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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 何國川(Kuo-Chuan Ho) | |
dc.contributor.author | Li-Yin Hsiao | en |
dc.contributor.author | 蕭力尹 | zh_TW |
dc.date.accessioned | 2021-07-09T15:51:58Z | - |
dc.date.available | 2023-08-08 | |
dc.date.copyright | 2018-08-08 | |
dc.date.issued | 2018 | |
dc.date.submitted | 2018-08-07 | |
dc.identifier.citation | 1. Granqvist, C. G., Chromogenic materials for transmittance control of large-area windows. Critical Reviews in Solid State and Materials Sciences 1990, 16 (5), 291-308.
2. Hadjoudis, E.; Vittorakis, M.; Moustakali-Mavridis, I., Photochromism and thermochromism of schiff bases in the solid state and in rigid glasses. Tetrahedron 1987, 43 (7), 1345-1360. 3. Araujo, R. J., Photochromism in glasses containing silver halides. Contemporary Physics 1980, 21 (1), 77-84. 4. Araujo, R. J., Opthalmic glass particularly photochromic glass. Journal of Non-Crystalline Solids 1982, 47 (1), 69-86. 5. Babulanam, S. M.; Eriksson, T. S.; Niklasson, G. A.; Granqvist, C. G., Thermochromic VO2 films for energy-efficient windows. Solar Energy Materials 1987, 16 (5), 347-363. 6. Lampert, C. M., Electrochromic materials and devices for energy efficient windows. Solar Energy Materials 1984, 11 (1-2), 1-27. 7. Svensson, J. S. E. M.; Granqvist, C. G., Electrochromic coatings for “smart windows”. Solar Energy Materials 1985, 12 (6), 391-402. 8. Araki, S.; Nakamura, K.; Kobayashi, K.; Tsuboi, A.; Kobayashi, N., Electrochemical optical-modulation device with reversible transformation between transparent, mirror, and black. Advanced Materials 2012, 24 (23), OP122-OP126. 9. Tsuboi, A.; Nakamura, K.; Kobayashi, N., A localized surface plasmon resonance-based multicolor electrochromic device with electrochemically size-controlled silver nanoparticles. Advanced Materials 2013, 25 (23), 3197-3201. 10. Thakur, V. K.; Ding, G.; Ma, J.; Lee, P. S.; Lu, X., Hybrid materials and polymer electrolytes for electrochromic device applications. Advanced Materials 2012, 24 (30), 4071-4096. 11. Yen, H. J.; Lin, K. Y.; Liou, G. S., Transmissive to black electrochromic aramids with high near-infrared and multicolor electrochromism based on electroactive tetraphenylbenzidine units. Journal of Materials Chemistry 2011, 21 (17), 6230-6237. 12. Runnerstrom, E. L.; Llordés, A.; Lounis, S. D.; Milliron, D. J., Nanostructured electrochromic smart windows: Traditional materials and NIR-selective plasmonic nanocrystals. Chemical Communications 2014, 50 (73), 10555-10572. 13. Chen, F.; Fu, X.; Zhang, J.; Wan, X., Near-infrared and multicolored electrochromism of solution processable triphenylamine-anthraquinone imide hybrid systems. Electrochimica Acta 2013, 99, 211-218. 14. Llordés, A.; Garcia, G.; Gazquez, J.; Milliron, D. J., Tunable near-infrared and visible-light transmittance in nanocrystal-in-glass composites. Nature 2013, 500 (7462), 323-326. 15. Deb, S. K., A Novel Electrophotographic System. Appl. Opt. 1969, 8 (S1), 192-195. 16. Mortimer, R. J.; Rosseinsky, D. R.; Monk, P. M. S., Electrochromic Materials and Devices. Angew. Chem. Int. Edit.2015, 1-638. 17. Beaujuge, P. M.; Ellinger, S.; Reynolds, J. R., The donor–acceptor approach allows a black-to-transmissive switching polymeric electrochrome. Nature Materials 2008, 7, 795. 18. Lampert, C. M., Large-area smart glass and integrated photovoltaics. Solar Energy Materials and Solar Cells 2003, 76 (4), 489-499. 19. Argun, A. A.; Aubert, P.-H.; Thompson, B. C.; Schwendeman, I.; Gaupp, C. L.; Hwang, J.; Pinto, N. J.; Tanner, D. B.; MacDiarmid, A. G.; Reynolds, J. R., Multicolored Electrochromism in Polymers: Structures and Devices. Chemistry of Materials 2004, 16 (23), 4401-4412. 20. Mortimer, R. J.; Dyer, A. L.; Reynolds, J. R., Electrochromic organic and polymeric materials for display applications. Displays 2006, 27 (1), 2-18. 21. Kurth, D. G.; Pitarch Lopez, J.; Dong, W.-F., A new Co(ii)-metalloviologen-based electrochromic material integrated in thin multilayer films. Chemical Communications 2005, (16), 2119-2121. 