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DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 梁文傑 | zh_TW |
dc.contributor.advisor | Man-Kit Leung | en |
dc.contributor.author | 宋品儀 | zh_TW |
dc.contributor.author | Pin-Yi Sung | en |
dc.date.accessioned | 2024-02-23T16:20:00Z | - |
dc.date.available | 2024-02-24 | - |
dc.date.copyright | 2024-02-23 | - |
dc.date.issued | 2023 | - |
dc.date.submitted | 2023-09-12 | - |
dc.identifier.citation | 1. Blackman LD, Gunatillake PA, Cass P, Locock KES. An introduction to zwitterionic polymer behavior and applications in solution and at surfaces. Chem Soc Rev. 2019;48(3):757-770.
2. 4-Hydroxy-1-butanesulfonic acid sultone [1-Butanesulfonic acid, 4-hydroxy-, δ-sultone]". Org. Synth. 1957, 37, 55 3. Jin Z, Zhao Y, Sun Y, et al. Structural basis for the inhibition of SARS-CoV-2 main protease by antineoplastic drug carmofur. Nat Struct Mol Biol. 2020;27(6):529-532. 4. Gregory GJ, Boas KE, Boyd EF. The organosulfur compound dimethylsulfoniopropionate (DMSP) is utilized as an osmoprotectant by Vibrio species. Appl Environ Microbiol. 2021;87(5):e02235-20. 5. Edmonds JS, Francesconi KA. Methylated arsenic from marine fauna. Nature. 1977;265(5593):436. 6. Lenky CC, McEntyre CJ, Lever M. Measurement of marine osmolytes in mammalian serum by liquid chromatography-tandem mass spectrometry. Anal Biochem. 2012;420(1):7-12. 7. Quan WY, Hu Z, Liu HZ, et al. Mussel-Inspired Catechol-Functionalized Hydrogels and Their Medical Applications. Molecules. 2019;24(14):2586. 8. Wilker JJ. Marine bioinorganic materials: mussels pumping iron. Curr Opin Chem Biol. 2010;14(2):276-283. 9. Monahan J, Wilker JJ. Cross-linking the protein precursor of marine mussel adhesives: bulk measurements and reagents for curing. Langmuir. 2004;20(9):3724-3729. 10. Monahan J, Wilker JJ. Specificity of metal ion cross-linking in marine mussel adhesives. Chem Commun (Camb). 2003;(14):1672-1673. 11. Burzio LA, Waite JH. Cross-linking in adhesive quinoproteins: studies with model decapeptides. Biochemistry. 2000;39(36):11147-11153. 12. Lee BP, Dalsin JL, Messersmith PB. Synthesis and gelation of DOPA-modified poly(ethylene glycol) hydrogels. Biomacromolecules. 2002;3(5):1038-1047 13. Quan WY, Hu Z, Liu HZ, Ouyang QQ, Zhang DY, Li SD, Li PW, Yang ZM. Mussel-Inspired Catechol-Functionalized Hydrogels and Their Medical Applications. Molecules. 2019 Jul 16;24(14):2586. 14. Skelton S., Bostwick M., O’Connor K., Konst S., Casey S., Lee B.P. Biomimetic adhesive containing nanocomposite hydrogel with enhanced materials properties. Soft Matter. 2013;9:3825–3833. 15. Waite J.H., Tanzer M.L. Polyphenolic substance of Mytilus edulis: Novel adhesive containing l-dopa and hydroxyproline. Science. 1981 16. Carrington E. Seasonal variation in the attachment strength of blue mussels: Causes and consequences. Limnol. Oceanogr. 2002;47:1723–1733. 17. Waite J.H. The phylogeny and chemical diversity of quinone-tanned glues and varnishes. Comp. Biochem. Physiol. Part. B Comp. Biochem. 1990;97:19–29. 18. Zhang M, Yu P, Xie J, Li J. Recent advances of zwitterionic-based topological polymers for biomedical applications. J Mater Chem B. 2022;10(14):2338-2356. 