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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 駱尚廉 | zh_TW |
| dc.contributor.advisor | Shang-Lien Lo | en |
| dc.contributor.author | 林侑辰 | zh_TW |
| dc.contributor.author | You-Chen Lin | en |
| dc.date.accessioned | 2024-07-30T16:09:07Z | - |
| dc.date.available | 2024-07-31 | - |
| dc.date.copyright | 2024-07-30 | - |
| dc.date.issued | 2024 | - |
| dc.date.submitted | 2024-07-23 | - |
| dc.identifier.citation | Abraham, K., El-Khatib, A. H., Schwerdtle, T., & Monien, B. H. (2021). Perfluorobutanoic acid (PFBA): No high-level accumulation in human lung and kidney tissue. International Journal of Hygiene and Environmental Health, 237, 113830.
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/93365 | - |
| dc.description.abstract | 全氟化合物 (Per and Polyfluoroalkyl Substances, PFAs) 具有疏水、疏油和熱穩定性，此特殊性來自碳鏈上穩定性良好的 C-F 鍵，因此被廣泛應用於各種工業製程及民生產品中。長碳鏈 PFAs（C8）因其持久性和生物累積毒性，各國開始制定政策，逐步以短碳鏈 PFAs（C4）取代，如全氟丁烷磺酸（Perfluorobutanesulfonic Acid, PFBS），有關 C4 對環境的影響和安全性的資料仍不完整，缺乏毒性、生物累積潛力和生物降解性等方面的研究。隨著C4 的使用量增加，其排放量也會隨之上升，從而增加環境和人體的暴露風險。因此，實有必要有效去除C4的方法。
本研究利用強鹼型陰離子交換樹脂(Anion Exchange Resin, IER) 去除水中之 PFBS，分析離子交換樹脂之界達電位、表面結構和組成物質，並研究離子交換樹脂添加量、攪拌速率、pH 值、初始 PFBS 濃度不同參數對去除效果之影響。根據實驗所得到之最佳結果，利用聚乙烯亞胺溶液 (Polyethylenimine,PEI) 研究胺改IER (IER-PEI) 對PFBS之去除影響。研究結果顯示，實驗水溶液pH 值為3.0、攪拌速率400 rpm、初始PFBS濃度100 ppm以及添加4g/L IER-PEI，反應10分鐘後去除率達97.56%，交換量為27.784 mg/g。IER與PFBS進行離子交換符合擬二階反應動力模式，等溫模型模擬結果符合Langmuir等溫模型。 | zh_TW |
| dc.description.abstract | Per and polyfluoroalkyl substances (PFAs) are renowned for their hydrophobic, oleophobic, and thermal stability properties. Their uniqueness stems from the highly stable C-F bonds in their carbon chains, making them widely utilized in various industrial processes and consumer products. Long-chain PFAs (C8), due to their persistence and bioaccumulative toxicity, have led countries to establish policies to gradually replace them with short-chain PFAs (C4), such as perfluorobutanesulfonic acid (PFBS). However, data on the environmental impact and safety of C4 PFAs remain incomplete, lacking research on toxicity, bioaccumulation potential, and biodegradability. With the use of C4 PFAs increases, their emissions will also rise, thereby escalating environmental and human exposure risks. Consequently, developing effective methods for the removal of C4 PFAs has become a crucial area of research and development.
