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http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/83729完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 游文岳(Wen-Yueh Yu) | |
| dc.contributor.author | Hao-Chuan Ku | en |
| dc.contributor.author | 古浩銓 | zh_TW |
| dc.date.accessioned | 2023-03-19T21:15:52Z | - |
| dc.date.copyright | 2022-08-22 | |
| dc.date.issued | 2022 | |
| dc.date.submitted | 2022-08-10 | |
| dc.identifier.citation | [1] S. Fernando, S. Adhikari, C. Chandrapal, N. Murali, Biorefineries: current status, challenges, and future direction, Energy & Fuels, 20 (2006) 1727-1737. [2] N. Mosier, C. Wyman, B. Dale, R. Elander, Y.Y. Lee, M. Holtzapple, M. Ladisch, Features of promising technologies for pretreatment of lignocellulosic biomass, Bioresource Technology, 96 (2005) 673-686. [3] I. ul Haq, K. Qaisar, A. Nawaz, F. Akram, H. Mukhtar, Z.H. Xin, Y. Xu, M.W. Mumtaz, U. Rashid, W. Ghani, T.S.Y. Choong, Advances in valorization of lignocellulosic biomass towards energy generation, Catalysts, 11 (2021) 309. [4] B.O. Abo, M. Gao, Y.L. Wang, C.F. Wu, Q.H. Wang, H.Z. Ma, Production of butanol from biomass: recent advances and future prospects, Environmental Science and Pollution Research, 26 (2019) 20164-20182. [5] E.J. Cho, L.T.P. Trinh, Y. Song, Y.G. Lee, H.J. Bae, Bioconversion of biomass waste into high value chemicals, Bioresource Technology, 298 (2020) 122386. [6] P. Gautam, Neha, S.N. Upadhyay, S.K. Dubey, Bio-methanol as a renewable fuel from waste biomass: current trends and future perspective, Fuel, 273 (2020) 117783. [7] A. Verardi, C.G. Lopresto, A. Blasi, S. Chakraborty, V. Calabr?, Bioconversion of lignocellulosic biomass to bioethanol and biobutanol, Lignocellulosic biomass to liquid biofuels, Elsevier, 2020, pp. 67-125. [8] S.K. Maity, Opportunities, recent trends and challenges of integrated biorefinery: Part I, Renewable & Sustainable Energy Reviews, 43 (2015) 1427-1445. [9] J.V. Bomtempo, F.C. Alves, F.D. Oroski, Developing new platform chemicals: what is required for a new bio-based molecule to become a platform chemical in the bioeconomy?, Faraday Discussions, 202 (2017) 213-225. [10] J.C. Escobar, E.S. Lora, O.J. Venturini, E.E. Yanez, E.F. Castillo, O. Almazan, Biofuels: environment, technology and food security, Renewable & Sustainable Energy Reviews, 13 (2009) 1275-1287. [11] Y. Roman-Leshkov, C.J. Barrett, Z.Y. Liu, J.A. Dumesic, Production of dimethylfuran for liquid fuels from biomass-derived carbohydrates, Nature, 447 (2007) 982. [12] H.L. Xiao, P.F. Zeng, Z.Z. Li, L.R. Zhao, X.W. Fu, Combustion performance and emissions of 2-methylfuran diesel blends in a diesel engine, Fuel, 175 (2016) 157-163. [13] H.L. Xiao, X.L. Yang, B.B. Hou, R. Wang, Q. Xue, H.L. Ju, Combustion performance and pollutant emissions analysis of a diesel engine fueled with biodiesel and its blend with 2-methylfuran, Fuel, 237 (2019) 1050-1056. [14] K. Alexandrino, Comprehensive review of the impact of 2,5-dimethylfuran and 2-methylfuran on soot emissions: experiments in diesel engines and at laboratory-scale, Energy & Fuels, 34 (2020) 6598-6623. [15] J.H. Zhang, J.K. Li, Y.J. Tang, L. Lin, M.N. Long, Advances in catalytic production of bio-based polyester monomer 2,5-furandicarboxylic acid derived from lignocellulosic biomass, Carbohydrate Polymers, 130 (2015) 420-428. [16] S. Sitthisa, W. An, D.E. Resasco, Selective conversion of furfural to methylfuran over silica-supported Ni-Fe bimetallic catalysts, Journal of Catalysis, 284 (2011) 90-101. [17] S. Sitthisa, D.E. Resasco, Hydrodeoxygenation of Furfural Over Supported Metal Catalysts: A Comparative Study of Cu, Pd and Ni, Catalysis Letters, 141 (2011) 784-791. [18] S. Sitthisa, T. Pham, T. Prasomsri, T. Sooknoi, R.G. Mallinson, D.E. Resasco, Conversion of furfural and 2-methylpentanal on Pd/SiO2 and Pd-Cu/SiO2 catalysts, Journal of Catalysis, 280 (2011) 17-27. [19] N. Pino, S. Sitthisa, Q.H. Tan, T. Souza, D. Lopez, D.E. Resasco, Structure, activity, and selectivity of bimetallic Pd-Fe/SiO2 and Pd-Fe/γ-Al2O3 catalysts for the conversion of furfural, Journal of Catalysis, 350 (2017) 30-40. [20] S.G. Wettstein, D.M. Alonso, Y.X. Chong, J.A. Dumesic, Production of levulinic acid and γ-valerolactone (GVL) from cellulose using GVL as a solvent in biphasic systems, Energy & Environmental Science, 5 (2012) 8199-8203. [21] J. Reichert, B. Brunner, A. Jess, P. Wasserscheid, J. Albert, Biomass oxidation to formic acid in aqueous media using polyoxometalate catalysts - boosting FA selectivity by in-situ extraction, Energy & Environmental Science, 8 (2015) 2985-2990. [22] P. Preuster, J. Albert, Biogenic formic acid as a green hydrogen carrier, Energy Technology, 6 (2018) 501-509. [23] R.F. Nie, Y.W. Tao, Y.Q. Nie, T.L. Lu, J.S. Wang, Y.S. Zhang, X.Y. Lu, C.C. Xu, Recent advances in catalytic transfer hydrogenation