Skip navigation

DSpace JSPUI

DSpace preserves and enables easy and open access to all types of digital content including text, images, moving images, mpegs and data sets

Learn More
DSpace logo
English
中文
  • Browse
    • Communities
      & Collections
    • Publication Year
    • Author
    • Title
    • Subject
    • Advisor
  • Search TDR
  • Rights Q&A
    • My Page
    • Receive email
      updates
    • Edit Profile
  1. NTU Theses and Dissertations Repository
  2. 工學院
  3. 化學工程學系
Please use this identifier to cite or link to this item: http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/99444
Full metadata record
???org.dspace.app.webui.jsptag.ItemTag.dcfield???ValueLanguage
dc.contributor.advisor吳哲夫zh_TW
dc.contributor.advisorJeffrey D. Warden
dc.contributor.author李佳穎zh_TW
dc.contributor.authorChia-Yin Leeen
dc.date.accessioned2025-09-10T16:18:25Z-
dc.date.available2025-09-11-
dc.date.copyright2025-09-10-
dc.date.issued2025-
dc.date.submitted2025-07-30-
dc.identifier.citation[1] A. A. Kiss, Advanced distillation technologies: design, control and applications. John Wiley & Sons, 2013.
[2] A. A. Kiss and R. Smith, "Rethinking energy use in distillation processes for a more sustainable chemical industry," Energy, vol. 203, p. 117788, 2020.
[3] R. B. Chapas and J. A. Colwell, "Industrial technologies program research plan for energy-intensive process industries," Pacific Northwest National Laboratory (PNNL), Richland, WA (United States), 2007.
[4] D. S. Sholl and R. P. Lively, "Seven chemical separations to change the world," Nature, vol. 532, no. 7600, pp. 435-437, 2016.
[5] M. Emtir and A. Etoumi, "Enhancement of conventional distillation configurations for ternary mixtures separation," Clean Technologies and Environmental Policy, vol. 11, no. 1, pp. 123-131, 2009.
[6] C. Cui, X. Zhang, and J. Sun, "Design and optimization of energy-efficient liquid-only side-stream distillation configurations using a stochastic algorithm," Chemical Engineering Research and Design, vol. 145, pp. 48-52, 2019.
[7] P. Murphy and D. Lobdell, "US environmental protection agency's (EPA) 2008 report on the environment (ROE): Identified gaps and future challenges for human exposure and health indicators," Epidemiology, vol. 20, no. 6, p. S91, 2009.
[8] W.-T. Tang and J. D. Ward, "Stacked complex sequences for ternary zeotropic distillation," Computers & Chemical Engineering, vol. 161, p. 107744, 2022.
[9] W.-T. Tang and J. D. Ward, "Energy and exergy analysis of a stacked complex sequence and alternatives for ternary distillation," Separation and Purification Technology, vol. 304, p. 122384, 2023.
[10] W.-T. Tang and J. D. Ward, "Comparison of Separation Alternatives for Two Industrial C6–C7 Aliphatic Hydrocarbon Mixtures Including Stacked Complex Sequences," Industrial & Engineering Chemistry Research, vol. 61, no. 36, pp. 13488-13504, 2022.
[11] W.-T. Tang, C.-K. Chien, and J. D. Ward, "Stacked Side-Stream distillation sequences," Chemical Engineering Science, vol. 280, p. 119075, 2023.
[12] W.-T. Tang, C.-K. Chien, and J. D. Ward, "A review of energy intensification strategies for distillation processes: Cyclic operation, stacking, heat pumps, side-streams, dividing walls and beyond," Separation and Purification Technology, p. 130030, 2024.
[13] C.-K. Chien and J. D. Ward, "A new metric for the evaluation and selection of energy-intensified extractive distillation sequences," Separation and Purification Technology, vol. 320, p. 124165, 2023.
[14] J. A. Caballero and I. E. Grossmann, "Structural considerations and modeling in the synthesis of heat-integrated− thermally coupled distillation sequences," Industrial & engineering chemistry research, vol. 45, no. 25, pp. 8454-8474, 2006.
[15] S. Hernandez, I. R. Gudino-Mares, J. C. Cardenas, J. G. Segovia-Hernandez, and V. Rico-Ramírez, "A short note on control structures for thermally coupled distillation sequences for four-component mixtures," Industrial & engineering chemistry research, vol. 44, no. 15, pp. 5857-5863, 2005.
