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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 康敦彥 | zh_TW |
dc.contributor.advisor | Dun-Yen Kang | en |
dc.contributor.author | 胡芳瑄 | zh_TW |
dc.contributor.author | Fang-Hsuan Hu | en |
dc.date.accessioned | 2023-08-15T17:02:53Z | - |
dc.date.available | 2023-11-09 | - |
dc.date.copyright | 2023-08-15 | - |
dc.date.issued | 2023 | - |
dc.date.submitted | 2023-07-27 | - |
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dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/88609 | - |
dc.description.abstract | 為了降低以蒸餾方式分離混合溶液造成的工業能源消耗,本論文研究滲透蒸發的方式分離乙醇與水的混合溶液。滲透蒸發不僅可以解決蒸餾分離過程中面臨的共沸點問題,同時也節省蒸餾所需的能源消耗。本論文研究金屬有機骨架(metal-organic frameworks,MOFs)當作薄膜材料,MOF因為具有高比表面積和可調控的孔洞大小,在氣體分離和氣體儲存等領域中廣為應用。在過去的研究中,發現以MOF-303薄膜做滲透蒸發具有很好的分離表現性;在本研究中,使用MOF-303的有機配體3,5-吡唑二甲酸(H3PDC)額外摻雜配體2,5-噻吩二羧酸(H2TDC)做混合配體MOF。希望透過此方式得到之MOF材料可以同時具有兩種有機配體之優點,由H3PDC提高對水的吸附能力,H2TDC提供較大最窄孔道直徑(pore-limiting diameter, PLD)。並將合成出的混合配體MOF,命名為MOF-303(TDC/PDC)。經由XRD結合結構精修的方式計算出不同有機配體比的MOF材料之PLD,結果顯示當加入H2TDC的比例越高,材料之PLD會逐漸變大。我們也利用水吸附等溫線分析材料的吸水性質,發現原本對水沒有吸附能力的材料MOF-303-TDC,在加入H3PDC配體後吸水能力大幅增加到與純MOF-303接近。除此之外,我們也藉由in-situ FT-IR光譜與高解析XRD的鑑定技術分析水分子進入材料後的相互作用。在乙醇水溶液滲透蒸發分離表現上,我們發現在混合配體比為(50/50)的薄膜應用於乙醇及水的分離中效果是最好的。在333K的條件下對90 wt.%乙醇水溶液可以達到10000以上,且通量比MOF-303來的高。在(50/50)薄膜的長時間測試中,我們進行24小時的滲透蒸發操作,薄膜分離表現性仍然維持穩定,說明薄膜穩定性比純MOF-303高。 | zh_TW |
dc.description.abstract | In order to reduce the industrial energy consumption caused by the distillation, this study adopted pervaporation for separating a mixed solution of ethanol and water. Pervaporation can address the problem of azeotropic points encountered in the distillation separation process, and also saves the energy consumption required for distillation. In the study, metal-organic frameworks (MOFs) were used as membrane materials. MOFs are widely applied in gas separation, and gas storage due to their high surface area and tunable pore sizes. In previous studies, it was found that using MOF-303 membranes in pervaporation exhibited excellent separation performance. In this study, a mixed-linker MOF based on MOF-303 was synthesized by incorporating the organic linker 3,5-pyrazoledicarboxylic acid (H3PDC) with an additional linker, 2,5-thiophenedicarboxylic acid (H2TDC). The aim of this approach is to obtain a MOF material that combines the advantages of both organic linkers, with H3PDC enhancing water adsorption capacity and H2TDC providing a larger pore-limiting diameter (PLD). The synthesized mixed-linker MOF is named as MOF-303(TDC/PDC). By combining XRD with Rietveld refinement, we calculated the PLD of MOF materials with different ratios of organic linkers. The results showed that as the proportion of H2TDC increased, the PLD of the material gradually became larger. We also analyzed the water adsorption properties of the materials using water adsorption isotherms. It was found that MOF-303-TDC, which had no water adsorption capacity, exhibited a significant increase in water adsorption ability after incorporating