請用此 Handle URI 來引用此文件：
http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/91276完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 童國倫 | zh_TW |
| dc.contributor.advisor | Kuo-Lun Tung | en |
| dc.contributor.author | 陶方廷 | zh_TW |
| dc.contributor.author | Fang-Ting Tao | en |
| dc.date.accessioned | 2023-12-20T16:16:19Z | - |
| dc.date.available | 2023-12-21 | - |
| dc.date.copyright | 2023-12-20 | - |
| dc.date.issued | 2023 | - |
| dc.date.submitted | 2023-09-06 | - |
| dc.identifier.citation | [1] M. Patel, R. Kumar, K. Kishor, T. Mlsna, C.U. Pittman, Jr., D. Mohan, Pharmaceuticals of emerging concern in aquatic systems: Chemistry, occurrence, effects, and removal methods, Chem. Rev., 119 (2019) 3510-3673.
[2] C. Gadipelly, A. Pérez-González, G.D. Yadav, I. Ortiz, R. Ibáñez, V.K. Rathod, K.V. Marathe, Pharmaceutical industry wastewater: Review of the technologies for water treatment and reuse, Ind. Eng. Chem. Res., 53 (2014) 11571-11592. [3] M.B. Ahmed, J.L. Zhou, H.H. Ngo, W. Guo, Adsorptive removal of antibiotics from water and wastewater: Progress and challenges, Sci. Total Environ., 532 (2015) 112-126. [4] M. Xing, J. Zhang, F. Chen, New approaches to prepare nitrogen-doped TiO2 photocatalysts and study on their photocatalytic activities in visible light, Appl. Catal. B Environ., 89 (2009) 563-569. [5] A.K. Ghosh, H.P. Maruska, Photoelectrolysis of water in sunlight with sensitized semiconductor electrodes, J. Electrochem. Soc., 124 (1977) 1516-1522. [6] S. Sakthivel, H. Kisch, Daylight photocatalysis by carbon-modified titanium dioxide, Angew. Chem. Int. Ed., 42 (2003) 4908-4911. [7] A. Meng, B. Cheng, H. Tan, J. Fan, C. Su, J. Yu, TiO2/polydopamine S-scheme heterojunction photocatalyst with enhanced CO2-reduction selectivity, Appl. Catal. B Environ., 289 (2021) 120039. [8] A. Fujishima, K. Honda, Electrochemical photolysis of water at a semiconductor electrode, nature, 238 (1972) 37-38. [9] A. Heller, Chemistry and applications of photocatalytic oxidation of thin organic films, Acc. Chem. Res., 28 (1995) 503-508. [10] A.L. Linsebigler, G. Lu, J.T. Yates Jr, Photocatalysis on TiO2 surfaces: principles, mechanisms, and selected results, Chem. Rev., 95 (1995) 735-758. [11] K.I. Hadjiivanov, D.G. Klissurski, Surface chemistry of titania (anatase) and titania-supported catalysts, Chem. Soc. Rev., 25 (1996) 61-69. [12] J. Wang, D.N. Tafen, J.P. Lewis, Z. Hong, A. Manivannan, M. Zhi, M. Li, N. Wu, Origin of photocatalytic activity of nitrogen-doped TiO2 nanobelts, J. Am. Chem. Soc., 131 (2009) 12290-12297. [13] J. Lin, R. Zong, M. Zhou, Y. Zhu, Photoelectric catalytic degradation of methylene blue by C60-modified TiO2 nanotube array, Appl. Catal. B Environ., 89 (2009) 425-431. [14] N. Todorova, T. Vaimakis, D. Petrakis, S. Hishita, N. Boukos, T. Giannakopoulou, M. Giannouri, S. Antiohos, D. Papageorgiou, E. Chaniotakis, N and N, S-doped TiO2 photocatalysts and their activity in NOx oxidation, Catal. today, 209 (2013) 41-46. [15] T. Maggos, A. Plassais, J. Bartzis, C. Vasilakos, N. Moussiopoulos, L. Bonafous, Photocatalytic degradation of NOx in a pilot street canyon configuration using TiO2-mortar panels, Environ. Monit. Assess., 136 (2008) 35-44. [16] T.T. Khan, G.A.R. Bari, H.-J. Kang, T.-G. Lee, J.-W. Park, H.J. Hwang, S.M. Hossain, J.S. Mun, N. Suzuki, A. Fujishima, Synthesis of N-doped TiO2 for efficient photocatalytic degradation of atmospheric NOx, Catalysts, 11 (2021) 109. [17] Y.V. Divyasri, N.L. Reddy, K. Lee, M. Sakar, V.N. Rao, V. Venkatramu, M.V. Shankar, N.C.G. Reddy, Optimization of N doping in TiO2 nanotubes for the enhanced solar light mediated photocatalytic H2 production and dye degradation, Environ. Pollut., 269 (2021) 116170. [18] M. Esmat, H. El-Hosainy, R. Tahawy, W. Jevasuwan, N. Tsunoji, N. Fukata, Y. Ide, Nitrogen doping-mediated oxygen vacancies enhancing co-catalyst-free solar photocatalytic H2 production activity in anatase TiO2 nanosheet assembly, Appl. Catal. B Environ., 285 (2021) 119755. [19] J. van de Lagemaat, A.J. Frank, Effect of the surface-state distribution on electron transport in dye-sensitized TiO2 solar cells: Nonlinear electron-transport kinetics, J. Phys. Chem. B, 104 (2000) 4292-4294. [20] J. Huo, Y. Hu, H. Jiang, X. Hou, C. Li, Continuous flame synthesis of near surface nitrogen doped TiO2 for dye-sensitized solar cells, Chem. Eng. J., 258 (2014) 163-170. [21] R. Asahi, T. Morikawa, H. Irie, T. Ohwaki, Nitrogen-doped titanium dioxide as visible-light-sensitive photocatalyst: designs, developments, and prospects, Chem. Rev., 114 (2014) 9824-9852. [22] G. Lu, X. Wang, Y. Wang, G. Shi, X. Xie, J. Sun, Anti-oxidative microstructure design of ultra-stable N-TiO2 composite for the gaseous photodegradation reactions, Chem. Eng. J., 408 (2021) 127257. [23] Ó.R. Andrade, V. Rodríguez, R. Camarillo, F. Martínez, C. Jiménez, J. Rincón, Photocatalytic reduction of CO2 with N-doped TiO2-based photocatalysts obtained in one-pot supercritical synthesis, Nanomaterials, 12 (2022) 1793. [24] T. Phongamwong, M. Chareonpanich, J. Limtrakul, Role of chlorophyll in Spirulina on photocatalytic activity of CO2 reduction under visible light over modified N-doped TiO2 photocatalysts, Appl. Catal. B Environ., 168 (2015) 114-124. [25] M. Anpo, Photocatalysis on titanium oxide catalysts: approaches in achieving highly efficient reactions and realizing the use of visible