請用此 Handle URI 來引用此文件：
http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/93750完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 余柏毅 | zh_TW |
| dc.contributor.advisor | Bor-Yih Yu | en |
| dc.contributor.author | 曾安紘 | zh_TW |
| dc.contributor.author | An-Hung Tseng | en |
| dc.date.accessioned | 2024-08-07T16:59:35Z | - |
| dc.date.available | 2024-12-27 | - |
| dc.date.copyright | 2024-08-07 | - |
| dc.date.issued | 2024 | - |
| dc.date.submitted | 2024-07-03 | - |
| dc.identifier.citation | [1] J. Conti, P. Holtberg, J. Diefenderfer, A. LaRose, J. T. Turnure, and L. Westfall, "International energy outlook 2016 with projections to 2040," USDOE Energy Information Administration (EIA), Washington, DC (United States), 2016.
[2] P. S. Deora, Y. Verma, R. A. Muhal, C. Goswami, and T. Singh, "Biofuels: An alternative to conventional fuel and energy source," Materials Today: Proceedings, vol. 48, pp. 1178-1184, 2022. [3] E. C. Tan, K. Harris, S. M. Tifft, D. Steward, C. Kinchin, and T. N. Thompson, "Adoption of biofuels for marine shipping decarbonization: A long‐term price and scalability assessment," Biofuels, Bioproducts and Biorefining, vol. 16, no. 4, pp. 942-961, 2022. [4] C. R. Chilakamarry, A. M. Sakinah, A. Zularisam, and A. Pandey, "Glycerol waste to value added products and its potential applications," Systems Microbiology and Biomanufacturing, vol. 1, no. 4, pp. 378-396, 2021. [5] U. Abubakar, Y. Bansod, L. Forster, V. Spallina, and C. D'Agostino, "Conversion of glycerol to acrylic acid: a review of strategies, recent developments and prospects," Reaction Chemistry & Engineering, 2023. [6] M. R. Arcanjo et al., "Glycerol valorization: Conversion to lactic acid by heterogeneous catalysis and separation by ion exchange chromatography," Biofuels, Bioproducts and Biorefining, vol. 14, no. 2, pp. 357-370, 2020. [7] I. Zahid et al., "Glycerol conversion to solketal: Catalyst and reactor design, and factors affecting the yield," ChemBioEng Reviews, vol. 8, no. 3, pp. 227-238, 2021. [8] A. Abdullah et al., "A review on recent developments and progress in sustainable acrolein production through catalytic dehydration of bio-renewable glycerol," Journal of Cleaner Production, vol. 341, p. 130876, 2022. [9] "Polyvinyl Alcohol Price Trend and Forecast." CHEMANALYST. https://www.chemanalyst.com/Pricing-data/polyvinyl-alcohol-1108 (accessed. [10] Y. Cui et al., "Poly-acrylic acid grafted natural rubber for multi-coated slow release compound fertilizer: Preparation, properties and slow-release characteristics," International journal of biological macromolecules, vol. 146, pp. 540-548, 2020. [11] X. Ma and G. Wen, "Development history and synthesis of super-absorbent polymers: a review," Journal of Polymer Research, vol. 27, no. 6, p. 136, 2020. [12] M. Pourmadadi et al., "Polyacrylic acid mediated targeted drug delivery nano-systems: A review," Journal of Drug Delivery Science and Technology, vol. 80, p. 104169, 2023. [13] H.