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http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/96441完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 鄭如忠 | zh_TW |
| dc.contributor.advisor | Ru-Jong Jeng | en |
| dc.contributor.author | 顏禎里 | zh_TW |
| dc.contributor.author | Zhen-Li Yan | en |
| dc.date.accessioned | 2025-02-18T16:08:47Z | - |
| dc.date.available | 2025-02-19 | - |
| dc.date.copyright | 2025-02-18 | - |
| dc.date.issued | 2024 | - |
| dc.date.submitted | 2025-02-04 | - |
| dc.identifier.citation | 1. Akkerman, Q. A.; Manna, L., What Defines a Halide Perovskite? ACS Energy Letters 2020, 5 (2), 604-610.
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/96441 | - |
| dc.description.abstract | 本研究致力於提升鈣鈦礦發光二極體 (PeLEDs) 的光電性能，同時構建具光學邏輯特性的半導體應用。在現今半導體元件的發展中，光電訊號的增益和邏輯性在提升資訊讀取與加密功能方面具有關鍵作用。鈣鈦礦材料因其優異的光電轉換效率、可調控的波長範圍及高純度的光學性質，成為新一代半導體技術的理想材料。然而，進一步增強其放光強度、穩定性及實現光學邏輯特性仍是當前研究的挑戰。
本研究提出兩大創新策略，分別針對增強鈣鈦礦放光性能及調控其晶體結構來實現光學邏輯特性。在第一部分中，我們利用聚己內酯 (PCL) 封端的銀奈米粒子 (AgNPs) 製備出穩定且高效的放光增益層。該增益層通過 Förster Resonance Energy Transfer (FRET) 機制，將鈣鈦礦次相發出的能量轉移至主相，大幅提高放光強度。此外，該增益層還具有 Purcell 效應，通過增強 plasmonic-excitons 來提升 PeLED 的自發輻射速率，使其在亮度和外部量子效率 (EQE) 方面取得顯著提升，展示出在高性能鈣鈦礦光電元件中的應用潛力。 在第二部分研究中，我們將結晶性酯基聚合物 (ester polymer) 與鈣鈦礦混摻，通過離子-偶極子相互作用 (ion-dipole interaction) 調控鈣鈦礦晶體的生長與尺寸，實現不同波段的放光邏輯特性。研究結果表明，酯基聚合物不僅有效改善了鈣鈦礦晶體的形貌和穩定性，還通過調節晶體結構提升了光致發光性能，特別是在高結晶性酯基聚合物 (hc-ester polymer) 的輔助下，光邏輯特性得到了進一步增強。此外，該系統展現出作為動態光邏輯傳感器的潛力，適用於未來柔性光電元件的應用。 期望本研究通過開發具有放光增益的鈣鈦礦-聚合物複合材料，並調控其晶體尺寸來構建多波段光學邏輯特性，能為新一代柔性光電元件的設計與應用提供全新思路。 | zh_TW |
| dc.description.abstract | This research is dedicated to improving the optoelectronic performance of perovskite light-emitting diodes (PeLEDs) and constructing semiconductor applications with optical logic properties. In the development of today's semiconductor components, the gain and logic of photoelectric signals play a crucial role in improving information reading and encryption functions. Perovskite materials have become ideal materials for the new generation of semiconductor technology due to their excellent photoelectric conversion efficiency, controllable wavelength range, and high-purity optical properties. However, further enhancing its luminous intensity and stability and realizing optical logic properties are still challenges in current research.
