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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 江建文 | zh_TW |
| dc.contributor.advisor | Kien Voon Kong | en |
| dc.contributor.author | 黃姿綾 | zh_TW |
| dc.contributor.author | Zi-Ling Huang | en |
| dc.date.accessioned | 2023-11-20T16:10:13Z | - |
| dc.date.available | 2023-11-21 | - |
| dc.date.copyright | 2023-11-20 | - |
| dc.date.issued | 2023 | - |
| dc.date.submitted | 2023-09-05 | - |
| dc.identifier.citation | 1. Yamazaki, Y.; Takeda, H.; Ishitani, O. Photocatalytic reduction of CO2 using metal complexes. J. Photochem. Photobiol., C. 2015, 25, 106-137.
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/91153 | - |
| dc.description.abstract | 為了實現有效的光催化CO2還原，開發了一種基於Mn(I) 的混合系統並將其固定在TiO2半導體顆粒上 (Mn@TiO2)。該混合系統展現了持續的光催化性能，產生顯著的周轉率和出色的產物選擇性。在常規的實驗過程中，將含有0.1M電子供體 (ED) 的溶液中的混合催化劑暴露於可見光照射下，產生的CO選擇性產物高達99%，並且只有微量的HCOO-生成；最終，經過7小時的照射後，透過Mn：bdp 比例的優化發現，1：2的比例在總周轉率 (TONmax (CO) = 54) 方面提供最佳性能。 催化反應後，13CO2氣氛下的同位素標記實驗可以證實CO是由CO2產生。為了透過太陽能驅動光最大限度地減少二氧化碳排放，我們將Mn@TiO2結合在一起應用於CO2還原反應。 | zh_TW |
| dc.description.abstract | To achieve an effective photocatalytic CO2 reduction, a Mn(I)-based hybrid system (Mn@TiO2) was created and arranged on TiO2 semiconductor particles. The hybrid demonstrates continual photocatalytic properties, producing remarkable turnover numbers and outstanding product selectivity. In the usual procedure, visible-light irradiation of the hybrid catalyst in a solution containing 0.1 M electron donor (ED) yielded CO with over 99% selectivity and only trace amounts of HCOO–; eventually, after 7 hours of illumination, The optimization of the Mn：bdp ratio shows that the 1:2 ratio offers the best performance in terms of total turnover number (TONmax (CO) = 54). After catalysis, the isotope labeling experiment under 13CO2 atmosphere can confirm that CO was produced from CO2. To minimize carbon dioxide emissions through solar-driven light, we brought together the Mn@TiO2 for CO2 reduction. | en |
| dc.description.provenance | Submitted by admin ntu (admin@lib.ntu.edu.tw) on 2023-11-20T16:10:13Z No. of bitstreams: 0 | en |
| dc.description.provenance | Made available in DSpace on 2023-11-20T16:10:13Z (GMT). No. of bitstreams: 0 | en |
| dc.description.tableofcontents | Acknowledgement i
摘要 ii Abstract iii Table of Contents iv List of Figures vii List of Schemes xiii List of Tables xiv Chapter 1 Introduction 1 1.1. Overview：CO2 reduction 1 1.2. Photocatalytic reduction of CO2 using metal complexes 4 1.3. Semiconducting TiO2 nanoparticles 13 1.4. Photocatalytic system of Mn(I) catalyst for multi-electron CO2 reduction 16 1.5. Anchoring functional groups to graft a metal complex onto a surface 18 1.6. Bio-inspired liquid crystal actuator materials 20 1.7. Research motivation 27 Chapter 2 Results and Discussion 29 2.1. Synthesis and Characterization of Manganese Complex 29 2.2. Synthesis and Characterization of TiO2 Microspheres 38 2.3. Preparation of the Hybrid Catalyst Mn@TiO2 MPs 44 2.4 Photocatalytic CO2 Reduction 52 2.2.1 PS-Mn@TiO2 hybrid photocatalytic system for photocatalytic CO2 reduction 52 2.2.2 Electrochemical properties 53 2.2.3 UV-vis spectroscopy, Emission spectra and Electrochemical properties of Photosensitizers 56 2.2.4 Mott-Schottky Analysis of TiO2 Microspheres Film 64 2.2.5 Mechanistic Studies of the Binary Hybrid System 74 2.5 Conclusion 78 Chapter 3 Experimental Section 79 General information 79 Physical Measurements 82 Preparation 87 4,4’-Bis(diethylphosphonatomethyl)-2,2’-bipyridine (L2) 87 fac-[Mn(4,4’-Bis(diethoxyphosphorylmethyl)-2,2’-bipyridine)(CO)3Br] (MnPE) 88 fac-[Mn(4,4’-Bis(dihydroxyphosphorylmethyl)-2,2’-bipyridine)(CO)3Br] (MnP) 89 4-hydroxyphenyl 4-hydroxybenzoate (HPHB) 90 4-[4-(vinyloxy)butoxy]phenyl 4-[4-(vinyloxy)-butoxy]benzoate (VBPB) 91 TiO2 Microspheres 92 Mn(bpy-R)CO3Br@microspheres (Mn@TiO2) 93 Preparation of pre-crosslinked LCE512 film. 94 Preparation of pre-crosslinked LCE1002 film. 95 References 96 Appendix 113 | - |
| dc.language.iso | en | - |
| dc.title | 利用Mn(I)催化劑進行光化學CO2還原反應 | zh_TW |
| dc.title | Photochemical Reduction of CO2 with a Mn(I) Catalyst | en |
| dc.type | Thesis | - |
| dc.date.schoolyear | 112-1 | - |
| dc.description.degree | 碩士 | - |
| dc.contributor.oralexamcommittee | 劉沂欣;陳振中;江偉宏 | zh_TW |
| dc.contributor.oralexamcommittee | Yi-Hsin Liu;Chun-Chung Chan;Wei-Hung Chiang | en |
| dc.subject.keyword | 光催化,有機-無機混合系統,二氧化碳還原,分子催化劑固定於TiO2, | zh_TW |
| dc.subject.keyword | photocatalysis,organic-inorganic hybrid systems,CO2 reduction,molecular catalyst TiO2 immobilization, | en |
| dc.relation.page | 146 | - |
| dc.identifier.doi | 10.6342/NTU202304212 | - |
| dc.rights.note | 同意授權(限校園內公開) | - |
| dc.date.accepted | 2023-09-06 | - |
| dc.contributor.author-college | 理學院 | - |
| dc.contributor.author-dept | 化學系 | - |
| dc.date.embargo-lift | 2028-09-05 | - |
| 顯示於系所單位： | 化學系 | |
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