-W. Wong, M. C. Cesa, J. T. Golab, J. F. Brazdil, and W. H. Green, "Kinetic modeling to estimate fundamental yield bounds for selective propylene oxidation over bifunctional catalysts," Applied Catalysis A: General, vol. 303, no. 2, pp. 177-191, 2006. [14] J. L. Rodrigues, "Heterologous production of acrylic acid: Current challenges and perspectives," SynBio, vol. 1, no. 1, pp. 3-32, 2022. [15] T. Attarbachi, M. D. Kingsley, and V. Spallina, "New trends on crude glycerol purification: A review," Fuel, vol. 340, p. 127485, 2023. [16] T. S. Hui, S. F. M. Ramle, W. Y. Ching, and Z. A. A. Hamid, "Purification of crude glycerol from waste cooking oil for the production of bio-soap," in AIP Conference Proceedings, 2024, vol. 2750, no. 1: AIP Publishing. [17] A. Abdullah, A. Z. Abdullah, M. Ahmed, P. U. Okoye, and M. Shahadat, "A review on bi/multifunctional catalytic oxydehydration of bioglycerol to acrylic acid: Catalyst type, kinetics, and reaction mechanism," The Canadian Journal of Chemical Engineering, vol. 100, no. 10, pp. 2956-2985, 2022. [18] F. Fernandes Barbosa and T. Pinheiro Braga, "Catalytic Conversion of Glycerol to Acetol and Acrolein Using Metal Oxides: Surface Reactions, Prospects and Challenges," ChemCatChem, vol. 15, no. 2, p. e202200950, 2023. [19] X. Li and Y. Zhang, "Highly efficient process for the conversion of glycerol to acrylic acid via gas phase catalytic oxidation of an allyl alcohol intermediate," ACS Catalysis, vol. 6, no. 1, pp. 143-150, 2016. [20] H. M. Zabed et al., "Biocatalytic gateway to convert glycerol into 3-hydroxypropionic acid in waste-based biorefineries: Fundamentals, limitations, and potential research strategies," Biotechnology Advances, vol. 62, p. 108075, 2023. [21] D. Sun, Y. Yamada, S. Sato, and W. Ueda, "Glycerol as a potential renewable raw material for acrylic acid production," Green Chemistry, vol. 19, no. 14, pp. 3186-3213, 2017. [22] S. T. Wu, Q. M. She, R. Tesser, M. D. Serio, and C. H. Zhou, "Catalytic glycerol dehydration-oxidation to acrylic acid," Catalysis Reviews, vol. 62, no. 4, pp. 481-523, 2020. [23] L. G. Possato, W. H. Cassinelli, T. Garetto, S. H. Pulcinelli, C. V. Santilli, and L. Martins, "One-step glycerol oxidehydration to acrylic acid on multifunctional zeolite catalysts," Applied Catalysis A: General, vol. 492, pp. 243-251, 2015. [24] A. Abdullah, M. Ahmed, D.-V. N. Vo, and A. Z. Abdullah, "Selective Production of Acrylic Acid from Glycerol Through a Single-stage Gas Phase Catalytic Oxydehydration over Vanadium-incorporated Zeolite Beta Catalysts," Waste and Biomass Valorization, vol. 15, no. 1, pp. 163-175, 2024. [25] A. Dimian and C. Bildea, "Sustainable process design for manufacturing acrylic acid from glycerol," Chemical Engineering Research and Design, vol. 166, pp. 121-134, 2021. [26] J. A. Sánchez-Gómez, J. Cabrera-Ruiz, and S. Hernández, "Design and optimization of an intensified process to produce acrylic acid as added product value from glycerol generated in the biodiesel production," Chemical Engineering Research and Design, vol. 184, pp. 543-553, 2022. [27] A. Sandid, J. Esteban, C. D'Agostino, and V. Spallina, "Process assessment of renewable-based acrylic acid production from glycerol valorisation," Journal of Cleaner Production, vol. 418, p. 138127, 2023. [28] J. Stengler, I. Bürger, and M. Linder, "Thermodynamic and kinetic investigations of the SrBr2 hydration and dehydration reactions for thermochemical energy storage and heat transformation," Applied Energy, vol. 277, p. 115432, 2020. [29] X. Zhai, H. Ge, C.