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  1. NTU Theses and Dissertations Repository
  2. 工學院
  3. 化學工程學系
請用此 Handle URI 來引用此文件: http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/82915
完整後設資料紀錄
DC 欄位值語言
dc.contributor.advisor何國川(Kuo-Chuan Ho)
dc.contributor.authorYu-Jia Huangen
dc.contributor.author黃鈺珈zh_TW
dc.date.accessioned2022-11-25T08:02:30Z-
dc.date.copyright2021-08-20
dc.date.issued2021
dc.date.submitted2021-08-04
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dc.identifier.urihttp://tdr.lib.ntu.edu.tw/jspui/handle/123456789/82915-
dc.description.abstract"如今,由於對環境的日益關注和電子設備需求的不斷增長,人們致力於開發儲能和節能技術。超級電容器和電致變色器件引起了人們的關注,本論文提供了兩種分別用於超級電容器和電致變色的材料,以提高整體電化學性能。 本研究第三章中,將MOF-74-CoMnS/V2C (MXene)材料引入超級電容器並進一步擴展到全固態元件。MOF-74-CoMn/V2C在MOF-74-CoMn合成過程中從添加的碳化釩中獲得了很大的比表面積 (722.5 m2 g-1)。本研究優化鈷和錳的比例以提升超級電容器的性能。優化後的 CoMnS-3:1/V2C在1 A g-1的電流密度下展示出1158 F g-1的比電容,並且在1000次循環後顯示出優異的循環穩定性。CoMnS-3:1/V2C比電容歸因於擬電容(26.8%)和電子雙層電容 (73.2%)。此外,由CoMnS-3:1/V2C作為電極組裝的可撓性固態對稱超級電容器裝置在335.7 W kg-1的功率密度下具有 4.7 Wh kg-1的能量密度。在彎曲測試中,可撓性CoMnS-3:1/V2C超級電容器表示80%、60%、40%和20%的彎曲度分別保持原電容的98%、97%、97%和94%,並且在20%的彎曲度下連續1000次循環後仍保持原電容的94%。這些結果表明CoMnS-3:1/V2C 在開發從液體系統到固體系統的儲能應用方面皆具有巨大潛力。 在本研究第四章中,為了解決紫精的聚集問題,引入了靜電排斥的概念,並使用鹵素基團來修飾芐基紫精分子。為了研究鹵素取代基對電致變色性能的影響,將兩種新型芐基紫精包括氟化芐基紫精(FBzV)和氯化芐基紫精(ClBzV)與芐基紫精(BzV)進行比較。本研究也探討由芐基紫精和二茂鐵組成的電致變色元件,根據電化學分析和光學測量結果,鹵素取代基不僅通過改變電子分佈來影響電化學性能,而且通過靜電排斥誘導提高光學性能和穩定性並防止自由基陽離子聚集。此氟化紫精/二茂鐵元件在二極式系統0 V與1.1 V的操作下具有64.8%之光學穿透度變化、小於2秒的著去色響應時間,並在10,000圈操作後仍保持其最初94%之光學度穿透度變化。根據結果顯示,氟化紫精/二茂鐵元件在光學對比度和長期穩定性方面表現出最好的電致變色性能。這意味著通過包含具有更強靜電排斥力的氟取代基減少了紫精的聚集。 "zh_TW
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Previous issue date: 2021
en
dc.description.tableofcontents致謝 I 中文摘要 II Abstract III Table of Contents V List of Tables VIII List of Figures IX Nomenclatures XII Chapter 1 Introduction 1 1.1 Introduction of supercapacitors 1 1.1.1 Background of supercapacitor 1 1.1.2 Introduction of supercapacitor materials 3 1.2 Introduction of electrochromism 8 1.2.1 Background of electrochromism 8 1.2.2 Electrochromic devices (ECDs) 11 1.2.3 Electrochromic materials 15 1.3 Scope of this thesis 17 Chapter 2 Experimental Procedure 20 2.1 Materials 20 2.2 Experimental detail related to Chapter 3 21 2.2.1 Synthesis of vanadium carbide (V2C) 21 2.2.2 Synthesis of CoMn-MOF-74/V2C 21 2.2.3 Synthesis of CoMnS/V2C on CC 22 2.2.4 Fabrication of symmetric all-solid-state device 22 2.3 Experimental detail related to Chapter 4 23 2.3.1 Synthesis of benzyl viologen derivatives 