light, Catal. Surv., 1 (1997) 169-179. [26] W. Choi, A. Termin, M.R. Hoffmann, Effects of metal‐ion dopants on the photocatalytic reactivity of quantum‐sized TiO2 particles, Angew. Chem., Int. Ed., 33 (1994) 1091-1092. [27] R. Asahi, T. Morikawa, T. Ohwaki, K. Aoki, Y. Taga, Visible-light photocatalysis in nitrogen-doped titanium oxides, science, 293 (2001) 269-271. [28] D.C. Cronemeyer, Infrared absorption of reduced rutile TiO2 single crystals, Phys. Rev., 113 (1959) 1222-1226. [29] X. Chen, L. Liu, P.Y. Yu, S.S. Mao, Increasing solar absorption for photocatalysis with black hydrogenated titanium dioxide nanocrystals, Science, 331 (2011) 746-750. [30] S. Hoang, S.P. Berglund, N.T. Hahn, A.J. Bard, C.B. Mullins, Enhancing visible light photo-oxidation of water with TiO2 nanowire arrays via cotreatment with H2 and NH3: synergistic effects between Ti3+ and N, J. Am. Chem. Soc., 134 (2012) 3659-3662. [31] H. Xu, S. Ouyang, L. Liu, P. Reunchan, N. Umezawa, J. Ye, Recent advances in TiO2-based photocatalysis, J. Mater. Chem. A, 2 (2014) 12642-12661. [32] S. Kalathil, M.M. Khan, S.A. Ansari, J. Lee, M.H. Cho, Band gap narrowing of titanium dioxide (TiO2) nanocrystals by electrochemically active biofilms and their visible light activity, Nanoscale, 5 (2013) 6323-6326. [33] S.A. Ansari, M.M. Khan, M.O. Ansari, J. Lee, M.H. Cho, Visible light-driven photocatalytic and photoelectrochemical studies of Ag–SnO2 nanocomposites synthesized using an electrochemically active biofilm, RSC Adv., 4 (2014) 26013-26021. [34] S. Sato, Photocatalytic activity of NOx-doped TiO2 in the visible light region, Chem. Phys. Lett., 123 (1986) 126-128. [35] A. Primo, A. Corma, H. García, Titania supported gold nanoparticles as photocatalyst, Phys. Chem. Chem. Phys., 13 (2011) 886-910. [36] S.A. Ansari, M.M. Khan, M.O. Ansari, M.H. Cho, Nitrogen-doped titanium dioxide (N-doped TiO2) for visible light photocatalysis, New J. Chem., 40 (2016) 3000-3009. [37] V. Vaiano, O. Sacco, D. Sannino, P. Ciambelli, Nanostructured N-doped TiO2 coated on glass spheres for the photocatalytic removal of organic dyes under UV or visible light irradiation, Appl. Catal. B Environ., 170 (2015) 153-161. [38] H.U. Lee, S.C. Lee, S. Choi, B. Son, S.M. Lee, H.J. Kim, J. Lee, Efficient visible-light induced photocatalysis on nanoporous nitrogen-doped titanium dioxide catalysts, Chem. Eng. J., 228 (2013) 756-764. [39] K. Pomoni, A. Vomvas, C. Trapalis, Dark conductivity and transient photoconductivity of nanocrystalline undoped and N-doped TiO2 sol–gel thin films, Thin Solid Films, 516 (2008) 1271-1278. [40] J. Wang, C. Fan, Z. Ren, X. Fu, G. Qian, Z. Wang, N-doped TiO2/C nanocomposites and N-doped TiO2 synthesised at different thermal treatment temperatures with the same hydrothermal precursor, Dalton Trans., 43 (2014) 13783-13791. [41] J. Wang, D.N. Tafen, J.P. Lewis, Z. Hong, A. Manivannan, M. Zhi, M. Li, N. Wu, Origin of photocatalytic activity of nitrogen-doped TiO2 nanobelts, Journal of the American Chemical Society, 131 (2009) 12290-12297. [42] L. Shouxin, C. Xiaoyun, C. Xi, Preparation of N-doped visible-light response nanosize TiO2 photocatalyst using the acid-catalyzed hydrolysis method, Chinese J. Catal., 27 (2006) 697-702. [43] M. Maeda, T. Watanabe, Visible light photocatalysis of nitrogen-doped titanium oxide films prepared by plasma-enhanced chemical vapor deposition, J. Electrochem. Soc., 153 (2006) C186. [44] G. Yang, Z. Jiang, H. Shi, T. Xiao, Z. Yan, Preparation of highly visible-light active N-doped TiO2 photocatalyst, J. Mater. Chem., 20 (2010) 5301-5309. [45] L. Gai, X. Duan, H. Jiang, Q. Mei, G. Zhou, Y. Tian, H. Liu, One-pot synthesis of nitrogen-doped TiO2 nanorods with anatase/brookite structures and enhanced photocatalytic activity, CrystEngComm, 14 (2012) 7662-7671. [46] Y. Zhou, Y. Liu, P. Liu, W. Zhang, M. Xing, J. Zhang, A facile approach to further improve the substitution of nitrogen into reduced TiO2−x with an enhanced photocatalytic activity, Appl. Catal. B Environ., 170 (2015) 66-73. [47] Y. Nosaka, M. Matsushita, J. Nishino, A.Y. Nosaka, Nitrogen-doped titanium dioxide photocatalysts for visible response prepared by using organic compounds, Sci. Technol. Adv., 6 (2005) 143. [48] W.-K. Jo, J.-T. Kim, Application of visible-light photocatalysis with nitrogen-doped or unmodified titanium dioxide for control of indoor-level volatile organic compounds, J. Hazard. Mater., 164 (2009) 360-366. [49] A. Kadam, R. Dhabbe, M. Kokate, Y. Gaikwad, K. Garadkar, Preparation of N doped TiO2 via microwave-assisted method and its photocatalytic activity for degradation of malathion, Spectrochim. Acta Mol. Biomol. Spectrosc., 133 (2014) 669-676. [50] M. Dawson, G.B. Soares, C. Ribeiro, Influence of calcination parameters on the synthesis of N-doped TiO2 by the polymeric precursors method, J. Solid State Chem., 215 (2014) 211-218. [51] X. Zhou, J. Lu, J. Jiang, X. Li, M. Lu, G. Yuan, Z. Wang, M. Zheng, H.J. Seo, Simple fabrication of N-doped mesoporous TiO2 nanorods with the enhanced visible light photocatalytic activity, Nanoscale Res. Lett., 9 (2014) 1-7. [52] K. Siuzdak, M. Szkoda, M. Sawczak, A. Lisowska-Oleksiak, Novel nitrogen precursors for electrochemically driven doping of titania nanotubes exhibiting enhanced photoactivity, New J. Chem., 39 (2015) 2741-2751. [53] X. Liu, Y. Chen, C. Cao, J. Xu, Q. Qian, Y. Luo, H. Xue, L. Xiao, Y. Chen, Q. Chen, Electrospun nitrogen and carbon co-doped porous TiO2 nanofibers with high visible light photocatalytic activity, New J. Chem., 39 (2015) 6944-6950. [54] V. Pore, M. Heikkilä, M. Ritala, M. Leskelä, S. Areva, Atomic layer deposition of TiO2− xNx thin films for photocatalytic applications, J. Photochem. Photobiol. A: Chem., 177 (2006) 68-75. [55] H. Shen, L. Mi, P. Xu, W. Shen, P.