-M. Shu, D. Obracaj, K. Wang, and B. Laiwang, "Effect of the heating rate on the spontaneous combustion characteristics and exothermic phenomena of weakly caking coal at the low-temperature oxidation stage," Fuel, vol. 268, p. 117327, 2020. [30] M. Y. Ahmad, S. N. M. Saleh, and A. Z. Abdullah, "One-pot synthesis of acrylic acid from glycerol over SBA-15 supported heteropoly acid catalysts: Influence of mesoporosity and acidity," Applied Catalysis A: General, vol. 670, p. 119534, 2024. [31] A. Talebian-Kiakalaieh and N. A. S. Amin, "Thermo-kinetic and diffusion studies of glycerol dehydration to acrolein using HSiW-γ-Al2O3 supported ZrO2 solid acid catalyst," Renewable Energy, vol. 114, pp. 794-804, 2017. [32] A. Drochner, P. Kampe, J. Kunert, J. Ott, and H. Vogel, "Steady State Isotopic Transient Kinetic Analysis of the acrolein oxidation on Mo–V–W-mixed oxide catalysts," Applied Catalysis A: General, vol. 289, no. 1, pp. 74-83, 2005. [33] H.-J. Zimmermann, "Fuzzy programming and linear programming with several objective functions," Fuzzy sets and systems, vol. 1, no. 1, pp. 45-55, 1978. [34] S. Y. Teh et al., "A hybrid multi-objective optimization framework for preliminary process design based on health, safety and environmental impact," Processes, vol. 7, no. 4, p. 200, 2019. [35] T. Shi et al., "Improved design of heat-pump extractive distillation based on the process optimization and multi-criteria sustainability analysis," Computers & Chemical Engineering, vol. 156, p. 107552, 2022. [36] R. Turton, R. C. Bailie, W. B. Whiting, and J. A. Shaeiwitz, Analysis, synthesis and design of chemical processes. Pearson Education, 2008. [37] H.-H. Chiu and B.-Y. Yu, "Synthesis of green light olefins from direct hydrogenation of CO2. Part I: Techno-economic, decarbonization, and sustainability analyses based on rigorous simulation," Journal of the Taiwan Institute of Chemical Engineers, vol. 156, p. 105340, 2024. [38] F. I. Khan and P. R. Amyotte, "Integrated inherent safety index (I2SI): a tool for inherent safety evaluation," Process safety progress, vol. 23, no. 2, pp. 136-148, 2004. [39] A.-M. Heikkilä, Inherent safety in process plant design: an index-based approach. VTT Technical Research Centre of Finland, 1999. [40] M. Y. Kariduraganavar, S. S. Kulkarni, and A. A. Kittur, "Pervaporation separation of water–acetic acid mixtures through poly (vinyl alcohol)-silicone based hybrid membranes," Journal of Membrane Science, vol. 246, no. 1, pp. 83-93, 2005. [41] Sigma-Aldrich, "SAFETY DATA SHEET ", Sigma-Aldrich, 2023. [42] X. Ge, R. Zhang, P. Liu, B. Liu, and B. Liu, "Optimization and control of extractive distillation for formic acid-water separation with maximum-boiling azeotrope," Computers & Chemical Engineering, vol. 169, p. 108075, 2023. [43] B. Mahida, H. Benyounes, and W. Shen, "Process analysis of pressure-swing distillation for the separation of formic acid–water mixture," Chemical Papers, vol. 75, no. 2, pp. 599-609, 2021. [44] M. Behroozi, M. Vahedpour, and M. Shardi Manaheji, "Separation of formic acid from aqueous solutions by liquid extraction technique at different temperatures," Physical Chemistry Research, vol. 7, no. 1, pp. 201-215, 2019. [45] A. Lucia, A. Amale, and R. Taylor, "Distillation pinch points and more," Computers & Chemical Engineering, vol. 32, no. 