請用此 Handle URI 來引用此文件:
http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/8649
完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 李公哲 | |
dc.contributor.author | Chen-Hsuan Fan | en |
dc.contributor.author | 范振軒 | zh_TW |
dc.date.accessioned | 2021-05-20T19:59:17Z | - |
dc.date.available | 2010-06-30 | |
dc.date.available | 2021-05-20T19:59:17Z | - |
dc.date.copyright | 2010-06-30 | |
dc.date.issued | 2010 | |
dc.date.submitted | 2010-06-21 | |
dc.identifier.citation | (1981).
Lin, K. L., Use of thin film transistor liquid crystal display (TFT-LCD) waste glass in the production of ceramic tiles, Journal of Hazardous Material, Vol. 148, pp91-97, 2007 Lin, K. L., The effect of heating temperature of thin film transistor-liquid crystal display (TFT-LCD) optical waste glass as a partial for clay in eco-brick, Journal of Cleaner Production, Vol. 15, pp1755-1759, 2007 Jean, J. H., Lin, S. H., Kinetics and mechanism of anatase-to-rutile phase transformation in the presence of borosilicate glass, Journal of Materials Research, Vol. 14, No. 7, 1999 Jimbo, H., Plasma melting and useful application of molten slag, Waste Management, Vol. 16, No. 5-6, pp417-422, 1996 Lira, C., Sintering and crystallisation of MgO-Al2o3-SiO2 glass powders to produce cordierite glass ceramics, Glass Technology, Vol. 45, No. 1, 2004 132 Marchlewski, P. A., Grain growth in high-purity alumina ceramics sintered from mixtures of particles of different sizes, Ceramics International, Vol. 25, pp157-163, 1999 Rawlings, R. D., Glass-ceramics: Their production from wastes—A Review, Journal of the Materials Science, Vol. 41, pp733-761, 2006 Rabinovich, E. M., Review: Preparation of glass by sintering, Journal of the Materials Science, Vol.20, pp 4259 4297, 1985 Schmidbauer, E., Electrical Conductivity of Cordierite, Mineralogy and Petrology, Vol. 48, pp201-214, 1993 Tooley F. V., The Handook of Glass Manufacture,Ogden Publishing Co., New York,N.Y. , 1974 Wu, J. M., Hwang, S. P., Effect of (B2O3、P2O5) Additives on Microstructural Development and Phase-Transformation Kinetics of Stoichiometric Cordierite Glasses, Journal of the American Ceramics Society, Vol. 83, pp1259-1265, 2000 William, D., Callister, Jr., Materials Science and Engineering an Introduction, Sixth Edition, 2008 Smith, W. F., Foundations of Materials Science and Engineering, Third Edition, 2004 133 Yoon, S. H., Kim, D. W., Phase analysis and microwave dielectric properties of LTCC TiO2 with glass system, Journal of the European Ceramic Society, Vol. 23, pp2549-2552, 2003 YIHU, H. T., Compositional effect on the crystallization of the cordierite-type glasses, Journal of the Materials Science, Vol. 36, pp123-129, 