22. Higuchi, M., Stimuli-responsive metallo-supramolecular polymer films: Design, synthesis and device fabrication. Journal of Materials Chemistry C 2014, 2 (44), 9331-9341. 23. Kurth, D. G.; Higuchi, M., Transition metal ions: Weak links for strong polymers. Soft Matter 2006, 2 (11), 915-927. 24. Han, F. S.; Higuchi, M.; Kurth, D. G., Metallo-supramolecular polymers based on functionalized bis-terpyridines as novel electrochromic materials. Advanced Materials 2007, 19 (22), 3928-3931. 25. Fu, S. H.; Higuchi, M.; Kurth, D. G., Metallosupramolecular polyelectrolytes self-assembled from various pyridine ring-substituted bisterpyridines and metal ions: Photophysical, electrochemical, and electrochromic properties. Journal of the American Chemical Society 2008, 130 (6), 2073-2081. 26. Trefonas Iii, P.; West, R., ORGANOSILANE HIGH POLYMERS: OXIDATION OF POLYCYCLOHEXYLMETHYLSILYLENE. Journal of polymer science. Polymer letters edition 1985, 23 (9), 469-473. 27. Zhang, J.; Hsu, C.-Y.; Higuchi, M., Anion Effects to Electrochromic Properties of Ru-based Metallo-supramolecular Polymers. Journal of Photopolymer Science and Technology 2014, 27 (3), 297-300. 28. Jelle, B. P.; Hagen, G., Transmission Spectra of an Electrochromic Window Based on Polyaniline, Prussian Blue and Tungsten Oxide. Journal of the Electrochemical Society 1993, 140 (12), 3560-3564. 29. DeLongchamp, D.; Hammond, P. T., Layer-by-layer assembly of PEDOT/polyaniline electrochromic devices. Advanced Materials 2001, 13 (19), 1455-1459. 30. Lin, C. F.; Hsu, C. Y.; Lo, H. C.; Lin, C. L.; Chen, L. C.; Ho, K. C., A complementary electrochromic system based on a Prussian blue thin film and a heptyl viologen solution. Solar Energy Materials and Solar Cells 2011, 95 (11), 3074-3080. 31. Kuo, T.-H.; Hsu, C.-Y.; Lee, K.-M.; Ho, K.-C., All-solid-state electrochromic device based on poly(butyl viologen), Prussian blue, and succinonitrile. Solar Energy Materials and Solar Cells 2009, 93 (10), 1755-1760. 32. DeLongchamp, D. M.; Hammond, P. T., High-contrast electrochromism and controllable dissolution of assembled prussian blue/polymer nanocomposites. Advanced Functional Materials 2004, 14 (3), 224-232. 33. Mortimer, R. J.; Rosseinsky, D. R., Electrochemical polychromicity in iron hexacyanoferrate films, and a new film form of ferric ferricyanide. Journal of Electroanalytical Chemistry 1983, 151 (1-2), 133-147. 34. Gotoh, A.; Uchida, H.; Ishizaki, M.; Satoh, T.; Kaga, S.; Okamoto, S.; Ohta, M.; Sakamoto, M.; Kawamoto, T.; Tanaka, H.; Tokumoto, M.; Hara, S.; Shiozaki, H.; Yamada, M.; Miyake, M.; Kurihara, M., Simple synthesis of three primary colour nanoparticle inks of Prussian blue and its analogues. Nanotechnology 2007, 18 (34). 35. Hara, S.; Shiozaki, H.; Omura, A.; Tanaka, H.; Kawamoto, T.; Tokumoto, M.; Yamada, M.; Gotoh, A.; Kurihara, M.; Sakamoto, M., Color-switchable glass and display devices fabricated by liquid processes with electrochromic nanoparticle 'ink'. Applied Physics Express 2008, 1 (10), 1040021-1040023. 36. Lee, K. M.; Tanaka, H.; Takahashi, A.; Kim, K. H.; Kawamura, M.; Abe, Y.; Kawamoto, T., Accelerated coloration of electrochromic device with the counter electrode of nanoparticulate Prussian blue-type complexes. Electrochimica Acta 2015, 163, 288-295. 37. Liao, T. C.; Chen, W. H.; Liao, H. Y.; Chen, L. C., Multicolor electrochromic thin films and devices based on the Prussian blue family nanoparticles. Solar Energy Materials and Solar Cells 2016, 145, 26-34. 38. Gruver, G. A.; Kuwana, T., Spectroelectrochemical studies of E.E. and E.E.C. mechanisms. Journal of Electroanalytical Chemistry 1972, 36 (1), 85-99. 39. Nelson, R. F.; W. Leedy, D.; T. Seo, E.; N. Adams, R., Anodic oxidation of 5,10-dihydro-5,10-dimethylphenazine. Anal. Bioanal. Chem. 1966, 224, 184-196. 40. Korth, C.; May, B. C. H.; Cohen, F. E.; Prusiner, S. B., Acridine and phenothiazine derivatives as pharmacotherapeutics for prion disease. Proceedings of the National Academy of Sciences 2001, 98 (17), 9836. 41. Kubota, K.; Kurebayashi, H.; Miyachi, H.; Tobe, M.; Onishi, M.; Isobe, Y., Synthesis and structure–activity relationships of phenothiazine carboxylic acids having pyrimidine-dione as novel histamine H1 antagonists. Bioorganic & Medicinal Chemistry Letters 2009, 19 (10), 2766-2771. 