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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 劉如熹 | zh_TW |
| dc.contributor.advisor | Ru-Shi Liu | en |
| dc.contributor.author | 陳怡安 | zh_TW |
| dc.contributor.author | Yi-An Chen | en |
| dc.date.accessioned | 2025-07-30T16:06:09Z | - |
| dc.date.available | 2025-07-31 | - |
| dc.date.copyright | 2025-07-30 | - |
| dc.date.issued | 2025 | - |
| dc.date.submitted | 2025-07-03 | - |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/98145 | - |
| dc.description.abstract | 環保意識高漲下，各國提倡藉電能作為汽車之動力來源，故具高能量密度與環保優勢之鎂氧氣(Mg–O2)電池受廣泛注目，然Mg–O2電池之發展受限於高過電位與循環能力不佳之問題，故本研究藉加入3,4,5,6-四氯-1,2-苯醌(3,4,5,6-tetrachloro-1,2-benzoquinone; TCBQ)作為氧化還原介質(redox mediator)以改善Mg–O2電池性能。
本研究首先藉量測吸收光譜與循環伏安法(cyclic voltammetry; CV)確認其反應路徑與催化效能，並比較添加TCBQ與否之Mg–O2電池差異，藉電化學測試結果可得知添加TCBQ使Mg–O2電池起始電壓由1.18 V提升至1.59 V，增幅達35%，而最大放電電容量則由19,722 mAh g–1提升至27,788 mAh g–1，增加約41%，且穩定循環次數由7圈提升至58圈，增長超過8倍，電池過電位自1.7 V降低至0.7 V，減少近60%。 本研究亦藉同步輻射X光繞射(synchrotron X-ray diffraction; S-XRD) 、X光吸收光譜(X-ray absorption spectroscopy; XAS) 、X光光電子能譜(X-ray photoelectron spectroscopy; XPS) 、掃描式電子顯微鏡(scanning electron microscope; SEM) 及穿透式電子顯微鏡(transmission electron microscopy; TEM) 儀器技術分析經放電後之陰極，可得知無論添加TCBQ與否其放電產物皆為MgO，且TCBQ使放電產物更均勻分布於陰極上。 本研究之新穎性為成功藉添加TCBQ作為氧化還原介質催化氧還原反應，解決Mg–O2電池面臨高過電位與循環能力不佳問題，以提升Mg–O2電池性能，為添加於Mg–O2電池之氧化還原介質提供新選擇。 | zh_TW |
| dc.description.abstract | In response to the growing global emphasis on environmental protection, the use of electric energy as a vehicle power source has been increasingly advocated worldwide. Magnesium–oxygen (Mg–O2) batteries, characterized by their high energy density and environmental benefits, have emerged as promising candidates for next-generation energy storage systems. However, their practical application remains limited due to challenges such as high overpotential and poor cycling stability.
In this study, 3,4,5,6-tetrachloro-1,2-benzoquinone (TCBQ) was introduced as a redox mediator to address these issues and enhance the overall performance of Mg–O2 batteries. The reaction pathways and catalytic efficiency of TCBQ were investigated through absorption spectroscopy and cyclic voltammetry (CV) measurements. Electrochemical testing revealed that the addition of TCBQ significantly increased the initial discharge voltage from 1.18 V to 1.59 V (a 35% enhancement), elevated the maximum discharge capacity from 19,722 mAh g⁻¹ to 27,788 mAh g⁻¹ (a 41% improvement), extended the stable cycle life from 7 cycles to 58 cycles, and reduced the overpotential from 1.7 V to 0.7 V, representing a nearly 60% reduction. Furthermore, synchrotron X-ray diffraction (S-XRD), X-ray absorption spectroscopy (XAS), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), and transmission electron microscopy (TEM) analyses indicated that the primary discharge product was magnesium oxide (MgO) regardless of the presence of TCBQ, with a more homogeneous distribution observed when TCBQ was incorporated. These results demonstrate that TCBQ effectively catalyzes the oxygen reduction reaction, thereby mitigating the major limitations of Mg–O2 batteries. This study provides a new strategy for improving the electrochemical performance and cycle life of Mg–O2 batteries through the use of redox mediators. | en |