-N. Wang, Visible-light photocatalysis of nitrogen-doped TiO2 nanoparticulate films prepared by low-energy ion implantation, Appl. Surf. Sci., 253 (2007) 7024-7028. [56] S.-Z. Chen, P.-Y. Zhang, D.-M. Zhuang, W.-P. Zhu, Investigation of nitrogen doped TiO2 photocatalytic films prepared by reactive magnetron sputtering, Catal. Commun., 5 (2004) 677-680. [57] L. Jiang, H. Tian, W. Shen, Y. Wang, Y. Ma, P. Hou, Y. Wu, P. Xiang, T. Xiao, X. Tan, N-doped TiO2 hierarchical microspheres as electrode for high-performance supercapacitors, Mater. Lett., 295 (2021) 129840. [58] S.-R. Woo, Y.-M. Sung, Enhanced photoelectrochemical water splitting of micro-arc oxidized TiO2 via anatase/rutile phase control and nitrogen doping, J. Electrochem. Soc., 163 (2016) H278. [59] S. Wei, X. Shi, C. Wang, H. Zhang, C. Jiang, G. Sun, C. Jiang, Facile synthesis of nitrogen-doped carbon dots as sensitive fluorescence probes for selective recognition of cinnamaldehyde and l-Arginine/l-Lysine in living cells, Spectrochim. Acta A Mol. Biomol. Spectrosc., 287 (2023) 122039. [60] B. Zhao, X. Wang, Y. Zhang, J. Gao, Z. Chen, Z. Lu, Synergism of oxygen vacancies, Ti3+ and N dopants on the visible-light photocatalytic activity of N-doped TiO2, J. Photochem. Photobiol. A: Chem., 382 (2019) 111928. [61] G.-W. Lin, Y.-H. Huang, W. Tseng, F.-H. Lu, Production of N-doped anatase TiO2 on TiN-coated Ti substrates by plasma electrolytic oxidation for visible-light photocatalysts, Ceram. Int., 45 (2019) 22506-22512. [62] C. Jin-Wook, L. Seong-Eun, L. Byung-Gwan, Y.-S. Jeong, O. Han-Jun, C. Choong-Soo, Purifying behavior of photocatalytic TiO2 anodized in nitrate ion containing solution, Trans. Nonferrous Met. Soc. China, 19 (2009) 1027-1030. [63] F. Zhou, H. Song, H. Wang, S. Komarneni, C. Yan, N-doped TiO2/sepiolite nanocomposites with enhanced visible-light catalysis: Role of N precursors, Appl. Clay Sci., 166 (2018) 9-17. [64] L. Zhao, X. Chen, X. Wang, Y. Zhang, W. Wei, Y. Sun, M. Antonietti, M.-M. Titirici, One-step solvothermal synthesis of a carbon@TiO2 dyade structure effectively promoting visible-light photocatalysis, Adv. Mater., 22 (2010) 3317. [65] V. Trevisan, A. Olivo, F. Pinna, M. Signoretto, F. Vindigni, G. Cerrato, C. Bianchi, CN/TiO2 photocatalysts: Effect of co-doping on the catalytic performance under visible light, Appl. Catal. B Environ., 160 (2014) 152-160. [66] T.S. Rajaraman, S.P. Parikh, V.G. Gandhi, Black TiO2: A review of its properties and conflicting trends, Chem. Eng. J., 389 (2020) 123918. [67] N. Liu, C. Schneider, D. Freitag, M. Hartmann, U. Venkatesan, J. Müller, E. Spiecker, P. Schmuki, Black TiO2 nanotubes: Cocatalyst-free open-circuit hydrogen generation, Nano Lett., 14 (2014) 3309-3313. [68] F. Teng, M. Li, C. Gao, G. Zhang, P. Zhang, Y. Wang, L. Chen, E. Xie, Preparation of black TiO2 by hydrogen plasma assisted chemical vapor deposition and its photocatalytic activity, Appl. Catal. B Environ., 148-149 (2014) 339-343. [69] R. Ren, Z. Wen, S. Cui, Y. Hou, X. Guo, J. Chen, Controllable synthesis and tunable photocatalytic properties of Ti3+-doped TiO2, Sci. Rep., 5 (2015). [70] Z. Wang, C. Yang, T. Lin, H. Yin, P. Chen, D. Wan, F. Xu, F. Huang, J. Lin, X. Xie, M. Jiang, Visible-light photocatalytic, solar thermal and photoelectrochemical properties of aluminium-reduced black titania, Energy Environ. Sci.p, 6 (2013) 3007. [71] T. Lin, C. Yang, Z. Wang, H. Yin, X. Lü, F. Huang, J. Lin, X. Xie, M. Jiang, Effective nonmetal incorporation in black titania with enhanced solar energy utilization, Energy Environ. Sci., 7 (2014) 967. [72] X. Liu, S. Gao, H. Xu, Z. Lou, W. Wang, B. Huang, Y. Dai, Green synthetic approach for Ti3+ self-doped TiO2−x nanoparticles with efficient visible light photocatalytic activity, Nanoscale, 5 (2013) 1870. [73] X. Xin, T. Xu, L. Wang, C. Wang, Ti3+-self doped brookite TiO2 single-crystalline nanosheets with high solar absorption and excellent photocatalytic CO2 reduction, Sci. Rep., 6 (2016). [74] Z. Pei, L. Ding, H. Lin, S. Weng, Z. Zheng, Y. Hou, P. Liu, Facile synthesis of defect-mediated TiO2−x with enhanced visible light photocatalytic activity, J. Mater. Chem. A, 1 (2013) 10099. [75] Y. Yang, J. Liao, Y. Li, X. Cao, N. Li, C. Wang, S. Lin, Electrochemically self-doped hierarchical TiO2 nanotube arrays for enhanced visible-light photoelectrochemical performance: an experimental and computational study, RSC Adv., 6 (2016) 46871-46878. [76] C. Kim, S. Kim, S.P. Hong, J. Lee, J. Yoon, Effect of doping level of colored TiO2 nanotube arrays fabricated by electrochemical self-doping on electrochemical properties, Phys. Chem. Chem. Phys., 18 (2016) 14370-14375. [77] Y. Yang, M.R. Hoffmann, Synthesis and stabilization of blue-black TiO2 nanotube arrays for electrochemical oxidant generation and wastewater treatment, Environ. Sci. Technol., 50 (2016) 11888-11894. [78] J. Dong, J. Han, Y. Liu, A. Nakajima, S. Matsushita, S. Wei, W. Gao, Defective black TiO2 synthesized via anodization for visible-light photocatalysis, ACS