42. Dixit, Y.; Dixit, R.; Gautam, N.; Gautam, D. C., Synthesis and Antimicrobial Activities of Novel Biologically Active Heterocycles: 10H-Phenothiazines, Their Ribofuranosides, and Sulfone Derivatives. Nucleosides, Nucleotides and Nucleic Acids 2009, 28 (11-12), 998-1006. 43. Singh, G.; Kumar, N.; Yadav Ashok, K.; Mishra, A. K., Potential antimicrobial agents: Trifluoromethyl-10H-phenothiazines and ribofuranosides. Heteroatom Chemistry 2003, 14 (6), 481-486. 44. Gautam, V.; Sharma, M.; Samarth, R. M.; Gautam, N.; Kumar, A.; Sharma, I. K.; Gautam, D. C., Synthesis of Some Substituted 10H-Phenothiazines, Ribofuranosides, and their Antioxidant Activity. Phosphorus, Sulfur, and Silicon and the Related Elements 2007, 182 (6), 1381-1392. 45. Kumar, M.; Rathore, R. K.; Gupta, V.; Gupta, R. R., Studies on diamagnetic susceptibility of biologically active heterocycles: Diamagnetic susceptibility of 1,4-benzothiazines. Chemical Physics Letters 1990, 170 (1), 121-124. 46. Kong, X.; Kulkarni, A. P.; Jenekhe, S. A., Phenothiazine-Based Conjugated Polymers: Synthesis, Electrochemistry, and Light-Emitting Properties. Macromolecules 2003, 36 (24), 8992-8999. 47. Hwang, D.-H.; Kim, S.-K.; Park, M.-J.; Lee, J.-H.; Koo, B.-W.; Kang, I.-N.; Kim, S.-H.; Zyung, T., Conjugated Polymers Based on Phenothiazine and Fluorene in Light-Emitting Diodes and Field Effect Transistors. Chemistry of Materials 2004, 16 (7), 1298-1303. 48. Lai, R. Y.; Kong, X.; Jenekhe, S. A.; Bard, A. J., Synthesis, Cyclic Voltammetric Studies, and Electrogenerated Chemiluminescence of a New Phenylquinoline-Biphenothiazine Donor−Acceptor Molecule. Journal of the American Chemical Society 2003, 125 (41), 12631-12639. 49. Tu, X.; Fu, X.; Jiang, Q., The synthesis and electrochemical properties of anodic electrochromic materials phenothiazine derivatives and their electrochromic devices. Displays 2010, 31 (3), 150-154. 50. Weng, D.; Li, M.; Zheng, J.; Xu, C., High-performance complementary electrochromic device based on surface-confined tungsten oxide and solution-phase N-methyl-phenothiazine with full spectrum absorption. Journal of Materials Science 2017, 52 (1), 86-95. 51. Monk, P. M. S., The effect of ferrocyanide on the performance of heptyl viologen-based electrochromic display devices. Journal of Electroanalytical Chemistry 1997, 432 (1-2), 175-179. 52. Yasuda, A.; Mori, H.; Takehana, Y.; Ohkoshi, A.; Kamiya, N., Electrochromic properties of the n-heptyl viologen-ferrocyanide system. Journal of Applied Electrochemistry 1984, 14 (3), 323-327. 53. Levey, G.; Ebbesen, T. W., Methyl viologen radical reactions with several oxidizing agents. Journal of Physical Chemistry 1983, 87 (5), 829-832. 54. Belinko, K., Electrochemical studies of the viologen system for display applications. Applied Physics Letters 1976, 29 (6), 363-365. 55. Kao, S. Y.; Lu, H. C.; Kung, C. W.; Chen, H. W.; Chang, T. H.; Ho, K. C., Thermally Cured Dual Functional Viologen-Based All-in-One Electrochromic Devices with Panchromatic Modulation. ACS Applied Materials and Interfaces 2016, 8 (6), 4175-4184. 56. Michaelis, L.; Hill, E. S., The viologen indicators. Journal of General Physiology 1933, 16 (6), 859-873. 57. Bird, C. L.; Kuhn, A. T., Electrochemistry of the viologens. Chemical Society Reviews 1981, 10 (1), 49-82. 58. Śliwa, W.; Bachowska, B.; Zelichowicz, N., Chemistry of viologens. Heterocycles 1991, 32 (11), 2241-2273. 59. Ho, K. C.; Greenberg, C. B., Tungsten Oxide-Prussian Blue Electrochromic System Based on a Proton-Conducting Polymer Electrolyte. Journal of the Electrochemical Society 1994, 141 (8), 2061-2067. 60. Cai, G.; Darmawan, P.; Cui, M.; Wang, J.; Chen, J.; Magdassi, S.; Lee, P. S., Highly Stable Transparent Conductive Silver Grid/PEDOT:PSS Electrodes for Integrated Bifunctional Flexible Electrochromic Supercapacitors. Advanced Energy Materials 2016, 6 (4). 61. Layani, M.; Kamyshny, A.; Magdassi, S., Transparent conductors composed of nanomaterials. Nanoscale 2014, 6 (11), 5581-5591. 62. Kobayashi, N.; Hirohashi, R.; Ohno, H.; Tsuchida, E., Electrochromic characteristics for all solid state ECD composed of polymer electrolytes. Solid State Ionics 1990, 40-41, 491-494. 