分析與比較 69 3.1.1交流阻抗量測 69 3.1.1.1定溫下離子電導率隨丁二腈添加比例變化之趨勢 69 3.1.1.2阻抗隨溫度變化之趨勢 71 3.1.1.3鎂離子遷移數量測 72 3.1.2聚合物電解質之成分與結晶度鑑定 73 3.1.2.1 X光繞射鑑定 73 3.1.2.2傅立葉轉換紅外光譜分析 75 3.1.2.3差熱分析量測 76 3.1.3熱重量分析量測 77 3.1.4 電化學勢窗口穩定度量測 78 3.1.5拉伸試驗 79 3.1.6表面與橫截面顯微形貌分析 80 3.2 準固態鎂氧氣電池之電化學性能表現 81 3.2.1鈕扣型準固態鎂氧氣電池 81 3.2.1.1最大放電測試 81 3.2.1.2循環充放電測試 82 3.2.1.3 循環伏安法量測 83 3.2.2 軟包型準固態鎂氧氣電池 84 3.2.2.1最大放電測試 85 3.2.2.2 LED應用與發光測試 86 3.3 陰極放電產物之鑑定 84 3.3.1 X光繞射鑑定 87 3.3.2拉曼光譜鑑定 88 3.3.3 X光光電子能譜鑑定 90 3.3.4 X光吸收光譜鑑定 92 3.3.5表面顯微形貌與元素分析 94 3.4陽極界面穩定性鑑定 97 3.4.1陽極界面副產物之鑑定 98 3.4.2陽極表面顯微形貌分析 99 第四章 結論 101 參考文獻 102 | - |
| dc.language.iso | zh_TW | - |
| dc.subject | PEO聚合物電解質 | zh_TW |
| dc.subject | SN添加劑 | zh_TW |
| dc.subject | 可充電Mg–O2電池 | zh_TW |
| dc.subject | 軟包型Mg–O2電池 | zh_TW |
| dc.subject | Mg–O2電池反應機制 | zh_TW |
| dc.subject | Mg–O2 battery reaction mechanisms | en |
| dc.subject | PEO-based polymer electrolytes | en |
| dc.subject | SN additives | en |
| dc.subject | rechargeable Mg–O2 batteries | en |
| dc.subject | pouch-type Mg–O2 batteries | en |
| dc.title | 應用聚合物電解質之準固態鎂氧氣電池與其相關研究 | zh_TW |
| dc.title | Quasi-Solid-State Magnesium Oxygen Battery with Polymer Electrolytes | en |
| dc.type | Thesis | - |
| dc.date.schoolyear | 112-2 | - |
| dc.description.degree | 碩士 | - |
| dc.contributor.oralexamcommittee | 陳致融;魏大華;關肇正;劉佳兒 | zh_TW |
| dc.contributor.oralexamcommittee | Chih-Jung Chen;Da-Hua Wei;Chao-Cheng Kaun;Chia-Erh Liu | en |
| dc.subject.keyword | PEO聚合物電解質,SN添加劑,可充電Mg–O2電池,軟包型Mg–O2電池,Mg–O2電池反應機制, | zh_TW |
| dc.subject.keyword | PEO-based polymer electrolytes,SN additives,rechargeable Mg–O2 batteries,pouch-type Mg–O2 batteries,Mg–O2 battery reaction mechanisms, | en |
| dc.relation.page | 117 | - |
| dc.identifier.doi | 10.6342/NTU202401340 | - |
| dc.rights.note | 同意授權(全球公開) | - |
| dc.date.accepted | 2024-06-26 | - |
| dc.contributor.author-college | 重點科技研究學院 | - |
| dc.contributor.author-dept | 奈米工程與科學學位學程 | - |
| 顯示於系所單位： | 奈米工程與科學學位學程 | |
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