[16] Y. Demirel, "Thermodynamic analysis of separation systems," Separation science and technology, vol. 39, no. 16, pp. 3897-3942, 2004.
[17] G. D. Loud and R. C. Waggoner, "The effects of interstage backmixing on the design of a multicomponent distillation column," Industrial & Engineering Chemistry Process Design and Development, vol. 17, no. 2, pp. 149-156, 1978.
[18] H.-G. Franck and J. W. Stadelhofer, Industrial aromatic chemistry: raw materials· processes· products. Springer Science & Business Media, 2012.
[19] W. Sweeney and P. Bryan, "BTX processing," Kirk‐Othmer Encyclopedia of Chemical Technology, 2000.
[20] M. McVey, Y. Elkasabi, and D. Ciolkosz, "Separation of BTX chemicals from biomass pyrolysis oils via continuous flash distillation," Biomass Conversion and Biorefinery, vol. 10, pp. 15-23, 2020.
[21] W.-J. Wang and J. D. Ward, "Control of three types of dividing wall columns," Industrial & Engineering Chemistry Research, vol. 52, no. 50, pp. 17976-17995, 2013.
[22] H. Ling and W. L. Luyben, "Temperature control of the BTX divided-wall column," Industrial & Engineering Chemistry Research, vol. 49, no. 1, pp. 189-203, 2010.
[23] A. Yang, S. Sun, A. Eslamimanesh, S. a. Wei, and W. Shen, "Energy-saving investigation for diethyl carbonate synthesis through the reactive dividing wall column combining the vapor recompression heat pump or different pressure thermally coupled technique," Energy, vol. 172, pp. 320-332, 2019.
[24] S. Tututi-Avila, L. A. Domínguez-Díaz, N. Medina-Herrera, A. Jiménez-Gutiérrez, and J. Hahn, "Dividing-wall columns: Design and control of a kaibel and a satellite distillation column for BTX separation," Chemical Engineering and Processing: Process Intensification, vol. 114, pp. 1-15, 2017.
[25] M. M. Donahue, B. J. Roach, J. J. Downs, T. Blevins, M. Baldea, and R. B. Eldridge, "Dividing wall column control: Common practices and key findings," Chemical Engineering and Processing-Process Intensification, vol. 107, pp. 106-115, 2016.
[26] A. A. Kiss and C. S. Bildea, "A control perspective on process intensification in dividing-wall columns," Chemical Engineering and Processing: Process Intensification, vol. 50, no. 3, pp. 281-292, 2011.
[27] M. Mohsen-Nia and F. M. Doulabi, "Liquid–liquid equilibria for mixtures of (ethylene carbonate+ aromatic hydrocarbon+ cyclohexane)," Thermochimica acta, vol. 445, no. 1, pp. 82-85, 2006.
[28] J. Xu, S. Li, Z. Zeng, and W. Xue, "Isobaric vapor–liquid equilibrium for binary system of isoamyl dl-lactate and isoamyl alcohol at 25.0, 50.0, and 101.3 kPa," Journal of Chemical & Engineering Data, vol. 65, no. 1, pp. 81-87, 2019.
[29] 金彰礼, 胡爱宝, and 刘昆元, "Vapor-liquid equilibrium for ternary mixtures of benzene, toluene, and p-xylene," 中国化学工程学报: 英文版, no. 1, pp. 49-53, 1993.
[30] O. Sartakova, O. Krutko, M. Khristenko, and L. Kormina, "Investigation of technical schemes for the separation of toluene and diglyme mixtures," Zh. Prikl. Khim, vol. 69, pp. 1077-1080, 1996.
[31] D. E. Seborg, T. F. Edgar, D. A. Mellichamp, and F. J. Doyle III, Process dynamics and control. John Wiley & Sons, 2016.
[32] W. L. Luyben, Practical distillation control. Springer Science & Business Media, 2012.
[33] S. Skogestad and I. Postlethwaite, Multivariable feedback control: analysis and design. john Wiley & sons, 2005.
[34] A. C. Dimian and C. S. Bildea, Chemical process design: Computer-aided case studies. John Wiley & Sons, 2008.
[35] W. L. Luyben, "Design and control of a fully heat-integrated pressure-swing azeotropic distillation system," Industrial & engineering chemistry research, vol. 47, no. 8, pp. 2681-2695, 2008.