Appl. Mater. Interfaces, 6 (2014) 1385-1388. [79] C. Fan, C. Chen, J. Wang, X. Fu, Z. Ren, G. Qian, Z. Wang, Black hydroxylated titanium dioxide prepared via ultrasonication with enhanced photocatalytic activity, Sci. Rep., 5 (2015). [80] X. Chen, D. Zhao, K. Liu, C. Wang, L. Liu, B. Li, Z. Zhang, D. Shen, Laser-modified black titanium oxide nanospheres and their photocatalytic activities under visible light, ACS Appl. Mater. Interfaces, 7 (2015) 16070-16077. [81] M. Zhai, Y. Liu, J. Huang, Y. Wang, K. Chen, Y. Fu, H. Li, Efficient suspension plasma spray fabrication of black titanium dioxide coatings with visible light absorption performances, Ceram. Int., 45 (2019) 930-935. [82] P. Fauchais, G. Montavon, M. Vardelle, J. Cedelle, Developments in direct current plasma spraying, Surf. Coat. Technol., 201 (2006) 1908-1921. [83] G.-S. Lin, Y.-C. Liu, R. Anbarasan, K. Nakagawa, T. Yoshioka, H. Matsuyama, H.-H. Tseng, K.-L. Tung, Silica gel-coated silicon carbide layer deposited by atmospheric plasma spraying, J. Taiwan Inst. Chem. Eng., 110 (2020) 173-181. [84] E. Pfender, Particle behavior in thermal plasmas, Plasma Chem., 9 (1989) 167S-194S. [85] P. Fauchais, J. Coudert, M. Vardelle, A. Vardelle, A. Denoirjean, Diagnostics of thermal spraying plasma jets, J. Therm. Spray Technol., 1 (1992) 117-128. [86] T.-Y. Hsu, T.-C. Huang, J.-H. Chou, Y.-F. Lin, K. Nakagawa, T. Yoshioka, H. Matsuyama, H.-H. Tseng, K.-L. Tung, A numerical simulation and experimental comparison of atmospheric thermal plasma spray coatings between internal and external powder injection processes, IEEE Trans. Plasma Sci., 48 (2020) 2759-2767. [87] A. Anupam, R.S. Kottada, S. Kashyap, A. Meghwal, B.S. Murty, C.C. Berndt, A.S.M. Ang, Understanding the microstructural evolution of high entropy alloy coatings manufactured by atmospheric plasma spray processing, Appl. Surf. Sci., 505 (2020) 144117. [88] M. Vardelle, A. Vardelle, P. Fauchais, Spray parameters and particle behavior relationships during plasma spraying, J. Therm. Spray Technol., 2 (1993) 79-91. [89] Y.-C. Liu, Y.-T. Lee, T.-C. Huang, G.-S. Lin, Y.-W. Chen, B.-S. Lee, K.-L. Tung, In vitro bioactivity and antibacterial activity of Strontium-, Magnesium-, and Zinc-multidoped hydroxyapatite porous coatings applied via atmospheric plasma spraying, ACS Appl. Bio Mater., 4 (2021) 2523-2533. [90] D. Wang, Z. Tian, L. Shen, Z. Liu, Y. Huang, Microstructural characteristics and formation mechanism of Al2O3–13 wt.% TiO2 coatings plasma-sprayed with nanostructured agglomerated powders, Surf. Coat. Technol., 203 (2009) 1298-1303. [91] J.P. Martins, H. Yu, Y. Chen, G. Brewster, R. McIntyre, P. Xiao, Effect of bond coat topography on the fracture mechanics and lifetime of air-plasma sprayed thermal barrier coatings, Surf. Coat. Technol., 421 (2021) 127447. [92] Y. Yang, K. Li, Z. Zhao, H. Li, Ablation resistance of HfC–SiC coating prepared by supersonic atmospheric plasma spraying for SiC-coated C/C composites, Ceram. Int., 42 (2016) 4768-4774. [93] M. Grimm, S. Conze, L.-M. Berger, G. Paczkowski, T. Lindner, T. Lampke, Microstructure and sliding wear resistance of plasma sprayed Al2O3-Cr2O3-TiO2 ternary coatings from blends of single oxides, Coatings, 10 (2020) 42. [94] H. Singh, B. Sidhu, D. Puri, S. Prakash, Use of plasma spray technology for deposition of high temperature oxidation/corrosion resistant coatings–a review, Mater. Corros., 58 (2007) 92-102. [95] E. Vetrivendan, G. Thendral, A.R. Shankar, C. Mallika, U. Kamachi Mudali, Aluminum phosphate sealing to improve insulation resistance of plasma-sprayed alumina coating, Mater. Manuf., 32 (2017) 1435-1441. [96] S. Tailor, R. Mohanty, A. Doub, Development of a new TBC system for more efficient gas turbine engine application, Mater. Today, 3 (2016) 2725-2734. [97] E. Lugscheider, R. Nickel, Finite element simulation of a coating formation on a turbine blade during plasma spraying, Surf. Coat. Technol., 174 (2003) 475-481. [98] J.-Y. Wang, Y.-C. Liu, G.-S. Lin, H.-H. Chang, Y.-T. Li, Y.-C. Yang, H. Matsuyama, B.-S. Lee, Y.-W. Chen, K.-L. Tung, Flame-sprayed strontium- and magnesium-doped hydroxyapatite on titanium implants for osseointegration enhancement, Surf. Coat. Technol., 386 (2020) 125452. [99] E. Georgiopoulos, A. Tsetsekou, C. Andreouli, The effect of YBa2Cu3O7-x powder characteristics on thick coatings prepared by atmospheric plasma spraying, Supercond Sci Technol, 13 (2000) 1539. [100] R. Hui, Z. Wang, O. Kesler, L. Rose, J. Jankovic, S. Yick, R. Maric, D. Ghosh, Thermal plasma spraying for SOFCs: Applications, potential advantages, and challenges, J. Power Sources, 170 (2007) 308-323. [101] G. Ramakrishnan, G. Dwivedi, S. Sampath, A. Orlov, Development and optimization of thermal sprayed ceramic microfiltration membranes, J. Membr. Sci., 489 (2015) 106-111. [102] S. Dosta, M. Robotti, S. Garcia-Segura, E. Brillas, I.G. Cano, J.M. Guilemany, Influence of atmospheric plasma spraying on the solar photoelectro-catalytic properties of TiO2 coatings, Appl. Catal. B Environ., 189 (2016) 151-159. [103] S. Karan, S. Samitsu, X. Peng, K. Kurashima, I. Ichinose, Ultrafast viscous permeation of organic solvents through diamond-like carbon nanosheets, Science, 335 (2012) 444-447. [104] J. Halloran, Making better ceramic composites with ice, Science, 311 (2006) 479-480. [105] I. Huskić, T. Friščić, Geomimetic approaches in the design and synthesis of metal-organic frameworks, Philos. Trans. Royal Soc. A, 377 (2019) 20180221. [106] R. Büttner, P. Dellino, B. Zimanowski, Identifying magma-water interaction from the surface features of ash particles, Nature, 401 (1999) 688-690. [107] K. Wohletz, Zimanowski, B., Büttner, R., in: S.A. Fagents, Gregg, T. K. P., Lopes, R. M. C., Eds. (Ed.) Modeling volcanic processes: The physics and mathematics of volcanism, Cambridge University Press, 2013, pp. 230-257. [108] N. Li, G. Liu, C. Zhen, F. Li, L. Zhang, H.