23 2.3.2 Anion exchange of benzyl viologen and its derivatives 23 2.3.3 Fabrication of the ECDs with benzyl viologen derivatives and ferrocene 24 2.4 Analytic techniques 25 2.4.1 Material characterizations 25 2.4.2 Electrochemical properties for SCs 25 2.4.3 Electrochemical properties for the solid-state symmetric SC 27 2.4.4 Electrochemical properties for ECDs 28 Chapter 3 MXenes Induced Bimetallic MOF-74 Derivative as a Flexible Electrode for All-solid-state Supercapacitor 29 3.1 Introduction 29 3.2 Results and discussion 32 3.2.1 Characterizations 32 3.2.2 Morphology 38 3.2.3 Electrochemical Performances 42 3.2.4 Solid-state supercapacitor 50 3.3 Conclusions 55 Chapter 4 Effect of Halogen Substituents in Benzyl-Based Viologen on the Electrochromic Performance: Optical Contrast and Stability 57 4.1 Introduction 57 4.2 Results and discussion 59 4.2.1 Electrochemical performances of benzyl-based viologen ECDs 59 4.2.2 Electrochromic characterization of benzyl-based viologen ECDs 69 4.2.3 Long-term stabilities of benzyl-based viologen ECDs 74 4.3 Conclusions 75 Chapter 5 Conclusions and suggestions 77 5.1 Conclusions 77 5.2 Suggestions 77 5.2.1 Suggestions for Chapter 3 77 5.2.2 Suggestions for Chapter 4 78 References 80 Appendix 102
dc.language.isoen
dc.subject芐基紫精zh_TW
dc.subject有機金屬骨架zh_TW
dc.subject鹵素zh_TW
dc.subject電致變色元件zh_TW
dc.subject雙金屬硫化物zh_TW
dc.subject二維碳材zh_TW
dc.subject固態超級電容器zh_TW
dc.subject碳化釩zh_TW
dc.subjectVanadium carbideen
dc.subjectBenzyl viologenen
dc.subjectBimetallic sulfideen
dc.subjectElectrochromic deviceen
dc.subjectHalogenen
dc.subjectMOF-74en
dc.subjectMXeneen
dc.subjectSolid-state Supercapacitoren
dc.title合成雙金屬MOF-74/MXene衍生物及含鹵素官能基之芐基紫精二聚體分別應用於超級電容與電致變色元件zh_TW
dc.titleSynthesizing Bimetallic MOF-74/MXene Derivatives and Benzyl Viologen Dimers with Halogen Functional Group for Supercapacitors and Electrochromic Devices Respectivelyen
dc.date.schoolyear109-2
dc.description.degree碩士
dc.contributor.oralexamcommittee陳林祈(Hsin-Tsai Liu),林正嵐(Chih-Yang Tseng)
dc.subject.keyword芐基紫精,雙金屬硫化物,電致變色元件,鹵素,有機金屬骨架,二維碳材,固態超級電容器,碳化釩,zh_TW
dc.subject.keywordBenzyl viologen,Bimetallic sulfide,Electrochromic device,Halogen,MOF-74,MXene,Solid-state Supercapacitor,Vanadium carbide,en
dc.relation.page104
dc.identifier.doi10.6342/NTU202101893
dc.rights.note未授權
dc.date.accepted2021-08-04
dc.contributor.author-college工學院zh_TW
dc.contributor.author-dept化學工程學研究所zh_TW
dc.date.embargo-lift2025-07-31-
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