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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 蔡豐羽 | |
dc.contributor.author | Cheng-Hung Hou | en |
dc.contributor.author | 侯政宏 | zh_TW |
dc.date.accessioned | 2021-06-17T03:44:25Z | - |
dc.date.available | 2018-02-23 | |
dc.date.copyright | 2018-02-23 | |
dc.date.issued | 2018 | |
dc.date.submitted | 2018-02-02 | |
dc.identifier.citation | Ch1
1. Julian Burschka, Norman Pellet, Soo-Jin Moon, Robin Humphry-Baker, Peng Gao, Mohammad K. Nazeeruddin and Michael Grätzel, “Sequential deposition as a route to high-performance perovskite-sensitized solar cells”, Nature, 499,316-319 2. Mingzhen Liu, Michael B. Johnston & Henry J. Snaith, “Efficient planar heterojuction perovskite solar cells by vapor deposition”, Nature, doi:10.1038/nature12509 3. Huanping Zhou, Qi Chen, Gang Li, Song Luo, Tze-bing Song, Hsin-Sheng Duan, Ziruo Hong, Jingbi You, Yongsheng Liu, Yang Yang, “Interface engineering of highly efficient perovskite solar cells”, Science, 345, 542-546 4. Nam Joong Jeon, Jun Hong Noh, Young Chan Kim,Woon Seok Yang, Seungchan Ryu, and Sang Il Seok, “Solvent engineering for high-performance inorganic–organic hybrid perovskite solar cells”, Nature Materials, 13, 897-903 5. Nam Joong Jeon, Jun Hong Noh, Woon Seok Yang, Young Chan Kim, Seungchan Ryu, Jangwon Seo & Sang Il Seok, “Compositional engineering of perovskite materials for high-performance solar cells”, Nature, 517, 476-480 6. Woon Seok Yang, Jun Hong Noh, Nam Joong Jeon, Young Chan Kim, Seungchan Ryu, Jangwon Seo, Sang Il Seok, “High-performance photovoltaic perovskite layers fabricated through intramolecular exchange” Science, 348, 1234-1237 7. Jeong-Hyeok Im, In-Hyuk Jang, Norman Pellet, Michael Grätzel and Nam-Gyu Park, “Growth of CH3NH3PbI3 cuboids with controlled size for high-efficiency perovskite solar cells”, Nature Nanotechnology, 9, 927-932 8. Wanyi Nie, Hsinhan Tsai, Reza Asadpour, Jean-Christophe Blancon, Amanda J. Neukirch, Gautam Gupta, Jared J. Crochet, Manish Chhowalla, Sergei Tretiak, Muhammad A. Alam, Hsing-Lin Wang, Aditya D. Mohite, “High-efficiency solution-processed perovskite solar cells with millimeter-scale grains”, Science, 347, 522-525 9. Feng Hao, Constantinos C. Stoumpos, Duyen Hanh Cao, Robert P. H. Chang, and Mercouri G. Kanatzidis, “Lead-free solid-state organic–inorganic halide perovskite solar cells”, Nature Photonics, 8, 489-494 10. Giacomo Giorgi, Jun-Ichi Fujisawa, Hiroshi Segawa, and Koichi Yamashita, “Small Photocarrier Effective Masses Featuring Ambipolar Transport in Methylammonium Lead Iodide Perovskite: A Density Functional Analysis”, The Journal of Physical Chemistry Letters, 4, 4213-4216 11. Feng Li, Chun Ma, Hong Wang, Weijin Hu, Weili Yu, Arif D. Sheikh & Tom Wu, “Ambipolar solution-processed hybrid perovskite phototransistors”, Nature Communications, DOI: 10.1038/ncomms9238 12. Dianyi Liu and Timothy L. Kelly, “Perovskite solar cells with a planar heterojunction structure prepared using room-temperature solution processing