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http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/43024Full metadata record
| ???org.dspace.app.webui.jsptag.ItemTag.dcfield??? | Value | Language |
|---|---|---|
| dc.contributor.advisor | 易富國 | |
| dc.contributor.author | Chih-Yung Chan | en |
| dc.contributor.author | 詹志勇 | zh_TW |
| dc.date.accessioned | 2021-06-15T01:33:19Z | - |
| dc.date.available | 2009-07-27 | |
| dc.date.copyright | 2009-07-27 | |
| dc.date.issued | 2009 | |
| dc.date.submitted | 2009-07-19 | |
| dc.identifier.citation | 1. Chiang, C.K., et al., Electrical Conductivity in Doped Polyacetylene. Physical Review Letters, 1977. 39(17): p. 1098-1101
2. U. Salzner, J.B.L., P.G. Pickup, P.A. Poririer, Synth. Met., 1998. 96: p. 177. 3. Burroughes, J.H., D.D.C. Bradley, and A.R. Brown, etal. Light emitting diodes based on conjugated polymers [J]. Nature, 1990. 347: p. 539 4. Wen-Hao Chen, Conjugated Polymer-based Solar Cell. CHEMISTRY (The Chinese Chemical Society, Taipei) 2009. Vol. 67, No. 1,62: p. 61-66 5. 施敏，Semiconductor devices Physics and Technology 2nd edition . 86. 6. Pai, D.M., Transient Photoconductivity in Poly (N-vinylcarbazole). The Journal of Chemical Physics, 2003. 52: p. 2285 7. Gill, W.D., Drift mobilities in amorphous charge-transfer complexes of trinitrofluorenone and poly-n-vinylcarbazole. Journal of Applied Physics, 2003. 43: p. 5033. 8. Bassler, Physica Status Solid, 1993. 175(15). 9. Miller, A. and E. Abrahams, Impurity Conduction at Low Concentrations. Physical Review, 1960. 120(3): p. 745-755. 10. Hamaguchi C, Basic Semiconductor Physics. Springer, New Delhi, p. 263, 2001. 11. P. W. M. Blom, M. J. M. de Jong and M. G. van Munster, Phys. Rev. B, 55, R656, 1997. 12. P. W. M. Blom and M. J. M. de Jong, IEEE J. Sel. T op. Quantum Electron, 4, 105, 1998. 13. P. W. M. Blom, M. J. M. de Jong and J. J. M. Vleggar, Appl. Phys. Lett., 68, 3308,1996. 14. Inigo, A.R., , Non-dispersive Hole Transport in a Soluble Poly (p-phenylene vinylene). Advanced Materials, 2001. 13(7): p. 504-508. 15. Ken KASHIMA, Hiroshi SATO, et al. The Japan Society for Analytical Chemistry VOL. 23 , 2007. P1249-1251. 16. G. Juska, M. Viliunas, K. Arlauskas, N. Nekrasas, N. Wyrsch and L. Feitknecht, Journal of Applied Physics, vol. 89, no. 9,2001, pp. 4971-4974. 17. Horowitz G, in Semiconducting Polymers: Chemistry, Physics and Engineering,ed. by Hadziioannou G and van Hutten PF. Wiley-VCH, Weinheim, 2000. 18. 邱雅文，國立中央大學化學所碩士論文，1997。 19. 馬迎煜，國立台灣大學高分子科學與工程學研究所碩士論文，2008。 20. L. Fumagalli, M. Binda,1 D. Natali, M. Sampietro, E. Salmoiraghi, and P. Di Gianvincenzo, JOURNAL OF APPLIED PHYSICS,2008, 104, 084513. 21. Chiatzun Goh, R. Joseph Kline, and Michael D. McGehee . APPLIED PHYSICS LETTERS 2005.86, 122110 . 22. C.-M. Yang et al. / Synthetic Metals 158 ,2008, 25–28. | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/43024 | - |
| dc.description.abstract | 本實驗以氯苯（Chlorobenzene）作為溶劑，將不同分子量的順丁烯亞醯胺共聚高分子衍生物（PT8ML8-F8）溶解，以液滴塗佈（Drop casting）的方式在ITO玻璃上製成薄膜，並使用真空蒸鍍的方式鍍上金電極。我們利用飛行時間法（Time of flight）來測量不同分子量的PT8ML8-F8的電荷載子遷移率（Charge carrier mobility ），並且測量在不同溫度下的電荷載子遷移率。我們在本研究中發現PT8ML8-F8的遷移率（Mobility），並不會因為平均分子量的不同而有明顯的差異。而又因為PT8ML8-F8是由一個Polyfluorene 和Polythiophene及其它原子團所共聚而成共聚高分子（copolymer），我們比較PT8ML8-F8與Polyfluorene 和Polythiophene相接近的P3HT的遷移率，發現遷移率並不會因為共聚的關係有所明顯的變化。 | zh_TW |