19. Shindhal T, Rakholiya P, Varjani S, et al. A critical review on advances in the practices and perspectives for the treatment of dye industry wastewater. Bioengineered. 2021;12(1):70-87. 20. Tkaczyk A, Mitrowska K, Posyniak A. Synthetic organic dyes as contaminants of the aquatic environment and their implications for ecosystems: A review. Sci Total Environ. 2020;717:137222. 21. Dassanayake RS, Acharya S, Abidi N. Recent Advances in Biopolymer-Based Dye Removal Technologies. Molecules. 2021;26(15):4697. 22. Benkhaya S, M'rabet S, El Harfi A. Classifications, properties, recent synthesis and applications of azo dyes. Heliyon. 2020;6(1):e03271. 23. Vara J, Ortiz CS. Thiazine dyes: Evaluation of monomeric and aggregate forms. Spectrochim Acta A Mol Biomol Spectrosc. 2016;166:112-120. 24. Qin Q, Ma J, Liu K. Adsorption of anionic dyes on ammonium-functionalized MCM-41. J Hazard Mater. 2009;162(1):133-139. 25. Jiang Y, Krishnan N, Heo J, Fang RH, Zhang L. Nanoparticle-hydrogel superstructures for biomedical applications. J Control Release. 2020;324:505-521. 26. Verma AK, Dash RR, Bhunia P. A review on chemical coagulation/flocculation technologies for removal of colour from textile wastewaters. J Environ Manage. 2012;93(1):154-168. 27. Piaskowski K, Świderska-Dąbrowska R, Zarzycki PK. Dye Removal from Water and Wastewater Using Various Physical, Chemical, and Biological Processes. J AOAC Int. 2018;101(5):1371-1384. 28. Zhou Y, Lu J, Zhou Y, Liu Y. Recent advances for dyes removal using novel adsorbents: A review. Environ Pollut. 2019;252(Pt A):352-365. 29. Chakraborty G, Bhattarai A, De R. Polyelectrolyte-Dye Interactions: An Overview. Polymers (Basel). 2022;14(3):598. 30. Qu Y, Lin L, Gao S, et al. A molecular dynamics study on adsorption mechanisms of polar, cationic, and anionic polymers on montmorillonite. RSC Adv. 2023;13(3):2010-2023. 31. He M, Shi L, Wang G, et al. Biocompatible and biodegradable chitosan/sodium polyacrylate polyelectrolyte complex hydrogels with smart responsiveness. Int J Biol Macromol. 2020;155:1245-1251. 32. Rodrigues MN, Oliveira MB, Costa RR, Mano JF. Chitosan/Chondroitin Sulfate Membranes Produced by Polyelectrolyte Complexation for Cartilage Engineering. Biomacromolecules. 2016;17(6):2178-2188. 33. Dähling C, Lotze G, Drechsler M, Mori H, Pergushov DV, Plamper FA. Temperature-induced structure switch in thermo-responsive micellar interpolyelectrolyte complexes: toward core-shell-corona and worm-like morphologies. Soft Matter. 2016;12(23):5127-5137. 34. Seymour JR, Simó R, Ahmed T, Stocker R. Chemoattraction to dimethylsulfoniopropionate throughout the marine microbial food web. Science. 2010;329(5989):342-345. 35. Curson AR, Liu J, Bermejo Martínez A, et al. Dimethylsulfoniopropionate biosynthesis in marine bacteria and identification of the key gene in this process. Nat Microbiol. 2017;2:17009. 36. Li M, Zhuang B, Yu J. Functional Zwitterionic Polymers on Surface: Structures and Applications. Chem Asian J. 2020;15(14):2060-2075. 37. Li Q, Wen C, Yang J, et al. Zwitterionic Biomaterials. Chem Rev. 2022;122(23):17073-17154. 38. Keith LH. Recent advances in the identification and analysis of organic pollutants in water. Life Sci. 1976;19(11):1631-1635. 