[36] T. Akinciturk and D. B. Kaymak, "Design and control of an energy-efficient triple-column pressure swing distillation configuration for separation of acetone-methanol-hexane mixture," Computers & Chemical Engineering, vol. 160, p. 107731, 2022.
[37] Z.-Y. Yang, B.-Y. Yu, and I.-L. Chien, "An environmentally benign, energy intensified single-column side stream extractive distillation (SC-SSED) process for Acetone/n-heptane separation," Journal of the Taiwan Institute of Chemical Engineers, vol. 149, p. 105018, 2023.
[38] Q. Zhang, A. Zeng, Y. Ma, X. Yuan, and J. Gao, "Dynamic control analyses of eco-efficient partially heat-integrated side-stream pressure-swing distillation processes," Separation and Purification Technology, vol. 239, p. 116571, 2020.
[39] B.-Y. Yu and I.-L. Chien, "Novel temperature-control strategy for single column side-stream extractive distillation process with intermediate-boiling entrainer," Separation and Purification Technology, vol. 310, p. 123163, 2023.
[40] T. Shi et al., "Optimization and control of energy saving side-stream extractive distillation with heat integration for separating ethyl acetate-ethanol azeotrope," Chemical Engineering Science, vol. 215, p. 115373, 2020.
[41] Y. Yuan, X. Tao, K. Huang, H. Chen, and X. Qian, "An effective temperature control method for dividing-wall distillation columns," Processes, vol. 10, no. 5, p. 1018, 2022.
[42] Z. Feng, W. Wang, D. Xu, G. P. Rangaiah, and L. Dong, "Dynamic controllability of temperature difference control for the operation of double liquid-only side-stream distillation," Computers & Chemical Engineering, vol. 164, p. 107870, 2022.
[43] A. Yang, R. Wei, S. Sun, S. a. Wei, W. Shen, and I.-L. Chien, "Energy-saving optimal design and effective control of heat integration-extractive dividing wall column for separating heterogeneous mixture methanol/toluene/water with multiazeotropes," Industrial & Engineering Chemistry Research, vol. 57, no. 23, pp. 8036-8056, 2018.
[44] Q. Zhang, M. Liu, C. Li, and A. Zeng, "Heat-integrated pressure-swing distillation process for separating the minimum-boiling azeotrope ethyl-acetate and ethanol," Separation and Purification Technology, vol. 189, pp. 310-334, 2017.
-
dc.identifier.urihttp://tdr.lib.ntu.edu.tw/jspui/handle/123456789/99444-
dc.description.abstract儘管蒸餾的能耗高,但它仍然是分離揮發性混合物最廣泛使用的方法,每年約佔全球能源消耗的 3%。傳統的蒸餾程序存在重混效應,這會降低分離效率並增加能量需求。為了解決這些問題,雖然已提出如分隔壁塔(Dividing-Wall Columns, DWCs)等能量強化策略,但這些方法在控制上存在挑戰,尤其是在僅使用單一再沸器時需管理蒸氣分流。相比之下,堆疊複合蒸餾程序(或稱堆疊側線程序)透過側線抽取來減少重混效應,並藉由整合的再沸器-冷凝器熱交換器降低能耗。此設計不需蒸氣分流,但也帶來了新的控制挑戰:由於熱整合,系統失去了兩個控制自由度。值得注意的是,目前尚無針對堆疊側線程序控制性能的系統性研究。在本研究中,我們比較了傳統蒸餾程序、分隔壁塔與堆疊複合程序於等摩分離 BTX(三苯:苯、甲苯、二甲苯)時的動態控制行為。結果顯示,堆疊複合程序不僅具備優異的節能效果,亦展現出比分隔壁塔更佳的可控性,是一種具可行性與操作性的永續蒸餾設計方案。zh_TW
dc.description.abstractDistillation remains the most widely used method for separating mixtures of volatile substances despite its high energy consumption, accounting for approximately 3% of global energy use annually. Traditional distillation sequences usually suffer from remixing effects that reduce separation efficiency and increase energy demand. The most widely-studied method for reducing the remixing effect is thermal coupling, including its embodiment as a dividing-wall column. Recently, however an alternative method called the stacked side-stream sequence has been shown to perform better in most cases. Dividing-wall columns face control challenges—particularly the need to manage vapor splits when only a single reboiler is used. A stacked side-stream