This study proposes two innovative strategies to enhance perovskite's light emission performance and regulate its crystal structure to achieve optical logic properties. In the first part, we prepare a stable and efficient light-emitting gain layer using polycaprolactone (PCL)-terminated silver nanoparticles (AgNPs). This gain layer transfers the energy emitted by the perovskite minor phase to the main phase through the Förster Resonance Energy Transfer (FRET) mechanism, significantly increasing the emission intensity. In addition, the gain layer also has the Purcell effect, which enhances the spontaneous emission rate of PeLED by enhancing plasmonic-excitons, resulting in significant improvements in brightness and external quantum efficiency (EQE), demonstrating its application potential in high-performance perovskite optoelectronic components. In the second part of the study, we mixed a crystalline ester polymer with a quasi-two-dimensional perovskite and controlled the growth and size of the perovskite crystal through ion-dipole interaction to achieve luminescence in different wavelength bands with logical characteristics. Research results show that ester-based polymers not only effectively improve the morphology and stability of perovskite crystals but also improve the photoluminescence performance by adjusting the crystal structure. Especially with the assistance of highly crystalline ester-based polymers, the optical logic properties of perovskites are further enhanced. Furthermore, the system shows potential as a dynamic optical logic sensor for future applications in flexible optoelectronic components. | en |
| dc.description.provenance | Submitted by admin ntu (admin@lib.ntu.edu.tw) on 2025-02-18T16:08:46Z No. of bitstreams: 0 | en |
| dc.description.provenance | Made available in DSpace on 2025-02-18T16:08:47Z (GMT). No. of bitstreams: 0 | en |
| dc.description.tableofcontents | 論文口試委員會審定書 i
謝辭 ii 中文摘要 iii 英文摘要 iv 第一章 緒論 1 1.1 研究背景 1 1.2 研究動機與目的 1 第二章 文獻回顧 3 2.1 鈣鈦礦材料 3 2.2 鈣鈦礦之光電性質 4 2.3 鈣鈦礦之光電半導體元件應用 7 2.4 鈣鈦礦發光二極體 11 2.5 有機高分子與金屬陽離子之 ion-dipole interaction 19 2.6 以 Energy transfer 提升鈣鈦礦發光二極體之放光表現 21 2.7 以金屬奈米粒子 Surface plasmon resonance優化鈣鈦礦發光二極體 22 2.8 本研究採用不同結晶程度之 Ester polymer 24 第三章 實驗方法與研究鑑定分析 26 實驗方法 26 3.1 鈣鈦礦材料 26 3.1.1 單晶鈣鈦礦 26 3.1.2 三維 (3D-Bulk) 鈣鈦礦 27 3.1.3 準二維 (Quasi-2D) 鈣鈦礦 28 3.1.4 量子點 (Quantum dot) 鈣鈦礦及雙齒性配體 (Bidentate ligand) 合成 31 3.1.5 奈米片 (Nanoplates) 鈣鈦礦 37 3.1.6 特殊結構鈣鈦礦 39 3.2 高吸收穩定性之銀奈米粒子 39 3.2.1 微波加熱法 39 3.2.2 Capping agent後添加法 40 3.3 鈣鈦礦發光二極體 40 3.3.1 綠光波長鈣鈦礦發光二極體 40 3.3.2 藍光波長鈣鈦礦發光二極體 41 3.3.3 紅光波長鈣鈦礦發光二極體 41 3.3.4 本研究高 EQE 綠光發光二極體 42 3.4 以 hc-ester P.V.S.K. 製備柔性可撓式發光二極體 43 3.5 PDMS軟板基材之可拉伸鈣鈦礦薄膜 43 研究鑑定分析 44 3.6 鈣鈦礦與polymer ion-dipole interaction 及 ligand bonding分析 44 3.6.1 傅立葉轉換紅外光譜Fourier transform infrared spectroscopy (FTIR) 44 3.6.2 核磁共振光譜 Nuclear magnetic resonance spectroscopy (NMR) 46 3.6.3 X-ray光電子能譜 X-ray photoelectron spectroscopy (XPS) 47 3.6.4 動態光散射Dynamic light scattering DLS及界達電位 Zeta potential 49 3.6.5 流變 Rheology 51 3.7 鈣鈦礦結晶晶相與orientation分析 53 3.7.1 X光繞射光譜 X-ray diffraction (XRD) 53 3.7.2 掠角入射 X-ray 廣角散射Grazing-incidence wide-angle x-ray scattering (GIWAXS) 54 3.7.3 掠角入射 X-ray 小角散射Grazing-incidence small-angle x-ray scattering (GISAXS) 55 3.7.4 穿透式電子顯微鏡 Transmission electron microscopy (TEM) 57 3.8 鈣鈦礦薄膜表面形貌分析 