with formic acid over heterogeneous transition metal catalysts, ACS Catalysis, 11 (2021) 1071-1095. [24] M. Beller, J. Seayad, A. Tillack, H. Jiao, Catalytic Markovnikov and anti-Markovnikov functionalization of alkenes and alkynes: recent developments and trends, Angewandte Chemie International Edition, 43 (2004) 3368-3398. [25] Y.L. Hsu, H.Z. Wu, M.H. Ye, J.P. Chen, H.L. Huang, P.H.P. Lin, An industrial-scale biodegradation system for volatile organics contaminated wastewater from semiconductor manufacturing process, Journal of the Taiwan Institute of Chemical Engineers, 40 (2009) 70-76. [26] R.A.W. Johnstone, A.H. Wilby, I.D. Entwistle, Heterogeneous catalytic transfer hydrogenation and its relation to other methods for reduction of organic compounds, Chemical Reviews, 85 (1985) 129-170. [27] Y.W. Han, J.Y. Shen, Y. Chen, Microkinetic analysis of isopropanol dehydrogenation over Cu/SiO2 catalyst, Applied Catalysis A: General, 205 (2001) 79-84. [28] R.M. Rioux, M.A. Vannice, Hydrogenation/dehydrogenation reactions: isopropanol dehydrogenation over copper catalysts, Journal of Catalysis, 216 (2003) 362-376. [29] M.J. Gilkey, B.J. Xu, Heterogeneous catalytic transfer hydrogenation as an effective pathway in biomass upgrading, ACS Catalysis, 6 (2016) 1420-1436. [30] P. Panagiotopoulou, N. Martin, D.G. Vlachos, Effect of hydrogen donor on liquid phase catalytic transfer hydrogenation of furfural over a Ru/RuO2/C catalyst, Journal of Molecular Catalysis A: Chemical, 392 (2014) 223-228. [31] M. Ghashghaee, M. Ghambarian, Z. Azizi, Molecular-level insights into furfural hydrogenation intermediates over single-atomic Cu catalysts on magnesia and silica nanoclusters, Molecular Simulation, 45 (2019) 154-163. [32] S. Sitthisa, T. Sooknoi, Y.G. Ma, P.B. Balbuena, D.E. Resasco, Kinetics and mechanism of hydrogenation of furfural on Cu/SiO2 catalysts, Journal of Catalysis, 277 (2011) 1-13. [33] R. Gunawan, H.S. Cahyadi, R. Insyani, S.K. Kwak, J. Kim, Density functional theory investigation of the conversion of 5-(hydroxymethyl)furfural into 2,5-dimethylfuran over the Pd(111), Cu(111), and Cu3Pd(111) surfaces, Journal of Physical Chemistry C, 125 (2021) 10295-10317. [34] J. Zhang, J.Z. Chen, Selective transfer hydrogenation of biomass-based furfural and 5-hydroxymethylfurfural over hydrotalcite-derived copper catalysts using methanol as a hydrogen donor, ACS Sustainable Chemistry & Engineering, 5 (2017) 5982-5993. [35] S. Srivastava, G.C. Jadeja, J. Parikh, Copper-cobalt catalyzed liquid phase hydrogenation of furfural to 2-methylfuran: an optimization, kinetics and reaction mechanism study, Chemical Engineering Research & Design, 132 (2018) 313-324. [36] Y. Nakagawa, K. Tomishige, Heterogeneous catalysis of the glycerol hydrogenolysis, Catalysis Science & Technology, 1 (2011) 179-190. [37] M.J. Gilkey, P. Panagiotopoulou, A.V. Mironenko, G.R. Jenness, D.G. Vlachos, B.J. Xu, Mechanistic insights into metal Lewis acid-mediated catalytic transfer hydrogenation of furfural to 2-methylfuran, ACS Catalysis, 5 (2015) 3988-3994. [38] J. Luo, J.Y. Yu, R.J. Gorte, E. Mahmoud, D.G. Vlachos, M.A. Smith, The effect of oxide acidity on HMF etherification, Catalysis Science & Technology, 4 (2014) 3074-3081. [39] J. He, M.R. Nielsen, T.W. Hansen, S. Yang, A. Riisager, Hierarchically constructed NiO with improved performance for catalytic transfer hydrogenation of biomass-derived aldehydes, Catalysis Science & Technology, 9 (2019) 1289-1300. [40] N.S. Biradar, A.M. Hengne, S.S. Sakate, R.K. Swami, C.V. Rode, Single pot transfer hydrogenation and aldolization of furfural over metal oxide catalysts, Catalysis Letters, 146 (2016) 1611-1619. [41] J. Jae, W.Q. Zheng, R.F. Lobo, D.G. Vlachos, Production of dimethylfuran from hydroxymethylfurfural through catalytic transfer hydrogenation with ruthenium supported on carbon, ChemSusChem, 6 (2013) 1158-1162. [42] A.S. Nagpure, P. Gogoi, N. Lucas, S.V. Chilukuri, Novel Ru nanoparticle catalysts for the catalytic transfer hydrogenation of biomass-derived furanic compounds, Sustainable Energy & Fuels, 4 (2020) 3654-3667. [43] D. Scholz, C. Aellig, I. Hermans, Catalytic transfer hydrogenation/hydrogenolysis for reductive upgrading of furfural and 5-(hydroxymethyl)furfural, ChemSusChem, 7 (2014) 268-275. [44] T.S. Hansen, K. Barta, P.T. Anastas, P.C. Ford, A. Riisager, One-pot reduction of 5-hydroxymethylfurfural via hydrogen transfer from supercritical methanol, Green Chemistry, 14 (2012) 2457-2461. [45] Z. Gao, C.Y. Li, G.L. Fan, L. Yang, F. Li, Nitrogen-doped carbon-decorated copper catalyst for highly efficient transfer hydrogenolysis of 5-hydroxymethylfurfural to convertibly produce 2,5-dimethylfuran or 2,5-dimethyltetrahydrofuran, Applied Catalysis B: Environmental, 226 (2018) 523-533. [46] X.M. Li, P.F. Yang, X.Y. Zhang, Y.A. Liu, C.L. Miao, J.T. Feng, D.Q. Li, Insights