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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 王建隆 | zh_TW |
| dc.contributor.advisor | Chien-Lung Wang | en |
| dc.contributor.author | 王永睿 | zh_TW |
| dc.contributor.author | Yong-Rui Wang | en |
| dc.date.accessioned | 2025-11-26T16:07:16Z | - |
| dc.date.available | 2025-11-27 | - |
| dc.date.copyright | 2025-11-26 | - |
| dc.date.issued | 2025 | - |
| dc.date.submitted | 2025-11-10 | - |
| dc.identifier.citation | 1. Nelson, D. L.; Lehninger, A. L.; Cox, M. M. Lehninger principles of biochemistry; Macmillan, 2008.
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/100925 | - |
| dc.description.abstract | 在超分子化學中，有序軟物質具更高的結構複雜度時可賦予其新興之功能。為了構築具備結構複雜性與功能性的 Frank–Kasper（FK）相，本研究導入類似脂筏（lipid raft）概念的異質性，將剛性芳香族樹枝狀分子（Ar2）與柔性脂肪族樹枝狀分子（D2）進行摻合。此策略可保持 FK σ 相晶格之長程週期性，並同時產生具表面凹陷結構的膠束。這些凹陷區域猶如酵素的活性口袋，能容納客體分子並促進其進行光二聚化反應。結構分析證實，該設計能提升階層性架構的複雜度，並展現可調控的催化表現。此研究提供一項多功能策略，用以設計兼具分子辨識、超分子精準組裝與催化功能的 FK 相有序材料。 | zh_TW |
| dc.description.abstract | In supramolecular chemistry, higher structural complexity enables emergent functions in ordered soft matter. To construct structurally complex and functional Frank–Kasper (FK) phases, lipid raft–inspired heterogeneity is introduced by blending rigid aromatic dendrons (Ar2) with flexible aliphatic dendrons (D2). This approach creates micelles with surface concavities while preserving long-range periodicity of the FK σ lattice. The concave domains serve as enzyme-like pockets that accommodate guest molecules and facilitate photo-dimerization reactions. Structural analyses confirm that these features enhance complexity in hierarchical architecture and enable tunable catalytic performance. This work presents a versatile strategy for designing FK phases that integrate molecular recognition, supramolecular precision, and catalytic function within an ordered framework. | en |
| dc.description.provenance | Submitted by admin ntu (admin@lib.ntu.edu.tw) on 2025-11-26T16:07:16Z No. of bitstreams: 0 | en |
| dc.description.provenance | Made available in DSpace on 2025-11-26T16:07:16Z (GMT). No. of bitstreams: 0 | en |
| dc.description.tableofcontents | 口試委員會審定書 i
誌謝 ii 摘要 v Abstract vi 目次 vii 圖次 x 式圖次 xvi 表次 xvii 第一章 緒論 1 1.1 超分子化學 1 1.2 複雜度 2 1.3 建構組元 2 1.4 生物體中的球狀相 4 1.5 Frank-Kasper相 6 1.6 對稱破壞 6 1.7 摻合 13 第二章 研究動機 15 第三章 實驗結果與討論 17 3.1 分子合成 17 3.1.1 雙親性脂肪族楔型分子 17 3.1.2 芳香族楔型分子 18 3.2 分子化學結構鑑定 18 3.2.1 脂肪族楔型分子 18 3.2.2 芳香族楔型分子 21 3.3 建構組元之特性 23 3.3.1 建構組元之熱穩定性分析 23 3.3.2 建構組元之結構分析 25 3.4 液態混合樣品 26 3.4.1 液態混合樣品之製備 26 3.4.2 液態混合樣品之特性 27 3.5 固態混合樣品 30 3.5.1 固態混合樣品之製備 30 3.5.2 固態混合樣品之相行為分析 32 3.5.3 