-M. Cheng, Battery performance and photocatalytic activity of mesoporous anatase TiO2 nanospheres/graphene composites by template-free self-assembly, Adv. Funct. Mater., 21 (2011) 1717-1722. [109] X. Ren, P. Gao, X. Kong, R. Jiang, P. Yang, Y. Chen, Q. Chi, B. Li, NiO/Ni/TiO2 nanocables with Schottky/p-n heterojunctions and the improved photocatalytic performance in water splitting under visible light, J. Colloid Interface Sci., 530 (2018) 1-8. [110] Y. Wu, Y. Li, H. Hu, G. Zeng, C. Li, Recovering hydrogen energy from photocatalytic treatment of pharmaceutical-contaminated water using Co3O4 modified TiO2 nanosheets, ACS EST Engg., 1 (2021) 603-611. [111] Z. Jiang, L. Kong, F. Alenazey, Y. Qian, L. France, T. Xiao, P.P. Edwards, Enhanced visible-light-driven photocatalytic activity of mesoporous TiO2-xNx derived from the ethylenediamine-based complex, Nanoscale, 5 (2013) 5396. [112] G. Wang, H. Wang, Y. Ling, Y. Tang, X. Yang, R.C. Fitzmorris, C. Wang, J.Z. Zhang, Y. Li, Hydrogen-treated TiO2 nanowire arrays for photoelectrochemical water splitting, Nano Lett., 11 (2011) 3026-3033. [113] S.T. Aruna, N. Balaji, J. Shedthi, V.K.W. Grips, Effect of critical plasma spray parameters on the microstructure, microhardness and wear and corrosion resistance of plasma sprayed alumina coatings, Surf. Coat. Technol., 208 (2012) 92-100. [114] F. Sajedi Alvar, M. Heydari, A. Kazemzadeh, M.R. Vaezi, L. Nikzad, Synthesis and characterization of corrosion-resistant and biocompatible Al2O3-TiB2 nanocomposite films on pure titanium, Ceram. Int., 46 (2020) 4215-4221. [115] J. Xu, Y. Liu, Z. Ma, S. Zhu, Y. Wang, H. Chen, K. Ma, Infrared radiative performance and anti-ablation behaviour of Sm2O3 modified ZrB2/SiC coatings, Ceram. Int., 47 (2021) 400-408. [116] J. Singh, S.S. Chatha, H. Singh, Synthesis and characterization of plasma sprayed functional gradient bioceramic coating for medical implant applications, Ceram. Int., 47 (2021) 9143-9155. [117] M. Vardavoulias, P. Gkomoza, M. Arkas, D.K. Niakolas, S.G. Neophytides, Thermal spray multilayer ceramic structures with potential for solid oxide cell applications, Coatings, 11 (2021) 682. [118] R. Chen, S.-L. Zhang, C.-J. Li, C.-X. Li, Plasma-sprayed high-performance (Bi2O3)0.75(Y2O3)0.25 electrolyte for intermediate-temperature solid oxide fuel cells (IT-SOFCs), J. Therm. Spray Technol., 30 (2021) 196-204. [119] M. Cassidy, M. Manga, K. Cashman, O. Bachmann, Controls on explosive-effusive volcanic eruption styles, Nat. Commun., 9 (2018) 2839. [120] K.H. Wohletz, Explosive magma-water interactions: Thermodynamics, explosion mechanisms, and field studies, Bull. Volcanol., 48 (1986) 245-264. [121] S. Wei, R. Wu, J. Jian, F. Chen, Y. Sun, Black and yellow anatase titania formed by (H,N)-doping: strong visible-light absorption and enhanced visible-light photocatalysis, Dalton Trans., 44 (2015) 1534-1538. [122] W. Fang, Y. Zhou, C. Dong, M. Xing, J. Zhang, Enhanced photocatalytic activities of vacuum activated TiO2 catalysts with Ti3+ and N co-doped, Catal. Today, 266 (2016) 188-196. [123] J. Jiang, Z. Xing, M. Li, Z. Li, X. Wu, M. Hu, J. Wan, N. Wang, A.S. Besov, W. Zhou, In situ Ti3+/N-codoped three-dimensional (3D) urchinlike black TiO2 architectures as efficient visible-light-driven photocatalysts, Ind. Eng. Chem. Res., 56 (2017) 7948-7956. [124] Y. Cao, Z. Xing, M. Hu, Z. Li, X. Wu, T. Zhao, Z. Xiu, S. Yang, W. Zhou, Mesoporous black N-TiO2−x hollow spheres as efficient visible-light-driven photocatalysts, J. Catal., 356 (2017) 246-254. [125] Y. Cao, Z. Xing, Y. Shen, Z. Li, X. Wu, X. Yan, J. Zou, S. Yang, W. Zhou, Mesoporous black Ti3+/N-TiO2 spheres for efficient visible-light-driven photocatalytic performance, Chem. Eng. J., 325 (2017) 199-207. [126] H. Zhang, Y. Zhang, J. Yin, Z. Li, Q. Zhu, Z. Xing, In-situ N-doped mesoporous black TiO2 with enhanced visible-light-driven photocatalytic performance, Chem. Phys., 513 (2018) 86-93. [127] H. Liu, H. Fan, R. Wu, L. Tian, X. Yang, Y. Sun, Nitrogen-doped black TiO2 spheres with enhanced visible light photocatalytic performance, SN Appl. Sci., 1 (2019) 487. [128] M. Sarafraz, M. Sadeghi, A. Yazdanbakhsh, M.M. Amini, M. Sadani, A. Eslami, Enhanced photocatalytic degradation of ciprofloxacin by black Ti3+/N-TiO2 under visible LED light irradiation: Kinetic, energy consumption, degradation pathway, and toxicity assessment, Proc. Saf. Environ. Prot., 137 (2020) 261-272. [129] M. Sarafraz, M.M. Amini, M. Adiban, A. Eslami, Facile synthesis of mesoporous black N-TiO2 photocatalyst for efficient charge separation and the visible-driven photocatalytic mechanism of ibuprofen degradation, Mater. Sci. Semicond. Process., 120 (2020) 105258. [130] Y. Zhao, M. Zhang, W. Wang, W. Song, K. Jiang, X. Zhang, Preparation of Ti3+/N-co-doped TiO2 by one-step hydrothermal synthesis method with high photocatalytic degradation performance under visible