39. Blachnio M., Budnyak T.M., Derylo-Marczewska A., Marczewski A.W., Tertykh V.A. Chitosan-Silica Hybrid Composites for Removal of Sulfonated Azo Dyes from Aqueous Solutions. Langmuir. 2018;34:2258–2273. 40. Sekar S., Surianarayanan M., Ranganathan V., Macfarlane D.R., Mandal A.B. Choline-Based Ionic Liquids-Enhanced Biodegradation of Azo Dyes. Environ. Sci. Technol. 2012;46:4902–4908. 41. Rehman TU, Shah LA, Khan M, Irfan M, Khattak NS. Zwitterionic superabsorbent polymer hydrogels for efficient and selective removal of organic dyes. RSC Adv. 2019;9(32):18565-18577. 42. Azari A, Nabizadeh R, Nasseri S, Mahvi AH, Mesdaghinia AR. Comprehensive systematic review and meta-analysis of dyes adsorption by carbon-based adsorbent materials: Classification and analysis of last decade studies. Chemosphere. 2020;250:126238. 43. Saeed M, Muneer M, Haq AU, Akram N. Photocatalysis: an effective tool for photodegradation of dyes-a review. Environ Sci Pollut Res Int. 2022;29(1):293-311. 44. Fan Y, Liu HJ, Zhang Y, Chen Y. Adsorption of anionic MO or cationic MB from MO/MB mixture using polyacrylonitrile fiber hydrothermally treated with hyperbranched polyethylenimine. J Hazard Mater. 2015;283:321-328. 45. Plazinski W, Rudzinski W, Plazinska A. Theoretical models of sorption kinetics including a surface reaction mechanism: a review. Adv Colloid Interface Sci. 2009;152(1-2):2-13. 46. Rudzinski W, Plazinski W. Kinetics of solute adsorption at solid/solution interfaces: a theoretical development of the empirical pseudo-first and pseudo-second order kinetic rate equations, based on applying the statistical rate theory of interfacial transport. J Phys Chem B. 2006;110(33):16514-16525. 47. Rudzinski W, Plazinski W. Kinetics of solute adsorption at solid/solution interfaces: on the special features of the initial adsorption kinetics. Langmuir. 2008;24(13):6738-6744. 48. Martins LR, Catone Soares L, Alves Gurgel LV, Gil LF. Use of a new zwitterionic cellulose derivative for removal of crystal violet and orange II from aqueous solutions. J Hazard Mater. 2022;424(Pt B):127401. 49. Gurgel LV, Júnior OK, Gil RP, Gil LF. Adsorption of Cu(II), Cd(II), and Pb(II) from aqueous single metal solutions by cellulose and mercerized cellulose chemically modified with succinic anhydride. Bioresour Technol. 2008;99(8):3077-3083. 50. Xu S, Zheng K, Boruntea CR, et al. Surface barriers to mass transfer in nanoporous materials for catalysis and separations [published online ahead of print, 2023 Jun 6]. Chem Soc Rev. 2023;10.1039/d2cs00627h. 51. Ahmad A, Rafatullah M, Sulaiman O, Ibrahim MH, Hashim R. Scavenging behaviour of meranti sawdust in the removal of methylene blue from aqueous solution. J Hazard Mater. 2009;170(1):357-365. 52. Nakajima-Kambe T, Shigeno-Akutsu Y, Nomura N, Onuma F, Nakahara T. Microbial degradation of polyurethane, polyester polyurethanes and polyether polyurethanes. Appl Microbiol Biotechnol. 1999;51(2):134-140. 53. Barrios CA. Pressure Sensitive Adhesive Tape: A Versatile Material Platform for Optical Sensors. Sensors (Basel). 2020;20(18):5303. 54. Yang CW. Synthesis of a Novel Biomimetic Waterborne Polyester Adhesive and the Potential of Three Terephthaloyl Polymers as Electrochromic Materials. 