63. Fletcher, S.; Duff, L.; Barradas, R. G., Nucleation and charge-transfer kinetics at the viologen/SnO2 interface in electrochromic device applications. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry 1979, 100 (1), 759-770. 64. Lin, C.-F.; Hsu, C.-Y.; Lo, H.-C.; Lin, C.-L.; Chen, L.-C.; Ho, K.-C., A complementary electrochromic system based on a Prussian blue thin film and a heptyl viologen solution. Solar Energy Materials and Solar Cells 2011, 95 (11), 3074-3080. 65. Green, S.; Backholm, J.; Georén, P.; Granqvist, C. G.; Niklasson, G. A., Electrochromism in nickel oxide and tungsten oxide thin films: Ion intercalation from different electrolytes. Solar Energy Materials and Solar Cells 2009, 93 (12), 2050-2055. 66. Baba, A.; Tian, S.; Stefani, F.; Xia, C.; Wang, Z.; Advincula, R. C.; Johannsmann, D.; Knoll, W., Electropolymerization and doping/dedoping properties of polyaniline thin films as studied by electrochemical-surface plasmon spectroscopy and by the quartz crystal microbalance. Journal of Electroanalytical Chemistry 2004, 562 (1), 95-103. 67. Hu, C. W.; Lee, K. M.; Huang, J. H.; Hsu, C. Y.; Kuo, T. H.; Yang, D. J.; Ho, K. C., Incorporation of a stable radical 2,2,6,6-tetramethyl-1-piperidinyloxy (TEMPO) in an electrochromic device. Solar Energy Materials and Solar Cells 2009, 93 (12), 2102-2107. 68. Zhang, J.; Tu, J. P.; Xia, X. H.; Qiao, Y.; Lu, Y., An all-solid-state electrochromic device based on NiO/WO3 complementary structure and solid hybrid polyelectrolyte. Solar Energy Materials and Solar Cells 2009, 93 (10), 1840-1845. 69. Lin, T. H.; Ho, K. C., A complementary electrochromic device based on polyaniline and poly(3,4-ethylenedioxythiophene). Solar Energy Materials and Solar Cells 2006, 90 (4), 506-520. 70. Wang, J. Y.; Yu, C. M.; Hwang, S. C.; Ho, K. C.; Chen, L. C., Influence of coloring voltage on the optical performance and cycling stability of a polyaniline-indium hexacyanoferrate electrochromic system. Solar Energy Materials and Solar Cells 2008, 92 (2), 112-119. 71. Ho, K. C.; Fang, Y. W.; Hsu, Y. C.; Chen, L. C., The influences of operating voltage and cell gap on the performance of a solution-phase electrochromic device containing HV and TMPD. Solid State Ionics 2003, 165 (1-4), 279-287. 72. Ho, K.-C.; Fang, Y.-W.; Hsu, Y.-C.; Chen, L.-C., The influences of operating voltage and cell gap on the performance of a solution-phase electrochromic device containing HV and TMPD. Solid State Ionics 2003, 165 (1), 279-287. 73. Moon, H. C.; Lodge, T. P.; Frisbie, C. D., Solution Processable, Electrochromic Ion Gels for Sub-1 V, Flexible Displays on Plastic. Chemistry of Materials 2015, 27 (4), 1420-1425. 74. Chidichimo, G.; Imbardelli, D.; De Simone, B. C.; Barone, P.; Barberio, M.; Bonanno, A.; Camarca, M.; Oliva, A., Spectroscopic and Kinetic Investigation of Ethyl Viologen Reduction in Novel Electrochromic Plastic Films. The Journal of Physical Chemistry C 2010, 114 (39), 16700-16705. 75. Gruver, G. A.; Kuwana, T., Spectroelectrochemical studies of E.E. and E.E.C. mechanisms. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry 1972, 36 (1), 85-99. 76. Watanabe, Y.; Imaizumi, K.; Nakamura, K.; Kobayashi, N., Effect of counter electrode reaction on coloration properties of phthalate-based electrochromic cell. Solar Energy Materials and Solar Cells 2012, 99, 88-94. 77. Hu, C. W.; Sato, T.; Zhang, J.; Moriyama, S.; Higuchi, M., Multi-colour electrochromic properties of Fe/Ru-based bimetallo- supramolecular polymers. Journal of Materials Chemistry C 2013, 1 (21), 3408-3413. 78. Roig, A.; Navarro, J.; Garcia, J. J.; Vicente, F., Voltammetric study of the stability of deposited Prussian blue films against succesive potential cycling. Electrochimica Acta 1994, 39 (3), 437-442. 79. Silva, G. A.; Costa, L. M. M.; Brito, F. C. F.; Miranda, A. L. P.; Barreiro, E. J.; Fraga, C. A. M., New class of potent antinociceptive and antiplatelet 10H-phenothiazine-1-acylhydrazone derivatives. Bioorganic & Medicinal Chemistry 2004, 12 (12), 3149-3158. 80. Chandra, D.; Sharma, V. N.; Mital, R. L., Studies on some new phenothiazines. Canadian Journal of Chemistry 1967, 45, 761-767. 