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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 吳嘉文 | zh_TW |
| dc.contributor.advisor | Kevin C.-W. Wu | en |
| dc.contributor.author | 陸建宇 | zh_TW |
| dc.contributor.author | Jian-Yu Lu | en |
| dc.date.accessioned | 2023-08-08T16:28:27Z | - |
| dc.date.available | 2023-11-09 | - |
| dc.date.copyright | 2023-08-08 | - |
| dc.date.issued | 2023 | - |
| dc.date.submitted | 2023-07-17 | - |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/88139 | - |
| dc.description.abstract | 自19世紀工業革命以來，大氣中CO2濃度持續上升，造成顯著的全球氣候變遷。因此從大氣中捕捉CO2是目前非常重要的課題。在此研究中，我們使用薄膜分離的方式來分離空氣中的CO2，並利用免乾燥法混合高分子Pebax和金屬有機框架(MOFs) ZIF-8，形成混合基質薄膜(ZIF-8/Pebax® MH 2030 MMMs)，設法提升高分子薄膜的氣體分離效能。
在此研究中，我們利用FE-SEM和EDX觀察到免乾燥混合法可以有效地提升ZIF-8在高分子中的分散性，有效避免ZIF-8的聚集。此外，透過DSC分析，我們利用Tg變化觀察到ZIF-8和Pebax之間的親和性會使部分的高分子產生鏈剛硬化(Polymer chain rigidification)的現象。 我們對ZIF-8/Pebax® MH 2030 MMMs進行氣體分離效能的測試。實驗結果顯示，在單一氣體的環境中，當ZIF-8的添加量為5 wt%時，氣體通透率從115 barrer提升至140 barrer，同時CO2/N2選擇率從26提升至35。除此之外，我們還模擬了大氣環境來捕捉CO2。在ZIF-8的添加量同樣為5 wt%時，氣體通透率從460 barrer提升至500 barrer ，CO2/N2選擇率從19提升至69。相較於未添加ZIF-8的Pebax，選擇率增加了263%。此研究不僅發現利用免乾燥法可以有效的改善ZIF-8在Pebax中的分散性，更重要的是，參雜適當比例的ZIF-8可以有效的提升Pebax薄膜在大氣環境下的氣體分離效能。 | zh_TW |
| dc.description.abstract | Significant global climate change has resulted from the continuous increase in atmospheric CO2 concentration since the Industrial Revolution in the 19th century. Therefore, capturing CO2 from the atmosphere is currently a crucial issue. In this study, we used the mixed matrix membranes (MMMs) for CO2/N2 separation. We incorporated the metal-organic frameworks (MOFs) ZIF-8 into Pebax® MH 2030 to form the mixed matrix membrane (ZIF-8/Pebax® MH 2030 MMMs) by the drying-free method.
In this research, we use FE-SEM and EDX analysis to observe that the drying-free method can effectively improve the dispersion of ZIF-8 in the polymer, effectively avoiding ZIF-8 aggregation. Additionally, based on DSC analysis, we found that the polymer chain rigidification phenomenon will increase glass transition temperature (Tg), which is due to the affinity between ZIF-8 and Pebax® MH 2030. We measured the gas separation performance of the ZIF-8/Pebax® MH 2030 MMMs. In a single gas environment case, the 5 wt% loading ZIF-8 MMMs can get higher permeability (140 barrer) than the pure Pebax® MH 2030 (115 barrer), as well as the CO2/N2 selectivity (increased from 26 to 35). Furthermore, we simulated CO2 capture in the atmospheric environment to test the gas separation performance. Adding 5 wt% ZIF-8 into Pebax® MH 2030 can increase gas permeability from 460 barrer to 500 barrer, and the CO2/N2 selectivity increased from 19 to 69 (263% increased). This study shows that the drying-free method effectively improves the dispersion of ZIF-8 in Pebax® MH 2030 . More importantly, the incorporation of an appropriate proportion of ZIF-8 significantly enhances the direct air capture (DAC) performance of Pebax® MH 2030 membranes in an atmospheric environment. | en |
| dc.description.provenance | Submitted by admin ntu (admin@lib.ntu.edu.tw) on 2023-08-08T16:28:27Z No. of bitstreams: 0 | en |
| dc.description.provenance | Made available in DSpace on 2023-08-08T16:28:27Z (GMT). No. of bitstreams: 0 | en |
| dc.description.tableofcontents | 致謝 i