techniques”, Nature Photonics, 8, 133-138 13. Jingbi You, LeiMeng, Tze-Bin Song, Tzung-Fang Guo, Yang (Michael) Yang, Wei-Hsuan Chang, Ziruo Hong, Huajun Chen, Huanping Zhou, Qi Chen, Yongsheng Liu, Nicholas De Marco, and Yang Yang, “Improved air stability of perovskite solar cells via solution-processed metal oxide transport layers”, Nature Nanotechnology, DOI: 10.1038/NNANO.2015.230 14. Kuo-Chin Wang, Jun-Yuan Jeng, Po-Shen Shen, Yu-Cheng Chang, Eric Wei-Guang Diau, Cheng-Hung Tsai, Tzu-Yang Chao, Hsu-Cheng Hsu, Pei-Ying Lin, Peter Chen, Tzung-Fang Guo, & Ten-Chin Wen, “p-type Mesoscopic Nickel Oxide/Organometallic Perovskite Heterojunction Solar Cells”, Scientific Reports, DOI: 10.1038/srep04756 15. Jong H. Kim, Po-Wei Liang, Spencer T. Williams, Namchul Cho, Chu-Chen Chueh, Micah S. Glaz, David S. Ginger, and Alex K.-Y. Jen, “High-Performance and Environmentally Stable Planar Heterojunction Perovskite Solar Cells Based on a Solution-Processed Copper-Doped Nickel Oxide Hole-Transporting Layer”, Advanced Materials, 27, 695-701 16. Jong Hoon Park, Jangwon Seo, Sangman Park, Seong Sik Shin, Young Chan Kim, Nam Joong Jeon, Hee-Won Shin, Tae Kyu Ahn, Jun Hong Noh, Sung Cheol Yoon, Cheol Seong Hwang, and Sang Il Seok, “Efficient CH3NH3PbI3 Perovskite Solar Cells Employing Nanostructured p-Type NiO Electrode Formed by a Pulsed Laser Deposition”, Advanced Materials, 27, 4013-4019 17. Wei Chen, Yongzhen Wu, Jian Liu, Chuanjiang Qin, Xudong Yang, Ashraful Islam, Yi-Bing Chengbc and Liyuan Han, “Hybrid interfacial layer leads to solid performance improvement of inverted perovskite solar cells”, Energy & Environmental Science, 8, 629-640 18. Henry J. Snaith, Antonio Abate, James M. Ball, Giles E. Eperon, Tomas Leijtens, Nakita K. Noel, Samuel D. Stranks, Jacob Tse-Wei Wang, Konrad Wojciechowski, and Wei Zhang, “Anomalous Hysteresis in Perovskite Solar Cells”, The Journal of Physical Chemistry Letters, 5, 1511-1515 19. Yuchuan Shao, Zhengguo Xiao, Cheng Bi, Yongbo Yuan & Jinsong Huang, “Origin and elimination of photocurrent hysteresis by fullerene passivation in CH3NH3PbI3 planar heterojunction solar cells”, Nature Communications, DOI: 10.1038/ncomms6784 20. W. Tress, N. Marinova, T. Moehl, S. M. Zakeeruddin, Mohammad Khaja Nazeeruddin, and M. Gr¨atzel, “Understanding the rate-dependent J–V hysteresis slow time component, and aging in CH3NH3PbI3 perovskite solar cells: the role of a compensated electric field”, Energy & Environmental Science, 8, 995-1004 21. Jarvist M. Frost, Keith T. Butler, and Aron Walsh, “Molecular ferroelectric contributions to anomalous hysteresis in hybrid perovskite solar cells”, APL Materials, 2, 081506 22. Jon M. Azpiroz,ab Edoardo Mosconi,a Juan Bisquertcd and Filippo De Angelis, “Defect migration in methylammonium lead iodide and its role in perovskite solar cell operation”, Energy & Environmental Science, 8, 2118-2127 23. Jarvist M. Frost, Keith T. Butler, Federico Brivio, Christopher H. Hendon, Mark van Schilfgaarde, and Aron Walsh, “Atomistic Origins of