into the role of dual-interfacial sites in Cu/ZrO2 catalysts in 5-HMF hydrogenolysis with isopropanol, ACS Applied Materials & Interfaces, 13 (2021) 22292-22303. [47] S. Srivastava, G.C. Jadeja, J. Parikh, Synergism studies on alumina-supported copper-nickel catalysts towards furfural and 5-hydroxymethylfurfural hydrogenation, Journal of Molecular Catalysis A: Chemical, 426 (2017) 244-256. [48] S. Mhadmhan, A. Franco, A. Pineda, P. Reubroycharoen, R. Luque, Continuous flow selective hydrogenation of 5-hydroxymethylfurfural to 2,5-dimethylfuran using highly active and stable Cu-Pd/reduced graphene oxide, ACS Sustainable Chemistry & Engineering, 7 (2019) 14210-14216. [49] X.D. Li, P. Jia, T.F. Wang, Furfural: a promising platform compound for sustainable production of C4 and C5 chemicals, ACS Catalysis, 6 (2016) 7621-7640. [50] M. Lesiak, M. Binczarski, S. Karski, W. Maniukiewicz, J. Rogowski, E. Szubiakiewicz, J. Berlowska, P. Dziugan, I. Witonska, Hydrogenation of furfural over Pd-Cu/Al2O3 catalysts. The role of interaction between palladium and copper on determining catalytic properties, Journal of Molecular Catalysis A: Chemical, 395 (2014) 337-348. [51] K. Fulajtarova, T. Sotak, M. Hronec, I. Vavra, E. Dobrocka, M. Omastova, Aqueous phase hydrogenation of furfural to furfuryl alcohol over Pd-Cu catalysts, Applied Catalysis A: General, 502 (2015) 78-85. [52] M. Hronec, K. Fulajtarova, I. Vavra, T. Sotak, E. Dobrocka, M. Micusik, Carbon supported Pd-Cu catalysts for highly selective rearrangement of furfural to cyclopentanone, Applied Catalysis B: Environmental, 181 (2016) 210-219. [53] X. Chang, A.F. Liu, B. Cai, J.Y. Luo, H. Pan, Y.B. Huang, Catalytic transfer hydrogenation of furfural to 2-methylfuran and 2-methyltetrahydrofuran over bimetallic copper-palladium catalysts, ChemSusChem, 9 (2016) 3330-3337. [54] F. Gonell, M. Boronat, A. Corma, Structure-reactivity relationship in isolated Zr sites present in Zr-zeolite and ZrO2 for the Meerwein-Ponndorf-Verley reaction, Catalysis Science & Technology, 7 (2017) 2865-2873. [55] D.I. Hunt, H-NMR Chemical shifts. (accessed 23 March 2022) [56] T.J. Osinga, B.G. Linsen, W.P. Vanbeek, Determination of specific copper surface area in catalysts, Journal of Catalysis, 7 (1967) 277-303. [57] J.J. Scholten, J.A. Konvalinks, Reaction of nitrous oxide with copper surfaces - application to determination of free-copper surface areas, Transactions of the Faraday Society, 65 (1969) 2465-2473. [58] G. Moretti, Auger parameter and Wagner plot in the characterization of chemical states by X-ray photoelectron spectroscopy: a review, Journal of Electron Spectroscopy and Related Phenomena, 95 (1998) 95-144. [59] S.W. Gaarenstroom, N. Winograd, Initial and final-state effects in ESCA spectra of cadmium and silver-oxides, Journal of Chemical Physics, 67 (1977) 3500-3506. [60] J.H. Scofield, Hartree-Slater subshell photoionization cross-sections at 1254 and 1487 eV, Journal of Electron Spectroscopy and Related Phenomena, 8 (1976) 129-137. [61] B. Ravel, M. Newville, ATHENA, ARTEMIS, HEPHAESTUS: data analysis for X-ray absorption spectroscopy using IFEFFIT, Journal of Synchrotron Radiation, 12 (2005) 537-541. [62] S. Grazulis, D. Chateigner, R.T. Downs, A.F.T. Yokochi, M. Quiros, L. Lutterotti, E. Manakova, J. Butkus, P. Moeck, A. Le Bail, Crystallography Open Database - an open-access collection of crystal structures, Journal of Applied Crystallography, 42 (2009) 726-729. [63] R.X. Zhou, B. Zhao, B.H. Yue, Effects of CeO2-ZrO2 present in Pd/Al2O3 catalysts on the redox behavior of PdOx and their combustion activity, Applied Surface Science, 254 (2008) 4701-4707. [64] Y.D. Cao, R. Ran, X.D. Wu, B.H. Zhao, J. Wan, D. Weng, Comparative study of ageing condition effects on Pd/Ce0.5Zr0.5O2 and Pd/Al2O3 catalysts: catalytic activity, palladium nanoparticle structure and Pd-support interaction, Applied Catalysis A: General, 457 (2013) 52-61. [65] G.X. Li, W. Hu, F.J. Huang, J.J. Chen, M.C. Gong, S.D. Yuan, Y.Q. Chen, L. Zhong, Pd catalyst supported on ZrO2-Al2O3 by double-solvent method for methane oxidation under lean conditions, Canadian Journal of Chemical Engineering, 95 (2017) 1117-1123. [66] J.Y. Liu, J.L. Shi, D.H. He, Q.J. Zhang, X.H. Wu, Y. Liang, Q.M. Zhu, Surface active structure of ultra-fine Cu/ZrO2 catalysts used for the CO2+H2 to methanol reaction, Applied Catalysis A: General, 218 (2001) 113-119. [67] C.Z. Yao, L.C. Wang, Y.M. Liu, G.S. Wu, Y. Cao, W.L. Dai, H.Y. He, K.N. Fan, Effect of preparation method on the hydrogen production from methanol steam reforming over binary Cu/ZrO2 catalysts, Applied Catalysis A: General, 297 (2006) 151-158. [68] A.G. Sato, D.P. Volanti, D.M. Meira, S. Damyanova, E. Longo, J.M.C. Bueno, Effect of the ZrO2 phase on the structure and behavior of supported Cu catalysts for ethanol conversion, Journal