Please use this identifier to cite or link to this item:
http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/45976| Title: | 二茂鐵為核心之噻吩衍生物合成及在有機染料上之應用 Synthesis of Ferrocene-based Thiophene compounds and their application on Organic Dye |
| Authors: | Hsien-Ju Tzou 鄒賢儒 |
| Advisor: | 梁文傑(Man-kit Leung) |
| Keyword: | 二茂鐵,有機染料,染料敏化太陽能電池, ferrocene,thiophene,organic dye,DSSC, |
| Publication Year : | 2010 |
| Degree: | 碩士 |
| Abstract: | 本論文工作主要探討以雙鍵及噻吩為分子內之架橋，二茂鐵與cyanoacrylic acid分別為推電子基與拉電子基的有機染料合成。透過核磁共振光譜儀 (NMR) 以及質譜儀鑑定化合物之結構；紫外光光譜儀鑑定化合物之吸收；配合由循環電位儀計算得知化合物之 HOMO 及 LUMO 能階；並將染料製作成染料敏化太陽能電池
(dye - sensitized solar cells，DSSCs) 元件探討其光電轉換效率。 Novel organic dyes consist of ferrocene as donor, thiophene as linker, and cyanoacrylic acid as acceptor have been synthesized. These compounds are characterized by 1H NMR, 13C NMR, mass spectrometry, UV-Vis spectrometer, and cyclic voltametry in the estimation of HOMO and LUMO energy levels. DSSCs device tests have been made in order to understand whether the charge transfer properties of these compounds are appropriate as the role of sensitizers for DSSCs. |
| URI: | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/45976 |
| Fulltext Rights: | 有償授權 |
| Appears in Collections: | 高分子科學與工程學研究所 |
Files in This Item:
| File | Size | Format | |
|---|---|---|---|
| ntu-99-1.pdf Restricted Access | 5.43 MB | Adobe PDF |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.