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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 吳嘉文 | zh_TW |
| dc.contributor.advisor | Kevin C.-W. Wu | en |
| dc.contributor.author | 蔡捷伃 | zh_TW |
| dc.contributor.author | Chieh-Yu Tsai | en |
| dc.date.accessioned | 2026-01-14T16:08:43Z | - |
| dc.date.available | 2026-01-15 | - |
| dc.date.copyright | 2026-01-14 | - |
| dc.date.issued | 2026 | - |
| dc.date.submitted | 2026-01-07 | - |
| dc.identifier.citation | References
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/101308 | - |
| dc.description.abstract | 為因應大氣中二氧化碳（CO₂）濃度持續上升的環境議題，並解決直接空氣捕捉（DAC）過程中水氣與 CO₂ 間競爭吸附的問題，本研究著重於開發具有良好耐水性、兼具高 CO₂ 滲透率與 CO₂/N₂ 選擇性的混合基質膜（mixed-matrix membranes, MMMs）。首先，透過 Monte Carlo 模擬計算 5,500 種金屬有機框架材料（MOFs）的亨利常數（KH），以篩選出對 CO₂ 與 H₂O 具中等選擇性的候選材料。最終選定 MIL-53、Al-NDC 與 Al-BDC 三種鋁系 MOFs 進行合成與水氣耐受性測試。透過接觸角量測與熱重–質譜分析（TGA-MS）進行評估，結果顯示 Al-BDC 具有最好的疏水性。接續將 Al-BDC 添加至 Pebax® MH 2030 高分子材料中，製備出MOF含量為 5–20 wt% 的混合基質膜。TGA-MS 與氣體滲透實驗結果顯示，隨著 Al-BDC 含量增加，膜中水氣吸附量下降，證實其可有效降低水氣干擾。另外，含有 15 wt% Al-BDC 的膜展現出優異的 CO₂/N₂ 分離性能（PCO₂：351.89 Barrer，αCO₂/N₂：46.10），表現已接近 Robeson 上限，優於多數文獻中已報導的 MOF–Pebax 複合膜。整體而言，該膜兼具良好的抗水性與分離效率，為未來應用於含有水氣環境下的碳捕捉膜材開發，提供了具體且可行的設計依據。 | zh_TW |
| dc.description.abstract | To address the pressing issue of rising atmospheric carbon dioxide (CO₂) levels and to overcome the challenge of competitive water vapor adsorption in direct air capture environments, this work focuses on the development of water-resistant mixed-matrix membranes (MMMs) with high CO₂ permeability and exceptional CO₂/N₂ selectivity. Monte Carlo simulations were used to screen 5,500 MOFs for moderate CO₂/H₂O selectivity, leading to the selection of three aluminum-based MOFs—MIL-53, Al-NDC, and Al-BDC. These MOFs were synthesized and evaluated for water resistance via contact angle measurements and TGA-MS analysis, with Al-BDC exhibiting the highest hydrophobicity. Al-BDC was subsequently incorporated into Pebax® MH 2030 to fabricate MMMs with filler loadings ranging from 5 to 20 wt%. Comprehensive characterization, including TGA-MS and gas permeability testing, confirmed that Al-BDC-based MMMs decrease water uptake with Al-BDC increasing, indicating that the incorporation of Al-BDC can effectively lower the water uptake. Notably, the 15 wt% Al-BDC membrane exhibited excellent CO₂/N₂ separation performance (PCO2 : 351.89 Barrer, αCO2/N2 : 46.10), approaching the Robeson upper bound more closely than most MOF-Pebax-based MMMs reported in the literature, marking a promising breakthrough in overcoming the traditional permeability–selectivity trade-off using a water-resistant membrane. These findings offer valuable insights for designing practical, high-performance membranes for sustainable carbon capture. | en |
| dc.description.provenance | Submitted by admin ntu (admin@lib.ntu.edu.tw) on 2026-01-14T16:08:43Z No. of bitstreams: 0 | en |
| dc.description.provenance | Made available in DSpace on 2026-01-14T16:08:43Z (GMT). No. of bitstreams: 0 | en |
| dc.description.tableofcontents | Table of Contents
