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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 金必耀 | zh_TW |
| dc.contributor.advisor | Bih-Yaw Jin | en |
| dc.contributor.author | 林彥廷 | zh_TW |
| dc.contributor.author | Yen-Ting Lin | en |
| dc.date.accessioned | 2024-09-25T16:35:30Z | - |
| dc.date.available | 2024-09-26 | - |
| dc.date.copyright | 2024-09-25 | - |
| dc.date.issued | 2024 | - |
| dc.date.submitted | 2024-09-04 | - |
| dc.identifier.citation | [1] Sarma, D. D.; Shukla, A. K. Building Better Batteries: A Travel Back in Time. ACS Energy Lett. 2018, 3, 2841–2845.
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/96008 | - |
| dc.description.abstract | 近年穿戴式裝置與電動車之發展，對於電池之需求逐漸上升，因兩者皆具移動性，降低電池重量以增加裝置之輕便性與電動車之續航力即為急需解決之問題，如何提升電池之能量密度與安全性為目前研究重要之方向。
本研究於鹵化物型固態電解質鋰銦氯(Li3InCl6)進行雙摻雜改質，摻雜鋯離子取代銦離子以增加固態電解質之離子導率，並摻雜氟離子取代氯離子以增加其電化學窗口。因摻雜氟離子將降低固態電解質之離子導率，故本研究以Li2.9In0.9Zr0.1Cl5.2F0.8作為固態電解質，其離子導率可達5.96 × 10-4 S/cm，與純鋰銦氯與純摻氟離子之固態電解質相比，其具較高之離子導率，同時其可抑制電解質於高電壓之氧化反應，降低副反應之問題。雙摻雜結構與純鋰銦氯相比，對稱電池可得較低之過電位與較長之循環壽命。 本研究亦對鎳錳酸鋰陰極(LiNi0.5Mn1.5O4; LNMO)與Li2.9In0.9Zr0.1Cl5.2F0.8進行界面反應研究，以X光電子能譜儀證實無序相鎳錳酸鋰陰極(disordered-LNMO)與Li2.9In0.9Zr0.1Cl5.2F0.8將產生副反應，形成銦金屬與Mn4+，然而若於LNMO表面包覆磷酸鋰(Li3PO4; LPO)則可抑制副反應發生。 最後本研究以鈷酸鋰(LiCoO2; LCO)與LNMO陰極組裝全電池。以Li2.9In0.9Zr0.1Cl5.2F0.8作為固態電解質之全固態LCO電池，其首圈電容為140 mAh且庫倫效率為90%，與純鋰銦氯與摻氟之結果相比可得較好循環穩定性與較高之電容。而以LNMO作為陰極之全固態電池，有序相鎳錳酸鋰(ordered-LNMO)因其離子導率較低，其組裝之固態電池因阻抗過高無法進行充放電，而disordered-LNMO包覆Li3PO4之陰極可得更高之電容，其首圈電容為78 mAh/g且庫倫效率為86%，其相較於僅摻氟之電池具較佳之電池表現。 | zh_TW |
| dc.description.abstract | In recent years, the development of wearable devices and electric vehicles has increasingly demanded batteries due to their need for mobility. Reducing battery weight to enhance the portability of devices and the endurance of electric vehicles is a critical issue that needs to be addressed. The enhancement of battery energy density and safety is currently a major focus of research.
This study modifies halide-type solid electrolyte lithium indium chloride (Li3InCl6) through dual doping to increase its ionic conductivity and electrochemical window. Considering that doping with fluorine ions may reduce the ionic conductivity, this study uses a dual-doped lithium indium chloride formulation, Li2.9In0.9Zr0.1Cl5.2F0.8, achieving an ionic conductivity of 5.96 × 10-4 S/cm, surpassing the results obtained with pure lithium indium chloride. This research assembles full batteries using lithium cobalt oxide (LiCoO2; LCO) and LNMO cathodes. A solid-state LCO battery using Li2.9In0.9Zr0.1Cl5.2F0.8 as the electrolyte shows a first-cycle capacity and coulombic efficiency superior to those obtained with pure lithium indium chloride and fluorine-doped lithium indium chloride. With LNMO as the cathode, the solid-state battery assembled using ordered LNMO has too high an impedance for charging and discharging due to its lower ionic conductivity. However, a cathode of disordered LNMO coated with Li3PO4 achieves a higher capacity compared to pure disordered LNMO. The novelty of this study lies in the use of dual-doped halide solid electrolyte lithium indium chloride, which not only increases its ionic conductivity but also enhances its electrochemical window. This reduces side reactions at high voltages and also enhances the cycling efficiency of the battery. | en |