6, pp. 1342-1364, 2008. [46] T. Attarbachi, M. Kingsley, and V. Spallina, "Experimental Scale-Up and Technoeconomic Assessment of Low-Grade Glycerol Purification from Waste-Based Biorefinery," Industrial & Engineering Chemistry Research, vol. 63, no. 11, pp. 4905-4917, 2024. [47] C. G. Chol, R. Dhabhai, A. K. Dalai, and M. Reaney, "Purification of crude glycerol derived from biodiesel production process: Experimental studies and techno-economic analyses," Fuel Processing Technology, vol. 178, pp. 78-87, 2018. [48] W. Chua, S. da Cunha, G. Rangaiah, and K. Hidajat, "Design and optimization of Kemira-Leonard process for formic acid production," Chemical Engineering Science: X, vol. 2, p. 100021, 2019. [49] K. T. Ranjit, I. Willner, S. Bossmann, and A. Braun, "Iron (III) phthalocyanine-modified titanium dioxide: A novel photocatalyst for the enhanced photodegradation of organic pollutants," The Journal of Physical Chemistry B, vol. 102, no. 47, pp. 9397-9403, 1998. [50] Y. W. Gong, X. N. Cheng, and H. X. Zhang, "Photocatalytic degradation of acrylic acid, acrolein and hydroquinone using TiO2 under simulated solar irradiation," Advanced Materials Research, vol. 781, pp. 2129-2132, 2013. [51] businessanalytiq. "Acrylic Acid price index." businessanalytiq. https://businessanalytiq.com/procurementanalytics/index/acrylic-acid/ (accessed. [52] A. Kendall, "Time-adjusted global warming potentials for LCA and carbon footprints," The International Journal of Life Cycle Assessment, vol. 17, pp. 1042-1049, 2012. [53] T. C. Ponsioen, M. D. Vieira, and M. J. Goedkoop, "Surplus cost as a life cycle impact indicator for fossil resource scarcity," The International Journal of Life Cycle Assessment, vol. 19, pp. 872-881, 2014. [54] W. Krewitt, D. W. Pennington, S. I. Olsen, P. Crettaz, and O. Jolliet, "Indicators for human toxicity in life cycle impact assessment," Toward Best Available Practice for Life Cycle Impact Assessment, vol. 123, 2002. [55] W. Gerbens-Leenes, M. Berger, and J. A. Allan, "Water footprint and life cycle assessment: The complementary strengths of analyzing global freshwater appropriation and resulting local impacts," vol. 13, ed: MDPI, 2021, p. 803. [56] A. L. Gade, M. Z. Hauschild, and A. Laurent, "Globally differentiated effect factors for characterising terrestrial acidification in life cycle impact assessment," Science of the Total Environment, vol. 761, p. 143280, 2021. [57] S. Lia, S. Zhilyaevb, D. Gallagherb, J. Subbiahc, and B. Dvoraka, "Sustainability of safe foods: an integrated life cycle assessment of antimicrobial systems in US beef processing." [58] S. Sun, H. Deng, J. Yang, D. Zhou, X. Wan, and F. Han, "Photodegradation of butyl 4-hydroxybenzoate in the presence of peroxides and mediated by dissolved organic matter," Environmental Engineering Science, vol. 37, no. 7, pp. 497-508, 2020. [59] S. Deepracha, A. Ayral, and M. Ogawa, "Acceleration of the photocatalytic degradation of organics by in-situ removal of the products of degradation," Applied Catalysis B: Environmental, vol. 284, p. 119705, 2021. [60] S. Sharma, Z. Chao Lim, and G. P. Rangaiah, "Process design for economic, environmental and safety objectives with an application to the cumene process," Multi‐Objective Optimization in Chemical Engineering: Developments and Applications, pp. 449-477, 2013. | - |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/93750 | - |