High-Performance in Hybrid Halide Perovskite Solar Cells”, Nano Letters, 14, 2584-2590 24. Xu Dong, Xiang Fang, Minghang Lv, Bencai Lin, Shuai Zhang, Jianning Ding and Ningyi Yuan, “Improvement of the humidity stability of organic–inorganic perovskite solar cells using ultrathin Al2O3 layers prepared by atomic layer deposition”, Journal of Materials Chemistry A, 3, 5360-5367 25. Jingbi You, Ziruo Hong, Yang (Michael) Yang, Qi Chen, Min Cai, Tze-Bin Song, Chun-Chao Chen, Shirong Lu, Yongsheng Liu, Huanping Zhou, and Yang Yang, “Low-Temperature Solution-Processed Perovskite Solar Cells with High Efficiency and Flexibility”, ACS Nano, 8, 1674-1680 26. Bert Conings, Jeroen Drijkoningen, Nicolas Gauquelin, Aslihan Babayigit, Jan D’Haen, Lien D’Olieslaeger, Anitha Ethirajan, Jo Verbeeck, Jean Manca, Edoardo Mosconi, Filippo De Angelis, and Hans-Gerd Boyen, “Intrinsic Thermal Instability of Methylammonium Lead Trihalide Perovskite”, Advanced Energy Materials, DOI: 10.1002/aenm.201500477 27. Yu Han, Steffen Meyer, Yasmina Dkhissi, Karl Weber, Jennifer M. Pringle, Udo Bach, Leone Spiccia and Yi-Bing Cheng, “Degradation observations of encapsulated planar CH3NH3PbI3 perovskite solar cells at high temperatures and humidity”, Journal of Materials Chemistry A, 3, 8139-8147 Ch2 1. X. Yu, T. J. Marks and A. Facchetti, Nat. Mater., 2016, 15, 383‐396 2. M. T. Greiner, M. G. Helander, W.-M. Tang, Z.–B. Wang, J. Qiu and Z.-H. Lu, Nat. Mater., 2012, 11, 76‐81 3. J. Meyer, S. Hamwi, M. Kröger, W. Kowalsky, T. Riedl and A. Kahn, Adv. Mater., 2012, 24, 5408‐5427 4. M.-G. Kim, M. G. Kanatzidis, A. Facchetti and T. J. Marks, Nat. Mater., 2011, 10, 382‐388 5. J. Liu, D. B. Buchholz, J. W. Hennek, R. P. H. Cheng, A. Facchetti and T. J. Marks, J. Am. Chem. Soc., 2010, 132, 11934‐11942 6. S. Ju, A. Facchetti, Y. Xuan, J. Liu, F. Ishikawa, P. Ye, C. Zhou, T. J. Marks and D. B. Janes, Nat. Nanotechnol., 2007, 2, 378‐384 7. W. Chen, Y. Wu, Y. Yue, J. Liu, W. Zhang, X. Yang, H. Chen, E. Bi, I. Ashraful, M. Grätzel and L. Han, Science, 2015, 350, 944‐948 8. S. R. Hammond, J. Meyer, N. E. Widjonarko, P. F. Ndione, A. K. Sigdel, A. Garcia, A. Miedaner, M. T. Lloyd, A. Kahn, D.S. Ginley, J. J. Berry and D. C. Olson, J. Mater. Chem., 2012, 22, 3249 9. P. F. Ndione, A. Garcia, N. E. Widjonarko, A. K. Sigdel, K. X. Steirer, D. C. Olson, P. A. Parilla, D. S. Ginley, N. R. Armstong, R. E. Richards, E. L. Ratcliff and J. J. Berry, Adv. Energy Mater., 2013, 3, 524‐531 10. J. You, L. Meng, T.-B. Song, T.-F. Guo, Y. Yang, W.-H. Chang, Z. Hong, H. Chen, H. Zhou, Q. Chen, Y. Liu, N. D. Marco and Y. Yang, Nat. Nanotechnol., 2016, 11, 75‐81 11. Z. Liang, Q. Zhang, L. Jiang and G. Cao, Energy Environ. Sci., 2015, 8, 3442 12. E. H. Anaraki, A. Kermanpur, L. Steier, K. Domanski, T. Matsui, W. Tress, M. Saliba, A. Abate, M. Grätzel, A. Haqfeldt and J.