of Catalysis, 307 (2013) 1-17. [69] I.C. Freitas, S. Damyanova, D.C. Oliveira, C.M.P. Marques, J.M.C. Bueno, Effect of Cu content on the surface and catalytic properties of Cu/ZrO2 catalyst for ethanol dehydrogenation, Journal of Molecular Catalysis A: Chemical, 381 (2014) 26-37. [70] F.Y. Zhou, X.X. Du, J. Yu, D.S. Mao, G.Z. Lu, Highly water-resistant carbon nanotube supported PdCl2-CuCl2 catalysts for low temperature CO oxidation, RSC Advances, 6 (2016) 66553-66563. [71] M.J. Islam, M.G. Mesa, A. Osatiashtiani, J.C. Manayil, M.A. Isaacs, M.J. Taylor, S. Tsatsos, G. Kyriakou, PdCu single atom alloys supported on alumina for the selective hydrogenation of furfural, Applied Catalysis B: Environmental, 299 (2021). [72] S. Leviness, V. Nair, A.H. Weiss, Z. Schay, L. Guczi, Acetylene hydrogenation selectivity control on PdCu/Al2O3 catalysts, Journal of Molecular Catalysis, 25 (1984) 131-140. [73] B. Coq, F. Figueras, Bimetallic palladium catalysts: influence of the co-metal on the catalyst performance, Journal of Molecular Catalysis A: Chemical, 173 (2001) 117-134. [74] J.W. Jiang, C.C. Tu, C.H. Chen, Y.C. Lin, Highly selective silica-supported copper catalysts derived from copper phyllosilicates in the hydrogenation of adipic acid to 1,6-hexanediol, ChemCatChem, 10 (2018) 5449-5458. [75] Y.J. Tsou, T.D. To, Y.C. Chiang, J.F. Lee, R. Kumar, P.W. Chung, Y.C. Lin, Hydrophobic copper catalysts derived from copper phyllosilicates in the hydrogenation of levulinic acid to γ-valerolactone, ACS Applied Materials & Interfaces, 12 (2020) 54851-54861. [76] A.N. Ardila, M.A. Sanchez-Castillo, T.A. Zepeda, A.L. Villa, G.A. Fuentes, Glycerol hydrodeoxygenation to 1,2-propanediol catalyzed by CuPd/TiO2-Na, Applied Catalysis B: Environmental, 219 (2017) 658-671. [77] X. Jiang, X.W. Nie, X.X. Wang, H.Z. Wang, N. Koizumi, Y.G. Chen, X.W. Guo, C.S. Song, Origin of Pd-Cu bimetallic effect for synergetic promotion of methanol formation from CO2 hydrogenation, Journal of Catalysis, 369 (2019) 21-32. [78] S. Haq, A. Hodgson, N2O adsorption and reaction at Pd(110), Surface Science, 463 (2000) 1-10. [79] A.V. Zeigarnik, Adsorption and reactions of N2O on transition metal surfaces, Kinetics and Catalysis, 44 (2003) 233-246. [80] K. Kim, S. Baek, J.J. Kim, J.W. Han, Catalytic decomposition of N2O on PdxCuy alloy catalysts: a density functional theory study, Applied Surface Science, 510 (2020). [81] I. Melian-Cabrera, M.L. Granados, J.L.G. Fierro, Reverse topotactic transformation of a Cu-Zn-Al catalyst during wet Pd impregnation: relevance for the performance in methanol synthesis from CO2/H2 mixtures, Journal of Catalysis, 210 (2002) 273-284. [82] I. Melian-Cabrera, M.L. Granados, J.L.G. Fierro, Pd-modified Cu-Zn catalysts for methanol synthesis from CO2/H2 mixtures: catalytic structures and performance, Journal of Catalysis, 210 (2002) 285-294. [83] M.H. Kim, J.R. Ebner, R.M. Friedman, M.A. Vannice, Dissociative N2O adsorption on supported Pt, Journal of Catalysis, 204 (2001) 348-357. [84] M.H. Kim, J.R. Ebner, R.M. Friedman, M.A. Vannice, Determination of metal dispersion and surface composition in supported Cu-Pt catalysts, Journal of Catalysis, 208 (2002) 381-392. [85] B.H. Davis, Effect of pH on crystal phase of ZrO2 precipitated from solution and calcined at 600 °C, Journal of the American Ceramic Society, 67 (1984) C168-C169. [86] G. Stefanic, S. Music, B. Grzeta, S. Popovic, A. Sekulic, Influence of pH on the stability of low temperature t-ZrO2, Journal of Physics and Chemistry of Solids, 59 (1998) 879-885. [87] Z.H. Zhang, L.Y. Zhang, M.J. Hulsey, N. Yan, Zirconia phase effect in Pd/ZrO2 catalyzed CO2 hydrogenation into formate, Molecular Catalysis, 475 (2019). [88] A.U. Nilekar, A.V. Ruban, M. Mavrikakis, Surface segregation energies in low-index open surfaces of bimetallic transition metal alloys, Surface Science, 603 (2009) 91-96. [89] N. Toshima, Y. Wang, Preparation and catalysis of novel colloidal dispersions of copper/noble metal bimetallic clusters, Langmuir, 10 (1994) 4574-4580. [90] M.V. Castegnaro, A. Gorgeski, B. Balke, M.C.M. Alves, J. Morais, Charge transfer effects on the chemical reactivity of PdxCu1-x nanoalloys, Nanoscale, 8 (2016) 641-647. [91] D.M. Alonso, S.G. Wettstein, J.A. Dumesic, Bimetallic catalysts for upgrading of biomass to fuels and chemicals, Chemical Society Reviews, 41 (2012) 8075-8098. [92] J.I. Langford, A.J.C. Wilson, Scherrer after 60 years: survey and some new results in determination of crystallite size, Journal of Applied Crystallography, 11 (1978) 102-113. [93] R. Qiu, Z.L. Ding, Y.M. Xu, Q.C. Yang, K.N. Sun, R.J. Hou, CuPd bimetallic catalyst with high Cu/Pd ratio and its application in CO2 hydrogenation, Applied Surface Science, 544 (2021). [94] M. Oezaslan, F. Hasche, P. Strasser, In situ observation of bimetallic alloy nanoparticle formation