2020. 55. Back JH, Kwon Y, Kim HJ, Yu Y, Lee W, Kwon MS. Visible-Light-Curable Solvent-Free Acrylic Pressure-Sensitive Adhesives via Photoredox-Mediated Radical Polymerization. Molecules. 2021;26(2):385. 56. Ye SH, Hong Y, Sakaguchi H, et al. Nonthrombogenic, biodegradable elastomeric polyurethanes with variable sulfobetaine content. ACS Appl Mater Interfaces. 2014;6(24):22796-22806. 57. Hong Y, Guan J, Fujimoto KL, Hashizume R, Pelinescu AL, Wagner WR. Tailoring the degradation kinetics of poly(ester carbonate urethane)urea thermoplastic elastomers for tissue engineering scaffolds. Biomaterials. 2010;31(15):4249-4258. 58. Driessen-Mol A, Emmert MY, Dijkman PE, et al. Transcatheter implantation of homologous "off-the-shelf" tissue-engineered heart valves with self-repair capacity: long-term functionality and rapid in vivo remodeling in sheep. J Am Coll Cardiol. 2014;63(13):1320-1329. 59. Semsarilar M, Perrier S. 'Green' reversible addition-fragmentation chain-transfer (RAFT) polymerization. Nat Chem. 2010;2(10):811-820. 60. Bouchékif H, Narain R. Reversible addition-fragmentation chain transfer polymerization of N-isopropylacrylamide: a comparison between a conventional and a fast initiator. J Phys Chem B. 2007;111(38):11120-11126. 61. Zhang X, Liu L, Peng W, et al. Phosphonate/zwitterionic/cationic terpolymers as high-efficiency bactericidal and antifouling coatings for metallic substrates. J Mater Chem B. 2021;9(20):4169-4177. 62. Huang T, Liu H, Liu P, Liu P, Li L, Shen J. Zwitterionic copolymers bearing phosphonate or phosphonic motifs as novel metal-anchorable anti-fouling coatings. J Mater Chem B. 2017;5(27):5380-5389. 63. Kim JW, Noh JH, Lee S, et al. The First Total Synthesis of 2,3,6-Tribromo-4,5-dihydroxybenzylMethyl Ether (TDB) and Its Antioxidant Activity. Bull. Korean Chem. Soc. 2002;23(5):661-662. 64. Merck. Reagents, Chemicals and Labware. Lab Filtration. Filter Holders and Accessories. Glass Microanalysis Filter Holders. Accessed June 14, 2023. Glass Microanalysis Filter Holders - Filter Holders and Accessories (merckmillipore.com) 65. Matos-Pérez CR, Wilker JJ. Ambivalent Adhesives: Combining Biomimetic Cross-Linking With Antiadhesive Oligo(ethylene glycol). Macromolecules. 2012;45(16):6634-6639. 66. Jenkins CL, Siebert HM, and Wilker JJ. Integrating Mussel Chemistry into a Bio-Based Polymer to Create Degradable Adhesives. Macromolecules. 2017; 50(2): 561–568. 67. Blackwell M, Kang H, Thomas A, Infante P. Formaldehyde: evidence of carcinogenicity. Am Ind Hyg Assoc J. 1981;42(7): A34, A36, A38, passim. 68. Chiao YH, Sengupta A, Ang MBMY, et al. Application of Zwitterions in Forward Osmosis: A Short Review. Polymers (Basel). 2021;13(4):583. 69. Belfort G. Membrane Filtration with Liquids: A Global Approach with Prior Successes, New Developments and Unresolved Challenges. Angew. Chem. Int. Ed. 2018;58:1892–1902. 70. Lin W., Klein J. Control of surface forces through hydrated boundary layers. Curr. Opin. Colloid Interface Sci. 2019;44:94–106. 