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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 許麗 | zh_TW |
dc.contributor.advisor | Li Xu | en |
dc.contributor.author | 陳冠維 | zh_TW |
dc.contributor.author | Kuan-Wei Chen | en |
dc.date.accessioned | 2024-03-26T16:16:32Z | - |
dc.date.available | 2024-03-27 | - |
dc.date.copyright | 2024-03-26 | - |
dc.date.issued | 2023 | - |
dc.date.submitted | 2023-11-30 | - |
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dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/92486 | - |
dc.description.abstract | 鈣鈦礦太陽能電池(perovskite solar cell, PSC)因其高光電轉換效率和低成本製程,成為近些年倍受矚目的研究領域。其中,尋找取代傳統透明氧化物(transparent conductive oxide, TCO)電極的材料也是研究的一大方向。奈米銀線(AgNWs)膜因為具高導電率、透明性、易於製備且可製作在柔性基材等優勢,是極具潛力的替代電極材料。然而,鈣鈦礦材料中的鹵素陰離子,會與銀離子進行化學反應,形成不導電的鹵化物,而大大降低鈣鈦礦太陽能電池的光電轉換效率,故需要有保護層添加至元件結構中,以抑制鹵化物的形成。本研究嘗試不同製備保護層的方式,並成功以噴射式大氣電漿系統(atmospheric pressure plasma jet, APPJ)沉積摻雜鎵的氧化鋅(GZO)薄膜作為保護層,且透過電漿頭掃描速度之變化,進行GZO薄膜厚度的調整,成功製作出以AgNWs為前電極的鈣鈦礦太陽能電池,且驗證了不同厚度之GZO對鈣鈦礦材料長晶影響不大。另外,結合連續波雷射焊接技術應用於AgNWs膜,提高了AgNWs的電性,並降低AgNWs膜的粗糙度。經過雷射焊接技術的應用,成功使鈣鈦礦太陽能電池的開路電壓(VOC )與短路電流(JSC)之積平均相對提升了3.3%、填充因子(FF)平均相對提升了8.9%,光電轉換效率(PCE)增加了1%,最高達9.2%。 | zh_TW |
dc.description.abstract | Perovskite solar cells have attracted significant research attention in the recent years owing to their high efficiency and low fabrication cost. Finding alternative materials to replace traditional transparent conductive oxide (TCO) electrodes is one of the research interests. Among these alternatives, silver nanowires (AgNWs) films have gained popularity for their high conductivity, transparency, ease of fabrication, and compatibility with flexible substrates.
However, halide anions present in perovskite materials can chemically react with silver ions, forming non-conductive halides. Therefore, a buffer layer needs to be incorporated into the device structure. In this study, we focuses on the development of buffer layer and successfully utilizes a Ga-doped zinc oxide (GZO) film deposited by an atmospheric pressure plasma jet (APPJ) system. The thickness of the GZO film is adjusted by varying the scanning speed of the plasma head. Perovskite solar cells with AgNWs as front electrodes are fabricated, and optimal thickness is acquired to be an effective barrier without increasing much of electric resistance. Additionally, continuous wave laser nano-welding technology was employed to optimize the electrical properties and surface roughness of AgNW films. Through the application of laser nano-welding technology, the product of open-circuit voltage (VOC) and short-circuit current (JSC) of the perovskite solar cells have been increased by an average of 3.3% relatively, the fill factor (FF) has increased by an average of 8.9% relatively, and the power conversion efficiency (PCE) has improved by 1% absolutely, reaching a maximum of 9.2%. | en |
