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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 黃慶怡 | |
| dc.contributor.author | Chih-Yuan Chang | en |
| dc.contributor.author | 張智遠 | zh_TW |
| dc.date.accessioned | 2021-06-16T16:35:26Z | - |
| dc.date.available | 2013-11-22 | |
| dc.date.copyright | 2012-11-22 | |
| dc.date.issued | 2012 | |
| dc.date.submitted | 2012-11-02 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/63333 | - |
| dc.description.abstract | 在眾多微胞當中，特別是奈米結構的囊泡，它可提供極大的潛力在藥物釋放。當微胞中能產生更多分層，而形成多間格微胞，他們能帶來更多元化更進一步的應用。在本論文中，我們利用自洽平均場理論在三維實空間中，探討雙親性ABCA線性四塊狀共聚合物於稀薄溶液中囊泡的形成。在添加對A有選擇性的溶劑，也就是喜歡A討厭B與C，當共聚物處在稀薄溶液的情況之下，我們發現了豐富多樣的多間隔微胞型態。首先，我們從B和C為中性溶劑且較不討厭溶劑情況下的探討微胞型態，接著在一樣是中性但較討厭溶劑情況下，觀察到可以產生更多的微胞型態，並且我們藉由改變作用力參數χAB=χAC、χBC，得到了BC相混囊泡、BC相混柱狀、BC相混球狀、BC相混環狀、BC分層囊泡、BC分層環狀、BC分層柱狀、BC分層橢圓狀、BC分層球狀等微胞型態。進一步的我們發現BC分層囊泡在其他參數χCS、χAS改變下，可以觀察到同心圓分層囊泡、BC分層橢圓狀等微胞型態。 | zh_TW |
| dc.description.abstract | In recent years, vesicles have attracted wide attention due to their potential applications in drug delivery. We used self-consistent field theory to investigate the formation of vesicles of ABCA linear tetrablock copolymer when a selective solvent is added, which is selective for A-blocks. Most interestingly, we find the various multicompartment micellar morphologies, such as multiple BC-mixed vesicles, BC-mixed cylinder-like micelles, BC-mixed spherical micelles, BC-mixed ring micelles,segmented vesicles, segmented ring micelles, segmented worm-like micelles, segmented disk stacked ellipsoidal micelles, segmented rod-like micelles, segmented spherical micelles,concentric layered vesicles. These multicompartment micelles are strongly affected by varying the interaction between blocks and blocks,and hydrophobicity of the blocks. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-16T16:35:26Z (GMT). No. of bitstreams: 1 ntu-101-R98549032-1.pdf: 1477244 bytes, checksum: 5b1274f797c5686f0f3b7ee8ff9e75bd (MD5) Previous issue date: 2012 | en |
| dc.description.tableofcontents | 摘要.................................................................I
Abstract..............................................................II 目 錄...............................................................III 圖目錄..............................................................IV 一、簡介.............................................................1 二、自洽平均場理論模擬方法...........................................8 2.1 ABCA線性四塊狀共聚物在溶液中的自洽平均場理論..................8 2.2在實空間下以準譜方法解鏈段擴散方程式...........................10 三、結果與討論......................................................15 3.1探討B和C對溶劑的作用力相同(χBS=χCS=1.1)情況下的微胞型態........15 3.2探討B和C對溶劑的作用力相同(χBS=χCS=1.3)情況下的微胞型態........16 3.3探討B、C甜甜圈堆疊分層囊泡(χBC=1.0)在其他參數變化下的微胞型態衍 變..............................................................18 四、結論............................................................30 五、參考文獻........................................................31 | |
| dc.language.iso | zh-TW | |
| dc.subject | 分層囊泡 | zh_TW |
| dc.subject | 共聚合物 | zh_TW |
| dc.subject | 自恰平均場 | zh_TW |
| dc.subject | copolymer | en |
| dc.subject | SCMF | en |
| dc.subject | segmented vesicle | en |
| dc.title | 運用自洽平均場理論模擬ABCA線性四塊狀共聚合物在稀薄溶液中的囊泡形成 | zh_TW |
| dc.title | The Formation of Vesicles of ABCA Linear Tetrablock Copolymers in the Dilute Solution by Self-Consistent Mean-Field Theory | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 101-1 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 童世煌,劉定宇 | |
| dc.subject.keyword | 共聚合物,自恰平均場,分層囊泡, | zh_TW |
| dc.subject.keyword | copolymer,SCMF,segmented vesicle, | en |
| dc.relation.page | 33 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2012-11-02 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 高分子科學與工程學研究所 | zh_TW |
| 顯示於系所單位： | 高分子科學與工程學研究所 | |
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