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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 邱勝賢 | |
| dc.contributor.author | Chun-Ju Chuang | en |
| dc.contributor.author | 莊純如 | zh_TW |
| dc.date.accessioned | 2021-06-14T17:00:21Z | - |
| dc.date.available | 2012-08-05 | |
| dc.date.copyright | 2008-08-05 | |
| dc.date.issued | 2008 | |
| dc.date.submitted | 2008-07-28 | |
| dc.identifier.citation | 1. Jean-Marie Lehn, Science 1993, 260, 1762-1763
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Soc., 2007, 129, 8944–8945. g) Ueng, S.-H.; Hsueh, S.-Y.; Lai, C.-C.; Liu, Y.-H.; Peng, S.-M.; Chiu, S.-H. Chem. Commun. 2008, 817–819. 17. Moonen, N. N. P.; Flood, A. H.; Fernàndez, J. M.; Stoddart, J. F. Top. Curr. Chem. 2005, 262, 99–132. 18. Villiers, A. Compt. Rend. Fr. Acad. Sci. 1891, 435-438 19. Balzani, V.; Credi, A.; Raymo, F. M.; Stoddart, J. F. Angew. Chem. Int. Ed. 2000, 39, 3348–3391. 20. Lin, C.-F.; Liu, Y.-H.; Lai, C.-C.; Peng, S.-M.; Chiu, S.-H. Angew. Chem. Int. Ed. 2006, 45, 3176–3181. 21. Lin, C.-F.; Lai, C.-C.; Liu, Y.-H.; Peng, S.-M.; Chiu, S.-H. Chem. Eur. J. 2007, 13, 4350–4355. 22. a) Iwata, M.; Kuzuhara, H. Bull. Chem. Soc. Jpn. 1982, 55, 2153–2157. b) Iwata, M.; Kuzuhara, H. J. Org. Chem.. 1983, 48, 1282–1286. 23. Crystal data for 5-H2•4PF6: [C118H170O16N4•4CH3CN•2CH3OH][4PF6], Mr = 2708.76, monoclinic, space group p21/c, a = 20.6795(12), b = 21.8470(8), c = 15.2230(7) Å, V = 6745.0(6) Å3, | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/40788 | - |
| dc.description.abstract | 實驗室先前所發展出來的分子籠1為一具備三維內部空腔的分子。有別於傳統”雙穿透”系統的分子肌肉，以分子籠1為基礎的[2]車輪烷分子，可以透過外加試劑和移除試劑，反復控制其啞鈴形組成進行”收縮 (contraction) ”和”舒張(stretch)”的動作。由於此行為亦可類比肌肉分子的運動模式，故可認為是一個「分子肌肉」的新設計。 | zh_TW |
| dc.description.abstract | We demonstrated that a molecular cage-based [2]rotaxane can functions as an artificial molecular muscle through the control of fluoride anions. We are at present investigating the further use of container-like host molecules within molecular machines and other functional molecules. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-14T17:00:21Z (GMT). No. of bitstreams: 1 ntu-97-R95223074-1.pdf: 2603659 bytes, checksum: 4235322ad80809cf1377707f0fe5edf2 (MD5) Previous issue date: 2008 | en |
| dc.description.tableofcontents | 謝誌………………………………………………………………………i
中文摘要………………………………………………………………ii 英文摘要………………………………………………………………iii 目錄……………………………………………………………………iv 圖表………………………………………………………………………v 流程…………………………………………………………………vii 第一章 導論………………………………………………………1 11 前言………………………………………………1 12 簡介內鎖分子…………………………………………2 13 車輪烷分子的合成策略………………………………4 14 分子肌肉……………………………………………7 141 Sauvage”雙穿透”系統的分子肌肉…8 142 Kaneda”雙穿透”系統的分子肌肉…11 143 修飾[3]車輪烷分子在金表面模擬肌肉運動13 15 簡介分子籠 1 ……………………………………15 第二章 研究與討論…………………………………………………18 21 研究動機……………………………………………18 22 分子肌肉的設計及預期功能………………………19 23 [2]車輪烷分子的合成……………………………21 24 以酸/鹼試劑控制分子肌肉…………………………26 25 以陰離子試劑控制分子肌肉………………………27 第三章 結論…………………………………………………………31 第四章 實驗部分……………………………………………………32 第五章 參考文獻……………………………………………………38 第六章 附錄…………………………………………………………41 | |
| dc.language.iso | zh-TW | |
| dc.subject | 分子肌肉 | zh_TW |
| dc.subject | 超分子 | zh_TW |
| dc.subject | molecular muscle | en |
| dc.subject | supramolecular chemistry | en |
| dc.title | 分子肌肉之合成與研究 | zh_TW |
| dc.title | Molecular Muscle Based on a Molecular Cage Incorporated [2]Rotaxane | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 96-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 徐秀福,賴建成 | |
| dc.subject.keyword | 超分子,分子肌肉, | zh_TW |
| dc.subject.keyword | supramolecular chemistry,molecular muscle, | en |
| dc.relation.page | 40 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2008-07-30 | |
| dc.contributor.author-college | 理學院 | zh_TW |
| dc.contributor.author-dept | 化學研究所 | zh_TW |
| 顯示於系所單位： | 化學系 | |
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