-P. Correa-Baena, Energy Environ. Sci., 2016, 9, 3128 13. J. P. C. Baena, L. Steier, W. Trees, M. Saliba, S. Neutzner, T. Matsui, F. Giordano, T. J. Jacobsson, A. R. S. Kandada, S. M. Zakeeruddin, A. Petrozza, A. Abate, M. K. Nazeeruddin, M. Grätzel and A. Hagfeldt, Energy Environ. Sci., 2015, 8, 2928 14. T. J. Konno and R. Sinclair, Mater. Sci. Eng., 1994, A179/180, 426‐432 15. J. Jang, J. Y. Oh, S. K. Kim, Y. J. Choi, S. Y. Yoon and C. O. Kim, Nature, 1998, 395, 481‐483 16. G. Radnoczi, A. Robertsson, H. T. G. Hentzell, S. F. Gong and M.-A. Hasan, J. Appl. Phys., 1991, 69, 6394‐6399 17. S. Y. Yoon, K. H. Kim, C. O. Kim, J. Y. OH and J. Jang, J. Appl. Phys., 1997, 82, 5865‐5867 18. S. Y. Yoon, S. J. Park, K. H. Kim and J. Jang, Thin Solid Film, 2001, 383, 34‐38 19. Z. M. Wang, J. Y. Wang, L. P. H. Jeurgens and E. J. Mittemeijer, Phys. Rev. B, 2008, 77, 045424 20. W. R. Erwin, H. F. Zarick, E. M. Talbert and R. Bardhan, Energy Environ. Sci., 2016, 9, 1577 21. W. Zhang, M. Saliba, S. D. Stranks, Y. Sun, X. Shi, U. Wiesner and H. J. Snaith, Nano Lett., 2013, 13, 4505‐4510 22. M. Saliba, W. Zhang, V. M. Burlakov, S. D. Stranks, Y. Sun, J. M. Ball, M. B. Johnston, A. Goriely, U. Wiesner and H. J. Snaith, Adv. Funct. Mater., 2015, 25, 5038‐5046 23. M. D. Irwin, D. B. Buchholz, A. W. Hains, R. P. H. Chang and T. J. Marks, Proc. Nat. Acad. Sci., 2008, 105, 2783‐2787 24. K. X. Steirer, J. P. Chesin, N. E. Widjonarko, J. J. Berry, A. Miedaner, D. S. Ginley and D. C. Olson, Org. Electron., 2010, 11, 1414 25. N. E. Widjonarko, E. L. Ratcliff, C. L. Perkins, A. K. Sigdel, A. Zakutayev, P. F. Ndione, D. T. Gillaspie, D. S. Ginley, D. C. Olson and J. J. Berry, Thin Solid Film, 2012, 520, 3813‐3818 26. J. J. Berry, N. E. Widjonarko, B. A. Bailey, A. K. Sigdel, D. S. Ginley and D. C. Olson, IEEE J. Sel. Top. Quantum Electron., 2010, 16, 1649 27. K. X. Steirer, P. F. Ndione, N. E. Widjonarko, M. T. Lloyd, J. Meyer, E. L. Ratcliff, A. Kahn, N. E. Armstrong, C. J. Curtis, D. S. Ginley, J. J. Berry and D. C. Olson, Adv, Energy Mater., 2011, 1, 813‐820 28. M. D. Irwin, J. D. Servaites, D. B. Buchholz, B. J. Leever, J. Liu, J. D. Emery, M. Zhang, J.-H. Song, M. F. Durstock, A. J. Freeman, M. J. Bedzyk, M. C. Hersam, R. P. H. Chang, M. A. Ratner and T. J. Marks, Chem. Mater., 2011, 23, 2218‐2226 29. J.-Y. Jeng, K.-C. Chen, T.-Y. Chiang, P.-Y. Lin, T.-D. Tsai, Y.-C Chang, T.-F. Guo, P. Chen, T.-C. Wen and Y.-J. Hsu, Adv. Mater., 2014, 26, 4107‐4113 30. K. X. Steirer, R. E. Richards, A. K. Sigdel, A. Garcia, P. F. Ndione, S. Hammond, D. Baker, E. L. Ratcliff, C. Curtis, T. Furtak, D. S. Ginley, D. C. Olson, N. R. Armstrong and J. J. Berry, J. Mater. Chem. A, 2015, 3, 10949 31. Y. Shao, Z. Xiao, C. Bi, Y. Yuan and J. Huang, Nat. Commun., 2014, 5, 5784 32. W. Zhou, J. Zhen, Q. Liu, Z. Fang, D. Li, P. Zhou, T. Chen and S. Yang, J. Mater. Chem. A, 2017, 5, 1724 33. C. Yang, Y. Hirose, S. Nakao, N. L. H. Hoang and T. Hasegawa, Appl. Phys. Lett. , 2012, 101, 052101 34. C. Yang, Y. Hirose, S. Nakao and T. Hasegawa, Thin Solid Film, 2014, 553, 17‐20 35. A. Y. Hwang, S. T. Kim, H. Ji, Y. Shin and J. K. Jeong, Appl. Phys, Lett., 2016, 108, 152111 Ch3 1. Severin N. Habisreutinger, Tomas Leijtens, Giles