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http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/82370完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 廖尉斯(Wei-Ssu Liao) | |
| dc.contributor.author | Shin Yi | en |
| dc.contributor.author | 易昕 | zh_TW |
| dc.date.accessioned | 2022-11-25T07:29:52Z | - |
| dc.date.available | 2024-07-01 | |
| dc.date.copyright | 2021-08-18 | |
| dc.date.issued | 2021 | |
| dc.date.submitted | 2021-07-01 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/82370 | - |
| dc.description.abstract | 一般來說，為了達成操作方便、快速反應及均勻混合的目標，化學反應多數在液相或氣相環境中進行。然而，在液相或氣相環境中進行的化學反應通常都需 要經過進一步的純化或過濾來區分產物及未反應之前驅物，而繁瑣的步驟將造 成產物的消耗並降低產率。這篇研究提出在類固態基材中進行化學反應，由於類 固態基材具有相較液相或氣相更侷限的空間，反應物更容易累積在特定位置，這 些條件都使類固態基材中局部濃度提升，近一步增加有效碰撞的機率，並因此使 反應速率提升。而由於類固態基材中分子移動的自由度不如液相或氣相環境，而 因此在類固態基材中分子的擴散速率相對化學反應速率慢，因此未反應的前驅 物能和反應完成之產物分離，避免一般液相或氣相反應所需的繁瑣純化步驟。由 於類固態基材具有增加反應速率的優勢且避免了液相或氣相反應的分離純化步 驟，使在類固態基材中進行化學反應成為一個具有競爭性的選項。 | zh_TW |
| dc.description.provenance | Made available in DSpace on 2022-11-25T07:29:52Z (GMT). No. of bitstreams: 1 U0001-2106202120583900.pdf: 7263611 bytes, checksum: 2781880bb3235eb34c022306b52ed9e7 (MD5) Previous issue date: 2021 | en |
| dc.description.tableofcontents | Chapter 1. Introduction 1 1.1 Motivation 1 1.2 Significance of the Study 1 1.3 Background Research 2 Chapter 2. Experiment Section 12 2.1 Materials and Reagents. 12 2.2 Instruments and Equipment. 12 2.3 Preparation of PDMS Cubes. 13 2.4 Molecular Diffusion Behavior Monitoring in PDMS. 13 2.5 Non-Reactive Multi-Component Mixing Effects. 14 2.6 Efficient Chemical Reactions in PDMS. 14 2.7 Reaction Rates Comparison between Pseudo-Solid and Liquid Phase Operations. 15 2.8 Reaction Rate Facilitation Mechanism Understanding. 16 2.9 Chemical Reactions with Simultaneous Product Separation. 16 Chapter 3. Discussion 18 3.1 Methodology 18 3.2 Examination of Different Factors to the Molecular Diffusion Behavior in the Pseudo Solid Phase 22 3.3 Diffusing Driven Mixing Event with Different Chemical Reaction Demonstration 30 3.4 Mechanism Detection of the Increasing Reaction Rate in the Pseudo Solid Phase 40 Chapter 4. Conclusion 55 Chapter 5. Future Perspective 57 Chapter 6. References 60 Chapter 7. Appendix 71 7.1 Ninhydrin Reaction 71 7.2 Diels-Alder Reaction 71 7.3 Aldol Condensation 72 7.4 Click Chemistry 72 7.5 Pdms Cross-Linking 74 | |
| dc.language.iso | en | |
| dc.title | 利用擬固體空間限制調控化學反應進程 | zh_TW |
| dc.title | Manipulating Chemical Processes by Pseudo-Solid Spatial Limitation | en |
| dc.date.schoolyear | 109-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.author-orcid | 0000-0003-3331-0980 | |
| dc.contributor.oralexamcommittee | 陳浩銘 (Hsin-Tsai Liu),詹益慈(Chih-Yang Tseng),張煥宗,王宗興 | |
| dc.subject.keyword | 擴散,空間侷限,反應速率,分離,擬固態機材, | zh_TW |
| dc.subject.keyword | Diffusion,Spatial limitation,Pseudo-solid phase,Separation,Reaction rate, | en |
| dc.relation.page | 74 | |
| dc.identifier.doi | 10.6342/NTU202101086 | |
| dc.rights.note | 同意授權(全球公開) | |
| dc.date.accepted | 2021-07-01 | |
| dc.contributor.author-college | 理學院 | zh_TW |
| dc.contributor.author-dept | 化學研究所 | zh_TW |
| dc.date.embargo-lift | 2024-07-01 | - |
| 顯示於系所單位： | 化學系 | |
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