Please use this identifier to cite or link to this item:
http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/67907| Title: | 以胍鹽為基礎之分子開關的合成研究 Study toward a Guanidinium Ion-Based Molecular Switch |
| Authors: | Yu-Hsuan Chang 張羽萱 |
| Advisor: | 邱勝賢(Sheng-Hsien Chiu) |
| Keyword: | 分子開關, Molecular Switch, |
| Publication Year : | 2017 |
| Degree: | 碩士 |
| Abstract: | 我們設計了一同時具有胍鹽與二乙二醇兩種辨識中心的車輪烷分子，期望藉由加入或移除適當金屬離子(或陰離子)來控制大環分子與胍鹽辨識中心之間的鍵結強度，進而使大環受控制而產生遷移。 We have designed a [2]rotaxane which incorporates a dumbbell-shaped component containing both guanidinium and diethylene glycol recognition sites for its macrocyclic component. We expect that the translational isomerization of the macrocyclic component between the two stations can be controlled through the addition or removal of suitable ions. |
| URI: | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/67907 |
| DOI: | 10.6342/NTU201701765 |
| Fulltext Rights: | 有償授權 |
| Appears in Collections: | 化學系 |
Files in This Item:
| File | Size | Format | |
|---|---|---|---|
| ntu-106-1.pdf Restricted Access | 4.09 MB | Adobe PDF |
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