| dc.description.provenance | Submitted by admin ntu (admin@lib.ntu.edu.tw) on 2025-07-30T16:06:09Z No. of bitstreams: 0 | en |
| dc.description.provenance | Made available in DSpace on 2025-07-30T16:06:09Z (GMT). No. of bitstreams: 0 | en |
| dc.description.tableofcontents | 口試委員會審定書 i
誌謝 ii 摘要 iii Abstract iv 目次 v 圖次 viii 表次 xii 英文縮寫表 xiii 第一章 緒論 1 1.1金屬空氣電池 1 1.2鋰氧氣電池 3 1.3鎂氧氣電池 10 1.4鎂空氣電池中之陽極材料 13 1.4.1金屬鎂表面修飾與塗層技術 13 1.4.2金屬鎂合金化設計 16 1.5鎂空氣電池中之電解質 19 1.5.1水性電解質 19 1.5.2非水系電解質 22 1.5.2.1有機溶劑電解質 23 1.5.2.2離子液體電解質 24 1.5.2.3聚合物電解質 27 1.6鎂空氣電池中之陰極材料與催化劑 31 1.6.1碳材料 32 1.6.2無金屬雜原子摻雜 32 1.6.3貴金屬 35 1.6.4過渡金屬氧化物 36 1.6.5含氮金屬大環化合物 37 1.7鎂電解質之添加劑介紹 39 1.7.1緩蝕劑 39 1.7.2氧化還原介質 41 1.8研究動機與目的 46 第二章 實驗步驟與儀器分析原理 47 2.1化學藥品 47 2.2實驗步驟 49 2.2.1液態電解質之配製 49 2.2.2陰極漿料之混合與塗佈 50 2.2.3鈕扣型鎂氧氣電池之組裝與充放電測試 50 2.3分析儀器與其原理 53 2.3.1循環伏安法(cyclic voltammetry; CV) 53 2.3.2充放電量測儀(cycling machine) 55 2.3.3同步輻射X光繞射(synchrotron X-Ray diffraction; S-XRD) 56 2.3.4 X光吸收光譜(X-ray absorption spectroscopy; XAS) 58 2.3.5 X光光電子能譜(X-ray photoelectron spectroscopy; XPS) 60 2.3.6掃描式電子顯微鏡(scanning electron microscope; SEM) 64 2.3.7穿透式電子顯微鏡(transmission electron microscopy; TEM) 66 2.3.8光致發光光譜(photoluminescence spectroscopy; PL) 68 第三章 結果與討論 71 3.1氧化還原介質之分析 71 3.1.1吸收光譜鑑定 71 3.1.2 循環伏安法量測 73 3.2電化學性能分析 75 3.2.1電池性能測試用鎂氧氣電池 75 3.2.2最大放電測試 76 3.2.3循環充放電測試 77 3.3 陰極放電產物之鑑定 81 3.3.1 X光繞射鑑定 81 3.3.2穿透式電子顯微鏡鑑定 82 3.3.3掃描式電子顯微鏡鑑定 85 3.3.4 X光吸收光譜鑑定 95 3.3.5 X光光電子能譜鑑定 99 第四章 結論 104 參考文獻 105 | - |
| dc.language.iso | zh_TW | - |
| dc.subject | 鎂氧氣電池 | zh_TW |
| dc.subject | 氧化還原介質 | zh_TW |
| dc.subject | 6-四氯-1 | zh_TW |
| dc.subject | 2-苯醌 | zh_TW |
| dc.subject | 循環伏安法 | zh_TW |
| dc.subject | 氧還原反應 | zh_TW |
| dc.subject | 6-tetrachloro-1 | en |
| dc.subject | oxygen reduction reaction | en |
| dc.subject | cyclic voltammetry | en |
| dc.subject | 2-benzoquinone | en |
| dc.subject | magnesium–oxygen battery | en |
| dc.subject | redox mediator | en |
| dc.title | 利用氧化還原介質提升鎂氧氣電池性能 | zh_TW |
| dc.title | Improve the Performance of Magnesium–Oxygen Batteries with Redox Mediators | en |
| dc.type | Thesis | - |
| dc.date.schoolyear | 113-2 | - |
| dc.description.degree | 碩士 | - |
| dc.contributor.oralexamcommittee | 陳致融;魏大華;王丞浩;廖譽凱 | zh_TW |
| dc.contributor.oralexamcommittee | Chih-Jung Chen;Da-Hua Wei;Chen-Hao Wang;Yu-Kai Liao | en |
| dc.subject.keyword | 鎂氧氣電池,氧化還原介質,3,4,5,6-四氯-1,2-苯醌,循環伏安法,氧還原反應, | zh_TW |
| dc.subject.keyword | magnesium–oxygen battery,redox mediator,3,4,5,6-tetrachloro-1,2-benzoquinone,cyclic voltammetry,oxygen reduction reaction, | en |
| dc.relation.page | 115 | - |
| dc.identifier.doi | 10.6342/NTU202501363 | - |
| dc.rights.note | 同意授權(全球公開) | - |
| dc.date.accepted | 2025-07-04 | - |
| dc.contributor.author-college | 重點科技研究學院 | - |
| dc.contributor.author-dept | 奈米工程與科學學位學程 | - |
| dc.date.embargo-lift | 2025-07-31 | - |
| 顯示於系所單位： | 奈米工程與科學學位學程 | |
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