固態混合樣品之光譜解析 38 3.5.4 固態樣品之異質性與動態特性分析 44 3.6 σ(Ar2)之客體封裝性 50 3.6.1 客體選擇 50 3.6.2 封裝系統之製備 51 3.6.3 封裝系統之相行為分析 51 3.6.4 An@σ(Ar2)樣品之光譜解析 54 3.7 σ(Ar2)之催化性 61 3.7.1 樣品製備 61 3.7.2 An之光二聚化反應 62 3.7.3 An@σ之光二聚化反應 64 3.7.4 An@σ(Ar2)之光二聚化反應 65 第四章 結論 69 第五章 實驗部分 71 5.1 試藥來源 71 5.2 量測儀器 71 5.2.1 核磁共振儀（Nuclear Magnetic Resonance Spectrometer, NMR） 71 5.2.2 質譜儀（Mass Spectrometer） 73 5.2.3 熱重分析法（Thermogravimetric Analysis, TGA） 73 5.2.4 微差掃描熱量法（Differential Scanning Calorimetry, DSC） 74 5.2.5 小角X光散射儀（Small Angle X-ray Scattering, SAXS） 74 5.2.6 廣角X光散射儀（Wide Angle X-ray Scattering, WAXS） 74 5.2.7 紫外-可見光光譜儀（Ultraviolet-Visible Spectroscopy, UV-Vis） 75 5.2.8 光學顯微鏡（Optical Microscope, OM） 75 5.2.9 光致發光光譜儀（Photoluminescence Spectroscopy, PL） 76 5.2.10 紅外線光譜法（Infrared Spectroscopy, IR） 76 5.2.11 動態光散射儀（Dynamic Light Scattering, DLS） 76 5.2.12 固態核磁共振光譜儀（Solid State Nuclear Magnetic Resonance Spectrometer, ssNMR） 77 5.3 分子合成 79 5.3.1 化合物Compound 1之合成 79 5.3.2 化合物3,4,5-TDBA之合成 80 5.3.3 化合物D2之合成 81 5.3.4 化合物Py2之合成 82 5.3.5 化合物Np2之合成 83 5.3.6 化合物Bn2之合成 84 5.4 凹陷深度計算 85 參考資料 87 附錄 97 | - |
| dc.language.iso | zh_TW | - |
| dc.subject | Frank-Kasper相 | - |
| dc.subject | 超分子自組裝 | - |
| dc.subject | 類脂筏異質性 | - |
| dc.subject | 類酵素口袋 | - |
| dc.subject | 階層性複雜結構 | - |
| dc.subject | Frank–Kasper phase | - |
| dc.subject | Supramolecular self-assembly | - |
| dc.subject | Lipid raft–inspired heterogeneity | - |
| dc.subject | Enzyme-like pockets | - |
| dc.subject | Hierarchical complexity | - |
| dc.title | 以脂筏啟發之分子異質性實現具功能性與結構複雜度之Frank-Kasper相 | zh_TW |
| dc.title | Toward Functional and Structurally Complex Frank–Kasper Phases via Lipid Raft-Inspired Heterogeneity | en |
| dc.type | Thesis | - |
| dc.date.schoolyear | 114-1 | - |
| dc.description.degree | 碩士 | - |
| dc.contributor.oralexamcommittee | 楊吉水;莊偉綜;王迪彥 | zh_TW |
| dc.contributor.oralexamcommittee | Jye-Shane Yang;Wei-Tsung Chuang;Di-Yan Wang | en |
| dc.subject.keyword | Frank-Kasper相,超分子自組裝類脂筏異質性類酵素口袋階層性複雜結構 | zh_TW |
| dc.subject.keyword | Frank–Kasper phase,Supramolecular self-assemblyLipid raft–inspired heterogeneityEnzyme-like pocketsHierarchical complexity | en |
| dc.relation.page | 110 | - |
| dc.identifier.doi | 10.6342/NTU202504658 | - |
| dc.rights.note | 同意授權(全球公開) | - |
| dc.date.accepted | 2025-11-10 | - |
| dc.contributor.author-college | 理學院 | - |
| dc.contributor.author-dept | 化學系 | - |
| dc.date.embargo-lift | 2030-11-10 | - |
| 顯示於系所單位： | 化學系 | |
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|---|---|---|---|
| ntu-114-1.pdf 此日期後於網路公開 2030-11-10 | 11.99 MB | Adobe PDF |
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