E. Eperon, Samuel D. Stranks, Robin J. Nicholas, and Henry Snaith, “Carbon Nanotube/Polymer Composites as a Highly Stable Hole Collection Layer in Perovskite Solar Cells”, Nano Letters, 14, 5561-5568 2. Jun Hong Noh, Sang Hyuk Im, Jin Hyuck Heo, Tarak N. Mandal, and Sang Il Seok, “Chemical Management for Colorful, Efficient, and Stable Inorganic−Organic Hybrid Nanostructured Solar Cells”, Nano Letters, 13, 1764-1769 3. Bert Conings, Jeroen Drijkoningen, Nicolas Gauquelin, Aslihan Babayigit, Jan D’Haen, Lien D’Olieslaeger, Anitha Ethirajan, Jo Verbeeck, Jean Manca, Edoardo Mosconi, Filippo De Angelis, and Hans-Gerd Boyen, “Intrinsic Thermal Instability of Methylammonium Lead Trihalide Perovskite”, Advanced Energy Materials, 5, 1500477 4. Kevin A. Bush, Colin D. Bailie, Ye Chen, Andrea R. Bowring, Wei Wang, Wen Ma, Tomas Leijtens, Farhad Moghadam, and Michael D. McGehee, “Thermal and Environmental Stability of Semi-Transparent Perovskite Solar Cells for Tandems Enabled by a Solution-Processed Nanoparticle Buffer Layer and Sputtered ITO Electrode”, Advanced Materials, 28, 3937-3943 5. K.O. Brinkmann, J. Zhao, N. Pourdavoud, T. Becker, T. Hu, S. Olthof, K. Meerholz, L. Hoffmann, T. Gahlmann, R. Heiderhoff, M.F. Oszajca, N.A. Luechinger, D. Rogalla, Y. Chen, B. Cheng & T. Riedl, “Suppressed decomposition of organometal halide perovskites by impermeable electron-extraction layers in inverted solar cells”, Nature Communications, DOI: 10.1038/ncomms13938 6. Chih-Yu Chang, Kuan-Ting Lee, Wen-Kuan Huang, Hao-Yi Siao, and Yu-Chia Chang, “High-Performance, Air-Stable, Low-Temperature Processed Semitransparent Perovskite Solar Cells Enabled by Atomic Layer Deposition”, Chemistry of Materials, 27, 5122-5130 7. Malgorzata Kot, Chittaranjan Das, Zhiping Wang, Karsten Henkel, Zied Rouissi, Konrad Wojciechowski, Henry J. Snaith, and Dieter Schmeisser, “Room-Temperature Atomic Layer Deposition of Al2O3: Impact on Efficiency, Stability and Surface Properties in Perovskite Solar Cells”, ChemSusChem, 9, 3401-3406 8. Xu Dong, Xiang Fang, Minghang Lv, Bencai Lin, Shuai Zhang, Jianning Ding and Ningyi Yuan, “Improvement of the humidity stability of organic–inorganic perovskite solar cells using ultrathin Al2O3 layers prepared by atomic layer deposition”, Journal of Materials Chemistry A, 3, 5360-5367 9. Achilleas Savva, Ignasi Burgués-Ceballos, and Stelios A. Choulis, “Improved Performance and Reliability of p-i-n Perovskite Solar Cells via Doped Metal Oxides”, Advanced Energy Materials, 6, 1600285 10. Yu-Hsien Chiang, Ching-Kuei Shih, Ang-Syuan Sie, Ming-Hsien Li, Chieh-Chung Peng, Po-Shen Shen, Yu-Po Wang, Tzung-Fang Guo, and Peter Chen, “Highly stable perovskite solar cells with all-inorganic selective contacts from microwave- synthesized oxide nanoparticles”, Journal of Materials Chemistry A, 5, 25485-25493 11. Jinli Yang, Braden D. Siempelkamp, Edoardo Mosconi, Filippo De Angelis, and Timothy L. Kelly, “Origin of the Thermal Instability in CH3NH3PbI3 Thin Films Deposited on ZnO”, Chemistry of Materials, 