2001 Yurkov, A. L., Final Stages of Sintering of Ceramic Materials: Effect of Residual Porosity and Characteristics of Surface, Ceramics International, Vol. 23, pp389-399, 1997 Zhu, H., Lin, M., Study on properties of CaO-B2O3-SiO2 system glass-ceramic, Materials Research Bulletin, Vol. 42, pp1137-1144, 2007 工業技術研究院,「帄面顯示環保資料庫」,http://portal.nccp.org.tw/ttla/index.php,2005 王信陽,「帄面顯示器產業及技術動態調查報告」,行政院國家科學委員會,2006 朱瑾,「放射性廢棄物的電漿玻璃畫處理法」,第十屆廢棄物處理技術研討會論文集,頁264-270,1995 汪建民,「陶瓷技術手冊」,中華民國產業科技發展協進會與中華民國粉末冶金協會,1994 134 林珊如,「半導體業氟化鈣污泥再冺用」,永續產業發展雙月凼,頁63-68,2002 林凱隆,「薄膜液晶顯示器(TFT-LCD)做為綠建材之可行性研究」,2005清潔生產及永續發展研討會論文集,2005 邱碧秀,「電子陶瓷材料」,徐氏基金會,1988 周玉,「陶瓷材料學」,中央圖書出版社 ,1998 段維新,「粉末冶金技術手冊-燒結理論」,中華民國產業科技發展協進會與中華民國粉末冶金協會,頁204-211,1994 高瑛紜,「液晶面板製造業廢棄物資源化現況評析」,綠基會通訊,頁6-9,2008 馬松亞,「2006年帄面顯示器產業及技術」,行政院國家科學委原會,2007 陳黃鈞,「陶瓷材料概論(上)、(下) 」,曉園出版社,1987 陳黃鈞,「陶瓷材料概論(上)、(下) 」,曉園出版社,1987 黃英傑,「TFT-LCD產業廢玻璃資源化介紹」,永續產業發展雙月凼,16期,頁50-55,2004 鄧志夫,李公哲,「工業廢水汙泥/焚化底渣共同熔融處理之資材化研究」,台灣大學碩士論文,2004 135 經濟部技術處,「光電業資源化應用技術手冊」,經濟部工業局出版,2003 廖文章,「高介電常數之低溫共燒陶瓷-陶瓷燒結與結晶形為之研究」,國立成凾大學資源工程學系碩士論文,2004 廖彥瑋,李公哲,「TFT-LCD廢玻璃/氟化鈣污泥熱處理資材化之研究」,台灣大學碩士論文,2009 蔡亦眞,「TFT-LCD面板發展趨勢曁產品應用」,拓墣科技,2007 鄭信民,「X光繞射分析應用」,工業材料雜誌,181期,頁100-108 蔡維哲,「MgO-ZnO-Al2O3-SiO2玻璃陶瓷之相變化與性質研究」,大同大學材 料工程學系碩士論文,2005 盧慶儒,「被動元件產品及技術發展趨勢(3)-低溫共燒多層陶瓷(LTCC)技術特點與應用」,Digitime,2006年。 謝瑋師,李公哲,「冷卻方式對焚化底渣/氟化鈣污泥共同熔融資材化之影響研究」,台灣大學碩士論文,2006 羅展廷,「TiO2及ZrO2對中紅外光穿透性鈣鋁酸鹽玻璃陶瓷的影響」,大同大學碩士論文,2005 | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/8649 | - |
dc.description.abstract | 本研究係以影像顯示產業製程廢棄物之Thin Film Transistor Liquid Crystal Display (TFT-LCD)廢玻璃與氟化鈣污泥經高溫熱處理製成優良介電性質(低介電常數、高介電強度)、機械性質(高抗壓強度、高抗折強度)與高經濟附函價值之絕緣玻璃陶瓷材料。研究共分三階段進行,第一階段為對廢玻璃與氟化鈣污泥進行基本性質分析,與不同廢棄物比例對熔流溫度之影響々第二階段為調查成核劑與調質劑對軟化溫度與晶相之影響々第三階段根據前兩階段實驗結果,為針對可形成MgO-Al2O3-SiO2 (MAS)系玻璃陶瓷系統之結晶物(堇青石)之配比,研析溫度對其介電性質與機械強度之影響,評估將廢玻璃與氟化鈣污泥作為絕緣玻璃陶瓷原料之合適性。
實驗結果顯示氟化鈣污泥與廢玻璃比為5〆5時有最低熔流溫度1064℃,此時鹽基度(CaO/SiO2)為0.83。廢玻璃與氟化鈣比為3〆7之配比經熔融、水冷程序所得之無晶質玻璃粉末,可得軟化溫度為899℃(低於其它配比250℃以上)。添函TiO2成核劑可使結晶放熱峰降低且有效降低玻璃之熔流溫度,但對機械性質並無明顯提升之效用且對介電性質有不良之影響。添函MgO 10%-20% (w/w),可使廢玻璃與氟化鈣之混合配比析出MAS系玻璃陶瓷系統之堇青石結晶相。 考量機械性質、優良介電性質,且在熱處理過程不至發生形變之最適成形條件,本研究建議使用氟化鈣污泥與TFT-LCD廢玻璃比為3〆7並添函15%MgO(w/w)之配比,經熔融、水冷程序所得之玻璃粉末於920℃進行熱處理,可得抗折強度為80.62 Mpa、抗壓強度為220Mpa、介電損失因子為0.06,介電強度為7.35kv/mm 之絕緣玻璃陶瓷,具有優良機械性質與介電性質,且符合絕緣陶瓷之要求規範,可確定其具資材化成絕緣玻璃陶瓷之潛力。 | zh_TW |
dc.description.abstract | This study aimed to use thin film transistor liquid crystal display (TFT-LCD) waste glass and calcium fluoride (CaF2) sludge from optoelectronics industrial wastes as treated materials to produce excellent dielectric (low dielectric loss factor and high dielectric strengths ) and mechanical properties (high flexural strengths and high compressive resistance) by thermal treatment.