71. Gantrade & Chemical Industry News. Chemicals & Polymers Blog. Methylene Diphenyl Diisocyanate (MDI) - Essential Building Blocks for Polyurethanes. November 2, 2018. Accessed June 18, 2023. Methylene Diphenyl Diisocyanate (MDI) - Essential Building Blocks for Polyurethanes (gantrade.com) 72. Klitsche F, Ramcke J, Migenda J, et al. Synthesis of tripodal catecholates and their immobilization on zinc oxide nanoparticles. Beilstein J Org Chem. 2015;11:678-686. 73. Kocieński PJ. Chapter 3: Diol Protecting Groups. In: Kocieński PJ, ed. Protecting Groups. 3rd ed. Thieme Medical Publishers; 2005:120-123. 74. Meltzer PC, McPhee M, Madras BK. Synthesis and biological activity of 2-carbomethoxy-3-catechol-8-azabicyclo[3.2.1]octanes. Bioorg Med Chem Lett. 2003;13(22):4133-4137. 75. Mylène L, Andrew K, Shaun DA, Boulos Z. Practical Cleavage of Acetals by Using an Odorless Thiol Immobilized on Silica. Eur J Org Chem. 2019;44: 7389–7393. 76. Kathryn CG, Brian TG, John FQ. Mild, versatile, and chemoselective indium(III) triflate-catalyzed deprotection of acetonides under microwave heating conditions. Tetrahedron Lett. 2010;51(31):4010-4013. 77. Cabiddu S, Maccioni A, Piras PP, Secci M. Metalation reactions. III. The action of n-butyllithium on 1,3-benzodioxole and 1,3-benzoxathiole derivatives. J Organomet Chem. 1977;136(2):139-146. 78. Zhiping X, Mechanics of metal-catecholate complexes: The roles of coordination state and metal types. Scientific Reports. 2013; 3(1):2914. 79. Woo KM, Jung HM, Oh JH, et al. Synergistic effects of dimethyloxalylglycine and butyrate incorporated into α-calcium sulfate on bone regeneration. Biomaterials. 2015;39:1-14. 80. Simpson J, Forrester R, Tisdale MJ, Billington DC, Rathbone DL. Effect of catechol derivatives on cell growth and lipoxygenase activity. Bioorg Med Chem Lett. 2003;13(15):2435-2439. 81. Matos-Pérez CR, White JD, Wilker JJ. Polymer composition and substrate influences on the adhesive bonding of a biomimetic, cross-linking polymer. J Am Chem Soc. 2012;134(22):9498-9505. | - |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/91860 | - |
dc.description.abstract | 本篇論文以二苯基甲烷二異氰酸酯做異氰酸酯官能基提供者,與帶有二元羥基的N-甲基二乙醇胺和自製含2,2-二甲基-1,3-苯並二氧戊環的三級胺化合物 (命名Cpd2) 分別進行加成聚合出聚氨酯同聚物,另結合兩者,以3:7之比例加成聚合出聚氨酯共聚物。
二苯基甲烷二異氰酸酯與N-甲基二乙醇胺同聚物以1,3-丙烷磺酸内酯修飾成兩性離子高分子,針對此化合物做色素吸附與纖維素改性實驗。用UV-VIS監測,可以發現經過1,3-丙烷磺酸修飾過的高分子在中性環境下即對吸附水性染劑甲基橙和亞甲基藍的效果良好,但對於非水性染劑的偶氮染色劑蘇丹三號就不具吸附能力,推測是因為聚氨酯本身就含有高極性的氨基甲酸酯基團,加上兩性離子高分子因為正負電荷分離而產生高極性,以至於對於僅溶在有機溶劑中的蘇丹三號不具吸附能力;除了本論文合成的兩性離子高分子,另使用三氧化二鋁和二氧化矽去做色素吸附比較。 將此高分子溶於三氟乙醇,在以纖維素為主要成分的定量濾紙上做表面塗層,不同介電常數 (Dielectric Constant) 的溶劑通過濾紙的趨勢有所不同。 另從自界中擷取貽貝黏附蛋白 (Mussel Adhesive Proteins, MAPs) 之靈感,貽貝黏附蛋白含有大量3,4-二羥苯丙氨酸,其中鄰苯二酚可以提供貽貝不怕水的黏著性,因此我們聚焦在鄰苯二酚,開發出1,3-苯駢二氧雜環戊熳和2,2-二甲基-1,3-苯並二氧戊環的去保護方式,產物命名為dCpd2,調和二苯基甲烷二異氰酸酯及dCpd2和兩性離子高分子共聚的比例,加入適量的軟鏈段、聚酯鏈段,可以應用在水性黏膠材料 (Waterborne Adhesive) 的開發。 | zh_TW |
dc.description.abstract | This paper examines the synthesis of polyurethane copolymers using diphenylmethane diisocyanate as the provider of isocyanate functional groups. We form the copolymers through addition polymerization reactions involving N-methyl diethanolamine with binary hydroxyl groups and a tertiary amine compound called Cpd2, with a 2,2-dimethyl-1,3-benzodioxole ring structure synthesized in-house. Additionally, we synthesize a polyurethane copolymer by combining these components in a 3:7 ratio through addition polymerization.