81. Zhang, W. W.; Yu, Y. G.; Lu, Z. D.; Mao, W. L.; Li, Y. Z.; Meng, Q. J., Ferrocene - Phenothiazine conjugated molecules: Synthesis, structural characterization, electronic properties, and DFT-TDDFT computational study. Organometallics 2007, 26, 865-873. 82. Kim, S.-K.; Lee, J.-H.; Hwang, D.-H., EL properties of an alternating copolymer composed of phenothiazine and thiophene heterocycles. Synthetic Metals 2005, 152 (1), 201-204. 83. Wang, W.; Sheng, C.; Che, X.; Ji, H.; Miao, Z.; Yao, J.; Zhang, W., Design, Synthesis, and Antifungal Activity of Novel Conformationally Restricted Triazole Derivatives. Archiv der Pharmazie 2009, 342 (12), 732-739. 84. Messali, M.; Aouad, R. M.; El-Sayed, S. W.; Al-Sheikh Ali, A.; Ben Hadda, T.; Hammouti, B., New Eco-Friendly 1-Alkyl-3-(4-phenoxybutyl) Imidazolium-Based Ionic Liquids Derivatives: A Green Ultrasound-Assisted Synthesis, Characterization, Antibacterial Activity and POM Analyses. Molecules 2014, 19 (8), 11741-11759. 85. Beniwal, V.; Kumar, A., Thermodynamic and molecular origin of interfacial rate enhancements and endo-selectivities of a Diels-Alder reaction. Physical Chemistry Chemical Physics 2017, 19 (6), 4297-4306. 86. Yao, C.-J.; Zhong, Y.-W.; Yao, J., Five-Stage Near-Infrared Electrochromism in Electropolymerized Films Composed of Alternating Cyclometalated Bisruthenium and Bis-triarylamine Segments. Inorganic Chemistry 2013, 52 (17), 10000-10008. 87. Andres, P. R.; Schubert, U. S., New Functional Polymers and Materials Based on 2,2′:6′,2″-Terpyridine Metal Complexes. Advanced Materials 2004, 16 (13), 1043-1068. 88. Dong, Y.-B.; Wang, P.; Huang, R.-Q.; Smith, M. D., Syntheses and Structures of Ag(I)-Containing Coordination Polymers and Co(II)-Containing Supramolecular Complex Based on Novel Fulvene Ligands. Inorganic Chemistry 2004, 43 (15), 4727-4739. 89. Hu, C.-W.; Sato, T.; Zhang, J.; Moriyama, S.; Higuchi, M., Multi-colour electrochromic properties of Fe/Ru-based bimetallo-supramolecular polymers. Journal of Materials Chemistry C 2013, 1 (21), 3408-3413. 90. Han, F. S.; Higuchi, M.; Ikeda, T.; Negishi, Y.; Tsukuda, T.; Kurth, D. G., Luminescence properties of metallo-supramolecular coordination polymers assembled from pyridine ring functionalized ditopic bis-terpyridines and Ru(ii) ion. Journal of Materials Chemistry 2008, 18 (38), 4555-4560. 91. Kanao, M.; Higuchi, M., Synthesis of Metallo-Supramolecular Polymers with Bis-NNN-Tridentate Ligand for Electrochromic Devices. Journal of Photopolymer Science and Technology 2015, 28 (3), 363-368. 92. Han, F. S.; Higuchi, M.; Kurth, D. G., Diverse Synthesis of Novel Bisterpyridines via Suzuki-Type Cross-Coupling. Organic Letters 2007, 9 (4), 559-562. 93. Ide, T.; Takeuchi, D.; Osakada, K.; Sato, T.; Higuchi, M., Aromatic Macrocycle Containing Amine and Imine Groups: Intramolecular Charge-Transfer and Multiple Redox Behavior. The Journal of Organic Chemistry 2011, 76 (22), 9504-9506. 94. Hsu, C.-Y.; Zhang, J.; Sato, T.; Moriyama, S.; Higuchi, M., Black-to-Transmissive Electrochromism with Visible-to-Near-Infrared Switching of a Co(II)-Based Metallo-Supramolecular Polymer for Smart Window and Digital Signage Applications. ACS Applied Materials & Interfaces 2015, 7 (33), 18266-18272. 95. Wu, J.-T.; Liou, G.-S., A novel panchromatic shutter based on an ambipolar electrochromic system without supporting electrolyte. Chemical Communications 2018, 54 (21), 2619-2622. 96. Kao, S.-Y.; Lu, H.-C.; Kung, C.-W.; Chen, H.-W.; Chang, T.-H.; Ho, K.-C., Thermally Cured Dual Functional Viologen-Based All-in-One Electrochromic Devices with Panchromatic Modulation. ACS Applied Materials & Interfaces 2016, 8 (6), 4175-4184. 97. Shin, H.; Kim, Y.; Bhuvana, T.; Lee, J.; Yang, X.; Park, C.; Kim, E., Color Combination of Conductive Polymers for Black Electrochromism. ACS Applied Materials & Interfaces 2012, 4 (1), 185-191. 98. Weng, D.; Shi, Y.; Zheng, J.; Xu, C., High performance black-to-transmissive electrochromic device with panchromatic absorption based on TiO2-supported viologen and triphenylamine derivatives. Organic Electronics 2016, 34, 139-145. 