and growth using high-temperature XRD, Chemistry of Materials, 23 (2011) 2159-2165. [95] X.Y. Liu, A.Q. Wang, L. Li, T. Zhang, C.Y. Mou, J.F. Lee, Structural changes of Au-Cu bimetallic catalysts in CO oxidation: in situ XRD, EPR, XANES, and FT-IR characterizations, Journal of Catalysis, 278 (2011) 288-296. [96] X. Jiang, N. Koizumi, X.W. Guo, C.S. Song, Bimetallic Pd-Cu catalysts for selective CO2 hydrogenation to methanol, Applied Catalysis B: Environmental, 170 (2015) 173-185. [97] S.X. Zhou, G. Garnweitner, M. Niederberger, M. Antonietti, Dispersion behavior of zirconia nanocrystals and their surface functionalization with vinyl group-containing ligands, Langmuir, 23 (2007) 9178-9187. [98] X. Tang, L. Hu, Y. Sun, G. Zhao, W.W. Hao, L. Lin, Conversion of biomass-derived ethyl levulinate into γ-valerolactone via hydrogen transfer from supercritical ethanol over a ZrO2 catalyst, RSC Advances, 3 (2013) 10277-10284. [99] B. Bachiller-Baeza, I. Rodriguez-Ramos, A. Guerrero-Ruiz, Interaction of carbon dioxide with the surface of zirconia polymorphs, Langmuir, 14 (1998) 3556-3564. [100] K. Pokrovski, K.T. Jung, A.T. Bell, Investigation of CO and CO2 adsorption on tetragonal and monoclinic zirconia, Langmuir, 17 (2001) 4297-4303. [101] E.M. Kock, M. Kogler, T. Bielz, B. Klotzer, S. Penner, In situ FT-IR spectroscopic study of CO2 and CO adsorption on Y2O3, ZrO2, and Yttria-stabilized ZrO2, Journal of Physical Chemistry C, 117 (2013) 17666-17673. [102] X.Y. Jia, X.S. Zhang, N. Rui, X. Hu, C.J. Liu, Structural effect of Ni/ZrO2 catalyst on CO2 methanation with enhanced activity, Applied Catalysis B: Environmental, 244 (2019) 159-169. [103] Z.Y. Ma, Y. Cheng, W. Wei, W.H. Li, Y.H. Sun, Surface properties and CO adsorption on zirconia polymorphs, Journal of Molecular Catalysis A: Chemical, 227 (2005) 119-124. [104] C. Morterra, E. Giamello, L. Orio, M. Volante, Formation and reactivity of Zr3+ centers at the surface of vacuum-activated monoclinic zirconia, Journal of Physical Chemistry, 94 (1990) 3111-3116. [105] P. Hollins, The influence of surface-defects on the infrared-spectra of adsorbed species, Surface Science Reports, 16 (1992) 51-94. [106] F. Coloma, F. Marquez, C.H. Rochester, J.A. Anderson, Determination of the nature and reactivity of copper sites in Cu-TiO2 catalysts, Physical Chemistry Chemical Physics, 2 (2000) 5320-5327. [107] C.S. Chen, J.H. You, J.H. Lin, Y.Y. Chen, Effect of highly dispersed active sites of Cu/TiO2 catalyst on CO oxidation, Catalysis Communications, 9 (2008) 2381-2385. [108] C.S. Chen, J.H. Lin, T.W. Lai, B.H. Li, Active sites on Cu/SiO2 prepared using the atomic layer epitaxy technique for a low-temperature water-gas shift reaction, Journal of Catalysis, 263 (2009) 155-166. [109] A. Dandekar, M.A. Vannice, Determination of the dispersion and surface oxidation states of supported Cu catalysts, Journal of Catalysis, 178 (1998) 621-639. [110] S.M. Rogers, C.R.A. Catlow, C.E. Chan-Thaw, A. Chutia, N. Jian, R.E. Palmer, M. Perdjon, A. Thetford, N. Dimitratos, A. Villa, P.P. Wells, Tandem site- and size-controlled Pd nanoparticles for the directed hydrogenation of furfural, ACS Catalysis, 7 (2017) 2266-2274. [111] S. Campisi, C.E. Chan-Thaw, L.E. Chinchilla, A. Chutia, G.A. Botton, K.M.H. Mohammed, N. Dimitratos, P.P. Wells, A. Villa, Dual-site-mediated hydrogenation catalysis on Pd/NiO: selective biomass transformation and maintenance of catalytic activity at low Pd loading, ACS Catalysis, 10 (2020) 5483-5492. [112] B. Shan, Y.J. Zhao, J. Hyun, N. Kapur, J.B. Nicholas, K. Cho, Coverage-dependent CO adsorption energy from first-principles calculations, Journal of Physical Chemistry C, 113 (2009) 6088-6092. [113] R.J. Behm, K. Christmann, G. Ertl, Adsorption of hydrogen on Pd(100), Surface Science, 99 (1980) 320-340. [114] A. Pintar, J. Batista, I. Musevic, Palladium-copper and palladium-tin catalysts in the liquid phase nitrate hydrogenation in a batch-recycle reactor, Applied Catalysis B: Environmental, 52 (2004) 49-60. [115] E. Asedegbega-Nieto, B. Bachiller-Baeza, A. Guerrero-Ruiz, I. Rodriguez-Ramos, Modification of catalytic properties over carbon supported Ru-Cu and Ni-Cu bimetallics - I. Functional selectivities in citral and cinnamaldehyde hydrogenation, Applied Catalysis A: General, 300 (2006) 120-129. [116] D.R. Fang, W.J. Li, J.B. Zhao, S. Liu, X.X. Ma, J.G. Xu, C.H. Xia, Catalytic hydrodechlorination of 4-chlorophenol over a series of Pd-Cu/γ-Al2O3 bimetallic catalysts, RSC Advances, 4 (2014) 59204-59210. [117] S. Jung, S. Bae, W. Lee, Development of Pd-Cu/hematite catalyst for selective nitrate reduction, Environmental Science & Technology, 48 (2014) 9651-9658. [118] X.X. Cao, A. Mirjalili, J. Wheeler, W. Xie, B.W.L. Jang, Investigation of the preparation methodologies of Pd-Cu single atom alloy catalysts for selective hydrogenation of