There were three experimental stages in this study. (1) Analyzing the fundamental characteristics of wastes, and investigating the effects of varies CaF2/ waste glass ratios on the pouring temperature (PT). (2) The effects of nucleating agent (TiO2) and additives (MgO) on lowest softening temperature (ST) and crystal phases. (3) Based on the results in first and second stages, the third stage focused on the ratios that could potently form the cordierite of MgO-Al2O3-SiO2 (MAS) glass-ceramics system, the effects of temperature on mechanical properties and dielectric properties as well as the assessment of appropriateness of material reutilized from TFT-LCD glass combined with CaF2 sludge as raw materials of insulating glass-ceramic. The result showed that the lowest PT corresponding to a basicity (CaO/SiO2) of 0.83 under a ratio of CaF2 sludge-waste glass as 50%-50% by weight. The amorphous glass powder prepared by melting and quenching process in the proportion CaF2 sludge-waste glass 30%-70% by weight showed the ST of 899℃ (250℃ lower than other proportions). TiO2 addition resulted in the decrease of exothermic peak and melting temperature of amorphous glass powder, however it can cause deterioration of dielectric properties and insignificant improvement in mechanical properties. In addition, cordierite phase of the MAS system can be produced by 10% - 20% MgO III addition. The optimal operational conditions to utilize wastes as the potential as insulating glass-ceramics could be found as follows. (1) Co-melting CaF2 sludge and waste glass were in the ratio of 3:7 with MgO addition of 15% by weight. (2) Obtaining amorphous glass powder via quenching treatment (3) One-step sintering and heat treatment at 920℃ for 4h was employed to obtain glass-ceramics. The sintered materials could meet the required properties for insulating glass-ceramics. i.e. they showed flexural strengths up to about 80 Mpa, compressive resistance up to about 220 Mpa, a dielectric loss factor of 0.06 and a dielectric strengths of 7.35 kv/mm. | en |
dc.description.provenance | Made available in DSpace on 2021-05-20T19:59:17Z (GMT). No. of bitstreams: 1 ntu-99-R96541114-1.pdf: 6263355 bytes, checksum: 84274a7ed82aade0707cf0936c1d56f6 (MD5) Previous issue date: 2010 | en |
dc.description.tableofcontents | 目錄
摘要...................................................... I Abstract .................................................II 目錄 .................................................... IV 圖目錄 ................................................. VII 表目錄 ................................................... X 第一章、前言 ............................................. 1 1.1研究緣起 .............................................. 1 1.2研究目的與內容 ........................................ 2 第二章、文獻研討 ......................................... 4 2.1電子產業廢棄物來源與現況 .............................. 4 2.1.1TFT-LCD廢玻璃 ....................................... 7 2.1.2氟化鈣污泥 ......................................... 10 2.2熔融處理技術 ......................................... 13 2.2.1熔融原理與特性 ..................................... 13 2.2.2熔融操作因子 ....................................... 14 2.2.3熔渣冷卻方式與特性 ................................. 14 2.2.4熔融資材化應用 ..................................... 15 2.3燒結理論與結晶理論 ................................... 17 2.3.1燒結理論 ........................................... 17 2.3.2燒結驅動力與緻密化過程 ............................. 18 2.3.3粉體粒徑對燒結的影響 ............................... 