This study utilizes a strong base anion exchange resin (Anion Exchange Resin, IER) to remove PFBS from water. The zeta potential, surface structure, and composition of the ion exchange resin were analyzed. The effects of various parameters, such as the amount of ion exchange resin added, stirring rate, pH value, and initial PFBS concentration, on the removal efficiency were investigated. Based on the optimal results obtained from the experiments, the effect of amine-modified IER (IER-PEI) on PFBS removal was studied using a polyethyleneimine solution (PEI). The research results show that, with a solution pH of 3.0, a stirring rate of 400 rpm, an initial PFBS concentration of 100 ppm, and the addition of 4 g/L IER-PEI, the removal rate reached 97.56% after 10 minutes, with an exchange capacity of 27.784 mg/g. The ion exchange between IER and PFBS follows the pseudo-second-order kinetic model, and the isothermal model simulation results conform to the Langmuir isothermal model. | en |
| dc.description.provenance | Submitted by admin ntu (admin@lib.ntu.edu.tw) on 2024-07-30T16:09:07Z No. of bitstreams: 0 | en |
| dc.description.provenance | Made available in DSpace on 2024-07-30T16:09:07Z (GMT). No. of bitstreams: 0 | en |
| dc.description.tableofcontents | 致謝 ii
摘要 iii Abstract iv 目次 v 圖次 vii 表次 ix 第一章 緒論 1 1.1前言 1 1.2研究目的 2 1.3研究內容 2 第二章 文獻回顧 4 2.1 全氟化合物特性以及相關議題 4 2.2 全氟化合物處理技術 11 2.3離子交換 15 2.3.1離子交換樹脂 15 2.3.2 動力學模型 19 2.4 胺改離子交換樹脂之物質 21 2.4.1 聚乙烯亞胺 21 2.4.2 胺官能化 23 第三章 研究方法 25 3.1 研究架構 25 3.2 實驗方法設計 27 3.3 實驗藥品 30 3.4 實驗儀器與設備 30 3.5 分析儀器 30 第四章 結果與討論 37 4.1 背景實驗 37 4.1.1 器材吸附實驗 37 4.1.2 緩衝溶液空白實驗 38 4.2 離子交換樹脂物化性質分析 39 4.2.1 界達電位分析 39 4.2.2 傅立葉紅外光譜儀 40 4.2.3掃描式電子顯微鏡分析 41 4.3 實驗操作之參數 47 4.3.1 離子交換樹脂添加量之影響 47 4.3.2 攪拌速率之影響 49 4.3.3 pH值之影響 50 4.3.4 PFBS初始濃度之影響 51 4.4胺改離子交換樹脂實驗 54 4.4.1 PEI濃度實驗 54 4.4.2 浸泡時間實驗 55 4.4.3 PEI溶液pH實驗 56 4.5反應動力學模型 59 4.6等溫反應模型 59 第五章 結論與建議 63 5.1結論 63 5.2 建議 63 參考文獻 65 附錄 實驗數據 71 | - |
| dc.language.iso | zh_TW | - |
| dc.subject | 聚乙烯亞胺 | zh_TW |
| dc.subject | 全氟丁烷磺酸 | zh_TW |
| dc.subject | 離子交換樹脂 | zh_TW |
| dc.subject | Polyethylenimine | en |
| dc.subject | Perfluorobutanesulfonic Acid | en |
| dc.subject | Ion Exchange Resin | en |
| dc.title | 陰離子交換樹脂胺官能化對全氟丁烷磺酸去除研究 | zh_TW |
| dc.title | Removal of Perfluorobutanesulfonic Acid by Amine-modified Anion Exchange Resin | en |
| dc.type | Thesis | - |
| dc.date.schoolyear | 112-2 | - |
| dc.description.degree | 碩士 | - |
| dc.contributor.oralexamcommittee | 胡景堯;林進榮 | zh_TW |
| dc.contributor.oralexamcommittee | Ching-Yao Hu;Chin-Jung Lin | en |
| dc.subject.keyword | 全氟丁烷磺酸,離子交換樹脂,聚乙烯亞胺, | zh_TW |
| dc.subject.keyword | Perfluorobutanesulfonic Acid,Ion Exchange Resin,Polyethylenimine, | en |
| dc.relation.page | 75 | - |
| dc.identifier.doi | 10.6342/NTU202402110 | - |
| dc.rights.note | 同意授權(限校園內公開) | - |
| dc.date.accepted | 2024-07-24 | - |
| dc.contributor.author-college | 工學院 | - |
| dc.contributor.author-dept | 環境工程學研究所 | - |
| 顯示於系所單位： | 環境工程學研究所 | |
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