acetylene, Frontiers of Chemical Science and Engineering, 9 (2015) 442-449. [119] G. Naresh, V.V. Kumar, C. Anjaneyulu, J. Tardio, S.K. Bhargava, J. Patel, A. Venugopal, Nano size H beta zeolite as an effective support for Ni and Ni-Cu for COx free hydrogen production by catalytic decomposition of methane, International Journal of Hydrogen Energy, 41 (2016) 19855-19862. [120] B. Pongthawornsakun, N. Wimonsupakit, J. Panpranot, Preparation of supported Au-Pd and Cu-Pd by the combined strong electrostatic adsorption and electroless deposition for selective hydrogenation of acetylene, Journal of Chemical Sciences, 129 (2017) 1721-1734. [121] H.L. Tierney, A.E. Baber, J.R. Kitchin, E.C.H. Sykes, Hydrogen dissociation and spillover on individual isolated palladium atoms, Physical Review Letters, 103 (2009) 246102. [122] G. Kyriakou, M.B. Boucher, A.D. Jewell, E.A. Lewis, T.J. Lawton, A.E. Baber, H.L. Tierney, M. Flytzani-Stephanopoulos, E.C.H. Sykes, Isolated metal atom geometries as a strategy for selective heterogeneous hydrogenations, Science, 335 (2012) 1209-1212. [123] M. FernandezGarcia, J.A. Anderson, G.L. Haller, Alloy formation and stability in Pd-Cu bimetallic catalysts, Journal of Physical Chemistry, 100 (1996) 16247-16254. [124] C. Sarkar, P. Koley, I. Shown, J. Lee, Y.F. Liao, K. An, J. Tardio, L. Nakka, K.H. Chen, J. Mondal, Integration of interfacial and alloy effects to modulate catalytic performance of metal-organic-framework-derived Cu-Pd nanocrystals toward hydrogenolysis of 5-hydroxymethylfurfural, ACS Sustainable Chemistry & Engineering, 7 (2019) 10349-10362. [125] J. Imbao, J.A. van Bokhoven, A. Clark, M. Nachtegaal, Elucidating the mechanism of heterogeneous Wacker oxidation over Pd-Cu/zeolite Y by transient XAS, Nature Communications, 11 (2020). [126] F. Platero, A. Lopez-Martin, A. Caballero, T.C. Rojas, M. Nolan, G. Colon, Overcoming Pd-TiO2 deactivation during H2 production from photoreforming using Cu@Pd nanoparticles supported on TiO2, ACS Applied Nano Materials, 4 (2021) 3204-3219. [127] M. Fernandez-Garcia, J.C. Conesa, A. Clotet, J.M. Ricart, N. Lopez, F. Illas, Study of the heterometallic bond nature in PdCu(111) surfaces, Journal of Physical Chemistry B, 102 (1998) 141-147. [128] N. Martensson, R. Nyholm, H. Calen, J. Hedman, B. Johansson, Electron-spectroscopic studies of the CuxPd1-x alloy system: chemical-shift effects and valence-electron spectra, Physical Review B, 24 (1981) 1725-1738. [129] J. Batista, A. Pintar, D. Mandrino, M. Jenko, V. Martin, XPS and TPR examinations of γ-alumina-supported Pd-Cu catalysts, Applied Catalysis A: General, 206 (2001) 113-124. [130] B. Wang, C. Wen, Y.Y. Cui, X. Chen, Y. Dong, W.L. Dai, Remarkable crystal phase effect of Cu/TiO2 catalysts on the selective hydrogenation of dimethyl oxalate, RSC Advances, 5 (2015) 29040-29047. [131] M.C. Biesinger, Advanced analysis of copper X-ray photoelectron spectra, Surface and Interface Analysis, 49 (2017) 1325-1334. [132] H. Guzman, F. Salomone, S. Bensaid, M. Castellino, N. Russo, S. Hernandez, CO2 conversion to alcohols over Cu/ZnO catalysts: prospective synergies between electrocatalytic and thermocatalytic routes, ACS Applied Materials & Interfaces, 14 (2022) 517-530. [133] S.H. Liu, H.P. Wang, H.C. Wang, Y.W. Yang, In situ EXAFS studies of copper on ZrO2 during catalytic hydrogenation of CO2, Journal of Electron Spectroscopy and Related Phenomena, 144 (2005) 373-376. [134] F.C.F. Marcos, F.M. Cavalcanti, D.D. Petrolini, L.L. Lin, L.E. Betancourt, S.D. Senanayake, J.A. Rodriguez, J.M. Assaf, R. Giudici, E.M. Assaf, Effect of operating parameters on H2/CO2 conversion to methanol over Cu-Zn oxide supported on ZrO2 polymorph catalysts: characterization and kinetics, Chemical Engineering Journal, 427 (2022). [135] I. Ro, Y.F. Liu, M.R. Ball, D.H.K. Jackson, J.P. Chada, C. Sener, T.F. Kuech, R.J. Madon, G.W. Huber, J.A. Dumesic, Role of the Cu-ZrO2 interfacial sites for conversion of ethanol to ethyl acetate and synthesis of methanol from CO2 and H2, ACS Catalysis, 6 (2016) 7040-7050. [136] J. Choi, H. Oh, S.W. Han, S. Ahn, J. Noh, J.B. Park, Preparation and characterization of graphene oxide supported Cu, Cu2O, and CuO nanocomposites and their high photocatalytic activity for organic dye molecule, Current Applied Physics, 17 (2017) 137-145. [137] J.D. Grunwaldt, M. Maciejewski, A. Baiker, In situ X-ray absorption study during methane combustion over Pd/ZrO2 catalysts, Physical Chemistry Chemical Physics, 5 (2003) 1481-1488. [138] Y.J. Chou, H.C. Ku, C.C. Chien, C.C. Hu, W.Y. Yu, Palladium nanoparticles supported on nanosheet-like graphitic carbon nitride for catalytic transfer hydrogenation reaction, Catalysis Science & Technology, 10 (2020) 7883-7893. [139] T. Ishida, K. Kume, K. Kinjo, T. Honma, K. Nakada, H. Ohashi, T. Yokoyama, A. Hamasaki, H. Murayama, Y. Izawa, M. Utsunomiya, M. Tokunaga, Efficient