| dc.description.provenance | Submitted by admin ntu (admin@lib.ntu.edu.tw) on 2024-09-25T16:35:30Z No. of bitstreams: 0 | en |
| dc.description.provenance | Made available in DSpace on 2024-09-25T16:35:30Z (GMT). No. of bitstreams: 0 | en |
| dc.description.tableofcontents | 口試委員會審定書 I
誌謝 II 摘要 III Abstract IV 目次 V 圖次 VIII 表次 XIII 第一章 緒論 1 1.1電池之演變與原理 1 1.2鋰離子二次電池 4 1.3鋰離子電池之陰極材料 6 1.3.1 鋰鈷氧化物 8 1.3.2 鎳鈷錳酸鋰 11 1.3.3 鎳錳酸鋰 14 1.4鋰離子電池之陽極材料 17 1.4.1 鋰金屬 17 1.4.2石墨烯 18 1.4.3合金 20 1.5液態電解質 23 1.6固態電解質 23 1.6.1鈉超離子型之固態電解質 26 1.6.2硫化物型固態電解質 28 1.6.3聚合物型固態電解質 31 1.6.4鹵化物型固態電解質 34 1.7研究動機與目的 39 第二章 實驗步驟與儀器分析原理 41 2.1 化學藥品 41 2.2 實驗步驟 42 2.2.1雙摻雜鹵化物固態電解質之合成 42 2.2.2磷酸鋰包覆鎳錳酸鋰陰極之合成 43 2.2.3固態鋰離子電池之組裝 43 2.3 儀器分析 44 2.3.1 X光繞射儀(X-ray diffractometer; XRD) 45 2.3.2 掃描式電子顯微鏡(scanning electron microscope; SEM) 46 2.3.3 穿透式電子顯微鏡 (transmission electron microscope; TEM) 48 2.3.4 拉曼光譜儀(Raman spectroscopy) 50 2.3.5 X光吸收光譜(X-ray absorption spectroscopy; XAS) 51 2.3.6 X射線光電子能譜儀(X-ray photoelectron spectroscopy; XPS) 53 2.3.7 線性掃描伏安圖(linear sweep voltammetry; LSV) 54 2.3.8 電化學阻抗譜(electrical impedance spectroscopy; EIS) 55 2.3.9 庫爾特粒徑分析(Coulter particle size analysis) 58 2.3.10 對稱電池測試儀(symmetrical batteries test machine) 59 2.3.11 充放電測試儀(cycling test machine) 60 第三章 結果與討論 61 3.1雙摻雜鹵化物型Li3−xIn1−xZrxCl6−yFy之鑑定 61 3.1.1 Li3−xIn1−xZrxCl6−yFy之X光繞射圖譜鑑定 61 3.1.2 Li3−xIn1−xZrxCl6−yFy之掃描式電子顯微鏡鑑定 62 3.1.3 Li3−xIn1−xZrxCl6−yFy之X光吸收光譜鑑定 65 3.1.4 Li3−xIn1−xZrxCl6−yFy之電化學阻抗譜鑑定 70 3.1.5 Li3−xIn1−xZrxCl6−yFy之線性掃描伏安圖鑑定 74 3.1.6 Li3−xIn1−xZrxCl6−yFy之對稱電池測試 75 3.2磷酸鋰包裹鎳錳酸鋰陰極之鑑定 76 3.2.1 X光繞射圖譜鑑定 77 3.2.2 掃描式電子顯微鏡鑑定 78 3.2.3穿透式電子顯微鏡鑑定 81 3.2.3 庫爾特粒徑分析 81 3.2.4 X射線光電子能譜儀鑑定 83 3.3 全固態電池鑑定 85 3.3.1 臨界電流密度測試 85 3.3.2 LCO陰極充放電測試 86 3.3.3 LNMO陰極充放電測試 88 第四章 結論 90 參考文獻 91 | - |
| dc.language.iso | zh_TW | - |
| dc.title | 應用於鋰離子電池之雙摻雜鹵化物型固態電解質 | zh_TW |
| dc.title | Co-doped Halide-Type Solid-State Electrolyte for Lithium-Ion Batteries | en |
| dc.type | Thesis | - |
| dc.date.schoolyear | 113-1 | - |
| dc.description.degree | 碩士 | - |
| dc.contributor.oralexamcommittee | 劉如熹;王復民;黃瑞雄 | zh_TW |
| dc.contributor.oralexamcommittee | Ru-Shi Liu;Fu-Ming Wang;Rui-Xiong Huang | en |
| dc.subject.keyword | 鹵化物固態電解質,鋰銦氯固態電解質,鋰離子全固態電池, | zh_TW |
| dc.subject.keyword | Halide Solid Electrolyte,Li3InCl6,All-Solid-State Lithium-Ion Battery, | en |
| dc.relation.page | 102 | - |
| dc.identifier.doi | 10.6342/NTU202404346 | - |
| dc.rights.note | 同意授權(全球公開) | - |
| dc.date.accepted | 2024-09-05 | - |
| dc.contributor.author-college | 理學院 | - |
| dc.contributor.author-dept | 化學系 | - |
| 顯示於系所單位： | 化學系 | |
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