sequence does not have a vapor split, but it introduces a different control challenge: the loss of two degrees of freedom due to thermal integration of a reboiler and a condenser. While hundreds of papers have been written on the control of dividing-wall columns, no prior studies have compared the control performance of stacked side-stream sequences with that of dividing-wall columns and conventional two-column sequences. Therefore, in this study, the dynamic control behavior of the conventional distillation sequence, the dividing-wall column, and the stacked side-stream sequence for the separation of BTX (benzene, toluene, xylene). Results show that the stacked side-stream sequence not only achieves superior energy savings but also demonstrates better controllability than the DWC, making it a promising option for sustainable and operable process design.en
dc.description.provenanceSubmitted by admin ntu (admin@lib.ntu.edu.tw) on 2025-09-10T16:18:25Z
No. of bitstreams: 0
en
dc.description.provenanceMade available in DSpace on 2025-09-10T16:18:25Z (GMT). No. of bitstreams: 0en
dc.description.tableofcontents口試委員會審定書 i
誌謝 ii
中文摘要 iii
ABSTRACT iv
CONTENTS v
LIST OF FIGURES vii
LIST OF TABLES xii
Chapter 1 Introduction 1
1.1 Overview 1
1.2 Drawback of conventional sequence 2
1.3 Literature Review 4
1.4 Motivation 6
1.5 Method 7
Chapter 2 Process Design 9
2.1 Thermodynamic Validation 9
2.2 Conventional Distillation Sequence 10
2.3 Stacked Side-Stream Sequence 12
2.4 Dividing-Wall Column 15
Chapter 3 Control Strategies 20
3.1 Control of Conventional Distillation Sequence 20
3.2 Control of Stacked Side-Stream Sequence 24
3.2.1 Basic inventory control 25
3.2.2 Pressure-Compensated Temperature Strategy 28
3.2.3 Reboiler Level Cascade Strategy 33
3.3 Control of Dividing-Wall Column 37
Chapter 4 Results and Discussions 44
4.1 Conventional Distillation Sequence 45
4.2 Stacked Side-Stream Sequence 51
4.2.1 Pressure-Compensated Temperature Strategy 51
4.2.2 Reboiler Level Cascade Strategy 60
4.3 Dividing-Wall Column 68
4.3.1 Drawback of Dividing-Wall Column 75
4.4 Comparison of Three Different Distillation Sequences 77
Chapter 5 Conclusion 82
REFERENCES 83
-
dc.language.isoen-
dc.subject堆疊式側線分離序列zh_TW
dc.subject製程控制zh_TW
dc.subject三苯zh_TW
dc.subject蒸餾zh_TW
dc.subject隔板塔zh_TW
dc.subjectBTXen
dc.subjectProcess controlen
dc.subjectDividing-Wall Columnen
dc.subjectStacked Side-stream Sequenceen
dc.subjectDistillationen
dc.title三種不同蒸餾序列之控制策略開發zh_TW
dc.titleControl Strategy Development for Three Different Distillation Sequencesen
dc.typeThesis-
dc.date.schoolyear113-2-
dc.description.degree碩士-
dc.contributor.oralexamcommittee陳誠亮;李豪業zh_TW
dc.contributor.oralexamcommitteeCheng-Liang Chen;Hao-Yeh Leeen
dc.subject.keyword蒸餾,堆疊式側線分離序列,隔板塔,製程控制,三苯,zh_TW
dc.subject.keywordDistillation,Stacked Side-stream Sequence,Dividing-Wall Column,Process control,BTX,en
dc.relation.page87-
dc.identifier.doi10.6342/NTU202502737-
dc.rights.note未授權-
dc.date.accepted2025-08-01-
dc.contributor.author-college工學院-
dc.contributor.author-dept化學工程學系-
dc.date.embargo-liftN/A-
Appears in Collections:化學工程學系

Files in This Item:
File SizeFormat 
ntu-113-2.pdf
  Restricted Access
6.42 MBAdobe PDF
Show simple item record


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

社群連結
聯絡資訊
10617臺北市大安區羅斯福路四段1號
No.1 Sec.4, Roosevelt Rd., Taipei, Taiwan, R.O.C. 106
Tel: (02)33662353
Email: ntuetds@ntu.edu.tw
意見箱
相關連結
館藏目錄
國內圖書館整合查詢 MetaCat
臺大學術典藏 NTU Scholars
臺大圖書館數位典藏館
本站聲明
© NTU Library All Rights Reserved