light, J. Mater. Sci: Mater. Electron., 32 (2021) 22910-22920. [131] P. Mazierski, M. Nischk, M. Gołkowska, W. Lisowski, M. Gazda, M.J. Winiarski, T. Klimczuk, A. Zaleska-Medynska, Photocatalytic activity of nitrogen doped TiO2 nanotubes prepared by anodic oxidation: The effect of applied voltage, anodization time and amount of nitrogen dopant, Appl. Catal. B Environ., 196 (2016) 77-88. [132] Z. Xing, W. Zhou, F. Du, Y. Qu, G. Tian, K. Pan, C. Tian, H. Fu, A floating macro/mesoporous crystalline anatase TiO2 ceramic with enhanced photocatalytic performance for recalcitrant wastewater degradation, Dalton Trans., 43 (2014) 790-798. [133] H. Zhang, Z. Xing, Y. Zhang, Z. Li, X. Wu, C. Liu, Q. Zhu, W. Zhou, Ni2+ and Ti3+ co-doped porous black anatase TiO2 with unprecedented-high visible-light-driven photocatalytic degradation performance, RSC Adv., 5 (2015) 107150-107157. [134] Y. Zhang, Z. Xing, J. Zou, Z. Li, X. Wu, L. Shen, Q. Zhu, S. Yang, W. Zhou, 3D urchin-like black TiO2−x/carbon nanotube heterostructures as efficient visible-light-driven photocatalysts, RSC Adv., 7 (2017) 453-460. [135] A.B. Dehkordi, A. Badiei, Insight into the activity of TiO2@nitrogen-doped hollow carbon spheres supported on g-C3N4 for robust photocatalytic performance, Chemosphere, 288 (2022) 132392. [136] E. Wang, T. He, L. Zhao, Y. Chen, Y. Cao, Improved visible light photocatalytic activity of titania doped with tin and nitrogen, J. Mater. Chem., 21 (2011) 144-150. [137] N. Ding, L. Zhang, M. Hashimoto, K. Iwasaki, N. Chikamori, K. Nakata, Y. Xu, J. Shi, H. Wu, Y. Luo, D. Li, A. Fujishima, Q. Meng, Enhanced photocatalytic activity of mesoporous carbon/C3N4 composite photocatalysts, J. Colloid Interface Sci., 512 (2018) 474-479. [138] C. Wang, L. Hu, B. Chai, J. Yan, J. Li, Enhanced photocatalytic activity of electrospun nanofibrous TiO2/g-C3N4 heterojunction photocatalyst under simulated solar light, Appl. Surf. Sci., 430 (2018) 243-252. [139] S. Joung, T. Amemiya, M. Murabayashi, K. Itoh, Relation between photocatalytic activity and preparation conditions for nitrogen-doped visible light-driven TiO2 photocatalysts, Appl. Catal. A, 312 (2006) 20-26. [140] G. Wu, P. Li, D. Xu, B. Luo, Y. Hong, W. Shi, C. Liu, Hydrothermal synthesis and visible-light-driven photocatalytic degradation for tetracycline of Mn-doped SrTiO3 nanocubes, Appl. Surf. Sci., 333 (2015) 39-47. [141] S. Kumar, V. Sharma, K. Bhattacharyya, V. Krishnan, N-doped ZnO–MoS2 binary heterojunctions: the dual role of 2D MoS2 in the enhancement of photostability and photocatalytic activity under visible light irradiation for tetracycline degradation, Mater. Chem. Front., 1 (2017) 1093-1106. [142] Y. Liu, J. Kong, J. Yuan, W. Zhao, X. Zhu, C. Sun, J. Xie, Enhanced photocatalytic activity over flower-like sphere Ag/Ag2CO3/BiVO4 plasmonic heterojunction photocatalyst for tetracycline degradation, Chem. Eng. J., 331 (2018) 242-254. [143] Y. Chen, Q. Wu, L. Liu, J. Wang, Y. Song, The fabrication of self-floating Ti3+/N co-doped TiO2/diatomite granule catalyst with enhanced photocatalytic performance under visible light irradiation, Appl. Surf. Sci., 467-468 (2019) 514-525. [144] S. Wu, H. Hu, Y. Lin, J. Zhang, Y.H. Hu, Visible light photocatalytic degradation of tetracycline over TiO2, Chem. Eng. J., 382 (2020) 122842. [145] S. Wu, X. Li, Y. Tian, Y. Lin, Y.H. Hu, Excellent photocatalytic degradation of tetracycline over black anatase-TiO2 under visible light, Chem. Eng. J., 406 (2021). [146] J. Niu, Z. Song, X. Gao, Y. Ji, Y. Zhang, Construction of Bi2WO6 composites with carbon-coated Cu2O for effective degradation of tetracycline, J. Alloy. Compd., 884 (2021) 161292. [147] Y. Li, Q. Zhang, Y. Lu, Z. Song, C. Wang, D. Li, X. Tang, X. Zhou, Surface hydroxylation of TiO2/g-C3N4 photocatalyst for photo-Fenton degradation of tetracycline, Ceram. Int., 48 (2022) 1306-1313. [148] Q. Chen, H. Zhou, J. Wang, J. Bi, F. Dong, Activating earth-abundant insulator BaSO4 for visible-light induced degradation of tetracycline, Appl. Catal. B Environ., 307 (2022) 121182. [149] A.L. Batt, I.B. Bruce, D.S. Aga, Evaluating the vulnerability of surface waters to antibiotic contamination from varying wastewater treatment plant discharges, Environ. Pollut., 142 (2006) 295-302. [150] J.-W. CHOI, S.-E. LEE, B.-G. Lee, Y.-S. Jeong, H.-J. OH, C.-S. CHI, Purifying behavior of photocatalytic TiO2 anodized in nitrate ion containing solution, Trans. Nonferrous Met. Soc. China, 19 (2009) 1027-1030. [151] T. Suwannaruang, J.P. Hildebrand, D.H. Taffa, M. Wark, K. Kamonsuangkasem, P. Chirawatkul, K. Wantala, Visible light-induced degradation of antibiotic ciprofloxacin over Fe–N–TiO2 mesoporous photocatalyst with anatase/rutile/brookite nanocrystal mixture, J. Photochem. Photobiol. A: Chem., 391 (2020) 112371. [152] L.-L. Chang, C. Hu, C.-C. Huang, C.-Y. Lin, P.-W. Chung, K.-L. Tung, Potassium citrate-activated porous carbon nanostructures for CO2 adsorption and electroreduction, ACS Appl. Nano Mater., (2023). [153] S. Sakthivel, M. Janczarek, H. Kisch, Visible light activity and photoelectrochemical properties of nitrogen-doped TiO2, J. Phys. Chem. B, 108 (2004) 19384-19387. [154] L.-B. Hou, H.N. Catherine, K. Harada, M. Yoshida, Y.-L. Chen, C. Hu, Reactive seeding growth of cobalt-doped MIL-88B(Fe) on Al2O3 membrane for phenol removal in a photocatalytic membrane reactor, J. Membr. Sci., 680 (2023) 121730. [155] C.