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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 陳賢燁 | zh_TW |
| dc.contributor.advisor | Hsien-Yeh Chen | en |
| dc.contributor.author | 林彥勳 | zh_TW |
| dc.contributor.author | Yen-Hsun Lin | en |
| dc.date.accessioned | 2023-09-11T16:07:34Z | - |
| dc.date.available | 2025-07-01 | - |
| dc.date.copyright | 2023-09-11 | - |
| dc.date.issued | 2023 | - |
| dc.date.submitted | 2023-06-28 | - |
| dc.identifier.citation | 1. Fortin, J.B. and T.-M. Lu, Chemical vapor deposition polymerization: the growth and properties of parylene thin films. 2003: Springer Science & Business Media.
2. Tomás, H., C.S. Alves, and J. Rodrigues, Laponite®: A key nanoplatform for biomedical applications? Nanomedicine: Nanotechnology, Biology and Medicine, 2018. 14(7): p. 2407-2420. 3. Tung, H.-Y., et al., Vapor sublimation and deposition to build porous particles and composites. Nature communications, 2018. 9(1): p. 2564. 4. Yeh, Y.L. and W.F. Gorham, Preparation and reactions of some [2.2] paracyclophane derivatives. The Journal of Organic Chemistry, 1969. 34(8): p. 2366-2370. 5. Golda-Cepa, M., et al., Recent progress on parylene C polymer for biomedical applications: A review. Progress in Organic Coatings, 2020. 140: p. 105493. 6. Ryu, K.S., et al., Micro magnetic stir-bar mixer integrated with parylene microfluidic channels. Lab on a Chip, 2004. 4(6): p. 608-613. 7. Ortigoza-Diaz, J., et al., Techniques and considerations in the microfabrication of Parylene C microelectromechanical systems. Micromachines, 2018. 9(9): p. 422. 8. Marei, I., et al., Assessment of parylene C thin films for heart valve tissue engineering. Tissue Engineering Part A, 2015. 21(19-20): p. 2504-2514. 9. Takeuchi, S., et al., Parylene flexible neural probes integrated with microfluidic channels. Lab on a Chip, 2005. 5(5): p. 519-523. 10. Chang, T.Y., et al., Cell and protein compatibility of parylene-C surfaces. Langmuir, 2007. 23(23): p. 11718-11725. 11. Parylene, A., Characteristics and applications of Parylene AF4. 12. Ko, H., et al., Surface modification of parylene-N with UV-treatment to enhance the protein immobilization. European Polymer Journal, 2015. 68: p. 36-46. 13. Dolbier Jr, W.R. and W.F. Beach, Parylene-AF4: a polymer with exceptional dielectric and thermal properties. Journal of fluorine chemistry, 2003. 122(1): p. 97-104. 14. Silverman, L., Filtration Through Porous Materials. American Industrial Hygiene Association Quarterly, 1950. 11(1): p. 11-20. 15. Zhao, X., et al., Immobilizing catalysts on porous materials. Materials Today, 2006. 9(3): p. 32-39. 16. Han, S., et al., Porous graphene materials for advanced electrochemical 45 energy storage and conversion devices. Advanced materials, 2014. 26(6): p. 849-864. 17. Mazzoli, A., Selective laser sintering in biomedical engineering. Medical & biological engineering & computing, 2013. 51: p. 245-256. 18. Rad, L.R. and M. Anbia, Zeolite-based composites for the adsorption of toxic matters from water: A review. Journal of Environmental Chemical Engineering, 2021. 9(5): p. 106088. 19. Slater, A.G. and A.I. Cooper, Function-led design of new porous materials. Science, 2015. 348(6238): p. aaa8075. 20. Feinle, A., M.S. Elsaesser, and N. Huesing, Sol–gel synthesis of monolithic materials with hierarchical porosity. Chemical Society Reviews, 2016. 45(12): p. 3377-3399. 21. Zhao, X., et al., Templating methods for preparation of porous structures. Journal of Materials Chemistry, 2006. 16(7): p. 637-648. 22. Zhang, Q., S. Yan, and M. Li, Silk fibroin based porous materials. Materials, 2009. 2(4): p. 2276-2295. 23. Qian, L. and H. Zhang, Controlled freezing and freeze drying: a versatile route for porous and micro‐/nano‐structured materials. Journal of Chemical Technology & Biotechnology, 2011. 