| dc.description.abstract | In this study, Chlorobenzene is used for dissolving the copolymers with different molecular weight which are H-PT8ML8-F8 and L-PT8ML8-F8. Film is fabricated on ITO glass by drop casting. Time of fight technique is used to measure the vertical charge carrier mobility at different temperature in this work. Based on the experimental results, the charge carrier mobility of H-PT8ML8-F8 and L-PT8ML8-F8 are almost the same. Because the copolymer PT8ML8-F8 is assembled by polythiophene polyfluorene and the other group, the mobility of PT8ML8-F8 could be compared with polyfluorene and P3HT. The charge carrier mobility of them are very approaching. It is suitable to infer that the copolymerization does not affect the charge mobility. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-15T01:33:19Z (GMT). No. of bitstreams: 1 ntu-98-P95222001-1.pdf: 1642952 bytes, checksum: 80fad20fc93f25b8b9834e11638ebc05 (MD5) Previous issue date: 2009 | en |
| dc.description.tableofcontents | 摘要．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．I
英文摘要 ．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．II 誌謝．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．III 目錄 ．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．IV 圖目錄 ．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．VI 表目錄VIII 第一章 研究背景與動機 1.1 共軛高分子（Conjugated Polymers）．．．．．．．．．．．．．．．． 1 1.1.1 有機發光二極體．．．．．．．．．．．．．．．．．．．．．．．3 1.1.2 共軛高分子太陽能電池．．．．．．．．．．．．．．．．．．． 4 1.2 電荷載子的傳輸行為．．．．．．．．．．．．．．．．．．．．．． 4 1.3 混亂系統模型（Disorder system model）．．．．．．．．．．．．． 6 1.4 研究動機．．．．．．．．．．．．．．．．．．．．．．．．．．． 9 第二章 量測技術及原理 2.1 TrEL量測技術（Transient Electroluminescence, TrEL）．．．．．．10 2.2 空間電荷限制傳輸電流（Space-charge limited currents , SCLC）量測技術．．．．．．．．．．．．．．．．．．．．．．．．．．．．．11 2.3 飛行時間法（Time of flight ，TOF）量測技術．．．．．．．．．．12 2.3.1 穿過時間（Transient time）分析．．．．．．．．．．．．．． 14 2.3.1.1 非色散型穿過時間分析．．．．．．．．．．．．．．．．．． 14 2.3.1.2 色散型穿過時間分析．．．．．．．．．．．．．．．．．．． 15 2.3.2 飛行時間法降低雜訊的方法．．．．．．．．．．．．．．．．． 16 2.4 CELIV (Charge Extraction by Linear Increasing Voltage)量測技術．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．21 2.5 FET（Field effect transistors）量測技術．．．．．．．．．．． 22 第三章 實驗架設 3.1 元件製作．．．．．．．．．．．．．．．．．．．．．．．．．．．23 3.1.1 基體（Substrate）的清潔．．．．．．．．．．．．．．．．．．23 3.1.2 溶液製備．．．．．．．．．．．．．．．．．．．．．．．．． 23 3.1.3 液滴塗佈（Drop cast）與元件製備．．．．．．．．．．．．．．24 3.2 飛行時間法建置．．．．．．．．．．．．．．．．．．．．．．．．25 第四章 實驗結果 4.1 吸收光譜及螢光光譜資料．．．．．．．．．．．．．．．．．．．．27 4.2 飛行時間法資料．．．．．．．．．．．．．．．．．．．．．．．．28 4.3 不同溫度下載子遷移率資料．．．．．．．．．．．．．．．．．．．30 第五章 討論 5.1 研究結果討論．．．．．．．．．．．．．．．．．．．．．．．．．36 5.2 未來展望．．．．．．．．．．．．．．．．．．．．．．．．．．．39 參考資料 ．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．40 | |
| dc.language.iso | zh-TW | |
| dc.subject | 不同鏈長 | zh_TW |
| dc.subject | 液滴塗佈 | zh_TW |
| dc.subject | 垂直載子遷移率 | zh_TW |
| dc.subject | 飛行時間法 | zh_TW |
| dc.subject | 平均分子量 | zh_TW |
| dc.subject | vertical charge carrier mobility | en |
| dc.subject | chain length | en |
| dc.subject | molecular weight | en |
| dc.subject | time of flight | en |
| dc.subject | drop-cast | en |
| dc.title | 利用飛行時間法測量不同鏈長PT8ML8-F8薄膜的電子遷移率 | zh_TW |
| dc.title | Electron Mobility of PT8ML8-F8 (Different Molecular Weight) Film Measured by Time of Flight Experiment | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 97-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 曹培熙,白小明 | |
| dc.subject.keyword | 液滴塗佈,垂直載子遷移率,飛行時間法,平均分子量,不同鏈長, | zh_TW |
| dc.subject.keyword | drop-cast,vertical charge carrier mobility,time of flight,molecular weight,chain length, | en |
| dc.relation.page | 41 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2009-07-20 | |
| dc.contributor.author-college | 理學院 | zh_TW |
| dc.contributor.author-dept | 物理研究所 | zh_TW |
| Appears in Collections: | 物理學系 | |
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| File | Size | Format | |
|---|---|---|---|
| ntu-98-1.pdf Restricted Access | 1.6 MB | Adobe PDF |
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