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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 陳建彰 | zh_TW |
| dc.contributor.advisor | Jian-Zhang Chen | en |
| dc.contributor.author | 劉蓁 | zh_TW |
| dc.contributor.author | Chen Liu | en |
| dc.date.accessioned | 2023-03-19T22:05:12Z | - |
| dc.date.available | 2023-11-10 | - |
| dc.date.copyright | 2022-07-22 | - |
| dc.date.issued | 2022 | - |
| dc.date.submitted | 2002-01-01 | - |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/84135 | - |
| dc.description.abstract | 利用奈米複合材料還原氧化石墨烯 (reduced graphene oxide, rGO) 、 聚吡咯 (polypyrrole, PPy) 與粘合劑殼聚醣 (chitosan, CS)混合，將絲網印刷於N2常壓噴射電漿(atmospheric pressure plasma jet, APPJ)處理之碳布基材，並將處理過之碳布通過介電質屏蔽放電噴射電漿 (dielectric barrier discharge plasma jet, DBDjet) 之後處理，最終與凝膠態電解質組裝成超級電容 (supercapacitors, SC)。評估並比較奈米複合材料 rGO/CS、PPy/CS和rGO/PPy/CS超級電容的性能。 DBDjet 之處理可提高這三種奈米複合電極材料的親水性。本研究使用電化學測量包含電阻抗譜 (electrical impedance spectroscopy, EIS)、循環伏安法 (cyclic volt-ammetry, CV) 和恆電流充放電 (galvanostatic charging-discharging, GCD) 用於評估三種類型 SC 的性能。利用Trasatti方法用於評估電容的雙電層電容（electric-double layer capacitance, EDLC）和擬電容（pseudocapacitance, PC）的特性。並使用 Ragone 圖分析並比較了三種 SCs 的能量和功率密度。在本研究證實，在相同重量的奈米複合活性材料下，rGO 和 PPy 在 SCs 中的組合使用可以顯著增加電容並提高其運行穩定性。 | zh_TW |
| dc.description.abstract | Reduced graphene oxide (rGO) and/or polypyrrole (PPy) are mixed with chitosan (CS) binder materials for screen-printing flexible supercapacitors (SCs) on the carbon cloth with the pre-treatment of arc atmospheric-pressure plasma jet (APPJ). The resulting gel-electrolyte rGO/CS, PPy/CS, and rGO/PPy/CS SCs are then processed by dielectric barrier discharge plasma jet (DBDjet), used for improving the hydrophilicity of these three nanocomposite electrode materials. To compare and assess the SCs, electrochemical measurements including cyclic volt-ammetry (CV), electrical impedance spectroscopy (EIS) and galvanostatic charging-discharging (GCD) were used. In the analysis of three types of SCs, the Trasatti method is utilized to evaluate the electric-double layer capacitance (EDLC) and pseudocapacitance (PC) of each supercapacitor; Rogone plots is utilized to compare and illustrate their energy density and power density. Our experiments confirm that, with the same weight of active materials, the combined use of rGO and PPy in SCs can significantly increase the capacitance and improve the operation stability. | en |
| dc.description.provenance | Made available in DSpace on 2023-03-19T22:05:12Z (GMT). No. of bitstreams: 1 U0001-1107202214221900.pdf: 7329367 bytes, checksum: 0c9107ea0592f73b6b37c45db5bf437b (MD5) Previous issue date: 2022 | en |
| dc.description.tableofcontents | 致謝 ii