Furthermore, we investigate the synthesis of zwitterionic polymers by modifying diphenylmethane diisocyanate and N-methyl diethanolamine copolymers with 1,3-propane sultone. We then experimented with dye adsorption and cellulose modification using the modified polymers. Our UV-VIS monitoring results demonstrate that the sultone-modified polymers exhibit effective adsorption capabilities for water-soluble dyes such as methyl orange and methylene blue under neutral conditions. However, they do not possess adsorption capabilities for the non-aqueous dye Sudan III. This can be attributed to the high polarity of urethane groups in polyurethane and the high polarity resulting from separating positive and negative charges in the zwitterionic polymers. Consequently, the modified polymers cannot adsorb Sudan III, as it is solely soluble in organic solvents. We also compare the dye adsorption properties of the synthesized zwitterionic polymers with those of aluminum oxide and silica. When dissolving this polymer in trifluoroethanol and used for surface coating on quantitated filter paper with cellulose as the main component, it combined with custom-made glass for filtration experiments. In that case, the trend of solvent passage through the filter paper varies for single-layer, double-layer, and triple-layer surface coatings with different dielectric constants. Taking inspiration from mussel adhesive proteins (MAPs) obtained from self-adhering mussels, which contain a significant amount of 3,4-dihydroxyphenylalanine (DOPA), with its catechol group providing water-resistant adhesion, we focused on the catechol moiety. We developed deprotection methods for 1,3-benzodioxole and 2,2-dimethyl-1,3-benzodioxole, naming the products dCpd2. In the future, by finding the right balance between diphenylmethane diisocyanate, dCpd2, and zwitterionic polymers in copolymerization or by incorporating appropriate amounts of soft chain segments or polyester segments, we can explore their potential applications in the development of waterborne adhesive materials. | en |
dc.description.provenance | Submitted by admin ntu (admin@lib.ntu.edu.tw) on 2024-02-23T16:20:00Z No. of bitstreams: 0 | en |
dc.description.provenance | Made available in DSpace on 2024-02-23T16:20:00Z (GMT). No. of bitstreams: 0 | en |
dc.description.tableofcontents | 口試委員審定書 i
謝辭 ii 中文摘要 iii Abstract iv 目錄 vi 化合物結構與命名 x 圖目錄 xiii 式目錄 xv 表目錄 xvii 第一章 緒論 1 1.1 兩性離子高分子 (Zwitterionic polymers) 1 1.2 貽貝黏附蛋白 (Mussel Adhesive Proteins, MAPs) 3 1.3 常見的染劑汙染 (Dye Pollutants) 5 1.4 常見的染劑去除方法 (Dye Removal Methods) 7 第二章 研究動機與文獻回顧 9 2.1 研究動機 9 2.1.1 兩性離子高分子與鄰苯二酚結構 9 2.1.2 色素吸附與纖維素改性 11 2.2 文獻回顧 12 2.2.1 兩性離子高分子與鄰苯二酚結構之應用 12 2.2.2 染劑吸附去除 17 第三章 實驗材料與方法 21 3.1 實驗材料 21 3.1.1 藥品與試劑 21 3.1.2 實驗儀器與耗材 22 3.2 合成策略與實驗設計 25 3.2.1 PDEA合成路徑 25 3.2.2 Cpd2合成路徑 26 3.2.3 兩性離子高分子合成路徑 28 3.2.4 色素吸附實驗 32 3.2.5 纖維素改性實驗 34 第四章 結果與討論 36 4.1 PDEA去保護試驗 36 4.2 Cpd2去保護試驗 40 4.3 兩性離子高分子與鈣離子交聯試驗 42 4.4 色素吸附實驗 45 4.5 纖維素改性實驗 50 第五章 結論 52 參考文獻 54 合成方法與步驟 63 附錄 77 NMR圖譜 77 高分子之TGA圖譜 102 高分子之DSC圖譜 103 氧化鋁色素吸附SEM圖譜 104 Raw Data 105 色素吸附實驗UV-Vis光譜 105 纖維素改性實驗溶劑通過時間 107 | - |
dc.language.iso | zh_TW | - |
dc.title | 新型仿生性兩性高分子材料合成及其在纖維素改性與色素吸附之應用 | zh_TW |
dc.title | Synthesis and Application of Innovative Bio-mimic Zwitterionic Polymer in Cellulose Modification and Dye Adsorption | en |
dc.type | Thesis | - |
dc.date.schoolyear | 112-1 | - |
dc.description.degree | 碩士 | - |
dc.contributor.oralexamcommittee | 游文岳;吳建欣;童世煌 | zh_TW |
dc.contributor.oralexamcommittee | Wen-Yueh Yu;Chien-Hsin Wu;Shih-Huang Tung | en |
dc.subject.keyword | 聚氨酯,兩性離子高分子,色素吸附,纖維素改性,紫外線/可見光分光光譜,貽貝黏附蛋白,鄰苯二酚, | zh_TW |
dc.subject.keyword | polyurethane,zwitterionic polymers,dye adsorption,cellulose modification,UV-VIS spectroscopy,mussel adhesive proteins,catechol, | en |
dc.relation.page | 109 | - |
dc.identifier.doi | 10.6342/NTU202304222 | - |
dc.rights.note | 未授權 | - |
dc.date.accepted | 2023-09-13 | - |
dc.contributor.author-college | 理學院 | - |
dc.contributor.author-dept | 化學系 | - |
顯示於系所單位: | 化學系 |
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