decarbonylation of furfural to furan catalyzed by zirconia-supported palladium clusters with low atomicity, ChemSusChem, 9 (2016) 3441-3447. [140] K. Okumura, H. Matsui, T. Tomiyama, T. Sanada, T. Honma, S. Hirayama, M. Niwa, Highly dispersed Pd species active in the Suzuki-Miyaura reaction, ChemPhysChem, 10 (2009) 3265-3272. [141] F.L. Xing, J. Jeon, T. Toyao, K. Shimizu, S. Furukawa, A Cu-Pd single-atom alloy catalyst for highly efficient NO reduction, Chemical Science, 10 (2019) 8292-8298. [142] K. Barbera, P. Lanzafame, A. Pistone, S. Millesi, G. Malandrino, A. Gulino, S. Perathoner, G. Centi, The role of oxide location in HMF etherification with ethanol over sulfated ZrO2 supported on SBA-15, Journal of Catalysis, 323 (2015) 19-32. [143] P.P. Yang, Q.Q. Cui, Y.H. Zu, X.H. Liu, G.Z. Lu, Y.Q. Wang, Catalytic production of 2,5-dimethylfuran from 5-hydroxymethylfurfural over Ni/Co3O4 catalyst, Catalysis Communications, 66 (2015) 55-59. [144] I. Elsayed, M.A. Jackson, E. Hassan, Hydrogen-free catalytic reduction of biomass-derived 5-hydroxymethylfurfural into 2,5-bis(hydroxymethyl)furan using copper-iron oxides bimetallic nanocatalyst, ACS Sustainable Chemistry & Engineering, 8 (2020) 1774-1785. [145] G.A.M. Hussein, N. Sheppard, M.I. Zaki, R.B. Fahim, Infrared spectroscopic studies of the reactions of alcohols over group IVB metal-oxide catalysts: Part 1. propan-2-ol over TiO2, ZrO2 and HfO2, Journal of the Chemical Society Faraday Transactions I, 85 (1989) 1723-1742. [146] G.A.M. Hussein, B.C. Gates, Surface and catalytic properties of yttrium oxide: Evidence from infrared spectroscopy, Journal of Catalysis, 176 (1998) 395-404. [147] H. Chen, L. Zhao, S.Z. Li, J. Xu, J.Y. Shen, Effects of water on the hydrogenation of acetone over Ni/MgAlO catalysts, Chinese Journal of Catalysis, 36 (2015) 380-388. [148] A. Gervasini, A. Auroux, Acidity and basicity of metal-oxide surfaces: part 2 determination by catalytic decomposition of isopropanol, Journal of Catalysis, 131 (1991) 190-198. [149] D. Kulkarni, S.E. Wachs, Isopropanol oxidation by pure metal oxide catalysts: number of active surface sites and turnover frequencies, Applied Catalysis A: General, 237 (2002) 121-137. [150] W. Turek, A. Krowiak, Evaluation of oxide catalysts' properties based on isopropyl alcohol conversion, Applied Catalysis A: General, 417 (2012) 102-110. [151] S. Roy, G. Mpourmpakis, D.Y. Hong, D.G. Vlachos, A. Bhan, R.J. Gorte, Mechanistic study of alcohol dehydration on γ-Al2O3, ACS Catalysis, 2 (2012) 1846-1853. [152] K. Larmier, C. Chizallet, N. Cadran, S. Maury, J. Abboud, A.F. Lamic-Humblot, E. Marceau, H. Lauron-Pernot, Mechanistic investigation of isopropanol conversion on alumina catalysts: location of active sites for alkene/ether production, ACS Catalysis, 5 (2015) 4423-4437. [153] H. Bahruji, M. Bowker, C. Brookes, P.R. Davies, I. Wawata, The adsorption and reaction of alcohols on TiO2 and Pd/TiO2 catalysts, Applied Catalysis A: General, 454 (2013) 66-73. [154] M.I. Zaki, N. Sheppard, An infrared spectroscopic study of the adsorption and mechanism of surface-reactions of 2-propanol on ceria, Journal of Catalysis, 80 (1983) 114-122. [155] M.I. Zaki, M.A. Hasan, F.A. Al-Sagheer, L. Pasupulety, Surface chemistry of acetone on metal oxides: IR observation of acetone adsorption and consequent surface reactions on silica-alumina versus silica and alumina, Langmuir, 16 (2000) 430-436. [156] M.I. Zaki, M.A. Hasan, L. Pasupulety, In situ FTIR spectroscopic study of 2-propanol adsorptive and catalytic interactions on metal-modified aluminas, Langmuir, 17 (2001) 4025-4034. [157] G. Feng, C.F. Huo, C.M. Deng, L. Huang, Y.W. Li, J.G. Wang, H.J. Jiao, Isopropanol adsorption on γ-Al2O3 surfaces: a computational study, Journal of Molecular Catalysis A: Chemical, 304 (2009) 58-64. [158] S.D. Zhou, C. Qian, X.Z. Chen, Comparative theoretical study of adsorption and dehydrogenation of formic acid, hydrazine and isopropanol on Pd(111) surface, Catalysis Letters, 141 ( | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/83729 | - |
| dc.description.abstract | 本研究目標研發催化轉移氫化(catalytic transfer hydrogenation, CTH)異相觸媒，將生質資源與液態氫源異丙醇進行反應，轉換成高值化的化學品。我們以共含浸法製備Cu-Pd/ZrO2雙金屬觸媒，應用於羥甲基糠醛(5-hydroxymethylfurfural, HMF)與異丙醇之加氫脫氧反應(hydrodeoxygenation)，生成新一代生質燃油—二甲基?喃(2,5-dimethylfuran, DMF)。反應測試結果顯示，Cu-Pd/ZrO2觸媒的反應物轉化率與產物選擇率皆優於相應之單金屬觸媒(Cu/ZrO2和Pd/ZrO2)。雙金屬觸媒優異的催化表現可歸因於Cu-Pd兩金屬之協同作用，包含三個層面：金屬分散性、幾何效應與電荷效應。觸媒物化性質鑑定指出，雙金屬形成合金顆粒後使得金屬分散度提升，增加觸媒活性表面積。再者，我們應用一氧化碳吸附紅外光譜與氫氣脈衝吸附實驗等表面探測技術，發現雙金屬擔載比例可改變Pd位點連續性，進而影響生質衍生物與異丙醇氫源之交互作用，此現象亦利用密度泛函理論計算得到證實。觸媒化學環境鑑定則觀察到，Cu-Pd雙金屬表面存在電荷傳遞效應，其中Cuδ+位點可作為路易士酸性位點幫助吸附異丙醇，並脫去異丙醇中羥基的H原子，生成異丙氧基反應中間體；而Pdδ-位點能攫取異丙氧基的α-H原子，完成異丙醇脫氫反應。此外，Pd1/Cu(111)活性位點構型亦有利於舒緩異丙醇、羥甲基糠醛及含氧反應中間產物在觸媒表面的競爭型吸附，進而促進二甲基?喃的選擇性生成。 | zh_TW |
