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http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/82679完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 陳賢燁(Hsien-Yeh Chen) | |
| dc.contributor.author | Tatsuya Kusanagi | en |
| dc.contributor.author | 草剪 達也 | zh_TW |
| dc.date.accessioned | 2022-11-25T07:57:40Z | - |
| dc.date.copyright | 2022-02-21 | |
| dc.date.issued | 2022 | |
| dc.date.submitted | 2022-02-14 | |
| dc.identifier.citation | References 1. Furukawa, H.; Cordova, K. E.; O’Keeffe, M.; Yaghi, O. M. The Chemistry and Applications of Metal-Organic Frameworks. Science 2013, 341, 1230444. 2. O. K. Farha, I. Eryazici, N. C. Jeong, B. G. Hauser, C. E. Wilmer, A. A. Sarjeant, R. Q. Snurr, S. T. Nguyen, A. O. Yazaydin, J.Am.Chem. Soc. 2012, 134, 15016-15021; 3. L. J. Murray, M. Dincă and J. R. Long, Hydrogen storage in metal–organic frameworks. Chem. Soc. Rev., 2009, 38, 1294. 4. Yuhan Wang, Dr. Hua Jin, QiangMa, Kai Mo,Haizhuo Mao, Prof. Dr. Armin Feldhoff, Prof. Dr. Xingzhong Cao, Prof. Dr. Yanshuo Li, Dr. Fusheng, Pan,Prof. Dr. Zhongyi Jiang, A MOF Glass Membrane for Gas Separation, A journal of the German Chemical Society, 2020, 59 (11), 4635-4369 5. Baiyan Li , Yiming Zhang , Dingxuan Ma , Lu Li , Guanghua Li , Guodong Li , Zhan Shi * and Shouhua Feng, A strategy toward constructing a bifunctionalized MOF catalyst: post-synthetic modification of MOFs on organic ligands and coordinatively unsaturated metal sites, Chemical Communications, 2012, 48, 6151-6153. 6. Zhichao Shao, Chao Huang, Qiong Wu, Yujie Zhao, Wenjuan Xu, Yeye Liu, Jian Dang,Hongwei Hou, Ion exchange collaborating coordination substitution: More efficient Cr(VI) removal performance of a water-stable CuII-MOF material, Journal of Hazardous Materials, 2019, 378 (15), 120719. 7. Dr. Kuthuru Suresh,Prof. Adam J. Matzger, Enhanced Drug Delivery by Dissolution of Amorphous Drug Encapsulated in a Water Unstable Metal–Organic Framework (MOF), A journal of the German Chemical Society, 2019, 58 (47), 16790-16794. 8. Qiu He, et al, Solvent-Free Synthesis of Uniform MOF Shell-Derived Carbon Confined SnO2/Co Nanocubes for Highly Reversible Lithium Storage, small, 2017, 13(37), 1701644. 9. Osama Shekhah, et al, A facile solvent-free synthesis route for the assembly of a highly CO2 selective and H2S tolerant NiSIFSIX metal–organic framework, Chem.Commun, 2015, 51,13595-15598. 10. Yang Li, et al, High performance nanoporous carbon microsupercapacitors generated by a solvent-free MOF-CVD method, Carbon, 2019, 152, 688-696. 11. Heather F et al, The Effect of Surface Hydroxylation on MOF Formation on ALD Metal Oxides: MOF-525 on TiO2/Polypropylene for Catalytic Hydrolysis of Chemical Warfare Agent Simulants, ACS Applied Materials Interfaces, 2020, 12(13),14690-14701. 12. Ibo Stassen et al, Chemical vapour deposition of zeolitic imidazolate frameworks thin films. Nature Materials, 2016, 15, 304-310. 13. Hang Lei et al, Atomic layer deposited Al2O3 layer confinement: an efficient strategy to synthesize durable MOF-derived catalysts toward the oxygen evolution reaction, Inorganic Chemistry Frontiers, 2021, 8, 1432-1438 14. Junjie Zhao et al, Highly Adsorptive, MOF-Functionalized Nonwoven Fiber Mats for Hazardous Gas Capture Enabled by Atomic Layer Deposition, Advanced Materials Interfaces, 2014, 1 (4), 1400040. 15. Junjie Zhao et al, Conformal and highly adsorptive metal- organic framework thin films via layer-by-layer growth on ALD-coated fiver mats, Journal of Materials Chemistry A, 2015, 3 ,1458-1464. 