dc.description.provenance | Submitted by admin ntu (admin@lib.ntu.edu.tw) on 2024-03-26T16:16:32Z No. of bitstreams: 0 | en |
dc.description.provenance | Made available in DSpace on 2024-03-26T16:16:32Z (GMT). No. of bitstreams: 0 | en |
dc.description.tableofcontents | 口試委員會審定書 i
誌謝 ii 中文摘要 iii Abstract iv 目次 vi 圖次 x 表次 xv 第一章 緒論 1 1.1 前言 1 1.2 鈣鈦礦太陽能電池介紹 4 1.2.1 鈣鈦礦結構材料介紹 4 1.2.2 鈣鈦礦太陽能電池元件結構 6 1.3 鈣鈦礦太陽能電池性質介紹 9 1.3.1 光電轉換效率(Power Conversion Efficiency, PCE) 10 1.3.2 短路電流(Short Circuit Current, ISC) 11 1.3.3 開路電壓(Open Circuit Voltage, VOC) 14 1.3.4 填充因子(Fill Factor, FF) 17 第二章 文獻回顧 20 2.1 不同前電極(Front Electrode)材料應用於太陽能電池 20 2.1.1 透明導電氧化物 20 2.1.2 奈米碳材料 21 2.1.3 奈米金屬線 22 2.2 以奈米銀線為前電極需要面對的挑戰 24 2.3 近年以奈米銀線為鈣鈦礦太陽能電池之前電極性能表現 27 2.4 介於奈米銀線與鈣鈦礦材料之間的保護層(Buffer Layer)沉積方式 32 2.4.1 滴塗法(Drop Coating) 32 2.4.2 旋轉塗佈法(Spin Coating) 33 2.4.3 濺鍍法(Sputter) 34 2.5 研究動機 35 第三章 實驗方法與架構 36 3.1 實驗方法 36 3.1.1 奈米銀線膜的置備 36 3.1.2 本實驗中鈣鈦礦太陽能電池元件製作流程 38 3.2 實驗用溶液置備方式 40 3.2.1 AgNWs溶液 40 3.2.2 ZnO 凝膠溶液(Sol-gel) 40 3.2.3 PH1000混和溶液 40 3.2.4 PEDOT:PSS溶液 40 3.2.5 GZO溶液 41 3.2.6 NiO溶液 41 3.2.7 2PACz溶液 41 3.2.8 MAPbI3溶液 41 3.2.9 PC61BM溶液 42 3.2.10 PEI溶液 42 3.3 大氣電漿系統架設與介紹 43 3.3.1 氣體供應系統 46 3.3.2 電力供應系統 47 3.3.3 霧化系統與前驅物 48 3.3.4 移動平台 49 3.3.5 加熱系統 50 3.3.6 電漿噴頭 51 3.4 雷射系統架設與介紹 54 第四章 實驗結果與討論 56 4.1 實驗設計及定義 56 4.2 不同前電極之鈣鈦礦太陽能電池元件 58 4.2.1 氧化銦錫(ITO)作為前電極(Front Electrode) 58 4.2.2 奈米銀線(AgNWs)作為前電極(Front Electrode) 58 4.3 預防碘化銀(AgI)產生在鈣鈦礦太陽能電池元件之實驗設計 60 4.3.1 利用旋轉塗佈法製備sol-gel ZnO作為Buffer Layer 60 4.3.2 利用旋轉塗佈法製備PH1000混和溶液作為Buffer Layer 64 4.3.3 利用大氣電漿沉積摻雜鎵的氧化鋅(GZO)作為Buffer Layer 69 4.4 利用雷射焊接技術應用於AgNWs前電極 83 4.5 本研究製作的所有鈣鈦礦太陽能電池性能總表 87 第五章 結論與未來展望 89 參考文獻 91 附錄 98 | - |
dc.language.iso | zh_TW | - |
dc.title | 開發與優化應用於鈣鈦礦太陽能電池之奈米銀線前電極的保護層 | zh_TW |
dc.title | Development and Optimization of Buffer Layer on Silver Nanowires Front Electrode for Perovskite Solar Cells | en |
dc.type | Thesis | - |
dc.date.schoolyear | 112-1 | - |
dc.description.degree | 碩士 | - |
dc.contributor.oralexamcommittee | 林明澤;劉建豪 | zh_TW |
dc.contributor.oralexamcommittee | Ming-Tzer Lin;Chien-Hao Liu | en |
dc.subject.keyword | 鈣鈦礦太陽能電池,奈米銀線,噴射式大氣電漿系統,保護層,摻雜鎵的氧化鋅,雷射焊接技術, | zh_TW |
dc.subject.keyword | Perovskite Solar Cells,Silver Nanowires,Atmospheric Pressure Plasma Jet System,Buffer Layer,Gallium-doped Zinc Oxide,Laser Nano-welding Technology, | en |
dc.relation.page | 109 | - |
dc.identifier.doi | 10.6342/NTU202304458 | - |
dc.rights.note | 同意授權(全球公開) | - |
dc.date.accepted | 2023-11-30 | - |
dc.contributor.author-college | 工學院 | - |
dc.contributor.author-dept | 機械工程學系 | - |
顯示於系所單位: | 機械工程學系 |
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