86(2): p. 172-184. 24. Qin, J., et al., Research process on property and application of metal porous materials. Journal of Alloys and Compounds, 2016. 654: p. 39-44. 25. Chiu, Y.-R., et al., Fabrication of asymmetrical and gradient hierarchy structures of poly-p-xylylenes on multiscale regimes based on a vapor-phase sublimation and deposition process. Chemistry of Materials, 2020. 32(3): p. 1120-1130. 26. Tung, H.-Y., et al., Construction and control of 3D porous structure based on vapor deposition on sublimation solids. Applied Materials Today, 2017. 7: p. 77-81. 27. Gong, J., X. Chen, and T. Tang, Recent progress in controlled carbonization of (waste) polymers. Progress in Polymer Science, 2019. 94: p. 1-32. 28. Lee, J., J. Kim, and T. Hyeon, Recent progress in the synthesis of porous carbon materials. Advanced materials, 2006. 18(16): p. 2073-2094. 29. Sivakumar, M., et al., Porous carbon-NiO nanocomposites for amperometric detection of hydrazine and hydrogen peroxide. Microchimica Acta, 2019. 186(2): p. 59. 30. Geim, A.K., Graphene: status and prospects. science, 2009. 324(5934): p. 1530-1534. 31. Liger, M., et al. Parylene-pyrolyzed carbon for MEMS applications. in 17th 46 IEEE International Conference on Micro Electro Mechanical Systems. Maastricht MEMS 2004 Technical Digest. 2004. IEEE. 32. Das, S.S., et al., Laponite-based nanomaterials for biomedical applications: a review. Current Pharmaceutical Design, 2019. 25(4): p. 424-443. 33. Sircar, S., T. Golden, and M. Rao, Activated carbon for gas separation and storage. Carbon, 1996. 34(1): p. 1-12. 34. Li, H., Application of porous carbon macrostructures for water purification. Progress in Chemistry, 2016. 28(10): p. 1462. 35. Yang, Y., K. Chiang, and N. Burke, Porous carbon-supported catalysts for energy and environmental applications: A short review. Catalysis Today, 2011. 178(1): p. 197-205. 36. Yin, J., et al., Synthesis strategies of porous carbon for supercapacitor applications. Small Methods, 2020. 4(3): p. 1900853. 37. Sevilla, M., N. Díez, and A.B. Fuertes, More sustainable chemical activation strategies for the production of porous carbons. ChemSusChem, 2021. 14(1): p. 94-117. 38. Su, H., et al., Carbon nanosphere–iron oxide nanocomposites as high-capacity adsorbents for arsenic removal. RSC advances, 2017. 7(57): p. 36138-36148. 39. Hussain, M.Z., et al., Porous ZnO/Carbon nanocomposites derived from metal organic frameworks for highly efficient photocatalytic applications: A correlational study. Carbon, 2019. 146: p. 348-363. 40. Karthikeyan, S., et al., Hydroxyl radical generation by cactus-like copper oxide nanoporous carbon catalysts for microcystin-LR environmental remediation. Catalysis Science & Technology, 2016. 6(2): p. 530-544. 41. Ji, Y., et al., Modular development of metal oxide/carbon composites for electrochemical energy conversion and storage. Journal of Materials Chemistry A, 2019. 7(21): p. 13096-13102. 42. Lu, Y., et al., Micro-nanostructured CuO/C spheres as high-performance anode materials for Na-ion batteries. Nanoscale, 2015. 7(6): p. 2770-2776. 43. Sivakumar, M., M. Sakthivel, and S.-M. Chen, One pot synthesis of CeO2 nanoparticles on a carbon surface for the practical determination of paracetamol content in real samples. RSC advances, 2016. 6(106): p. 104227- 104234. 44. Ren, L., et al., One-step solvothermal synthesis of Fe3O4@Carbon composites and their application in removing of Cr (VI) and Congo red. Ceramics International, 2019. 45(7, Part B): p. 9646-9652. 45. Dong, S., et al., ZnO/porous carbon composite from a mixed-ligand MOF for ultrasensitive electrochemical immunosensing of C-reactive protein. Sensors 47 and Actuators B: Chemical, 2019. 284: p. 354-361. | - |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/89533 | - |