27, 4229-4236 12. Dianyi Liu, Jinli Yang, and Timothy L. Kelly, “Compact Layer Free Perovskite Solar Cells with 13.5% Efficiency”, Journal of The American Chemical Society, 136, 17116-17122 13. Yuanhang Cheng, Qing-Dan Yang, Jingyang Xiao, Qifan Xue, Ho-Wa Li, Zhiqiang Guan, Hin-Lap Yip, and Sai-Wing Tsang, “Decomposition of Organometal Halide Perovskite Films on Zinc Oxide Nanoparticles”, ACS Applied Materials & Interfaces, 7, 19986-19993 14. Elham Halvani Anaraki, Ahmad Kermanpur, Ludmilla Steier, Konrad Domanski, Taisuke Matsui, Wolfgang Tress, Michael Saliba, Antonio Abate, Michael Grätzel, Anders Hagfeldt and Juan-Pablo Correa-Baena, “Highly efficient and stable planar perovskite solar cells by solution-processed tin oxide”, Energy & Environmental Science, 9, 3128-3134 15. Weijun Ke, Guojia Fang, Qin Liu, Liangbin Xiong, Pingli Qin, Hong Tao, Jing Wang, Hongwei Lei, Borui Li, Jiawei Wan, Guang Yang, and Yanfa Yan, “Low-Temperature Solution-Processed Tin Oxide as an Alternative Electron Transporting Layer for Efficient Perovskite Solar Cells”, Journal of The American Chemical Society, 137, 6730-6733 | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/70117 | - |
dc.description.abstract | 隨著科技進步以及人類對全球各區域開發程度的提升,日益高漲的能源需求促使科學家不斷找尋可永續利用並且潔淨安全的能量來源。其中,可望在未來成為便宜電力來源之高效率鈣鈦礦太陽能電池無疑是近期學術研究的重點項目。在本研究中,我們發現利用黃金奈米顆粒來觸發金屬誘發結晶機制,可使鈣鈦礦太陽能電池中利用溶膠-凝膠法製造的氧化鎳電洞傳輸層與氧化鈦電子傳輸層之最佳製程溫度分別被降低至180 ˚C與280 ˚C。由元素縱深與熱重/示差掃描熱分析,我們確認了發生於溶膠-凝膠法製程中的金屬誘發結晶機制,其中金屬不僅可降低氧化物結晶溫度,更可催化溶膠-凝膠法中前驅物之有機官能基脫去反應,使我們得以在低製程溫度下得到高純度與高結晶的氧化物薄膜。
本研究也驗證了以水熱法合成之氧化錫奈米顆粒,可用於製造高效率鈣鈦礦太陽能電池中之電子傳輸層。在以銻與釩作為氧化錫混摻元素的測試結果中發現,以5 %釩混摻之氧化錫奈米顆粒所製備的電子傳輸層可提供最佳元件表現。此外,過去利用水熱法合成之金屬氧化物奈米顆粒分散液中,大多是以極性醇類溶劑當作分散媒介,此極性溶劑若直接與鈣鈦礦層接觸會破壞其晶體結構,進而限制了奈米顆粒溶液在鈣鈦礦太陽能電池中的使用自由度。本研究提出了一個多步驟水熱法,並在最後一步驟中利用低極性之丁醇取代過去文獻中常用的乙醇或異丙醇,成功合成出可直接使用於鈣鈦礦層上的氧化錫奈米顆粒溶液。利用此氧化錫奈米顆粒分散液,搭配氧化鎳作為電洞傳輸層材料,本研究成功驗證了全以金屬氧化物作為載子傳輸層材料的鈣鈦礦太陽能電池具有良好的熱穩定性。 | zh_TW |
dc.description.abstract | The rapidly grown demand on energy supply, driven by the advancing technology and increasing degree of industrialization, has encouraged researchers to search for a sustainable and clean energy source. Perovskite solar cell, among all the highly efficient solar cell technologies, holds particular promise due to its compatibility with the low-cost, solution-based fabrication procedures. In this study, we found that the optimal sintering temperatures of sol-gel TiO2 and NiO film, functioning as electron- and hole-transporting layer in the perovskite solar cell, could be decreased to 280 ˚C and 180 ˚C, respectively, via metal-induced-crystallization (MIC) triggered by Au nanoparticle. We verified the MIC mechanism through element depth profile and simultaneous thermogravimetric (TGA) /differential scanning calorimeter (DSC) analysis. During the MIC process, the metal not only decreases the crystallization temperature, but also promotes the organic ligand removal and condensation reaction of the sol-gel precursor, enabling the fabrication of highly pure and crystallized metal oxide film via low-temperature process.