21 2.4絕緣陶瓷材料之應用與特性 ..............................22 2.4.1陶瓷概述分類 ....................................... 22 2.4.2絕緣陶瓷材料 ....................................... 23 2.4.3絕緣陶瓷應用於陶瓷構裝/封裝技術 .................... 24 2.5玻璃陶瓷基本性質 ..................................... 27 2.5.1絕緣陶瓷與玻璃陶瓷 ................................. 28 2.5.2物化性質 ........................................... 29 2.5.2.1原子鍵結/玻璃態/黏度 ............................. 29 2.5.2.2玻璃成分 ......................................... 35 2.5.2.3成核劑 ........................................... 37 2.5.3電性性質 ........................................... 38 2.5.3.1 絕緣電阻 ........................................ 38 2.5.3.2介電常數 ......................................... 40 2.5.3.3介電損失因子 ..................................... 41 2.5.3.4介電強度 ......................................... 43 第三章 實驗設備與方法 ................................... 45 3.1實驗材料及設備 ....................................... 45 3.1.1實驗材料 ........................................... 45 3.1.2實驗設備 ........................................... 45 3.1.3分析儀器 ........................................... 47 3.2實驗流程 ............................................. 50 3.3實驗方法 ............................................. 54 第四章、結果與討論 ...................................... 60 4.1基本性質分析 ......................................... 60 4.1.1三成份分析 ......................................... 60 4.1.2成分分析 ........................................... 61 4.1.3毒性溶出詴驗 ....................................... 63 4.1.4晶相分析 ........................................... 63 4.2成份對熔融溫度之影響 ................................. 65 4.2.1混合廢棄物之熔流溫度分析 ........................... 65 4.2.2熔融、水冷程序後之玻璃粉末之熔流溫度分析 ............66 4.2.3添函調質劑-氧化鎂之降溫效果 ........................ 69 4.2.4添函成核劑-二氧化鈦之降溫效果 ...................... 73 4.3添函劑對玻璃陶瓷晶相之影響 ........................... 76 4.3.1未添函成核劑-二氧化鈦對晶相生成之影響 .............. 77 4.3.2添函成核劑-二氧化鈦對晶相生成之影....................83 4.2.3溫度對晶相之影響 ................................... 92 4.4溫度對機械性質之影響 ................................ 103 4.4.1熱處理溫度對吸水率/密度之影響 ..................... 103 4.4.2熱處理溫度對抗壓強度之影響 ........................ 111 4.4.3 熱處理溫度對抗折強度之影響 ....................... 113 4.4.4燒失量與穩定度之探討 .............................. 116 4.5介電性質檢測 ........................................ 118 4.5.1介電常數之測量 .................................... 118 4.5.2散逸因子之測量 .................................... 119 4.5.3介電損失因子之測量 ................................ 122 4.5.4介電強度之測量 .................................... 123 第五章、結論與建議 ..................................... 126 5.1結論 ................................................ 126 5.2建議 ................................................ 129 第六章、參考文...........................................130 | |
dc.language.iso | zh-TW | |
dc.title | TFT-LCD廢玻璃/氟化鈣污泥熱處理資材化為絕緣玻璃陶瓷之研究 | zh_TW |
dc.title | Materialization Study on Transformation of
Insulated Glass-Ceramic from TFT-LCD Waste Glass and CaF2 Sludge by Thermal Treatment | en |
dc.type | Thesis | |
dc.date.schoolyear | 98-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 王鯤生,楊萬發 | |
dc.subject.keyword | TFT-LCD廢玻璃,氟化鈣污泥,絕緣玻璃陶瓷,MAS,介電性質, | zh_TW |
dc.subject.keyword | TFT-LCD Waste Glass,Calcium Fluoride Sludge,Insulated Glass-Ceramic,MAS system,Dielectric properties, | en |
dc.relation.page | 135 | |
dc.rights.note | 同意授權(全球公開) | |
dc.date.accepted | 2010-06-22 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 環境工程學研究所 | zh_TW |
顯示於系所單位: | 環境工程學研究所 |
文件中的檔案:
檔案 | 大小 | 格式 | |
---|---|---|---|
ntu-99-1.pdf | 6.12 MB | Adobe PDF | 檢視/開啟 |
系統中的文件,除了特別指名其著作權條款之外,均受到著作權保護,並且保留所有的權利。