| dc.description.abstract | 本研究結合氣相昇華與沉積製程和高溫燒結製程，將parylene 薄膜與3D 多孔parylene 分別轉化為保形碳膜和三維多孔碳材，經拉曼光譜和X 光繞射光譜證實碳化結果。其中孔洞結構為透過操控熱力學環境，控制冰塊模板昇華與對二甲苯自由基沉積之質傳而獲得。因此本製程無須任何毒性化學物質作為致孔劑，甚至可透過操縱載台溫度控制冰塊昇華速率，製造不同孔徑大小之多孔碳材。各種冰塊模板的製造方式，使300μm╳300μm╳300μm方塊陣列多孔碳材和多層結構之多孔碳材得以實現。最後，本研究使用氧化鈰、四氧化三鐵和氧化鋅之懸浮液製造厚度1mm 之三層金屬氧化物/多孔碳複材，經能量色散X 射線分析得知金屬氧化物之分界清晰。本研究提供綠色、簡單且創新之多孔碳複材製程，在吸附材、汙染物降解、光觸媒、傳感器、超級電容等領域發展有巨大的潛力。 | zh_TW |
| dc.description.abstract | This study utilized vapor sublimation & deposition, and high-temperature annealing to convert parylene films and 3D porous parylene into conformal carbon films and 3D porous carbon materials, confirmed via Raman spectroscopy and X-ray diffraction spectroscopy. The porous structure was achieved by manipulating the thermodynamic environment to control ice template sublimation and the deposition of p-xylene free radicals. Consequently, this process eliminated the need for toxic chemicals as porogen and enabled the production of porous carbon materials with varying pore sizes through substrate temperature manipulation to control ice sublimation rates. Various creative ice templates could be generated, including porous carbon materials in cube arrays with dimensions of 300μm╳300μm╳300μm or with multi-layered structure. In this study, three suspensions were employed to fabricate a 1mm-thick three-layered metal oxides/porous carbon composite with well-defined interfaces. The research presented an environmentally friendly, straightforward, and innovative method for manufacturing porous carbon composites, which exhibited substantial potential for advancements in adsorbents, pollutant degradation, photocatalysis, sensors, and supercapacitors. | en |
| dc.description.provenance | Submitted by admin ntu (admin@lib.ntu.edu.tw) on 2023-09-11T16:07:34Z No. of bitstreams: 0 | en |
| dc.description.provenance | Made available in DSpace on 2023-09-11T16:07:34Z (GMT). No. of bitstreams: 0 | en |
| dc.description.tableofcontents | 致謝 I
摘要 II Abstract III Contents IV List of figures VI Chapter 1. Introduction 1 1.1 Parylene 1 1.2 Porous material 4 1.3 Carbonization 10 1.4 Laponite 12 1.5 Porous Carbon 15 1.6 Metal oxide/porous carbon composites 16 Chapter 2. Experimental Section 18 2.1 Characterization 18 2.1.1 Scanning electron microscopy 18 2.1.2 3D profile microscope 18 2.1.3 Raman spectroscopy 18 2.1.4 X-ray diffraction 18 2.2 Ice template fabrication 19 2.3 Vapor sublimation and deposition process 20 2.4 Annealing process 20 Chapter 3. Results and Discussion 21 3.1 Carbon film 21 3.2 Patterned porous carbon 26 3.3 Controlled porous carbon structure 31 3.4 Three-layer metal oxides/porous carbon composite 35 Chapter 4. Conclusion 41 4.1 Conclusion 41 4.2 Future work 43 References 44 | - |
| dc.language.iso | en | - |
| dc.subject | 多孔材料 | zh_TW |
| dc.subject | 氣相沉積 | zh_TW |
| dc.subject | 金屬氧化物/碳複合材料 | zh_TW |
| dc.subject | vapor deposition | en |
| dc.subject | porous material | en |
| dc.subject | metal oxide/carbon composite | en |
| dc.title | 圖案化金屬氧化物/多孔碳複合材料之建造基於氣相昇華與沉積 | zh_TW |
| dc.title | Construction of porous and patterned metal oxides and carbon composites based on vapor sublimation and deposition | en |
| dc.type | Thesis | - |
| dc.date.schoolyear | 111-2 | - |
| dc.description.degree | 碩士 | - |
| dc.contributor.oralexamcommittee | 游佳欣;陳柏均 | zh_TW |
| dc.contributor.oralexamcommittee | Jia-Shing Yu;Po-Chun Chen | en |
| dc.subject.keyword | 氣相沉積,多孔材料,金屬氧化物/碳複合材料, | zh_TW |
| dc.subject.keyword | vapor deposition,porous material,metal oxide/carbon composite, | en |
| dc.relation.page | 47 | - |
| dc.identifier.doi | 10.6342/NTU202301178 | - |
| dc.rights.note | 未授權 | - |
| dc.date.accepted | 2023-06-29 | - |
| dc.contributor.author-college | 工學院 | - |
| dc.contributor.author-dept | 化學工程學系 | - |
| 顯示於系所單位： | 化學工程學系 | |
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