| dc.description.abstract | 本研究旨在提出並評估兩種利用來自生質廢棄物粗甘油作為原料的丙烯酸（AA）生產流程。方案1使用丙烯醛作為中間體，而方案2則使用丙烯醇作為中間體。根據流程中可獲得的不同層級資訊，系統性地優化了這兩個流程（方案1以三個目標進行優化，方案2以單一目標進行優化）。在技術經濟評估方面，方案2的最低所需銷售價格（MRSP）為每公斤2.122美元，略優於方案1的每公斤2.537美元。這兩個數值都明顯高於以丙烯為原料的傳統製程的市場價格（每公斤1.24至1.32美元）。隨後，進行了從搖籃到大門的生命週期評估，並在五個影響類別（即全球暖化潛力、化石資源稀缺性、人體非致癌毒性、用水量和陸地酸化）中對這些流程進行比較。我們觀察到，如果能解決丙烯醛在廢水中殘留的問題，方案1可以比方案2和傳統製程更具可持續性。相反，方案2即使與傳統製程相比也遠不環保，主要原因是使用甲酸作為共反應物。 | zh_TW |
| dc.description.abstract | This study aims to propose and evaluate two acrylic acid (AA) production processes that utilize bio-based crude glycerol as a feedstock. Scheme 1 employs acrolein as an intermediate, while Scheme 2 utilizes allyl alcohol as an intermediate. Both processes were systematically optimized based on varying levels of information available in the process (i.e. three objectives for Scheme 1, single objective for Scheme 2). From a techno-economic evaluation, Scheme 2 (2.122 USD/kg) slightly outperforms Scheme 1 (2.537 USD/kg) in terms of the minimum required selling price (MRSP). Both values are significantly higher than the market price (1.24 to 1.32 USD/kg) based on the conventional process that uses propene as a feedstock. Subsequently, a cradle-to-gate life cycle assessment was conducted to compare these processes across five impact categories (i.e., global warming potential, fossil source scarcity, human non-carcinogenic toxicity, water consumption, and terrestrial acidification). We have observed that Scheme 1 can be more sustainable than Scheme 2 and the conventional process if the issue associated with the acrolein left in the wastewater can be addressed. In contrast, Scheme 2 is far from environmentally friendly even compared to the conventional process, primarily because of the use of formic acid as a co-reactant. | en |
| dc.description.provenance | Submitted by admin ntu (admin@lib.ntu.edu.tw) on 2024-08-07T16:59:35Z No. of bitstreams: 0 | en |
| dc.description.provenance | Made available in DSpace on 2024-08-07T16:59:35Z (GMT). No. of bitstreams: 0 | en |
| dc.description.tableofcontents | 誌謝 i
中文摘要 ii ABSTRACT iii CONTENTS iv LIST OF FIGURES vi LIST OF TABLES vii Chapter 1 Introduction 1 1.1 Background 1 1.2 Glycerol as a Feedstock for Acrylic Acid: Potential and Challenges 1 1.3 Motivation 2 Chapter 2 Overview 4 2.1 Physical properties and reaction kinetics for the acrolein path (Scheme 1) 4 2.2 Physical properties and reaction kinetics(Allyl alcohol path) 6 2.3 Optimization 7 Chapter 3 Process development 10 3.1 Process design of Scheme 1 10 3.2 Process design of Scheme 2 16 Chapter 4 Result and discussion 20 4.1 Techno-Economic Analysis 20 4.2 Life Cycle Assessment 26 4.2.1 System Boundary 27 4.2.2 Life Cycle Inventory (LCI) 28 4.2.3 Life Cycle Impact Assessment (LCIA) 29 Chapter 5 Conclusion 33 REFERENCE 35 APPENDIX 46 Section A1. Details for Physical properties and reaction validation 46 Section A2. Details for optimization of two process 51 A2.1 Simulated Annealing algorithm for optimization 51 A2.2 Fuzzy algorithm for optimization 54 A2.3 Detail calculations of Damage Index (DI)[60] 56 Section A3. Details for life cycle assessment 60 Other figures and tables: 62 LIST OF FIGURES Figure 3 1. The detailed flowsheet of the acrolein path 12 Figure 3 2. The temperature profiles of reactors. (a). R1; (b). R2 13 Figure 3 3. The optimization trajectories. 