99. McCargar, J. W.; Neff, V. D., Thermodynamics of mixed-valence intercalation reactions: The electrochemical reduction of Prussian blue. Journal of Physical Chemistry 1988, 92 (12), 3598-3604. 100. Mortimer, R. J.; Reynolds, J. R., In situ colorimetric and composite coloration efficiency measurements for electrochromic Prussian blue. Journal of Materials Chemistry 2005, 15 (22), 2226-2233. 101. Maestri, M.; Armaroli, N.; Balzani, V.; Constable, E. C.; Thompson, A. M. W. C., Complexes of the Ruthenium(II)-2,2′:6′,2″ -Terpyridine Family. Effect of Electron-Accepting and -Donating Substituents on the Photophysical and Electrochemical Properties. Inorganic Chemistry 1995, 34 (10), 2759-2767. 102. Schott, M.; Szczerba, W.; Posset, U.; Šurca Vuk, A.; Beck, M.; Riesemeier, H.; Thünemann, A. F.; Kurth, D. G., In operando XAFS experiments on flexible electrochromic devices based on Fe(II)-metallo-supramolecular polyelectrolytes and vanadium oxide. Solar Energy Materials and Solar Cells 2016, 147, 61-67. 103. Chen, W.-H.; Chang, T.-H.; Hu, C.-W.; Ting, K.-M.; Liao, Y.-C.; Ho, K.-C., An electrochromic device composed of metallo-supramolecular polyelectrolyte containing Cu(I) and polyaniline-carbon nanotube. Solar Energy Materials and Solar Cells 2014, 126, 219-226. 104. Ho, T. D.; Zhang, C.; Hantao, L. W.; Anderson, J. L., Ionic Liquids in Analytical Chemistry: Fundamentals, Advances, and Perspectives. Analytical Chemistry 2014, 86 (1), 262-285. 105. Scrosati, B.; Hassoun, J.; Sun, Y.-K., Lithium-ion batteries. A look into the future. Energy & Environmental Science 2011, 4 (9), 3287-3295. 106. Park, M.; Zhang, X.; Chung, M.; Less, G. B.; Sastry, A. M., A review of conduction phenomena in Li-ion batteries. Journal of Power Sources 2010, 195 (24), 7904-7929. 107. Lewandowski, A.; Świderska-Mocek, A., Ionic liquids as electrolytes for Li-ion batteries—An overview of electrochemical studies. Journal of Power Sources 2009, 194 (2), 601-609. 108. de Souza, R. F.; Padilha, J. C.; Gonçalves, R. S.; Dupont, J., Room temperature dialkylimidazolium ionic liquid-based fuel cells. Electrochemistry Communications 2003, 5 (8), 728-731. 109. Gírio, F. M.; Fonseca, C.; Carvalheiro, F.; Duarte, L. C.; Marques, S.; Bogel-Łukasik, R., Hemicelluloses for fuel ethanol: A review. Bioresource Technology 2010, 101 (13), 4775-4800. 110. Wang, P.; Zakeeruddin, S. M.; Moser, J.-E.; Grätzel, M., A New Ionic Liquid Electrolyte Enhances the Conversion Efficiency of Dye-Sensitized Solar Cells. The Journal of Physical Chemistry B 2003, 107 (48), 13280-13285. 111. Wang, P.; Zakeeruddin, S. M.; Moser, J. E.; Nazeeruddin, M. K.; Sekiguchi, T.; GrÄTzel, M., A stable quasi-solid-state dye-sensitized solar cell with an amphiphilic ruthenium sensitizer and polymer gel electrolyte. In Materials for Sustainable Energy, Co-Published with Macmillan Publishers Ltd, UK: 2010; pp 88-93. 112. Ito, S.; Zakeeruddin, S. M.; Humphry-Baker, R.; Liska, P.; Charvet, R.; Comte, P.; Nazeeruddin, M. K.; Péchy, P.; Takata, M.; Miura, H.; Uchida, S.; Grätzel, M., High-efficiency organic-dye-sensitized solar cells controlled by nanocrystalline-TiO2 electrode thickness. Advanced Materials 2006, 18 (9), 1202-1205. 113. Ye, Y.-S.; Rick, J.; Hwang, B.-J., Ionic liquid polymer electrolytes. Journal of Materials Chemistry A 2013, 1 (8), 2719-2743. 114. Qian, W.; Jin, E.; Bao, W.; Zhang, Y., Clean and selective oxidation of alcohols catalyzed by ion-supported TEMPO in water. Tetrahedron 2006, 62 (4), 556-562. 115. Chu, T.-C.; Lin Ryan, Y.-Y.; Lee, C.-P.; Hsu, C.-Y.; Shih, P.-C.; Lin, R.; Li, S.-R.; Sun, S.-S.; Lin Jiann, T.; Vittal, R.; Ho, K.-C., Ionic Liquid with a Dual-Redox Couple for Efficient Dye-Sensitized Solar Cells. ChemSusChem 2013, 7 (1), 146-153. 116. Bui-Thi-Tuyet, V.; Trippé-Allard, G.; Ghilane, J.; Randriamahazaka, H., Surface and Electrochemical Properties of Polymer Brush-Based Redox Poly(Ionic Liquid). ACS Applied Materials & Interfaces 2016, 8 (42), 28316-28324. 117. Forgie, J. C.; El Khakani, S.; MacNeil, D. D.; Rochefort, D., Electrochemical characterisation of a lithium-ion battery electrolyte based on mixtures of carbonates with a ferrocene-functionalised imidazolium electroactive ionic liquid. Physical Chemistry Chemical Physics 2013, 15 (20), 7713-7721. 