-J. Wu, I. Valerie Maggay, C.-H. Chiang, W. Chen, Y. Chang, C. Hu, A. Venault, Removal of tetracycline by a photocatalytic membrane reactor with MIL-53(Fe)/PVDF mixed-matrix membrane, Chem. Eng. J., 451 (2023) 138990. [156] Z. Ma, L. Hu, X. Li, L. Deng, G. Fan, Y. He, A novel nano-sized MoS2 decorated Bi2O3 heterojunction with enhanced photocatalytic performance for methylene blue and tetracycline degradation, Ceram. Int., 45 (2019) 15824-15833. [157] Y. Shi, J. Li, D. Wan, J. Huang, Y. Liu, Peroxymonosulfate-enhanced photocatalysis by carbonyl-modified g-C3N4 for effective degradation of the tetracycline hydrochloride, Sci. Total Environ., 749 (2020) 142313. [158] R. Zhang, Y. Li, W. Zhang, Y. Sheng, M. Wang, J. Liu, Y. Liu, C. Zhao, K. Zeng, Fabrication of Cu2O/Bi2S3 heterojunction photocatalysts with enhanced visible light photocatalytic mechanism and degradation pathways of tetracycline, J. Mol. Struct., 1229 (2021) 129581. [159] Z. Shi, Y. Zhang, X. Shen, G. Duoerkun, B. Zhu, L. Zhang, M. Li, Z. Chen, Fabrication of g-C3N4/BiOBr heterojunctions on carbon fibers as weaveable photocatalyst for degrading tetracycline hydrochloride under visible light, Chem. Eng. J., 386 (2020) 124010. [160] Y. Yang, Z. Zeng, C. Zhang, D. Huang, G. Zeng, R. Xiao, C. Lai, C. Zhou, H. Guo, W. Xue, Construction of iodine vacancy-rich BiOI/Ag@AgI Z-scheme heterojunction photocatalysts for visible-light-driven tetracycline degradation: Transformation pathways and mechanism insight, Chem. Eng. J., 349 (2018) 808-821. [161] E. Turiel, G. Bordin, A.R. Rodríguez, Study of the evolution and degradation products of ciprofloxacin and oxolinic acid in river water samples by HPLC-UV/MS/MS-MS, J. Environ. Monit., 7 (2005) 189-195. [162] A. Salma, S. Thoröe-Boveleth, T.C. Schmidt, J. Tuerk, Dependence of transformation product formation on pH during photolytic and photocatalytic degradation of ciprofloxacin, J. Hazard. Mater., 313 (2016) 49-59. [163] X. Zheng, S. Xu, Y. Wang, X. Sun, Y. Gao, B. Gao, Enhanced degradation of ciprofloxacin by graphitized mesoporous carbon (GMC)-TiO2 nanocomposite: Strong synergy of adsorption-photocatalysis and antibiotics degradation mechanism, J. Colloid Interface Sci., 527 (2018) 202-213. [164] L. Chen, B. Xu, M. Jin, L. Chen, G. Yi, B. Xing, Y. Zhang, Y. Wu, Z. Li, Excellent photocatalysis of Bi2WO6 structured with oxygen vacancies in degradation of tetracycline, J. Mol. Struct., 1278 (2023) 134911. [165] H. Liang, C. Zhu, A. Wang, K. Palanisamy, F. Chen, Facile synthesis of NiAl2O4/g-C3N4 composite for efficient photocatalytic degradation of tetracycline, J. Environ. Sci., 127 (2023) 700-713. [166] A. Hassani, A. Khataee, S. Karaca, Photocatalytic degradation of ciprofloxacin by synthesized TiO2 nanoparticles on montmorillonite: Effect of operation parameters and artificial neural network modeling, J. Mol. Catal. A: Chem., 409 (2015) 149-161. [167] A. Raja, P. Rajasekaran, K. Selvakumar, M. Arunpandian, K. Kaviyarasu, S. Asath Bahadur, M. Swaminathan, Visible active reduced graphene oxide-BiVO4-ZnO ternary photocatalyst for efficient removal of ciprofloxacin, Sep. Purif. Technol., 233 (2020) 115996. [168] Z. Zhu, H. Xia, H. Li, Construction of CoMoO4/g-C3N4 binary heterojunction photocatalyst with improving photocatalytic performance for ciprofloxacin under visible light, Diam. Relat. Mater., 133 (2023) 109735. [169] H.-S. Ngo, T.-L. Nguyen, N.-T. Tran, H.-C. Le, Experimental study on kinetics and mechanism of ciprofloxacin degradation in aqueous phase using Ag-TiO2/rGO/Halloysite photocatalyst, Catalysts, 13 (2023) 225. | - |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/91276 | - |
| dc.description.abstract | 本篇研究中，提出一個結合仿地質概念與大氣電漿噴塗，快速且一步驟完成多孔性氮摻雜還原態二氧化鈦光觸媒塗層的新穎製程。是第一篇利用大氣電漿技術實現氮摻雜材料修飾的研究。在噴塗過程中，透過自然啟發的蒸氣造孔技術，將儲存在基材孔洞中的含氮水溶液快速蒸發，使氮來源分解形成氨氣，與二氧化鈦粉體進行摻雜。研究中先後對於氮來源的濃度以及種類進行比較與分析，再針對四環素(TC)以及環丙沙星(CIP)進行可見光降解實驗，以此來評價光觸媒的光催化活性。並且透過液相層析質譜儀以及犧牲試劑測驗，了解其降解機制以及路徑。結果在較高的濃度下，化學表面吸附氮比例上升，這種形式的氮不會提升二氧化鈦在可見光下的光催化活性。在濃度較低的情況下，反而可以有效提升晶格氮/吸附氮的比例，可以增強光催化活性。以5 wt% (TN5)與15 wt% (TN15)的乙醯胺做為氮來源的結果中可以看到，TN5的降解率比TN15高56.47%。在不同種類的氮來源比較下選用的是結構中擁有一個氮原子的乙醯胺以及兩個氮原子的尿素。結構中擁有氮的數量會決定氮摻雜時環境中氮的濃度。從結果表明，以乙醯胺做為氮摻雜來源所製備出的樣品(T1N)比以尿素做為氮摻雜來源所製備出的樣品(T2N)，在TC以及CIP的降解中，分別高出32.91以及31.2%。本次研究最大的價值在首次利用大氣電漿技術實現氮摻雜材料修飾，並且在製備時間上具有非常大的優勢。這是一個適合放大規模的製程，省時且對自然環境無害。除了替材料合成開創新的可能性之外，在未來也是非常具有商業化以及工業化潛力的一項技術。 | zh_TW |
| dc.description.abstract | In this study, a novel process combining simulated geological concepts with atmospheric plasma spraying is proposed to achieve a rapid and one-step fabrication of porous nitrogen-doped reduced TiO2 photocatalytic coatings. This is the first study to utilize atmospheric plasma technology for nitrogen-doped material modification. During the spraying process, a naturally inspired vapor-induced pore formation technique is employed to rapidly evaporate the nitrogen-containing solution stored in the substrate pores, resulting in the decomposition of nitrogen sources to form ammonia gas, which is then doped into TiO2 powder. The study compares and analyzes the concentration and types of nitrogen sources, and subsequently conducts visible light degradation experiments on tetracycline (TC) and ciprofloxacin (CIP) to evaluate the photocatalytic activity of the catalyst. Additionally, liquid chromatography-mass spectrometry and sacrificial reagent tests are employed to understand the degradation mechanism and pathways.