| dc.description.abstract | This research is aimed at developing heterogeneous catalysts for catalytic transfer hydrogenation of biomass resources into value-added chemicals using isopropanol (IPA) as the liquid hydrogen source. In this work, Cu-Pd/ZrO2 bimetallic catalysts were prepared by co-impregnation method for the hydrodeoxygenation of 5-hydroxymethylfurfural (HMF) with IPA to form 2,5-dimethylfuran (DMF), a next-generation biofuel. Catalytic reaction tests show that Cu-Pd/ZrO2 exhibits higher bio-derived substrate conversion and product selectivity than its monometallic counterparts (i.e., Cu/ZrO2 and Pd/ZrO2). The outstanding catalytic performance of Cu-Pd/ZrO2 is attributed to the synergistic effect of Cu-Pd conjunction, which includes metal dispersion, geometric and electronic effect. Physicochemical characterization indicates that the formation of Cu-Pd alloy raises metal dispersion, increasing the active surface area. Also, on the basis of surface probing techniques, such as CO-chemisorbed infrared spectra and H2 pulse chemisorption, we observed that the continuity of Pd sites could be controlled by tuning the loading ratio of Cu-Pd metals, which further influence the interaction of bio-derivatives and IPA and was proved by theoretical investigation employing density functional theory (DFT) calculations. Characterizations on chemical environment of the catalysts found that the electron transfer occurs on the Cu-Pd bimetallic surface, where the Cuδ+ could serve as Lewis acid site to adsorb isopropanol and help abstract the hydroxyl H in IPA to form isopropoxide intermediate, and Pdδ- could dissociate the α-H from the isopropoxide to complete the dehydrogenation of IPA. Additionally, the observed configuration of Pd1/Cu(111) active sites is beneficial to relieve the competitive adsorption among IPA, HMF, and other oxygen-containing reaction intermediates on the catalyst surface, thus promoting the selective formation of 2,5-dimethylfuran. | en |
| dc.description.provenance | Made available in DSpace on 2023-03-19T21:15:52Z (GMT). No. of bitstreams: 1 U0001-1008202200511500.pdf: 11206341 bytes, checksum: e97b3ffe9970ec4e261130c2ff2d5f3e (MD5) Previous issue date: 2022 | en |
| dc.description.tableofcontents | 口試委員會審定書 i 誌謝 ii 摘要 iv ABSTRACT v 目錄 vi 圖目錄 ix 表目錄 xiii Chapter 1 緒論 1 1.1 研究背景 1 1.1.1 生質資源之轉化與應用 1 1.1.2 生質能源 4 1.2 反應介紹 6 1.2.1 由羥甲基糠醛生成二甲基?喃 6 1.2.2 催化轉移氫化反應 7 1.2.3 催化轉移氫化之氫源選擇 8 1.2.4 催化轉移氫化之反應機制 10 1.3 觸媒介紹 12 1.3.1 應用於催化轉移氫化反應之觸媒 12 1.3.2 銅金屬擔載觸媒之研究進展 14 1.3.3 銅–鈀雙金屬觸媒 18 1.4 研究目標 20 Chapter 2 實驗方法 21 2.1 實驗藥品 21 2.2 觸媒製備 22 2.2.1 二氧化鋯載體製備 22 2.2.2 金屬奈米顆粒擔載 22 2.3 活性測試與產物分析 24 2.3.1 催化活性測試 24 2.3.2 產物分析–氣相層析火焰離子化偵測儀 (GC-FID) 26 2.3.3 產物分析–氣相層析質譜儀 (GC-MS) 29 2.3.4 產物分析–氫核磁共振頻譜儀 (1H-NMR) 30 2.4 觸媒鑑定 35 2.4.1 X光繞射儀 (XRD) 35 2.4.2 比表面積及孔隙分布測定儀 (ASAP) 37 2.4.3 感應耦合電漿光學發射光譜儀 (ICP-OES) 38 2.4.4 掃描式電子顯微鏡 (SEM) 40 2.4.5 穿透式電子顯微鏡 (TEM) 40 2.4.6 化學吸附分析儀 41 2.4.7 傅立葉轉換紅外線光譜儀 (FTIR) 45 2.4.8 X光光電子能譜儀 (XPS) 48 2.4.9 X光吸收光譜 (XAS) 51 2.4.10 熱重分析儀-示差熱掃描分析儀 (TGA-DSC) 54 Chapter 3 結果與討論 55 3.1 觸媒鑑定 55 3.1.1 觸媒H2-TPR鑑定 55 3.1.2 觸媒XRD與物理性質鑑定 58 3.1.3 觸媒SEM與TEM鑑定 63 3.1.4 觸媒CO-IR鑑定 66 3.1.5 觸媒H2 pulse chemisorption鑑定 70 3.1.6 觸媒XPS鑑定 72 3.1.7 觸媒XAS鑑定 74 3.2 催化活性測試 81 3.2.1 反應參數篩選測試 81 3.2.2 金屬擔載比例測試 85 3.2.3 反應中間產物活性測試 89 3.2.4 觸媒回收測試 96 3.3 反應機制討論 104 3.3.1 異丙醇脫氫反應 105 3.3.2 羥甲基糠醛之氫化反應 114 3.3.3 羥基化合物之氫解反應 116 3.3.4 競爭型吸附與幾何效應 121 Chapter 4 結論 124 Chapter 5 未來展望 125 REFERENCE 126 APPENDIX 142 在學經歷 154 | |
| dc.language.iso | zh-TW | |
| dc.subject | 異丙醇 | zh_TW |
| dc.subject | 催化轉移氫化 | zh_TW |
| dc.subject | 雙金屬觸媒 | zh_TW |
| dc.subject | 羥甲基糠醛 | zh_TW |
| dc.subject | 二甲基?喃 | zh_TW |
| dc.subject | isopropanol | en |
| dc.subject | catalytic transfer hydrogenation (CTH) | en |
| dc.subject | bimetallic catalyst | en |
| dc.subject | 5-hydroxymethylfurfural | en |
| dc.subject | 5-dimethylfuran | en |
| dc.title | 應用銅-鈀/二氧化鋯雙金屬觸媒於羥甲基糠醛與異丙醇之催化轉移氫化反應 | zh_TW |
| dc.title | Transfer Hydrogenation of 5-Hydroxymethylfurfural with Isopropanol over Copper-Palladium Bimetallic Nanoparticles Supported on Zirconia | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 110-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.advisor-orcid | 游文岳(0000-0001-6818-3075) | |
| dc.contributor.oralexamcommittee | 黃炳照(Bing-Joe Hwang),林裕川(Yu-Chuan Lin),李奕霈(Yi-Pei Li) | |
| dc.contributor.oralexamcommittee-orcid | 黃炳照(0000-0002-3873-2149),林裕川(0000-0002-2229-6354),李奕霈(0000-0002-1314-3276) | |
| dc.subject.keyword | 催化轉移氫化,雙金屬觸媒,羥甲基糠醛,二甲基?喃,異丙醇, | zh_TW |
| dc.subject.keyword | catalytic transfer hydrogenation (CTH),bimetallic catalyst,5-hydroxymethylfurfural,2,5-dimethylfuran,isopropanol, | en |
| dc.relation.page | 154 | |
| dc.identifier.doi | 10.6342/NTU202202234 | |
| dc.rights.note | 未授權 | |
| dc.date.accepted | 2022-08-10 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
| 顯示於系所單位： | 化學工程學系 | |
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