16. Ivo Stassen et al, Solvent-free synthesis of supported ZIF-8 film patterns through transformation of deposited precursors, CrystEngComm, 2013, 15, 9308. 17. William Gorham et al, A New General Synthetic Method for the Preparation of Linear Poly-p-xylylenes, Polymer Chemistry, 1966, 4(12), 3027-3039. 18. B. A. Gryzybowski et al, Generation of micrometer-sized patterns for miranalytical applications using a laser direct-write method and microcontact printing. Analytical Chemistry,1998, 70,4645-4652. 19. D. C. Duffy et al, Rapid prototyping of microfluidic systems in poly ( dimethylsiloxane). Analytical Chemistry, 1998, 70,4947-4948. 20. M. A. Ionescu et al, Parylene-N a better Candidate for Medical Substrate Coating than Parylene-C, Revista De Chimie, 2015, 66, | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/82679 | - |
| dc.description.abstract | 金屬有機框架(MOF)在氣體儲存、微電子(MEMS)和醫學領域的潛在應用而備受關注。因此，利用MOF實現設備的應用需要合成方法來製造出精細的MOF。此外，近年來有機溶劑在醫學上是有毒的，伴隨著環境污染、易燃危險和成本增加等問題。針對MOFs來說，各種無溶劑合成方法已經被報導。開發一種能夠合成緻密MOFs的方法也是可取的，例如MEMS的MOFs。在這項研究中，我們建立了一種簡單的方法，通過CVD合成方法，僅使用少量的有機溶劑合成MOFs，通過RGA和IR合成MOFs所需的有機連接劑，並通過XRD和SEM鑑定合成的MOFs。得到極薄的MOF薄膜（約5μm），有望應用於MEMS。傳統合成方法中經常使用的ALD，是一種極其專業的儀器，而CVD是一種通用的實驗工具，在工業上已被廣泛使用，使得MOFs的合成更加方便。這項研究還證明了一種新的圖案化策略的應用，因為金屬前體可以通過無溶劑的加工而任意排列。 | zh_TW |
| dc.description.provenance | Made available in DSpace on 2022-11-25T07:57:40Z (GMT). No. of bitstreams: 1 U0001-1202202223272400.pdf: 4130531 bytes, checksum: 6ccb7f4210d6b0c265ac4c74b0847641 (MD5) Previous issue date: 2022 | en |
| dc.description.tableofcontents | " Contents ABSTRACT Ⅰ,Ⅱ,Ⅲ CONTENT Ⅳ LIST OF FIGURES Ⅴ CHAPTER 1 INTRODUCTION 1 1.1 METAL ORGANIC FRAMEWORK (MOF) 1 1.2 CHEMICAL VAPOR DEPOSITION (CVD) 2 1.3 POLY-PARA-XYLYLENE (PPX) 3 CHAPTER 2 EXPERIMENTAL SECTION 6 2.1 PREPARATION AND PREHEATING ZN PLATE 6 2.2 CVD FOR MOF FABRICATION 6 2.3 AFTER TREATMENTS FOR MOF 7 2.4 CHARACTERIZATION OF VAPOR PHASE 9 2.5 FOURIER TRANSFORM INFRARED SPECTROSCOPY (IRRAS) 9 2.6 SCANNING ELECTRON MICROSCOPY (SEM) 10 CHAPTER-3 RESULTS AND DISCUSSION 11 3.1 RGA 11 3.2 IR SPECTRAM 13 3.3 XRD RESULTS 14 3.4 TEMPERATURE DEPENDENCE IN THE MOF FABRICATION 16 3.5 SEM RESULTS 18 CHAPTER-4 CONCLUSIONS 20 4.1 CONCLUSION 20 4.2 FUTURE WORK 21 REFERENCES 22 ACKNOWLEDGEMENT 23" | |
| dc.language.iso | en | |
| dc.subject | 奈米材料 | zh_TW |
| dc.subject | 化學氣相沉積 | zh_TW |
| dc.subject | MOF-2 | zh_TW |
| dc.subject | 無溶劑合成 | zh_TW |
| dc.subject | 金屬有機框架 | zh_TW |
| dc.subject | Metal Organic Framework | en |
| dc.subject | Chemical Vapor Deposition | en |
| dc.subject | Solvent-free synthesis | en |
| dc.subject | MOF-2 | en |
| dc.subject | Nano-material | en |
| dc.title | 基於化學氣相沉積與昇華的製程構建金屬有機框架 | zh_TW |
| dc.title | Vapor-phase fabrication based on sublimation and deposition to construct metal organic framework | en |
| dc.date.schoolyear | 110-1 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 游文岳(Tang-Long Shen),蕭育生(Yuh-Kun Chen),(Loong-Sheng Chang),(Shiuh-Feng Shiao) | |
| dc.subject.keyword | 金屬有機框架,化學氣相沉積,MOF-2,無溶劑合成,奈米材料, | zh_TW |
| dc.subject.keyword | Metal Organic Framework,Chemical Vapor Deposition,MOF-2,Solvent-free synthesis,Nano-material, | en |
| dc.relation.page | 23 | |
| dc.identifier.doi | 10.6342/NTU202200580 | |
| dc.rights.note | 未授權 | |
| dc.date.accepted | 2022-02-14 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
| dc.date.embargo-lift | 2024-02-14 | - |
| 顯示於系所單位： | 化學工程學系 | |
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