The results show that at higher concentrations, the proportion of chemisorbed nitrogen on the surface increases, but this form of nitrogen does not enhance the photocatalytic activity of titanium dioxide under visible light. At lower concentrations, however, the proportion of lattice nitrogen/adsorbed nitrogen is effectively increased, leading to enhanced photocatalytic activity. The results from using 5 wt% (TN5) and 15 wt% (TN15) acetamide as nitrogen sources indicate that the degradation rate of TN5 is 56.47% higher than TN15. Among different types of nitrogen sources, acetamide with one nitrogen atom in its structure and urea with two nitrogen atoms are selected for comparison. The quantity of nitrogen in the structure determines the nitrogen concentration during doping. The results suggest that samples prepared with acetamide as the nitrogen source (T1N) outperform those prepared with urea as the nitrogen source (T2N) in TC and CIP degradation, with improvements of 32.91% and 31.2%, respectively. The major significance of this study lies in the first-time utilization of atmospheric plasma technology for nitrogen-doped material modification, offering significant advantages in preparation time. This process is suitable for scaling up, saving time, and being environmentally friendly. In addition to opening new possibilities for material synthesis, this technology also holds strong potential for commercialization and industrialization in the future. | en |
| dc.description.provenance | Submitted by admin ntu (admin@lib.ntu.edu.tw) on 2023-12-20T16:16:19Z No. of bitstreams: 0 | en |
| dc.description.provenance | Made available in DSpace on 2023-12-20T16:16:19Z (GMT). No. of bitstreams: 0 | en |
| dc.description.tableofcontents | 口試委員審定書 I
Acknowledgements II 中文摘要 III Abstract IV Contents VI List of Figures XI List of Tables XVII Chapter 1. Introduction 1 1.1 Objectives of The Research Project 5 1.2 Structure of Thesis 6 Chapter 2. Literature Review 10 2.1 TiO2 and its photocatalytic applications 10 2.2 TiO2 modification 11 2.2.1 Transition metal doping modification 11 2.2.2 Nitrogen doping modification 12 2.2.3 Ti3+ self-doped/reduction modification 13 2.3 Methodologies for preparing N-doped TiO2 and reduced TiO2 15 2.3.1 Photoexcitation mechanism over N-doped TiO2 15 2.3.2 Methodologies for preparing N-doped TiO2 17 2.3.3 Nitrogen sources 19 2.3.4 Photoexcitation mechanism and Methodologies for preparing reduced TiO2 20 2.4 Atmospheric plasma spraying 22 2.4.1 Influence of spraying parameters 24 2.4.2 Applications of APS 37 2.5 Geomimetic concept 37 Chapter 3. Materials and Experimental 39 3.1 Experimental equipment 39 3.1.1 Atmospheric plasma spraying 39 3.1.2 Substrate and substrate holder 45 3.2 Material identification instruments 47 3.2.1 Morphology 47 3.2.2 Crystal structure 49 3.2.3 Surface functional group 50 3.2.4 Chemical composition 50 3.2.5 Optical properties 51 3.2.6 Electrochemical properties 52 3.3 Photocatalytic experiments 52 3.3.1 Antibiotics 52 3.3.2 Light source 53 3.3.3 Photocatalytic activity evaluation 54 3.3.4 Intermediate products tracing 55 3.4 Geomimetic vapor-induced pore-forming (VI-PF) method 56 3.5 Experimental steps 58 3.5.1 N-doped reduced TiO2 preparation 58 3.5.2 Photocatalytic degradation experiments 61 Chapter 4. Porous N-doped TiO2 through an APS Approach for Photocatalytic TC Removal 63 4.1 Abstract 63 4.2 Introduction 64 4.3 Experimental 71 4.4 Results and Discussion 74 4.4.1 Morphology of photocatalyst coating layer 74 4.4.2 Phase structure and surface functional groups of the photocatalyst 75 4.4.3 Chemical composition of the photocatalyst 78 4.4.4 Optical properties and photoelectrochemical performance of the photocatalyst 83 4.4.5 Synthetic mechanism of N-doped reduced TiO2 using APS. 89 4.4.6 Evaluation of the photocatalytic degradation of tetracycline 90 4.5 Conclusions 96 Chapter 5. Influence of Nitrogen Sources on N-Doped Reduced TiO2 Prepared Using APS for Photocatalytic Antibiotics Degradation 98 5.1 Abstract 98 5.2 Introduction 99 5.3 Experimental 104 5.4 Results and Discussion 106 5.4.1 SEM/EDS/TXM analysis 106 5.4.2 XRD/ATR-FT-IR analysis 108 5.4.3 XPS analysis 111 5.4.4 UV-vis, PL, and EIS analysis 115 5.4.5 Mechanism od N-doped reduced TiO2 produced by APS 118 5.4.6 Evaluation of the photocatalytic degradation of TC and CIP 120 5.4.7 Analysis of photodegradation intermediate products and degradation pathways 128 5.5 Conclusions 136 Chapter 6. Summary and Perspectives 137 6.1 Summary 138 6.1.1 Geomimetic vapor-induced pore-forming mechanism 138 6.1.2 Synthetic mechanism of N-doped reduced TiO2 using APS 139 6.1.3 Nitrogen sources 140 6.1.4 Evaluation of photocatalytic activity by TC and CIP photodegradation 141 6.2 Perspectives 142 Reference 145 | - |
| dc.language.iso | en | - |
| dc.subject | 抗生素 | zh_TW |
| dc.subject | 氮摻雜 | zh_TW |
| dc.subject | 二氧化鈦 | zh_TW |
| dc.subject | 光觸媒 | zh_TW |
| dc.subject | 大氣電漿噴塗 | zh_TW |
| dc.subject | 抗生素 | zh_TW |
| dc.subject | 氮摻雜 | zh_TW |
| dc.subject | 二氧化鈦 | zh_TW |
| dc.subject | 光觸媒 | zh_TW |
| dc.subject | 大氣電漿噴塗 | zh_TW |
| dc.subject | Antibiotics | en |
| dc.subject | Atmospheric plasma spraying | en |
| dc.subject | Photocatalyst | en |
| dc.subject | Titanium dioxide | en |
| dc.subject | Nitrogen-doped | en |
| dc.subject | Antibiotics | en |
| dc.subject | Atmospheric plasma spraying | en |
| dc.subject | Photocatalyst | en |
| dc.subject | Titanium dioxide | en |
| dc.subject | Nitrogen-doped | en |
| dc.title | 大氣電漿噴塗氮摻雜還原態二氧化鈦光觸媒塗層製程開發並應用於光催化降解抗生素 | zh_TW |
| dc.title | Development of N-Doped Reduced TiO2 Photocatalyst Coating via Atmospheric Plasma Spraying for Photocatalytic Degradation of Antibiotics | en |
| dc.type | Thesis | - |
| dc.date.schoolyear | 112-1 | - |
| dc.description.degree | 博士 | - |
| dc.contributor.oralexamcommittee | 胡哲嘉;吳紀聖;林立強;李奕霈;鄭東文;蘇鎮芳;吳思恩 | zh_TW |
| dc.contributor.oralexamcommittee | Che-Chia Hu;Chi-Sheng Wu;Li-Chiang Lin;Yi-Pei Li;Tung-Wen Cheng;Jenn-Fang Su;Su-En Wu | en |
| dc.subject.keyword | 大氣電漿噴塗,光觸媒,二氧化鈦,氮摻雜,抗生素, | zh_TW |
| dc.subject.keyword | Atmospheric plasma spraying,Photocatalyst,Titanium dioxide,Nitrogen-doped,Antibiotics, | en |
| dc.relation.page | 157 | - |
| dc.identifier.doi | 10.6342/NTU202304197 | - |
| dc.rights.note | 同意授權(全球公開) | - |
| dc.date.accepted | 2023-09-07 | - |
| dc.contributor.author-college | 工學院 | - |
| dc.contributor.author-dept | 化學工程學系 | - |
| 顯示於系所單位： | 化學工程學系 | |
文件中的檔案：
| 檔案 | 大小 | 格式 | |
|---|---|---|---|
| ntu-112-1.pdf | 9.77 MB | Adobe PDF | 檢視/開啟 |
系統中的文件，除了特別指名其著作權條款之外，均受到著作權保護，並且保留所有的權利。