118. Zhang, W.; Qiu, L.; Chen, X.; Yan, F., Imidazolium Functionalized Bis-2,2,6,6-Tetramethyl-piperidine-1-oxyl (TEMPO) Bi-redox Couples for Highly Efficient Dye-Sensitized Solar Cells. Electrochimica Acta 2014, 117, 48-54. 119. Gélinas, B.; Das, D.; Rochefort, D., Air-Stable, Self-Bleaching Electrochromic Device Based on Viologen- and Ferrocene-Containing Triflimide Redox Ionic Liquids. ACS Applied Materials & Interfaces 2017, 9 (34), 28726-28736. 120. Liao, Y.; Jiang, P.; Chen, S.; Xiao, F.; Deng, G.-J., Synthesis of phenothiazines from cyclohexanones and 2-aminobenzenethiols under transition-metal-free conditions. RSC Advances 2013, 3 (40), 18605-18608. 121. Kao, S.-Y.; Kawahara, Y.; Nakatsuji, S. i.; Ho, K.-C., Achieving a large contrast, low driving voltage, and high stability electrochromic device with a viologen chromophore. Journal of Materials Chemistry C 2015, 3 (14), 3266-3272. 122. Lu, H.-C.; Kao, S.-Y.; Chang, T.-H.; Kung, C.-W.; Ho, K.-C., An electrochromic device based on Prussian blue, self-immobilized vinyl benzyl viologen, and ferrocene. Solar Energy Materials and Solar Cells 2016, 147, 75-84. 123. Chang, T.-H.; Lu, H.-C.; Lee, M.-H.; Kao, S.-Y.; Ho, K.-C., Multi-color electrochromic devices based on phenyl and heptyl viologens immobilized with UV-cured polymer electrolyte. Solar Energy Materials and Solar Cells 2018, 177, 75-81. 124. Monk, P. M. S.; Fairweather, R. D.; Ingram, M. D.; Duffy, J. A., Evidence for the product of the viologen comproportionation reaction being a spin-paired radical cation dimer. Journal of the Chemical Society, Perkin Transactions 2 1992, 2(11), 2039-2041. 125. Goddard, N. J.; Jackson, A. C.; Thomas, M. G., Spectrelectrochemical studies of some viologens used in electrochromic display applications. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry 1983, 159 (2), 325-335. 126. van Dam, H. T.; Ponjeé, J. J., Electrochemically Generated Colored Films of Insoluble Viologen Radical Compounds. Journal of the Electrochemical Society 1974, 121 (12), 1555-1558. 127. Rosokha, S. V.; Kochi, J. K., Continuum of Outer- and Inner-Sphere Mechanisms for Organic Electron Transfer. Steric Modulation of the Precursor Complex in Paramagnetic (Ion-Radical) Self-Exchanges. Journal of the American Chemical Society 2007, 129 (12), 3683-3697. 128. Fan, M.-S.; Lee, C.-P.; Vittal, R.; Ho, K.-C., A novel ionic liquid with stable radical as the electrolyte for hybrid type electrochromic devices. Solar Energy Materials and Solar Cells 2017, 166, 61-68. 129. Tahara, H.; Baba, R.; Iwanaga, K.; Sagara, T.; Murakami, H., Electrochromism of a bipolar reversible redox-active ferrocene–viologen linked ionic liquid. Chemical Communications 2017, 53 (16), 2455-2458. | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/76411 | - |
dc.description.abstract | 在本論文中,本研究主要製備了兩種電致色變元件並加以探討其電化學性質,組成第一種電致色變元件的變色材料為釕鐵雙金屬超分子高分子和普魯士藍,第二種電致色變元件則由N-甲基吩噻嗪離子液體和苯基紫精所製備而成。
在本研究第三章,首先製備出釕鐵雙金屬超分子高分子,並對其單膜電化學性質仔細探討。另外,由於普魯士藍是廣為人知非常穩定的電變色材料,且在光學表現上在600至800 nm處有不錯的吸收強度,而釕鐵雙金屬超分子高分子具有400到600 nm之強烈吸收峰,因此我們提出藉由此兩種材料之搭配,製備出能吸收全波段可見光的電致色變元件。為了防止漏液,此元件的電解質採用高分子電解質,當操作電位在1.3 V和-2.2 V之間,此元件在分別503、580和690 nm之波長下具有52.7%、46.9%和28.0%穿透度變化,在503 nm、580 nm波長下有小於0.5 s的快速著去色時間,還發現此元件具有特殊的三段式著色效率變化,而最大著色效率為525.1 cm2/C。另一方面,本研究還探討了記憶效應與長期穩定性相關性,藉由添加酸化過後的多壁奈米碳管,其表面所具有酸化官能基可以吸附過氯酸根離子,因此當釕鐵雙金屬超分子高分子加入些許多壁奈米碳管,在經過200秒之後,在相較記憶效應不好的503奈米波段,此薄膜仍可以維持42%原來之最高去色穿透度。 在本研究第四章,藉由五種步驟反應成功合成出全新之帶有N-甲基吩噻嗪的離子液體,分別為硫化、脘基化、取代反應、離子化和陰離子製換。且每步驟之中間產物和最終產物之結構皆用核磁共振和質譜儀確認。首先,在三級式之電解槽中對N-甲基吩噻嗪的離子液體做電化學分析,發現接上離子液體後,因為分子結構由原本平面分子(N-甲基吩噻嗪)改變為非平面分子,導致N-甲基吩噻嗪離子液體之吸收波長從520奈米偏移到575 nm之位置,顏色從紅色變為紫色。為了進一步確認N-甲基吩噻嗪離子液體在元件中電化學表現,我們使用穩定度很高的苯基紫精與之作為搭配來組成電致色變元件,此元件0 V與1.2 V的操作下,在575 nm波段下具有69.2%之光學穿透度化,小於4 s的著去色響應時間、高著色效率(531 cm2/C),在10,000圈操作後仍保持其最初97.8%之光學度穿透度變化。由此可知,本研究所合成出來的新型氧化著色材料:N-甲基吩噻嗪的離子液體同時保有N-甲基吩噻嗪的高吸收度變化和離子液體的高穩定性。 | zh_TW |
dc.description.abstract | In this thesis, the electrochromic (EC) performance of two electrochromic devices (ECDs), Ru(II)/Fe(II)-based heterometallo-supramolecular polymer/Prussian blue (PolyRuFe/PB) and N-methylphenothiazine-based ionic liquid/phenyl viologen (NMP-IL/PV) was carefully investigated.