摘要 ii Abstract iii Table of Content v List of Figures ix List of Tables xiii 1. Introduction 1 1.1. Direct air capture (DAC) 1 1.2. Gas separation technology 3 1.2.1. Chemical absorption 4 1.2.2. Adsorption 5 1.2.3. Membrane separation 6 1.3. Membrane separation technology 8 1.4. Gas separation mechanism 10 1.4.1. Solution-diffusion model 11 1.4.2. Molecular sieve model 13 1.5. Type of membrane 14 1.5.1. Polymeric membrane 14 1.5.2. Inorganic membrane 14 1.5.3. Mixed-matrix membrane 16 2. Literature Review 18 2.1. Polymeric membrane 18 2.2. Mixed-matrix membrane 19 2.3. Drying-free method 21 3. Objectives 22 4. Experimental 23 4.1. Chemicals and Materials 23 4.2. Equipment 23 4.3. Synthesis of ZIF-8 nanoparticles 25 4.3.1. Synthesis of ZIF-8 nanoparticles suspension solution 25 4.3.2. Synthesis of ZIF-8 nanoparticles powder 26 4.4. Fabrication of Pebax® MH 2030 membrane 26 4.5. Fabrication of ZIF-8/Pebax® MH 2030 membrane 27 4.5.1. Drying-free method 27 4.5.2. Drying method 27 4.6. Characterization of MOF 28 4.6.1. X-ray diffraction analysis (XRD) 28 4.6.2. Transmission electron microscope (TEM) 28 4.6.3. Dynamic Light Scattering (DLS) 29 4.6.4. Specific Surface Area and Porosimetry Analyzer (BET) 29 4.6.5. Thermogravimetric Analysis (TGA) 29 4.7. Characterization of ZIF-8/Pebax® MH 2030 membranes 30 4.7.1. Field Emission Scanning Electron Microscope (FE-SEM) 30 4.7.2. Energy-Dispersive X-ray Spectroscopy (EDX) 30 4.7.3. X-ray diffraction analysis (XRD) 31 4.7.4. Differential Scanning Calorimetry (DSC) 31 4.7.5. Fourier-Transform Infrared Spectrometer (FTIR) 32 4.7.6. Mechanical strength test 32 4.8. Single gas permeability measurement 33 4.8.1. Gas permeation system introduction 33 4.8.2. Single gas permeation system installation 34 4.8.3. Performance Testing of Gas Permeation System 35 4.8.4. Gas permeation measurement 36 4.9. Mixed gas permeability measurement 38 5. Results and Discussion 39 5.1. ZIF-8 characterization 39 5.1.1. XRD analysis 39 5.1.2. TEM analysis 40 5.1.3. DLS analysis 41 5.1.4. BET analysis 41 5.1.5. FTIR analysis 43 5.1.6. TGA analysis 44 5.2. ZIF-8/Pebax® MH 2030 characterization 45 5.2.1. FE-SEM analysis 45 5.2.2. EDX analysis 47 5.2.3. XRD analysis 48 5.2.4. FTIR analysis 50 5.2.5. DSC analysis 52 5.2.6. TGA analysis 54 5.2.7. The mechanical properties of membranes 55 5.3. ZIF-8/Pebax® MH 2030 gas separation performance 56 5.3.1. Single gas performance 56 5.3.2. Mixed gas performance 60 6. Conclusion 63 References 64 | - |
| dc.language.iso | en | - |
| dc.subject | Pebax® MH 2030 | zh_TW |
| dc.subject | 沸石咪唑酯骨架 | zh_TW |
| dc.subject | 奈米粒子 | zh_TW |
| dc.subject | 有機無機複合薄膜 | zh_TW |
| dc.subject | 免乾燥混合法 | zh_TW |
| dc.subject | 二氧化碳/氮氣分離 | zh_TW |
| dc.subject | MMM | en |
| dc.subject | CO2/N2 separations | en |
| dc.subject | Pebax® MH 2030 | en |
| dc.subject | Drying-Free Mixing | en |
| dc.subject | Nanoparticles | en |
| dc.subject | ZIF-8 | en |
| dc.title | 使用免乾燥混合法結合沸石咪唑酯骨架-8奈米粒子與Pebax® MH 2030 之高效有機無機複合薄膜在二氧化碳/氮氣分離上的應用 | zh_TW |
| dc.title | A Drying-Free Mixing Process of Zeolitic Imidazolate Frameworks-8 (ZIF-8) Nanoparticles and Pebax® MH 2030 for Fabricating Highly Efficient Mixed-Matrix Membrane (MMM) in CO2/N2 Separation | en |
| dc.type | Thesis | - |
| dc.date.schoolyear | 111-2 | - |
| dc.description.degree | 碩士 | - |
| dc.contributor.oralexamcommittee | 湯偉鉦;康敦彥;郭紹偉;葉禮賢 | zh_TW |
| dc.contributor.oralexamcommittee | Wei-Cheng Tang;Dun-Yen Kang;Shiao Wei Kuo;Li-Hsien Yeh | en |
| dc.subject.keyword | 沸石咪唑酯骨架,奈米粒子,有機無機複合薄膜,免乾燥混合法,Pebax® MH 2030,二氧化碳/氮氣分離, | zh_TW |
| dc.subject.keyword | ZIF-8,Nanoparticles,MMM,Drying-Free Mixing,Pebax® MH 2030,CO2/N2 separations, | en |
| dc.relation.page | 76 | - |
| dc.identifier.doi | 10.6342/NTU202301497 | - |
| dc.rights.note | 未授權 | - |
| dc.date.accepted | 2023-07-17 | - |
| dc.contributor.author-college | 工學院 | - |
| dc.contributor.author-dept | 化學工程學系 | - |
| 顯示於系所單位： | 化學工程學系 | |
文件中的檔案：
| 檔案 | 大小 | 格式 | |
|---|---|---|---|
| ntu-111-2.pdf 未授權公開取用 | 7.43 MB | Adobe PDF |
系統中的文件，除了特別指名其著作權條款之外，均受到著作權保護，並且保留所有的權利。