58 3.8.1 掃描式電子顯微鏡 Scanning electron microscope (SEM) 58 3.8.2 原子力顯微鏡 Atomic force microscopy (AFM) 60 3.8.3 光學顯微鏡 Optical microscope (OM) 61 3.8.4 接觸角 Contact angle 63 3.8.5 缺陷密度 Trap density 64 3.9 鈣鈦礦光學性質分析 65 3.9.1 紫外-可見光光譜 UV-Vis absorption 66 3.9.2 螢光分光光譜儀 Photoluminescence spectroscopy (PL) 及光致發光量子產率 Photoluminescence quantum yield (PLQY) 67 3.9.3 時間解析螢光光譜 Time-resolved photoluminescence spectroscopy (TR-PL) 69 3.9.4 紫外光電子能譜 Ultraviolet photoelectron spectroscopy (UPS) 71 3.10 鈣鈦礦發光二極體性能分析 72 實驗藥品與儀器操作分析參數 72 3.11 使用具有 Förster Resonance Energy Transfer 和 Purcell Effects 的聚己內酯 (PCL)-銀奈米粒子來建構鈣鈦礦發光二極體的發光增益層 72 3.11.1 藥品 72 3.11.2 儀器操作分析參數 73 3.12 透過混摻結晶性酯基聚合物以對準二維鈣鈦礦晶體進行尺寸控制來建構光學邏輯特性 74 3.12.1 藥品 74 3.12.2 儀器操作分析參數 74 第四章 結果與討論 77 4.1 使用具有 Förster Resonance Energy Transfer 和 Purcell Effects 的聚己內酯 (PCL)-銀奈米粒子來建構鈣鈦礦發光二極體的發光增益層 77 4.1.1 Homogeneous 銀奈米粒子 (AgNPs) 的製備 77 4.1.2 AgNPs 的吸收長期穩定性 83 4.1.3 AgNPs 薄膜的表面形貌 86 4.1.4 用於強 Förster Resonance Energy Transfer 的發光增益層 89 4.1.5 使用 PCL@AgNPs-P 層製造具有高效輻射發光的 PeLED 95 4.2 透過混摻結晶性酯基聚合物以對準二維鈣鈦礦晶體進行尺寸控制來建構光學邏輯特性 99 4.2.1 酯基聚合物與鈣鈦礦之間的 ion-dipole interaction 99 4.2.2 不同結晶性酯基聚合物與鈣鈦礦產生 ion-dipole interaction 後之鏈動態行為 104 4.2.3 Ion-dipole interaction對於酯基聚合物-鈣鈦礦複合物結晶性行為之影響 109 4.2.4 酯基聚合物-鈣鈦礦複合物之光學性質探討 114 4.2.5 酯基聚合物-鈣鈦礦複合物之發光二極體應用 119 4.2.6 具邏輯放光訊號的柔性動態響應元件 123 第五章 結論 132 5.1 使用具有 Förster Resonance Energy Transfer 和 Purcell Effects 的聚己內酯 (PCL)-銀奈米粒子來建構鈣鈦礦發光二極體的發光增益層-結論 132 5.2 透過混摻結晶性酯基聚合物以對準二維鈣鈦礦晶體進行尺寸控制來建構光學邏輯特性-結論 132 第六章 未來展望 134 第七章 參考文獻 135 附錄 145 | - |
| dc.language.iso | zh_TW | - |
| dc.subject | 離子-偶極作用力 | zh_TW |
| dc.subject | 激子能量轉移 | zh_TW |
| dc.subject | 螢光共振能量轉移 | zh_TW |
| dc.subject | 聚己內酯 | zh_TW |
| dc.subject | 鈣鈦礦發光二極體 | zh_TW |
| dc.subject | 柔性光電元件 | zh_TW |
| dc.subject | 珀塞爾效應 | zh_TW |
| dc.subject | Exciton energy transfer | en |
| dc.subject | Perovskite light-emitting diodes | en |
| dc.subject | Flexible optoelectronic devices | en |
| dc.subject | Polycaprolactone | en |
| dc.subject | Förster Resonance Energy Transfer | en |
| dc.subject | Purcell effect | en |
| dc.subject | Ion-dipole interaction | en |
| dc.title | 以酯基聚合物構建無機鹵化物鈣鈦礦之放光增益與邏輯特性 | zh_TW |
| dc.title | Framing the Emission Gain and Logic Characteristics of All Inorganic Halide Perovskite via Ester-Based Polymers | en |
| dc.type | Thesis | - |
| dc.date.schoolyear | 113-1 | - |
| dc.description.degree | 博士 | - |
| dc.contributor.coadvisor | 郭霽慶 | zh_TW |
| dc.contributor.coadvisor | Chi-Ching Kuo | en |
| dc.contributor.oralexamcommittee | 童世煌;闕居振;劉偉仁;黃英治 | zh_TW |
| dc.contributor.oralexamcommittee | Shih-Huang Tung;Chu-Chen Chueh;Wei-Ren Liu;Ying-Chi Huang | en |
| dc.subject.keyword | 鈣鈦礦發光二極體,柔性光電元件,聚己內酯,螢光共振能量轉移,珀塞爾效應,離子-偶極作用力,激子能量轉移, | zh_TW |
| dc.subject.keyword | Perovskite light-emitting diodes,Flexible optoelectronic devices,Polycaprolactone,Förster Resonance Energy Transfer,Purcell effect,Ion-dipole interaction,Exciton energy transfer, | en |
| dc.relation.page | 153 | - |
| dc.identifier.doi | 10.6342/NTU202500350 | - |
| dc.rights.note | 同意授權(限校園內公開) | - |
| dc.date.accepted | 2025-02-04 | - |
| dc.contributor.author-college | 工學院 | - |
| dc.contributor.author-dept | 高分子科學與工程學研究所 | - |
| dc.date.embargo-lift | 2027-02-03 | - |
| 顯示於系所單位： | 高分子科學與工程學研究所 | |
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