Firstly, Ru(II)/Fe(II)-based heterometallo-supramolecular polymer (PolyRuFe) has been successfully synthesized and the electrochromic properties are carefully investigated. Also, Prussian blue (PB) is selected as counter electrode owing to its good stability and large absorbance change of UV-visible spectra from 600 to 800 nm, which is cooperated with main absorbance change of PolyRuFe from 400 to 600 nm. The PolyRuFe/PB ECD has been successfully fabricated with panchromatic characteristic and the mechanism is proposed. Switching between -1.3 and 2.2 V, the proposed ECD utilizing the gel-typed electrolyte based on PMMA preventing the leakage problem exhibits the transmittance changes of 52.7%, 46.9%, and 28.0% at 503, 580, and 690 nm, respectively. Moreover, the fast response time of less than 0.5 s could be observed at 503 and 580 nm for both coloring and bleaching. The PolyRuFe/PB ECD also exhibits three-step coloration efficiency and the highest values are 525.1 cm2/C at 503 nm. Furthermore, we proposed the relationship between the long-term stability and the memory effect of PolyRuFe/PB ECD. It was found that PolyRuFe incorporated with multi-walled carbon nanotubes (PolyRuFe-MWCNT) exhibits longer memory effect than bare PolyRuFe thin film. PolyRuFe-MWCNT remained 75%, 59% and 42% of their initial saturated bleaching state at 503 nm after 50, 100 and 200 s, respectively. In the second part, we synthesized the novel NMP-based IL via five-step reaction, including thionation, methylation, substitution, ionization and anion exchange that no one demonstrated before. Each structure of intermediates was confirmed by 1H-NMR, 13C-NMR and mass spectra. When the functional groups graft on the benzene, the obvious absorbance change to 575 nm is found. It is explained that molecular structures changes from open ion-radical to hindered ion-radical. Namely, the planar structure of NMP convert into NMP-IL which belongs to hindered system. In order to investigate the EC performance of NMP-IL in ECD, the complementary ECD was fabricated incorporating the cathodically coloring material, PV, which is well-known for its high optical contrast and good stability. The NMP-IL/PV ECD exhibits largest transimittance change of 69.2% and desirable coloration efficiency of 531 cm2/C at 575 nm, which is contributed to the additive absorbance change of both coloring material. Moreover, the short switching times of less 4 s and good long-term stability (remained 92%, 96.2% and 97.8% of its original ΔT after 10,000 cycles at 430, 575 and 710 nm respectively) is obtained. These evidences reveal that the new potential anodically coloring material, NMP-IL, combining both the advantages of NMP and ionic liquid have successfully synthesized. | en |
dc.description.provenance | Made available in DSpace on 2021-07-09T15:51:58Z (GMT). No. of bitstreams: 1 ntu-107-R05524050-1.pdf: 4832937 bytes, checksum: 72c4e30ab6ad84e140138ac924272082 (MD5) Previous issue date: 2018 | en |
dc.description.tableofcontents | 致謝 I
中文摘要 III Abstract IV Table of contents VI List of tables IX List of figures X Nomenclatures XIV Chapter 1 Introduction 1 1.1 Overview of electrochromism 1 1.2 Electrochromic performance parameters 2 1.3 Introduction of electrochromic materials 5 1.4 Electrochromic devices 15 1.5 Scope of this thesis 19 Chapter 2 Experimental Procedure 21 2.1 General experimental details 21 2.1.1 Materials 21 2.1.2 Apparatus 22 2.2 Experimental detail related to Chapter 3 22 2.2.1 Synthesis of PolyRuFe and preparation of PolyRuFe thin film 22 2.2.2 Synthesis of PB nanoparticles and preparation of PB thin film 22 2.2.3 Cell assembly 23 2.3 Experimental detail related to Chapter 4 23 2.3.1 Synthesis of NMP-IL 23 2.3.2 Preparation of PV (PV(BF4)2) 28 2.3.3 Cell assembly 28 Chapter 3 A Panchromatic Electrochromic Device Composed of Ru(II)/Fe(II)-based Heterometallo-supramolecular Polymer and Prussian Blue 29 3.1 Introduction 29 3.2 Results and discussion 31 3.2.1 Characterization of PolyRuFe in a three electrode system 31 3.2.2 Characterization of PB in a three electrode system (vs. Ag/Ag+) 37 3.2.3 Characterization of PolyRuFe/PB ECD 39 3.3 Conclusions 54 Chapter 4 N-methylphenothiazine Derived Ionic Liquid as Redox Couple with Phenyl Viologen for ECD 55 4.1 Introduction 55 4.2 Results and discussion 57 4.2.1 Characterization of NHP-OH by 1H NMR, 13C NMR and mass spectrometry 57 4.2.2 Characterization of NMP-OH by 1H NMR, 13C NMR and mass spectrometry 60 4.2.3 Characterization of NMP-Br by 1H NMR, 13C NMR and mass spectrometry 62 4.2.4 Characterization of NMP-IL by 1H NMR, 13C NMR and mass spectrometry 64 4.2.5 Characterization of NMP, NMP-Br and NMP-IL in a three-electrode system 66 4.2.6 Characterization of NMP-IL/PV ECD 70 4.3 Conclusion 78 Chapter 5 Conclusions and Suggestions 79 5.1 General conclusions 79 5.2 Suggestions 80 5.2.1 Suggestions for Chapter 3 80 5.2.1 Suggestions for Chapter 4 80 References 81 Appendix A 94 | |
dc.language.iso | en | |
dc.title | 雙金屬超分子高分子或N-甲基吩噻嗪離子液體應用於電致色變元件 | zh_TW |
dc.title | Electrochromic Devices Based on Heterometallo-supramolecular Polymer or N-methylphenothiazine Derived Ionic Liquid | en |
dc.type | Thesis | |
dc.date.schoolyear | 106-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 林正嵐,周澤川,戴子安 | |
dc.subject.keyword | 電致色變元件,全波段吸收,金屬超分子高分子,N-甲基吩??離子液體,多壁奈米碳管, | zh_TW |
dc.subject.keyword | Electrochromic device,Panchromatic,Metallo-supramolecular polymer,N-methylphenothiazine,Ionic liquid,Multi-walled carbon nanotube, | en |
dc.relation.page | 95 | |
dc.identifier.doi | 10.6342/NTU201802607 | |
dc.rights.note | 同意授權(全球公開) | |
dc.date.accepted | 2018-08-07 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
dc.date.embargo-lift | 2023-08-08 | - |
顯示於系所單位: | 化學工程學系 |
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