the H3PDC linker. Additionally, we utilized in-situ FT-IR spectroscopy and high-resolution XRD techniques to investigate the interactions of water molecules within the channel of materials.In the pervaporation separation of ethanol-water solutions, it was observed that the (50/50) mixed-linker membrane demonstrated superior performance. At a temperature of 333 K, the membrane achieved an impressive separation factor of over 10,000 for a 90 wt.% ethanol-water solution, surpassing the performance of MOF-303. Additionally, the (50/50) membrane exhibited a higher flux compared to pure MOF-303. During the 24-hour long-term testing, the MOF-303(50/50) membrane maintained a stable separation performance, indicating greater stability compared to pure MOF-303. | en |
dc.description.provenance | Submitted by admin ntu (admin@lib.ntu.edu.tw) on 2023-08-15T17:02:53Z No. of bitstreams: 0 | en |
dc.description.provenance | Made available in DSpace on 2023-08-15T17:02:53Z (GMT). No. of bitstreams: 0 | en |
dc.description.tableofcontents | 致謝 I
摘要 II Abstract III 目錄 IV 圖目錄 VI 表目錄 VIII 第一章 緒論與文獻回顧 1 1-1 研究動機 1 1-2 薄膜滲透蒸發簡介 3 1-3 薄膜滲透蒸發機制 5 1-4 金屬有機骨架薄膜應用於滲透蒸發之效能 8 1-5 混合配體之金屬有機骨架 14 1-6 本論文之研究架構 16 第二章 實驗方法 19 2-1 實驗使用之藥品 19 2-2 材料合成 19 2-3 材料鑑定 22 X光繞射儀(X-ray diffractometer, XRD) 22 臨場(in-situ)與高解析 XRD 22 水吸附等溫線(Isothermal water adsorption) 23 掃描式電子顯微鏡(Scanning electron microscope, SEM) 23 X射線能量散布分析儀(Energy-dispersive X-ray spectroscopy, EDS) 23 臨場紅外線光譜儀(in-situ Infrared Spectrometer, in-situ IR) 23 氮氣吸附 (Nitrogen adsorption isotherms) 24 接觸角量測儀(Contact Angle Goniometer) 24 氣相層析儀(gas chromatography, GC) 24 2-4 最小孔洞直徑(PLD)之理論計算 25 2-5 薄膜氣體通透實驗 26 2-6 薄膜滲透蒸發實驗 27 第三章 結果與討論 30 3-1 MOF之粉體鑑定與分析 30 3-1-1 XRD鑑定分析 30 3-1-2 Rietveld結構精修後與PLD計算 31 3-1-3 材料氮氣吸附檢測 34 3-1-4 材料水吸附性質 36 3-1-5 粉體SEM與EDS元素分析 37 3-2 MOF薄膜之結構鑑定與分析 39 3-2-1 薄膜XRD鑑定 39 3-2-2 SEM鑑定 40 3-2-3 薄膜接觸角測試 42 3-2-4 薄膜氣體通透實驗 44 3-3 薄膜滲透蒸發測試 45 3-3-1 混合配體薄膜之滲透蒸發效能 45 3-3-2 溫度效應 46 3-3-3 長時間操作穩定性 48 3-4 臨場紅外線光譜儀(in-situ IR)與XRD分析材料接觸水、乙醇後的變化 50 3-4-1 臨場紅外線光譜儀(in-situ IR)分析水與MOF-303、MOF-303-TDC間的作用 50 3-4-2 MOF-303、MOF-303-TDC與混合配體與水、乙醇接觸後的XRD變化 54 3-5 混合配體MOF薄膜之滲透蒸發效能差異探討 57 第四章 結論與未來展望 62 參考文獻 64 | - |
dc.language.iso | zh_TW | - |
dc.title | 以混合配體製備金屬有機骨架薄膜於滲透蒸發之應用 | zh_TW |
dc.title | Mixed-linker metal-organic framework membranes for pervaporation | en |
dc.type | Thesis | - |
dc.date.schoolyear | 111-2 | - |
dc.description.degree | 碩士 | - |
dc.contributor.oralexamcommittee | 游文岳;羅世強;邱昱誠 | zh_TW |
dc.contributor.oralexamcommittee | Wen-Yueh Yu;Shyh-Chyang Luo;Yu-Cheng Chiu | en |
dc.subject.keyword | 金屬有機骨架,滲透蒸發,混合配體金屬有機骨架, | zh_TW |
dc.subject.keyword | metal-organic frameworks(MOFs),pervaporation,mixed-linker MOFs, | en |
dc.relation.page | 70 | - |
dc.identifier.doi | 10.6342/NTU202302043 | - |
dc.rights.note | 同意授權(限校園內公開) | - |
dc.date.accepted | 2023-07-28 | - |
dc.contributor.author-college | 工學院 | - |
dc.contributor.author-dept | 化學工程學系 | - |
顯示於系所單位: | 化學工程學系 |
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