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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 邱勝賢(Sheng-Hsien Chiu) | |
| dc.contributor.author | Yong-Jay Lee | en |
| dc.contributor.author | 李勇杰 | zh_TW |
| dc.date.accessioned | 2021-07-10T21:41:43Z | - |
| dc.date.available | 2021-07-10T21:41:43Z | - |
| dc.date.copyright | 2020-08-07 | |
| dc.date.issued | 2020 | |
| dc.date.submitted | 2020-08-03 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/76962 | - |
| dc.description.abstract | 由於陰離子對比陽離子具有尺寸較大、形狀獨特以及溶劑合能較高等特性，要設計出能夠藉由陰離子來操控的分子開關相對困難，因此實際例證相對也較為稀少。我們設計了一個在桿狀客體上具有兩個辨識中心的[2]車輪烷，成功合成之後，接著研究分子開關的初始狀態，也就是大環傾向停留的位置，也藉由加入/移除陰離子來控制大環在桿狀客體上的位置。 | zh_TW |
| dc.description.abstract | Compared to cations, interlocked molecular switches that can be controlled by anions are relatively rare, due to their bigger ionic sizes, larger shape variations, and higher solvation energies. We prepared a [2]rotaxane-type molecular switch which has two binding sites on the interlocked dumbbell and we proved that the position of the interlocked macrocycle can be controlled by the presence/absence of proper anions. | en |
| dc.description.provenance | Made available in DSpace on 2021-07-10T21:41:43Z (GMT). No. of bitstreams: 1 U0001-0308202011170200.pdf: 9514998 bytes, checksum: d4edc1905566941b1fd32a9d10e8ef3b (MD5) Previous issue date: 2020 | en |
| dc.description.tableofcontents | 口試委員會審定書 i 誌謝 ii 中文摘要 iii 英文摘要 iv 論文發表 v 目錄 vi 圖目錄 vii 流程目錄 viii 第一章、導論 1 1.1前言 1 1.2分子開關簡介 2 第二章、實驗結果與討論 5 2.1新一代分子開關的設計與動機 5 2.2中間產物的製備與合成 7 2.3車輪烷 6-H·TFPB的合成 10 2.4車輪烷上大環元件與胍鹽基團鍵結比例的談討 12 2.5車輪烷上大環元件的穿隧運動研究 16 2.6目標分子 1-H·TFPB的合成與其催化 22 2.7結論 25 第三章 實驗部分 26 第四章 參考文獻 45 附錄 49 新產物的1H與13C NMR光譜 50 車輪烷與啞鈴形分子之2D NMR光譜 78 [2]車輪烷的質譜 86 | |
| dc.language.iso | zh-TW | |
| dc.subject | 超分子化學 | zh_TW |
| dc.subject | 分子機械 | zh_TW |
| dc.subject | 穿隧運動 | zh_TW |
| dc.subject | 陰離子控制 | zh_TW |
| dc.subject | 車輪烷 | zh_TW |
| dc.subject | molecular machine | en |
| dc.subject | translational motion | en |
| dc.subject | anion-driven | en |
| dc.subject | rotaxane | en |
| dc.subject | supramolecular chemistry | en |
| dc.title | 以陰離子操控[2]車輪烷的開關動作 | zh_TW |
| dc.title | Using Anions to Operate the Motion of a [2]Rotaxane-Type Molecular Switch | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 108-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 徐秀福(Hsiu-Fu Hsu),陳平(Ping Cheng),賴建成(Chien-Chen Lai),李文山(Wen-Shan Li) | |
| dc.subject.keyword | 超分子化學,車輪烷,分子機械,陰離子控制,穿隧運動, | zh_TW |
| dc.subject.keyword | supramolecular chemistry,rotaxane,molecular machine,anion-driven,translational motion, | en |
| dc.relation.page | 88 | |
| dc.identifier.doi | 10.6342/NTU202002254 | |
| dc.rights.note | 未授權 | |
| dc.date.accepted | 2020-08-04 | |
| dc.contributor.author-college | 理學院 | zh_TW |
| dc.contributor.author-dept | 化學研究所 | zh_TW |
| 顯示於系所單位： | 化學系 | |
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