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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 劉懷勝 | |
| dc.contributor.author | Yueh-Ting Lai | en |
| dc.contributor.author | 賴岳廷 | zh_TW |
| dc.date.accessioned | 2021-06-07T23:43:08Z | - |
| dc.date.copyright | 2014-07-29 | |
| dc.date.issued | 2014 | |
| dc.date.submitted | 2014-07-21 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/16663 | - |
| dc.description.abstract | NTU-1是從石油汙泥中分離並透過16S rDNA序列鑑定確立其所屬菌屬為Rhodococcus erythropolis。經由培養、烘乾後，可得到NTU-1結塊之粉末，此粉末具有很好的破乳化能力。
本研究比較以柴油培養的NTU-1粉末及以正十六烷培養的NTU-1粉末之破乳化效率。經實驗結果發現，以柴油培養的NTU-1粉末具有生產成本較低、使用量較少以及破乳化能力較佳之優勢。若以柴油培養的NTU-1粉末進行破乳化測試，其最適添加量與Tween-80體積存在著三分之二次方的關係。於O/W/T比例為4/1/0.01，在480分鐘時油相回收百分比可達95%。此外，當乳化液的油/水比(O/W)較大時或連續相黏度較低時，可提升油相回收百分比。細胞表面疏水性是影響破乳化重要的因素。實驗結果顯示，微生物細胞疏水性與油相回收百分比呈現正相關。 綜括上述，以烘乾後的NTU-1粉末處理水包油(O/W)型乳化液具有相當的潛力以及發展性。 | zh_TW |
| dc.description.abstract | NTU-1, a highly efficient demulsifying strain, was isolated from petroleum contaminated soil and identified as Rhodococcus erythropolis by 16S rDNA gene analysis. NTU-1 powder with high demulsifying performance could be obtained by heat-drying after collecting bioflocculi in medium.
This study first evaluated the demulsifying performance of NTU-1 cultured by diesel and n-hexadecane, and found that NTU-1 powder by diesel is a better choice for its lower cost and better performance. At an optimal quantity of dried NTU-1 powder for de-emulsification that was proportional to the volume of Tween-80 to the 2/3 power, a recovery of 95 % oil was achieved in 480 min. This was made possible when the oil/water/Tween80 volume ratio was set at 4/1/0.01. The higher O/W ratio and the lower viscosity both contributed to such a high oil recovery rate. The positive correlation between CSH (MATH) and oil recovery ratio also implies that the diesel grown NTU-1 culture may provide a commercial scale-up method to break oil -in-water emulsion directly at the primary oil recovery site. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-07T23:43:08Z (GMT). No. of bitstreams: 1 ntu-103-R01524011-1.pdf: 243816936 bytes, checksum: 98e368a021686fc30fb35ad67a6d0b87 (MD5) Previous issue date: 2014 | en |
| dc.description.tableofcontents | 摘要 I
Abstract II 目錄 III 圖目錄 VI 表目錄 X 照片目錄 XI 第一章 緒論 1 1.1 前言 1 1.2 研究目的及論文綱要 2 第二章 文獻回顧 3 2.1 油水乳化液 3 2.1.1 乳化液的形成 3 2.1.2 乳化液的穩定性 6 2.1.3 界面活性劑 8 2.1.3.1 化學性界面活性劑 11 2.1.3.2 生物性界面活性劑 15 2.1.3.3 界面活性劑的HLB值 18 2.2 石油乳化液 21 2.2.1 石油簡介及開採方式 21 2.2.2 穩定原油乳化液因素 23 2.2.2.1 瀝青質 23 2.2.2.2 樹脂 24 2.2.2.3 蠟 24 2.2.3 原油乳化液的形成因素及影響 25 2.3 破乳化的方法 28 2.4 微生物處理油水乳化液 33 2.4.1 微生物破乳化法 33 2.4.2 影響微生物破乳化程度的因素 36 2.5 破乳化的過程 39 2.5.1 破乳化機制 39 2.5.2 破乳化數學關係式 42 2.6 實驗菌株Rhodococcus erythropolis之介紹 46 2.6.1 Rhodococcus菌屬簡介 46 2.6.2 微生物降解碳氫化合物之代謝途徑 49 2.6.2.1 柴油之組成 49 2.6.2.2 直鏈烷之氧化機制 50 2.6.2.3 支鏈烷及環烷類之氧化機制 52 2.6.3 Rhodococcus erythropolis之特性及應用 56 2.7 微生物烘乾技術及應用 61 第三章 實驗材料與方法 63 3.1 實驗菌株 63 3.2 培養基的組成與配置 65 3.2.1 液態礦物培養基 65 3.2.2 菌株保存培養基 68 3.2.3 菌株活化培養基 69 3.2.4 計數平板培養基 69 3.3 實驗方法 70 3.3.1 菌株的活化及生長曲線 70 3.3.2 礦物培養基菌液製作 71 3.3.3 以不同碳源培養Rhodococcus erythropolis NTU-1 73 3.3.4 將不同碳源培養的NTU-1結塊進行烘乾 77 3.3.5 利用乾燥後NTU-1粉末進行破乳化實驗 78 3.3.6 利用正己烷移除NTU-1粉末之疏水性物質 80 3.3.7 NTU-1粉末之細胞表面疏水性測定 80 3.4 實驗藥品及儀器 81 3.4.1 實驗藥品 81 3.4.2 實驗儀器 82 第四章 實驗結果與討論 83 4.1 Rhodococcus erythropolis NTU-1以1% (v/v)市售柴油為碳源之細胞生長情形 83 4.2 利用柴油培養NTU-1粉末破乳化及找出最適添加量 93 4.2.1 配置穩定之油/水乳化液 93 4.2.2 NTU-1粉末最適添加量 99 4.2.3 不同油相對於破乳化之影響 106 4.2.4 相同NTU-1粉末添加量對於不同初始煤油體積乳化液破乳化之影響 113 4.2.5 不同O/W/T比例NTU-1粉末最適添加量 118 4.2.6 結果討論 125 4.3 比較不同碳源培養的NTU-1粉末於破乳化之應用 127 4.3.1 不同油相體積乳化液之破乳化 127 4.3.2 不同Tween-80體積乳化液之破乳化 138 4.3.3 不同油/水(O/W)比乳化液之破乳化 156 4.3.4 改變乳化液連續相黏度破乳化 167 4.3.5 結果討論 186 4.4 影響破乳化的因素 188 4.4.1 不同培養方式之NTU-1粉末表面疏水性測定 188 4.4.2 NTU-1粉末表面疏水性對於破乳化的影響 191 4.4.3 NTU-1粉末破乳化機制 204 4.4.4 結果討論 207 第五章 結論 208 參考文獻 212 | |
| dc.language.iso | zh-TW | |
| dc.title | 以柴油培養之Rhodococcus erythropolis NTU-1結塊處理水包油(O/W)型乳化液 | zh_TW |
| dc.title | De-emulsification of oil-in-water emulsion by Rhodococcus erythropolis NTU-1 bioflocculi grown in diesel | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 102-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 許駿發,王孟菊 | |
| dc.subject.keyword | Rhodococcus erythropolis NTU-1,破乳化,油相回收百分比,細胞表面疏水性,水包油(O/W)型乳化液, | zh_TW |
| dc.subject.keyword | Rhodococcus erythropolis NTU-1,de-emulsification,oil recovery,cell surface hydrophobicity,oil-in-water emulsion, | en |
| dc.relation.page | 223 | |
| dc.rights.note | 未授權 | |
| dc.date.accepted | 2014-07-21 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
| 顯示於系所單位： | 化學工程學系 | |
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