誌謝 ii ABSTRACT iii 大綱 iv Table of Contents v List of Figures viii List of Tables xi 1 Introduction 1 1.1 Global carbon dioxide (CO₂) emissions and climate impact 1 1.2 Brief introduction of CO2 capture routes 3 1.2.1 Post-combustion capture 3 1.2.2 Pre-combustion capture 3 1.2.3 Direct air capture 4 1.3 CO2 separation technologies 5 1.3.1 Chemical absorption 5 1.3.2 Physical adsorption 6 1.3.3 Membrane-based separation 7 1.4 Gas separation mechanism 12 1.4.1 Solution-diffusion model 13 2 Literature Review 15 2.1 Polymeric membrane and Robeson Upper Bound 15 2.2 Mixed-matrix membrane 16 2.3 Humidity Interference in Direct Air Capture 21 3 Objective 23 4 Experimental 24 4.1 Chemicals and Materials 24 4.2 Equipment 25 4.3 Synthesis of Metal-Organic Frameworks 26 4.3.1 Synthesis of MIL-53(Al) 26 4.3.2 Synthesis of Al-NDC 26 4.3.3 Synthesis of Al-BDC 27 4.4 Fabrication of membrane 29 4.4.1 Fabrication of Pebax® MH 2030 membrane 29 4.4.2 Fabrication of Mixed-matrix membrane (MMM) 29 4.5 Characterization of MOFs and MMM 31 4.5.1 X-ray Diffractometer (XRD) 31 4.5.2 Field Emission Scanning Electron Microscope (FE-SEM) 31 4.5.3 Energy Dispersive Spectroscopy (EDS) 32 4.5.4 Specific Surface Area and Pore Size Distribution 32 4.5.5 Thermogravimetric Analysis (TGA) 33 4.5.6 Fourier-Transform Infrared Spectroscopy (FTIR) 33 4.5.7 Differential scanning calorimetry (DSC) 33 4.6 Monte Carlo Simulation 34 4.7 Single gas permeability measurement 35 4.7.1 Introduction of gas permeation system 35 4.7.2 Single gas and mixed gas permeability measurement 36 5 Results and Discussion 39 5.1 Screening for the MOFs candidates of the MMMs 39 5.2 Characterizations of the as-synthesized MOFs 40 5.2.1 MIL-53 40 5.2.2 Al-NDC 43 5.2.3 Al-BDC 46 5.3 Characterizations of the MMMs 49 5.3.1 MMM-MIL-53 49 5.3.2 MMM-Al-NDC 51 5.3.3 MMM-Al-BDC 53 5.4 Hydrophobicity and water content of the as-synthesized MOFs 55 5.4.1 Analytical Techniques for Water Resistance Assessment 55 5.4.2 The results of the Water Resistant test 56 5.5 Characterization of MMM with varying MOF loadings 58 5.5.1 NDC content of MMM-Al-NDC 58 5.5.2 BDC content of MMM-Al-BDC 61 5.6 Hydrophobicity test of the as-synthesized MMMs 64 5.7 Gas permeability performance of MMMs 67 6 Conclusions 75 7 Future work 76 References 77 | - |
| dc.language.iso | en | - |
| dc.subject | 直接空氣捕獲 | - |
| dc.subject | 混合基質膜 | - |
| dc.subject | 金屬有機骨架材料 | - |
| dc.subject | 二氧化碳/氮氣分離 | - |
| dc.subject | 耐水性 | - |
| dc.subject | Direct Air Capture | - |
| dc.subject | DAC | - |
| dc.subject | Mixed-Matrix Membrane | - |
| dc.subject | MMM | - |
| dc.subject | Metal-Organic Framework | - |
| dc.subject | MOF | - |
| dc.subject | CO₂/N₂ Separation | - |
| dc.subject | Water resistance | - |
| dc.title | 應用具耐水性金屬有機骨架（MOFs）之混合基質膜於二氧化碳選擇性分離之研究與開發 | zh_TW |
| dc.title | Development of Mixed-Matrix Membranes with Water-Resistant Metal-Organic Frameworks (MOFs) for Selective CO2 Separation | en |
| dc.type | Thesis | - |
| dc.date.schoolyear | 114-1 | - |
| dc.description.degree | 碩士 | - |
| dc.contributor.oralexamcommittee | 康敦彥;林立強;葉禮賢;湯偉鉦 | zh_TW |
| dc.contributor.oralexamcommittee | Dun-Yen Kang;Li-Chiang Lin;Li-Hsien Yeh;Wei-Cheng Tang | en |
| dc.subject.keyword | 直接空氣捕獲,混合基質膜金屬有機骨架材料二氧化碳/氮氣分離耐水性 | zh_TW |
| dc.subject.keyword | Direct Air Capture,DACMixed-Matrix MembraneMMMMetal-Organic FrameworkMOFCO₂/N₂ SeparationWater resistance | en |
| dc.relation.page | 83 | - |
| dc.identifier.doi | 10.6342/NTU202600019 | - |
| dc.rights.note | 未授權 | - |
| dc.date.accepted | 2026-01-08 | - |
| dc.contributor.author-college | 工學院 | - |
| dc.contributor.author-dept | 化學工程學系 | - |
| dc.date.embargo-lift | N/A | - |
| 顯示於系所單位： | 化學工程學系 | |
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