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  1. NTU Theses and Dissertations Repository
  2. 工學院
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請用此 Handle URI 來引用此文件: http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/99444
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dc.contributor.advisor吳哲夫zh_TW
dc.contributor.advisorJeffrey D. Warden
dc.contributor.author李佳穎zh_TW
dc.contributor.authorChia-Yin Leeen
dc.date.accessioned2025-09-10T16:18:25Z-
dc.date.available2025-09-11-
dc.date.copyright2025-09-10-
dc.date.issued2025-
dc.date.submitted2025-07-30-
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[29] 金彰礼, 胡爱宝, and 刘昆元, "Vapor-liquid equilibrium for ternary mixtures of benzene, toluene, and p-xylene," 中国化学工程学报: 英文版, no. 1, pp. 49-53, 1993.
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dc.identifier.urihttp://tdr.lib.ntu.edu.tw/jspui/handle/123456789/99444-
dc.description.abstract儘管蒸餾的能耗高,但它仍然是分離揮發性混合物最廣泛使用的方法,每年約佔全球能源消耗的 3%。傳統的蒸餾程序存在重混效應,這會降低分離效率並增加能量需求。為了解決這些問題,雖然已提出如分隔壁塔(Dividing-Wall Columns, DWCs)等能量強化策略,但這些方法在控制上存在挑戰,尤其是在僅使用單一再沸器時需管理蒸氣分流。相比之下,堆疊複合蒸餾程序(或稱堆疊側線程序)透過側線抽取來減少重混效應,並藉由整合的再沸器-冷凝器熱交換器降低能耗。此設計不需蒸氣分流,但也帶來了新的控制挑戰:由於熱整合,系統失去了兩個控制自由度。值得注意的是,目前尚無針對堆疊側線程序控制性能的系統性研究。在本研究中,我們比較了傳統蒸餾程序、分隔壁塔與堆疊複合程序於等摩分離 BTX(三苯:苯、甲苯、二甲苯)時的動態控制行為。結果顯示,堆疊複合程序不僅具備優異的節能效果,亦展現出比分隔壁塔更佳的可控性,是一種具可行性與操作性的永續蒸餾設計方案。zh_TW
dc.description.abstractDistillation remains the most widely used method for separating mixtures of volatile substances despite its high energy consumption, accounting for approximately 3% of global energy use annually. Traditional distillation sequences usually suffer from remixing effects that reduce separation efficiency and increase energy demand. The most widely-studied method for reducing the remixing effect is thermal coupling, including its embodiment as a dividing-wall column. Recently, however an alternative method called the stacked side-stream sequence has been shown to perform better in most cases. Dividing-wall columns face control challenges—particularly the need to manage vapor splits when only a single reboiler is used. A stacked side-stream sequence does not have a vapor split, but it introduces a different control challenge: the loss of two degrees of freedom due to thermal integration of a reboiler and a condenser. While hundreds of papers have been written on the control of dividing-wall columns, no prior studies have compared the control performance of stacked side-stream sequences with that of dividing-wall columns and conventional two-column sequences. Therefore, in this study, the dynamic control behavior of the conventional distillation sequence, the dividing-wall column, and the stacked side-stream sequence for the separation of BTX (benzene, toluene, xylene). Results show that the stacked side-stream sequence not only achieves superior energy savings but also demonstrates better controllability than the DWC, making it a promising option for sustainable and operable process design.en
dc.description.provenanceSubmitted by admin ntu (admin@lib.ntu.edu.tw) on 2025-09-10T16:18:25Z
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dc.description.provenanceMade available in DSpace on 2025-09-10T16:18:25Z (GMT). No. of bitstreams: 0en
dc.description.tableofcontents口試委員會審定書 i
誌謝 ii
中文摘要 iii
ABSTRACT iv
CONTENTS v
LIST OF FIGURES vii
LIST OF TABLES xii
Chapter 1 Introduction 1
1.1 Overview 1
1.2 Drawback of conventional sequence 2
1.3 Literature Review 4
1.4 Motivation 6
1.5 Method 7
Chapter 2 Process Design 9
2.1 Thermodynamic Validation 9
2.2 Conventional Distillation Sequence 10
2.3 Stacked Side-Stream Sequence 12
2.4 Dividing-Wall Column 15
Chapter 3 Control Strategies 20
3.1 Control of Conventional Distillation Sequence 20
3.2 Control of Stacked Side-Stream Sequence 24
3.2.1 Basic inventory control 25
3.2.2 Pressure-Compensated Temperature Strategy 28
3.2.3 Reboiler Level Cascade Strategy 33
3.3 Control of Dividing-Wall Column 37
Chapter 4 Results and Discussions 44
4.1 Conventional Distillation Sequence 45
4.2 Stacked Side-Stream Sequence 51
4.2.1 Pressure-Compensated Temperature Strategy 51
4.2.2 Reboiler Level Cascade Strategy 60
4.3 Dividing-Wall Column 68
4.3.1 Drawback of Dividing-Wall Column 75
4.4 Comparison of Three Different Distillation Sequences 77
Chapter 5 Conclusion 82
REFERENCES 83
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dc.language.isoen-
dc.subject堆疊式側線分離序列zh_TW
dc.subject製程控制zh_TW
dc.subject三苯zh_TW
dc.subject蒸餾zh_TW
dc.subject隔板塔zh_TW
dc.subjectBTXen
dc.subjectProcess controlen
dc.subjectDividing-Wall Columnen
dc.subjectStacked Side-stream Sequenceen
dc.subjectDistillationen
dc.title三種不同蒸餾序列之控制策略開發zh_TW
dc.titleControl Strategy Development for Three Different Distillation Sequencesen
dc.typeThesis-
dc.date.schoolyear113-2-
dc.description.degree碩士-
dc.contributor.oralexamcommittee陳誠亮;李豪業zh_TW
dc.contributor.oralexamcommitteeCheng-Liang Chen;Hao-Yeh Leeen
dc.subject.keyword蒸餾,堆疊式側線分離序列,隔板塔,製程控制,三苯,zh_TW
dc.subject.keywordDistillation,Stacked Side-stream Sequence,Dividing-Wall Column,Process control,BTX,en
dc.relation.page87-
dc.identifier.doi10.6342/NTU202502737-
dc.rights.note未授權-
dc.date.accepted2025-08-01-
dc.contributor.author-college工學院-
dc.contributor.author-dept化學工程學系-
dc.date.embargo-liftN/A-
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