We also demonstrated that efficient electron-transporting layers could be deposited by spin-coating hydrothermal synthesized SnOx nanoparticle suspensions without any sintering treatment. After testing SnOx nanoparticle with a series doping concentrations of vanadium (V) and antimony (Sb), we found that the optimal device performance was achieved when utilizing 5 % V-doped SnOx nanoparticle. More importantly, we developed a multistep hydrothermal synthesis procedure in which nonpolar 1-butanol was used to suspend the SnOx nanoparticle, greatly enhancing the compatibility of nanoparticle suspension with the perovskite layer. By utilizing MIC and multistep hydrothermal synthesis procedure, we demonstrated highly efficient perovskite solar cell with all-metal-oxide carrier-transporting layer with excellent thermal stability. | en |
dc.description.provenance | Made available in DSpace on 2021-06-17T03:44:25Z (GMT). No. of bitstreams: 1 ntu-107-F98527017-1.pdf: 5209950 bytes, checksum: 53f366d681c4ac9facba30a96ef86e38 (MD5) Previous issue date: 2018 | en |
dc.description.tableofcontents | 摘要 I
ABSTRACT II CONTENTS IV LIST OF FIGURES VI LIST OF TABLES X Chapter 1 Introduction 1 1.1 Motivation 1 1.2 Overview of Perovskite Solar Cells 3 1.3 Carrier-Transporting Layers (CTLs) of Perovskite Solar Cells 5 1.3.1 Electron-Transporting Layer (ETL) 5 1.3.2 Hole-Transporting Layer (HTL) 6 1.3.3 CTL Deposition Methods 8 1.4 Hysteresis of Perovskite Solar Cells 10 1.5 Stability of Perovskite Solar Cells 13 1.5.1 Humidity Stability 13 1.5.2 Thermal Stability 14 1.6 Objective Statement 15 1.7 Dissertation Organization 17 Reference 18 Chapter 2 Catalytic Metal-Induced-Crystallization of Sol-Gel Metal Oxides and Its Application in Perovskite Solar Cells 24 2.1 Research Background 24 2.2 Experimental 26 2.3 Result and Discussion 30 2.3.1 Catalytic Metal-Induced-Crystallization of Sol-Gel NixO 30 2.3.2 Catalytic Metal-Induced-Crystallization of Sol-Gel TiOx 41 2.3.3 Mechanism of Catalytic Metal-Induced-Crystallization 45 2.4 Summary 50 Reference 51 Chapter 3 Hydrothermal Synthesis of SnOx Nanoparticle and Its Application in Perovskite Solar Cells 55 3.1 Research Background 55 3.2 Experimental 57 3.3 Results and Discussion 59 3.3.1 SnOx nanoparticle ETL 59 3.3.2 Sb-doped SnOx nanoparticle ETL 65 3.3.3 V-doped SnOx nanoparticle ETL 69 3.3.4 Multistep synthesized SnOx nanoparticle 73 3.4 Summary 80 Reference 81 Chapter 4 Conclusions 84 | |
dc.language.iso | en | |
dc.title | 金屬氧化物於高效率、無電流電壓遲滯且具大氣穩定性之鈣鈦礦太陽能電池中之應用 | zh_TW |
dc.title | Application of Metal Oxides in Highly Efficient, Hysteresis-Free, and Air-Stable Perovskite Solar Cells | en |
dc.type | Thesis | |
dc.date.schoolyear | 106-1 | |
dc.description.degree | 博士 | |
dc.contributor.oralexamcommittee | 林唯芳,郭宗枋,薛景中,陳昭宇 | |
dc.subject.keyword | 金屬誘發結晶,鈣鈦礦太陽能電池,電子/電洞傳輸層,水熱法, | zh_TW |
dc.subject.keyword | metal-induced-crystallization,perovskite solar cells,electron-/ hole-transporting layer,hydrothermal synthesis, | en |
dc.relation.page | 85 | |
dc.identifier.doi | 10.6342/NTU201800233 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2018-02-02 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 材料科學與工程學研究所 | zh_TW |
顯示於系所單位: | 材料科學與工程學系 |
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ntu-107-1.pdf 目前未授權公開取用 | 5.09 MB | Adobe PDF |
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