中文摘要 iii ABSTRACT iv 目錄 v 圖目錄 ix 表目錄 xiv 第一章 緒論 1 1.1前言 1 1.2研究動機 2 1.3論文大綱 3 第二章 實驗原理與文獻回顧 4 2.1 超級電容 4 2.1.1 超級電容之介紹 4 2.1.2 超級電容之儲能機制與材料組成 6 2.2 電漿 15 2.2.1 電漿之介紹 15 2.2.2 常電漿的種類及應用 19 2.3 材料特性 23 2.3.1 石墨烯之介紹 23 2.3.2 聚吡咯之介紹 25 2.3.3 殼聚醣之介紹 28 2.4 製程與量測儀器原理 31 2.4.1 常壓噴射電漿(Atmospheric pressure plasma jet, APPJ) 31 2.4.2 介電質屏蔽放電(dielectric barrier discharge, DBD) 33 2.4.3 掃描式電子顯微鏡 (Scanning Electron Microscope) 34 2.4.4 水接觸角儀 (Water contact angle instrument) 36 2.4.5 X射線光電子能譜儀(X-ray photoelectron spectroscopy) 37 2.4.6 電化學工作站量測與分析 39 第三章 實驗步驟及儀器介紹 44 3.1實驗材料及儀器 44 3.2 實驗步驟 47 3.2.1 網印刷漿料之製備 47 3.2.2 凝膠態電解液之製備 48 3.2.3 奈米複合材料電極之製備 48 3.2.4 軟性超級電容之製備 49 第四章 實驗結果與討論 50 4.1 介電質屏蔽放電噴射電漿處理還原氧化石墨烯/聚吡咯與殼聚醣奈米複合電極之水接觸角量測 50 4.2 介電質屏蔽放電噴射電漿處理還原氧化石墨烯/聚吡咯與殼聚醣奈米複合電極之表面型態結構 52 4.3 介電質屏蔽放電噴射電漿處理還原氧化石墨烯/聚吡咯與殼聚醣奈米複合電極之X射線光電子能譜儀分析 53 4.4 介電質屏蔽放電噴射電漿處理還原氧化石墨烯/聚吡咯與殼聚醣軟性超級電容之循環伏安法量測 56 4.5 介電質屏蔽放電噴射電漿處理還原氧化石墨烯/聚吡咯與殼聚醣軟性超級電容之Trasatti方法 57 4.6 介電質屏蔽放電噴射電漿處理還原氧化石墨烯/聚吡咯與殼聚醣軟性超級電容之恆電流充放電法量測 59 4.7 介電質屏蔽放電噴射電漿處理還原氧化石墨烯/聚吡咯與殼聚醣軟性超級電容之能量密度與功率密度比較 62 4.8 介電質屏蔽放電噴射電漿處理還原氧化石墨烯/聚吡咯與殼聚醣軟性超級電容之電化學阻抗分析 64 4.9 介電質屏蔽放電噴射電漿處理還原氧化石墨烯/聚吡咯與殼聚醣軟性超級電容之彎曲穩定性測試 66 4.10 介電質屏蔽放電噴射電漿處理還原氧化石墨烯/聚吡咯與殼聚醣軟性超級電容之長循環穩定性測試 68 第五章 結論 70 附錄A 實驗二: 低壓電漿處理釕沉積鎳泡沫電極於氫氣析出反應之應用 71 Low-Pressure-Plasma-Processed Ruthenium/Nickel Foam Elec-trocatalysts for Hydrogen Evolution Reaction 71 摘要 71 A.1 序論 72 A.1.1前言 72 A.1.2研究動機 72 A.2 實驗原理 74 A.2.1 電解水簡介 74 A.2.2 反應機制 75 A.2.3 電催化劑 76 A.2.4 過電位 77 A.2.5 塔弗方程式 78 A.3 實驗步驟 79 A.3.1 實驗材料 79 A.3.2 電催化劑之合成 80 A.3.3 實驗儀器介紹 81 A.4 實驗結果與討論 82 A.4.1 低壓電漿處理釕沉積鎳泡沫電極之水接觸角量測 82 A.4.2 低壓電漿處理釕沉積鎳泡沫電極之表面型態結構 84 A.4.3 低壓電漿處理釕沉積鎳泡沫電極之X射線繞射儀之量測 86 A.4.4 低壓電漿處理釕沉積鎳泡沫電極之X射線光電子能譜儀 87 A.4.5 低壓電漿處理釕沉積鎳泡沫電極之X射線光譜儀之量測 94 A.4.6 低壓電漿處理釕沉積鎳泡沫電極之線性掃伏安法和塔弗方程式分析 96 A.4.7 低壓電漿處理釕沉積鎳泡沫電極之電化學交流阻抗頻譜分析 100 A.4.8 低壓電漿處理釕沉積鎳泡沫電極之循環伏安法量測 103 A.4.9 低壓電漿處理釕沉積鎳泡沫電極之長循環穩定性量測 106 A.5 結論 107 參考文獻 108 個人期刊發表 134 | - |
| dc.language.iso | zh_TW | - |
| dc.subject | 大氣常壓電漿 | zh_TW |
| dc.subject | 還原氧化石墨烯 | zh_TW |
| dc.subject | 聚吡咯 | zh_TW |
| dc.subject | 超級電容 | zh_TW |
| dc.subject | atmospheric-pressure plasma | en |
| dc.subject | reduced graphene oxide | en |
| dc.subject | polypyrrole | en |
| dc.subject | plasma | en |
| dc.subject | dielectric barrier discharge | en |
| dc.subject | supercapacitor | en |
| dc.title | 介電質屏蔽放電噴射電漿處理還原氧化石墨烯/聚吡咯/殼聚醣奈米複合超級電容 | zh_TW |
| dc.title | Dielectric barrier discharge plasma jet (DBDjet) processed reduced graphene oxide/polypyrrole/chitosan nanocomposite supercapacitors | en |
| dc.type | Thesis | - |
| dc.date.schoolyear | 110-2 | - |
| dc.description.degree | 碩士 | - |
| dc.contributor.oralexamcommittee | 陳奕君;羅世強 | zh_TW |
| dc.contributor.oralexamcommittee | I-Chun Cheng;Shyh-Chyang Luo | en |
| dc.subject.keyword | 還原氧化石墨烯,聚吡咯,超級電容,大氣常壓電漿, | zh_TW |
| dc.subject.keyword | reduced graphene oxide,polypyrrole,plasma,dielectric barrier discharge,supercapacitor,atmospheric-pressure plasma, | en |
| dc.relation.page | 134 | - |
| dc.identifier.doi | 10.6342/NTU202201394 | - |
| dc.rights.note | 同意授權(限校園內公開) | - |
| dc.date.accepted | 2022-07-12 | - |
| dc.contributor.author-college | 工學院 | - |
| dc.contributor.author-dept | 應用力學研究所 | - |
| dc.date.embargo-lift | 2027-07-12 | - |
| 顯示於系所單位： | 應用力學研究所 | |
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