15 Figure 3 4. The optimal flowsheet of the basic allyl alcohol pathway 17 Figure 3 5. The improved flowsheet of the allyl alcohol pathway 18 Figure 4 1. Techno-Economic Analysis 23 Figure 4 2. The sensitivity test results of MRSP for acrolein path and allyl alcohol path 27 Figure 4 3. The system boundary of a cradle-to-gate LCA for acrylic acid production from biorefinery 30 Figure 4 4. Results of cradle-to-gate life cycle impact assessment (LCIA). 33 Figure A-1. The kinetic validation of glycerol dehydration (Step1) in Scheme 1 52 Figure A-2. The kinetic validation of acrolein oxidation (Step2) in Scheme 1 53 Figure A-3. The Flowchart of SAA 56 Figure A-4. Calculation of pn1 60 Figure A-5. Calculation of pn2 60 LIST OF TABLES Table 2 1. Reaction kinetic model for the acrolein pathway (Scheme 1) 5 Table 2 2. Reaction information of the allyl alcohol pathway (Scheme 2) 7 Table 2 3. Information of different grades of steam employed in this study[37] 8 Table 4 1. The financial model for techno-economic evaluation 22 Table 4 2. Utility requirement of AA production 26 Table A-1. The binary interaction parameters for acrolein path (Scheme 1) 49 Table A-2. The binary interaction parameters for allyl alcohol path (Scheme 2) 51 Table A-3. Calculation of pn3 61 Table A-4. Global warming potential (kg/ AA kg) 63 Table A-5. Human non-carcinogenic toxicity (kg 1,4-DCB eq / AA kg) 63 Table A-6. Water consumption (m3/AA kg) 63 Table A-7. Fossil source scarcity (kg oil eq/AA kg) 64 Table A-8. Terrestrial acidification (kg SO2 eq/AA kg) 64 Table A-9. Detailed optimization results of Scheme 1 65 Table A-10. Detailed optimization results for Scheme 2 67 | - |
| dc.language.iso | en | - |
| dc.subject | 丙烯酸 | zh_TW |
| dc.subject | 生命週期評估 | zh_TW |
| dc.subject | 經濟分析 | zh_TW |
| dc.subject | 甘油 | zh_TW |
| dc.subject | 程序強化 | zh_TW |
| dc.subject | process intensification | en |
| dc.subject | glycerol | en |
| dc.subject | techno-economic analysis | en |
| dc.subject | acrylic acid | en |
| dc.title | 粗甘油生產丙烯酸之不同合成路徑分析：嚴格製程設計、技術經濟、及生命週期評估 | zh_TW |
| dc.title | From Crude Glycerol to Acrylic Acid: Analysis of Different Pathways via Rigorous Process Design, Techno-Economic Evaluation, and Life Cycle Assessment | en |
| dc.type | Thesis | - |
| dc.date.schoolyear | 112-2 | - |
| dc.description.degree | 碩士 | - |
| dc.contributor.oralexamcommittee | 謝依芸;李瑞元;陳誠亮;林育正 | zh_TW |
| dc.contributor.oralexamcommittee | I-Yun Lisa Hsieh;Jui-Yuan Lee;Cheng-Liang Chen;Yu-Jeng Lin | en |
| dc.subject.keyword | 甘油,丙烯酸,經濟分析,生命週期評估,程序強化, | zh_TW |
| dc.subject.keyword | glycerol,acrylic acid,techno-economic analysis,process intensification, | en |
| dc.relation.page | 64 | - |
| dc.identifier.doi | 10.6342/NTU202401480 | - |
| dc.rights.note | 同意授權(限校園內公開) | - |
| dc.date.accepted | 2024-07-04 | - |
| dc.contributor.author-college | 工學院 | - |
| dc.contributor.author-dept | 化學工程學系 | - |
| dc.date.embargo-lift | 2029-07-02 | - |
| 顯示於系所單位： | 化學工程學系 | |
文件中的檔案：
| 檔案 | 大小 | 格式 | |
|---|---|---|---|
| ntu-112-2.pdf 未授權公開取用 | 2.19 MB | Adobe PDF | 檢視/開啟 |
系統中的文件，除了特別指名其著作權條款之外，均受到著作權保護，並且保留所有的權利。